| Project/Area Number |
63303004
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| Research Category |
Grant-in-Aid for Co-operative Research (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
分析・地球化学
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| Research Institution | Chiba University |
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Principal Investigator |
KURODA Rokuro Chiba University, Faculty of Engineering, Professor, 工学部, 教授 (50009198)
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| Co-Investigator(Kenkyū-buntansha) |
TAKAGI Makoto Kyushu University, Faculty of Engineering, Professor, 工学部, 教授 (90037739)
KUMAMARU Takahiro Hiroshima University, Faculty of Science, Professor, 理学部, 教授 (50033816)
MATSUI Masakazu Kyoto University, Chemical Institute, Professor, 化学研究所, 教授 (90027037)
SUZUKI Nobuo Tohoku University, Faculty of Science, Professor, 理学部, 教授 (10006025)
TAGA Mitsuhiko Hokkaido University, Faculty of Science, Professor, 理学部, 教授 (90000778)
平出 正孝 名古屋大学, 工学部, 講師 (20111833)
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| Project Period (FY) |
1988 – 1989
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| Project Status |
Completed (Fiscal Year 1989)
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| Budget Amount *help |
¥11,800,000 (Direct Cost: ¥11,800,000)
Fiscal Year 1989: ¥4,800,000 (Direct Cost: ¥4,800,000)
Fiscal Year 1988: ¥7,000,000 (Direct Cost: ¥7,000,000)
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| Keywords | Metal speciation / Trace characterization / Rare earth elements / Specific reagents / Solvent extraction / Ion-exchange / On-line separation / Highly sensitive chemical analysis / キャラクタリゼ-ション / 特異的試離 / 高感度分析 / 微量元素 / 機能性樹脂合成 / 特異試薬 / オンライン分離濃縮 |
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| Research Abstract |
Because of scientific significance of characterization of materials and speciation of trace elements in environmental materials intensive development of separation-speciation chemistry and related highly sensitive analytical techniques have been jointly investigated by fifteen-five scientific members.In order to achieve the goal five themes have been attacked. 1 Highly sensitive preconcentration-fluorophotometry,FIA combined with catalytic reaction,palladium-enhanced GFAAS for volatile trace metals and a new trace characterization method based on thermoluminescence color image photography have been developed. 2 Synthesis of metal specific resins,chelating resins,new ligands and macrocyclic and pseudo-macrocyclic extractants and their evaluation from the view points of trace characterization have been worked out. 3 Novel extraction system for rhodium,and new approach on the design of extractive separation scheme based on the HSAB rule are established.Fundamental approach for exploring the possible separation of metalhalogenocomplexes in ion association systems allows to develop highly selective separation and photometric quantitation techniques. 4 Dynamic ion-exchange separation of adjacent rare earths, preconcentration of trace metal complexes on poly[chlorotrifluoroethylene]resin, and heavy metal speciation in fresh waters with solid absorbents are also accomplished. 5 On-line preconcentration and separation methods are developed for the determination of traces by atomic/molecular spectrometry.
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