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Fundamental Research for Rare Earth Metals, Compounds and Their Application for Functional Materials

Research Project

Project/Area Number 63303007
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionNagoya University

Principal Investigator

OKI Takeo  Nagoya University, Fac.of Eng., Professor, 工学部, 教授 (30023039)

Co-Investigator(Kenkyū-buntansha) YAMAUCHI Chikabumi  Nagoya University, Fac.of Eng., Professor, 工学部, 教授 (40115647)
NAGAI Tadao  Hokkaido University, Fac.of Eng., Professor, 工学部, 教授 (80001155)
AZAGAMI Takeshi  Tohoku University, Fac.of Eng., Professor, 工学部, 教授 (50006029)
KOUZUKA Zensaku  Osaka University, Fac.of Eng., Professor, 工学部, 教授 (80028935)
UEDA Yasuaki  Kyushu Inst.of Tech., Fac.of Eng., Professor, 工学部, 教授 (70039006)
Project Period (FY) 1988 – 1989
Project Status Completed (Fiscal Year 1989)
Budget Amount *help
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1989: ¥3,200,000 (Direct Cost: ¥3,200,000)
KeywordsRefining of Rare Earth Metals / Functions of Rare Earth Metals / Materials design of Rare Earth Compounds / レアアース金属 / 機能材料化 / 希土類化合物
Research Abstract

The authors have investigated the refining and characterization of rare earth metals and compounds by means of pyrometallurgical, hydrometallurgical and electrometallurgical methods. The influence of impurity in the rare earth metals were also investigated in order to apply these metals for functional materials. Some main research results areas follows; 1.The new electrolytic separation process of the rare earth metals (La and Nd) from the chloride-fluoride bath has been evaluated according to the different stability of lanthanum chloride-fluoride complex ions and the cathodic potential control. 2.the production rates of Fe-Nd, Fe-Sm, Co-Nd and Co-Sm in the reduction-diffusion process were determined by ..the diffusion rate of the rare earth elements in the compounds phases. 3.The suitable condition was clarified in the Sm recovering from the solvent solution from which Sm was extracted. 4.The impurity such as oxygen in rare earth(Pr) was reduced by the Ca vapour effectively. 5.The activity of Cu-Dy alloy was measured for the analysis of the thermodynamic data, which is fundamentals for the application of Cu-Rare earth metals alloys to functional materials, at high temperature.

Report

(3 results)
  • 1989 Annual Research Report   Final Research Report Summary
  • 1988 Annual Research Report
  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] T.Oki: "Electrochemical Studies of Zirconium and Hafnium in Alkali Chloride and Allkali FluorideーChloride Molten Salts." J.Applied.Electrochemistry. 20. 77-84 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 嶋影和宜: "直接還元法によるレア・ア-スメタル(Sm,Eu,TmおよびYb)の製造に関する基礎研究" 資源・素材学会誌. 105. 175-180 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 板垣乙未生: "機能性合金の製造に関する二,三の熱力学的検討" 資源・材料学会誌. 105. 163-168 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Itagaki: "High Temperature Phase Relations in NiーRE(RE=La,Ce,Pr,Nd)Binary and Termary Alloy Systems" Materials Trans.JIM. 30. 583-593 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Oki: "Electrochemical Separation of La and Nd in ChlorideーFluoride Molten Salts" Proc of 1st Intern Conf.on the Metallurgy and Materials Sci.of WーTiーREーSb. 422-431 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 幸塚善作: "プラセオジム酸化物の相変化と安定性に与える要因に関する研究" 資源・素材学会秋季大会分科研究会資料〔K〕. 47-50 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Itagaki et al: "High Temperature Heat Content Measurements of Cu-RE(RE=Y, La, Ce, Pr, Nd) Binary Systems," Materials Trans.JIM. Vol.30. 273-282 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Itagaki et al: "High Temperature Phase Relations in Ni-RE(RE=La, Ce, Pr, Nd) Binary and Ternary Systems", Materials" Trans.JIM, Vol.30, 589-593, 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Itagaki et al: "Heat Content Measurement and Thermodynamic Evaluation of Cu-La System" Z.Matallkde, Vol.80, 883-887, 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Oki et al: "Electrochemical Studies of Zirconium and Hafnium in Alkali Chloride and Alkali Fluoride-Chloride Molten Salts" J.Applied Electrochem., Vol.20, 77-84, 1990.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Oki et al: "Electrochemical Separation of La and Nd in Chloride-Fluoride Molten Salts" Proc. of the lst Intern. conf. Metallurgy and Materials Sci. of W, Ti, RE and Sb, 422-431, 1988.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Shimakage: "Reduction Reactions of Samarium and Ytterbium Oxides with Rare Earth Metals(La, Ce, Nd and Pr) in Vacuum Atmosphere" Proc. of the lst Intern. conf. Metallurgy and Materials Sci. of W, Ti, RE and Sb, 399-403, 1988.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Oki: "Electrochemical Studies of Zirconium and Hafnium in Alkali Chloride and Alkali Fluoride-Chloride Molten Salts." J.Applied Electrochemistry. 20. 77-84 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 嶋影和宜: "直接還元法によるレア・ア-スメタル(Sm,Eu,TmおよびYb)の製造に関する基礎研究" 資源・素材学会誌. 105. 175-180 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 板垣己未生: "機能性合金の製造に関する二、三の熱力学的検討" 資源・素材学会誌. 105. 163-168 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Itagaki: "High Temperature Phase Relations in Ni-RE(RE=La,Ce,Pr.Nd)Binary and Ternary Alloy Systems" Materials Trans.JIM. 30. 583-593 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Oki: "Electrochemical Separation of La and Nd in Chloride-Fluoride Molten Salts" Proc.of 1st Intern.Conf.on the Metallurgy and Materials Sci.of W-Ti-RE-Sb. 422-431 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] 幸塚善作: "プラセオジム酸化物の相変化と安定性に与える要因に関する研究" 資源素材学会秋季大会分科研究会資料[K]. 47-50 (1989)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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