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CONTROL OF SYNTHESIZING PROCESS FOR INORGANIC MATERIALS AND IMPROVEMENT OF THEIR FUNCTIONS.

Research Project

Project/Area Number 63303008
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 無機工業化学
Research InstitutionUNIVERSITY OF TSUKUBA

Principal Investigator

WAKATSUKI Masao  UNIVERSITY OF TSUKUBA, INSTITUTE OF MATERIALS SCIENCE, PROFESSOR, 物質工学系, 教授 (50114153)

Co-Investigator(Kenkyū-buntansha) HIRAI Toshio  TOHOKU UNIVERSITY, THE RESEARCH INSTITUTE FOR IRON, STEEL AND OTHER METALS, PROF, 金属材料研究所, 教授 (50005865)
INAGAKI Michio  TECHNOLOGY AND SCIENCE UNIVERSITY OF TOYOHASHI, PROFESSOR, 工学部, 教授 (20023054)
BANDO Yoshichika  KYOTO UNIVERSITY, THE INSTITUTE FOR CHEMICAL RESEARCH, PROFESSOR, 化学研究所, 教授 (70027027)
SAKKA Sumio  KYOTO UNIVERSITY, THE INSTITUTE FOR CHEMICAL RESEARCH, PROFESSOR, 化学研究所, 教授 (10027021)
KAWAI Shichio  OSAKA UNIVERSITY, INSTITUTE OF SCIENTIFIC AND INDUSTRIAL RESEARCH, PROFESSOR, 産業科学研究所, 教授 (60127214)
金丸 文一  大阪大学, 産業科学研究所, 教授 (40029848)
平野 眞一  名古屋大学, 工学部, 教授 (30016828)
曽我 直弘  京都大学, 工学部, 教授 (80026179)
島田 昌彦  東北大学, 工学部, 教授 (80029701)
Project Period (FY) 1988 – 1989
Project Status Completed (Fiscal Year 1989)
Budget Amount *help
¥8,500,000 (Direct Cost: ¥8,500,000)
Fiscal Year 1989: ¥3,900,000 (Direct Cost: ¥3,900,000)
Fiscal Year 1988: ¥4,600,000 (Direct Cost: ¥4,600,000)
KeywordsInorganic Materials / Functional Materials / New Materials / Syntesis / Process Control / Optimization / Characterization
Research Abstract

Inorganic materials can have a wide variety of functions depending on their widely controllable compositions and structures. Tuning their characteristics and functions is dependent on controllability of the synthesizing process. In this subject, many synthesizing processes, such as reactions at high pressures, super-rapid cooling of melts, crystal growth from melts, foreation of materials in solutions, physical and clienical vapor depositions, etc, are dealt with. Analysis of the foreation mechanisms, control of the synthesis processes and characterization and application of the obtained materials were perforlied, under an interdisciplinary cooperation by the members, different in their specialities of the synthesis methods.
Results of the researches for two years are evaluated as follows: (1)Tuning or control of characteristics of the synthesized materials by selection and control of the reaction environments. (2)Trials of in-process characterization, such as in site determination of structure. (3)New Processes, such as self-combustion, utilization of photon energy and ultra-high temperature, a process controlled by an accompanied reaction, highly efficient process for intercalation, etc. (4)Control of compositions and phases. (5)Application of a developed process, such as coating with films. (6)New materials, such as of an oxy-fluoride family.
Materials, such as diamond and cBM (as super-hard materials), GIC, composites and glasses made from nitrides, carbides and oxides, including high-Tc superconductors, coating materials, magnetic materials and dielectric materials, are dealt with.

Report

(3 results)
  • 1989 Annual Research Report   Final Research Report Summary
  • 1988 Annual Research Report

Research Products

(177 results)

All Other

All Publications

  • [Publications] K.J.Takano(若槻): "Visual observation of pressure-driven crystal growth." Japan.J.Appl.Phys.28. L1449-L1452 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 若槻雅男: "ダイヤモンドの核形成と成長" 日本結晶成長学会誌. 16. 106-116 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Miyamoto(福長): "Morphology and formation process of diamond from glassy carbon." J.Crystal Drowth. 97. 731-738 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 福長脩: "静的超高圧装置" “圧力技術の現状と将来"(圧力技術)(日本高圧力技術協会編集). 特別号. 2-14 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] S.Kume(久米): "Electron microscopy observations of high pressere-allotopyof ZrO_2" Adv.Ceramics. 24. 83-87 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] S.Kume(久米): "High pressure polymorphs in ceramics and minerals GeO_2 and ZrO_2" Solid State Ionics. 32/33. 285-287 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Sekino(嶋田): "High pressure synthesis of CoF_<2-x>O_x(O≦x≦0.2)" J.Solid State Chemistry(投稿中). (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Sekino(嶋田): "Hifg pressure synthesis of LiTiMF_6(M=Mn,Fe,Co,Ni)with trirutile and Na_2SiF_6 structure." J.Solid State Chemistry(投稿中). (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] J.Zeng(宮本): "Hot isostatic pressing of Si_3N_4-SiC composite powders prepared by the nitriding combustion reaction." Proc.2nd Int.HIP Conference,Gaithersburg,U.S.A.,(印刷中). (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Y.Miyamoto(宮本): "New ceramic processing approaches using combustion synthesisunder gas pressure." Am,Ger.Soc.Bull.(印刷中,4月号). (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Hirao(小泉): "Reaction analysis of the combustion synthesis of transtion metal nitrides." Proc.Int.Inst.for Science of Sintering Symposium,Tokyo,(Elsevio Science Publishing Co.,Inc.). Vol.1. 511-516 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 高橋章(小泉): "Nb-N傾斜機能材料の燃焼合成" 粉体および粉末冶金. 37. 263-266 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Ohashi(服部): "Hydrogen uptake by layer structuredβ-ZrNCl." Solid State Ionics. 32/33. 97-103 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Ohashi(服部): "Co-intercalation of tetrahydrofuran with lithium inβ-ZrNCl layered crystal." Chem.Lett.Jan.93-96 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 稲垣道夫: "クロロホルム中における新しい塩化鉄-黒鉛層間化合物の合成" 炭素. 136. 15-20 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Inagaki(稲垣): "Application of graphite intercalation compounds" L.Mat.Res.4. 1560-1568 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I.Tanaka(児島): "Superconducting single crystals." Nature. 337. 21-22 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I.Tanaka(児島): "Single crystal growth of superconducting La_<2x>Sr_xCuO_4 by the TSFZ" J.Crystal Growth. 96. 711-715 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Hanada(曽我): "Properties and structure of rf-sputtered amorphous films in the A1PO_4-A1_2O_3 system." Nippon Seramikkusu Kyoukai Gakujutu Rombunshi. 97. 279-283 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Hanada(曽我): "Elastic constants of amorphous thin films in the systems SiO_2-A1_2O_3 and A1PO_4O_3" J.NonCryst.Solids. 113. 213-220 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Ioku(吉村): "Dense/porous layered apatite ceramics prepared by HIP post-sintering." J.Mater.Sci.Letters. 8. 1203-1204 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Yoshimura(吉村): "Preparation of BaTiO_3 thin film by hydrothermal electrochemical method." Japan.J.Appl.Phys.28. L2007-L2009 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Furusaki(小平): "Properties of beryl single crystals grown by a high pressure hydrothermal method." Mater.Res.Bull.24. 967-972 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 古崎毅(小平): "内熱式水熱装置によるベリル単結晶の育成" 日本セラミックス協会学術論文誌. 97. 1462-1465 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Y.Toda(加藤): "Silica coating of ultrafine MgO" Ceramics International. 15. 161-166 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] A.Kato(加藤): "Preparation of spherical titania particles from inorganic precursor by homogeneous precipitation." MRS(Processing Science of Advanced Cermaics). 155. 13-22 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I.Hasegawa(作花): "Rapid solidification of(2-hydroxyethyl)-trimethylammnonium silicate." Chemistry Letters. 1319-1322 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I.Hasegawa(作花): "Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by ^<29>Si nuclear magnetic resonance." Chemistry Letters. 140-151 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I.Hirano(平野): "Chemical synthesis of ceramic powders by organometallic routes." Ceramic Transactions. 1. 171-181 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] S.Hirano(平野): "Preparation of YBa_2Cu_3O_7-δ superconductor through organometallic routes." Chemistry Letters. 1988. 665-668 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Izumi(南): "ZrO_2 coating on stainless steel sheets from organo-zirconium compound" J.Am.Cer.Soc.72. 1465-1648 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] N.Thoge(南): "Preparation of B_2O_3-SiO_2 and MO-B_2O_3-SiO_2(M=Zn,Mg) glass films by the sol-gel method." J.Non-Cryst.Solids. 112. 432-436 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Y.Sato(佐藤): "Texture and properties of vapor-deposited diamond films." Surf.Coatings Technology. 39/40. 183-198 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] A.T.Collins(佐藤): "Optical centers related to nitrogen,Vacancies and interstaitials in polycrystalline diamond films grown by plasma-assisted chemical vapor deposition." J.Phys.D:Appl.Phys.22. 1402-1405 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H.Yamane(平井): "High crytical current density of Y-Ba-Cu-O superconducting films prepared by CVD." Supercond.Sci.Technol.2. 115-117 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H.Yamane(平井): "Effect of deposition temperature on the superconducting properties of Y-Ba-Cu-O films prepared by CVD." J.Crystal Growth. 94. 880-884 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Kanai(河合): "Low-temperature formation of multilayered Bi(Pb)-Sr-Ca-Cu-O thin films successive deposition using laser ablation." Appl.Phys.Lett.54. 1802 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H.Tabata(河合): "Formation of the High-Tc phase of the superconducting Bi-Pb-Sr-Ca-Cu-O thin film by the laser ablation method." Japan.J.Appl.Phys.28. L430-L433 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Terashima(吉田): "Synthesis of high-Tc superconducting oxide films and fine particles by thermal plasma flash euaporation method." Proc.Int.Symp Plasma Chem.9. 1491-1496 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Yoshida(吉田): "The future of thermal plasma processing." Materials Transactions JIM. 31. 1-11 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] G-c.Lai(金丸): "Phase transition in Bl-type Mol-xNBxN aputtered films under ammonia annealing." J.Solid.State Chem.82. 1-7 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] G-C.Lai(金丸): "Preparation and characterization of superconducting Bl type Mol-xNCxN thin films." J.Am.Cer.Soc.72. 2310-2313 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Fujii(坂東): "Preparation and characterization of(lll)-oriented Fe_3O_4 films deposited of sapphire." J.Appl.Phys.66. 3168-3172 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.Iijima(坂東): "Preparation of ferroelectric BaTiO_3 thin films by activated reactive evaporation." Appl.Phys.Lett.56. 527-529 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H.Itoh(伊藤): "Rotary powder bed chemical vapor deposition of titanium nitride on spherical iron powder." J.Mater.Sci.24. 3643-3646 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H.Itoh(伊藤): "Nucleation control of diamond synthesized by microwave plasma CVD on cemented carbide substrate." J.Mater.Sci.(投稿中). (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 若槻雅男(編集:瀬高信雄,難波義捷,松長正久,若槻雅男): "人造ダイヤモンド技術ハンドブック(第1編,第1章,I及びIII節を担当)" サイエンスフォ-ラム,東京, 20-26,34-39 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 坂東尚周(編集:小石真純): "超微粒子開発応用ハンドブック(第3章,第3節を担当)" サイエンスフォ-ラム,東京, 384-390 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K. J. Takano: "Visual observation of a pressure-driven crystal growth" Japan. J. Appl. Phys. 28(1). 1449-1452 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M. Miyamoto: "Morphology and formation process of diamond from glassy carbon" J. Crystal Growth, 97, 731-738 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] S. Kume: "Electron microscopy observations of high-pressure allotropy of ZrO_2" Adv. Ceramics, 24, 83-87 (1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] S. Kume: "High pressure polymorphs in ceramics and minerals GeO_2 and ZrO_2" Solid State Ionics, 32/33, 285-287 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Sekino: "High pressure synthesis of CoF_<2-2x>O_x (0 x 0.2)" J. Solid State Chemistry (submitted) (1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Sekino: "High pressure synthesis of LiTiMF_6 (M = Mn, Fe, Co, Ni) with trirutile and Na_2SiF_6 structure" J. Solid State Chemistry (submitted) (1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] J. Zeng: "Hot isostatic pressing of Si_3N_4-SiC composite powders prepared by the nitriding combustion reaction" Proc. 2nd Int. HIP Conference, Gaithersburg, U.S.A., June 1989, in press (1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Y. Miyamoto: "New ceramic processing approaches using combustion synthesis under gas pressure" Am. Cer. Soc. Bull., April Issue (submitted) (1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K. Hirao: "Reaction analysis of the combustion synthesis of transition metal nitrides" Proc. Int. Inst. for Science of Sintering Symposium, Tokyo, Elsevior Science Publishing Co., Inc., Vol. 1, pp.511-516 (1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M. Ohashi: "Hydrogen uptake by layer structured beta-ZrNCl" Solid State Ionics, 32/33, 97-103 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M. Ohashi: "Co-intercalation of tetrahydrofuran with lithium in beta-ZrNCl layered crystal" Chem. Lett., Jan. 1990, 93-96 (1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M. Inagaki: "Application of graphite intercalation compounds" J. Mat. Res., 4, 1560-1568.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I. Tanaka: "Superconducting single crystals" Nature, 337, 21-22 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I. Tanaka: "Single crystal growth of superconducting La_<2-x>Sr_xCuO_4 by the TSFZ method" J. Crystal Growth, 96, 711-715 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Hanada: "Properties and structure of rf-sputtered amorphous films in the AlPO_4-Al_2O_3 system" Nippon Seramikkusu Kyokai Gakujutu Rombunshi, 97, 279-283 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Hanada: "Elastic constants of amorphous thin films in the systems SiO_2-Al_2O_3 and AlPO_4-Al_2O_3" J. Non-Cryst. Solids, 113, 213-220 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K. Ioku: "Dense/porous layered apatite ceramics prepared by HIP post-sintering" J. Mater. Sci. Letters, 8(10), 1203-1204 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M. Yoshimuraa: "Preparation of BaTiO_3 thin film by hydrothermal electrochemical method" Japan. J. Appl. Phys., 28(11), L2007-L2009 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Furusaki: "Properties of beryl single crystals grown by a high pressure hydrothermal method" Mater. Res. Bull., 24, 967-972(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Y. Toda: "Silica coating of ultrafine MgO" Ceramics International, 15(3), 161-166 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] A. Kato: "Preparation of spherical titania particles from inorganic precursor by homogeneous precipitation" MRS, 155 (Processing Science of Advanced Ceramics), 13-22 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I. Hasegawa: "Rapid solidification of (2-hydroxyethyl)-trimethylammonium silicate" Chemistry Letters, 1319-1322 (1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] I. Hasegawa: "Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by ^<29>Si nuclear magnetic resonance" J. Chem. Soc. Chemical Communications, 140-151 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] S. Hirano: "Chemical synthesis of ceramic powders by organometallic routes" Ceramic transactions, 1, 171-181 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K. Izumi: "ZrO_2 coating on stainless steel sheets from organo-zirconium compounds" J. Am. Cer. Soc., 72(8), 1465-1468 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] N. Tohge: "Preparation of B_2O_3-SiO_2 and MO-B_2O_3-SiO_2 (M = Zn, Mg) glass films by the sol-gel method" J. Non-Cryst. Solids., 112(1-3), 432-436 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Y. Sato: "Texture and properties of vapor-deposited diamond films" Surf. Coatings Technology, 39/40, 183-198 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] A. T. Collins: "Optical centers related to nitrogen, vacancies and interstitials in polycrystalline diamond films grown by plasma-assisted chemical vapor deposition" J. Phys. D: Appl. Phys., 22, 1402-1405 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H. Yamane: "High critical-current density of Y-Ba-Cu-O superconducting films prepared by CVD" Supercond. Sci. Technol., 2(2), 115-117 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H. Yamane: "Effect of deposition temperature on the superconducting properties of Y-Ba-Cu-O films prepared by CVD" J. Crystal Growth., 94(4), 880-884 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M. Kanai: "Low-temperature formation of multilayered Bi(Pb)-Sr-Ca-Cu-O thin films by successive deposition using laser ablation" Appl. Phys. Lett., 54(18), 1802 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H. Tabata: "Formation of the high-Tc phase of the superconducting Bi-Pb-Sr-Ca-Cu-O thin film by the laser ablation method" Japn. J. Appl. Phys., 28, L430-L433 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K. Terashima: "Synthesis of high-Tc superconductingoxide films and fine particles by thermal plasma flash evaporation method" Proc. Int. Symp. Plasma Chem., 9, (3), 1491-1496 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Yoshida: "The future of thermal plasma processing" Materials Transactions, JIM, 31, 1-11 (1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] G-C.Lai: "Phase transition in Bl-type Mo_<1-x>Nb_xN sputtered films under ammonia annealing" J. Solid State Chem., 82, 1-7 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] G-C.Lai: "Preparation and characterization of superconducting Bl type Mo_<1-x>Nb_xN thin films" J. Am. Cer. Soc., 72, 2310-2313 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Fujii: "Preparation and characterization of (111)-oriented Fe_3O_4 films deposited on sapphire" J. Appl. Phys., 66, 3168-3172 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K. Iijima: "Preparation of ferroelectric BaTiO_3 thin films by activated reactive evaporation" Appl. Phys. Lett., 56, 527-529 (1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H. Itoh: "Rotary powder bed chemical vapor deposition of titanium nitride on sherical iron powder" J. Mater. Sci., 24(10), 3643-3646 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H. Itoh: "Nucleation control of diamondsynthesized by microwave plasma CVD on cemented carbide substrate" J. Mater. Sci. (submitted).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] K.J.Takano: "Visual observation of a pressure-driven crystal growth." Japan.J.Appl.Phys.28. 1449-1452 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 若槻雅男: "ダイヤモンドの核形成と成長" 日本結晶成長学会誌. 16. 106-116 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] M.Miyamoto: "Morphology and formation process of diamond from glassy carbon." J.Crystal Growth. 97. 731-738 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 福長脩: "静的超高正装置" “清圧技術の現状と将来"(圧力技術)(日本高圧力技術協会編集). 特別号. 2-14 (1989)

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      1989 Annual Research Report
  • [Publications] S.Kume: "Electron microscopy observations of high pressure-allotropy of ZrO_2" Adv.Ceramics. 24. 83-87 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Kume: "High pressure polymorphs in ceramics and minerals GeO_2 and ZrO_2" Solid State Ionics. 32/33. 285-287 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Sekino: "High pressure synthesis of CoF_<2-x>O_x(0≦x≦0.2)" J.Solid State Chemistry. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Sekino: "High pressure synthesis of LiTiMF_6(M=Mn,Fe,Co,Ni)with trirutile and Na_2SiF_6structure." J.Solid State Chemistry. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] J.Zeng: "Hot isostatic pressing of Si_3N_4-SiC composite powders prepared by the nitriding combustion reaction." Proc.2nd Int.HIP Conference,Gaithersburg,U.S.A.,June 1989. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Y.Miyamoto: "New ceramic processing approaches using combustion synthesisunder gas pressure." Am.Cer.Soc.Bull.(1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Hirao: "Reaction analysis of the combustion synthesis of transition metal nitrides." Proc Int.Inst.for Science of Sintering Symposium,Tokyo,(Elsevio Science Publishing Co.,Inc.). Vol.1. 511-516 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] 高橋章: "Nb-N傾斜機能材料の燃焼合成" 粉体および粉末冶金. 37. 263-266 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] M.Ohashi: "Hydrogen uptake by layer structued β-ZrNCL." Solid State Ionics. 32/33. 97-103 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] M.Ohashi: "Co-intercalation of tetrahydrofuran with lithium in β-ZrNCl layered crystal." Chem.Lett.Jan.93-96 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 稲垣道夫: "クロロホルム中における新しい塩化鉄-黒鉛層間化合物の合成" 炭素. No.136. 15-20 (1989)

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      1989 Annual Research Report
  • [Publications] M.Inagaki: "Application of graphite intercalation compounds" J.Mat.Res.4. 1560-1568 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] I.Tanaka: "Superconducting single crystals" Nature. 337. 21-22 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] I.Tanaka: "Single crystal growth of superconducting La_<2-x>Sr_xCuO_4 by the TSFZ" J.Crystal Growth. 96. 711-715 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Hanada: "Properties and structure of rf-sputtered amorphous films in the AlPO_4-Al_2O_3 system." Nippon Seramikkusu Kyoukai Gakujutu Rombunshi. 97. 279-283 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Hanada: "Elastic constants of amorphous thin films in the systems SiO_2-Al_2O_3 and AlPO_4-Al_2O_3" J.NonCryst.Solids. 113. 213-220 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Ioku: "Dense/porous layered apatite ceramics prepared by HIP post-sintering." J.Mater.Sci.Letters. 8. 1203-1204 (1989)

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      1989 Annual Research Report
  • [Publications] M.Yoshimura: "Preparation of BaTiO_3 thin film by hydrothermal electrochemical method." Japan.J.Appl.Phys.28. 2007-2009 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Furusaki: "Properties of beryl single crystals grown by a high pressure hydrothermal method." Mater.Res.Bull.24. 967-972 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 古崎毅: "内熱式水熱装置によるベリル単結晶の育成" 日本セラミックス協会学術論文誌. 97. 1462-1465 (1989)

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      1989 Annual Research Report
  • [Publications] Y.Toda: "Silica coating of ultrafine MgO" Ceramics International. 15. 161-166 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] A.Kato: "Preparation of spherical titania particles from inorganic precursor by homogeneous precipitation." MRS(Processing Science of Advanced Ceramics). 155. 13-22 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] I.Hasegawa: "Rapid solidification of (2-hydroxyethyl)-trimethylammnonium silicate." Chemistry Letters. 1319-1322 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] I.Hasegawa: "Silicate anions formed in tetrametylammonium Silicate methanolic solutions as studied by ^<29>Si nuclear magnetic resonance." J.Chem.Soc.Chemical Communications. 140-151 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Hirano: "Chemical synthesis of ceramic powders by organometallic routes." Ceramic Transactions. 1. 171-181 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Hirano: "Preparation of YBa_2Cu_3O_<7-δ> superconductor through organometallic routes." Chemistry Letters. 1988. 665-668 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Izumi: "ZrO_2 coating on stainless steel sheets from organo-zirconium compounds" J.Am.Cer.Soc.72. 1465-1468 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] N.Tohge: "Preparation of B_2O_3-SiO_2 and MO-B_2O_3-SiO_2(M=Zn,Mg)glass films by the sol-gel method." J.Non-Cryst.Solids. 112. 432-436 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Y.Sato: "Texture and properties of vapor-deposited diamond films" Surf.Coatings Technology. 39/40. 183-198 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] A.T.Collins: "Optical centers related to nitrogen,Vacancies and interstaitials in polycrystaline diamond films grown by plasma-assisted chemical vapor deposition." J.Phys.D:Appl.Phys.22. 1402-1405 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Yamane: "High crytical rurrent density of Y-Ba-Cu-O superconducting films prepared by CVD." Supercond.Sci.Technol. 2. 115-117 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Yamane: "Effect of deposition temperature on the superconducting properties of Y-Ba-Cu-O films prepared by CVD." J.Crystal Growth. 94. 880-884 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] M.Kanai: "Low-temperature formation of multilayered Bi(Pb)-Sr-Ca-Cu-O thin films by successive deosition using laser ablation." Appl.Phys.Lett.54. 1802 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Tabata: "Formation of the High-Tc phase of the superconducting Bi-Pb-Sr-Ca-Cu-O thin film by the laser ablation method." Japan.J.Appl.Phys.28. 430-433 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Terashima: "Synthesis of high-Tc superconducting oxide films and fine particles by thermal plasma flash evaporation method." Proc.Int.Symp Plasma Chem.9. 1491-1496 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Yoshida: "The future of themal plasma processing." Materials Transactions JIM. 31. 1-11 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] G-C.Lai: "Phase transition in Bl-type Mo_1-_xNb_xN sputtered films under ammonia annealing." J.Solid.State Chem.82. 1-7 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] G-C.Lai: "Preparetion and characterization of superconducting B1 type Mo_<1-x>-_xNb_xN thin films" J.Am.Cer.Soc.72. 2310-2313 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Fujii: "Prepatation and characterization of(111)oriented Fe_3O_4 films deposited on sapphire." J.Appl.Phys.66. 3168-3172 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Iijima: "Preparation of ferroelectric BatiO_3 thin films by activatid reactive evaporation." Appl.Phys.Lett.56. 527-529 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Itoh: "Rotary powder bed chemical vapor deposition of titanium nitride on spherical irom powder." J.Mater.Sci.24. 3643-3646 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Itoh: "Nucleation control of diamond synthesized by microwave plasma CVD on cemented carbide substrate." J.Mater.Sci.(投稿中). (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 若槻雅男(編集:瀬高信雄、難波義捷松長正久,若槻雅男): "1989" サイエンスフォ-ラム、東京, (20-2634-39)

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      1989 Annual Research Report
  • [Publications] 坂東尚周(編集:小石真純): "超微粒子開発応用ハンドブック(第3章、第3節を担当)" サイエンスフォ-ラム、東京, 384-390 (1989)

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      1989 Annual Research Report
  • [Publications] Shoichi Kume.: J 立業.(若槻): Phys.Chem.Minerals. 応用物理. 16. 57. 239-245 1071-1077 (1988)(1988)

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      1988 Annual Research Report
  • [Publications] T.Endo.(島田): Kaoru J.Takano.(若槻): Japan.J.appl.Phys. J.Mater.Research. 28. 3. 392-397 80-85 (1988)(1989)

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      1988 Annual Research Report
  • [Publications] 若槻雅男: T.Endo.(嶋田): J.Solid State Chemistry. 応用物理. 57. 366-374 (1989)

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      1988 Annual Research Report
  • [Publications] H.Shi-Ming.(福長): K.Hirao.: Proc.International Inst.for Science of Sintering Symposium. J.Mater.Sci.23. Vol.1. 551-556 3821-3826 (1988)(1988)

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      1988 Annual Research Report
  • [Publications] K.Tanihata.(宮本): H.Kanda.: J.Crystal Growth. J.Am.Cer.Soc.94. 115-124 (1989)

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      1988 Annual Research Report
  • [Publications] K.Urabe.(小泉): Shoichi Kume.: Proc.International Conf.on Combustion and Plasma Synthesis of High-Temperature Materials. J.Am.Cer.Soc.71. 448-449 (1988)(1989)

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      1988 Annual Research Report
  • [Publications] S.Ikeda.(小泉): Proc.International Conf.on Combustion and Plasma Synthesis of High-Temperature Materials. (1989)

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      1988 Annual Research Report
  • [Publications] M.Ohhashi.(服部): J.Solid State Chem.75. 99-104 (1988)

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      1988 Annual Research Report
  • [Publications] M.Ohhashi.(服部): J.Solid State Chem.77. 342-347 (1988)

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      1988 Annual Research Report
  • [Publications] 稲垣道夫: 繊維学会誌. 44. 437-439 (1988)

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      1988 Annual Research Report
  • [Publications] 稲垣道夫: 炭素. 1989. 15-20 (1989)

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      1988 Annual Research Report
  • [Publications] G.Blasse.(児嶋): Mat.Res.Bull.33. 1727-1730 (1988)

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      1988 Annual Research Report
  • [Publications] I.Tanaka.(児嶋): Nature. 337. 21-22 (1989)

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      1988 Annual Research Report
  • [Publications] 花田禎一(曽我): Nippon Seramikkusu Kyokai Gakujutu Ronbunshi. 97. 297-283 (1989)

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      1988 Annual Research Report
  • [Publications] N.Soga.: J.Appl.Phys.63. 4451-4454 (1988)

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      1988 Annual Research Report
  • [Publications] T.Nomo.(吉村): J.Mater.Sci.23. 2689-2692 (1988)

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      1988 Annual Research Report
  • [Publications] M.Yoshimura.: Japan.J.Appl.Phys.27. L1757-1760 (1988)

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  • [Publications] S.Shimada.(小平): Thermochimica Acta. 133. 73-78 (1988)

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      1988 Annual Research Report
  • [Publications] M.Higuchi.(小平): J.Crystal Growth. 92. 341-343 (1988)

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      1988 Annual Research Report
  • [Publications] A.Kato.: Mater.Res.Bull.22. 1275-1281 (1987)

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      1988 Annual Research Report
  • [Publications] 永島和郎.(加藤): 日本化学会誌. 1987. 2293-2300 (1987)

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      1988 Annual Research Report
  • [Publications] Isao Hasegawa.(作花): J.Organometallic Chem.340. 31-36 (1988)

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      1988 Annual Research Report
  • [Publications] Isao Hasegawa.(作花): Bull.Chem.Soc.Japan. 61. 4087-4092 (1988)

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      1988 Annual Research Report
  • [Publications] Shin-ichiro Hirano.: Ceramic TransactionsQ1. 1988. (171-181)

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      1988 Annual Research Report
  • [Publications] N.Tohge.(南): J.Ceram.Soc.Jpn.96. 1127-1136 (1988)

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      1988 Annual Research Report
  • [Publications] H.Uchihashi.(南): J.Ceram.Soc.Jpn.97(3). (1989)

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      1988 Annual Research Report
  • [Publications] M.Kamo.(佐藤): Allpied Surface Sci.33/34. 535-560 (1988)

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      1988 Annual Research Report
  • [Publications] Y.Sato.: Proc.1st Int.Conf.New Diamond Sci.Tech(1988,Toky). (1989)

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      1988 Annual Research Report
  • [Publications] H.Yamane.(平井): Chemistry Letters. 939-940 (1988)

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      1988 Annual Research Report
  • [Publications] H.Yamane.(平井): Japan.J.Appl.Phys.27. L1275-1276 (1988)

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      1988 Annual Research Report
  • [Publications] Hirohide Nakamatsu.(河合): Mat.Res.Soc.Symp.Proc.101. 397-402 (1988)

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      1988 Annual Research Report
  • [Publications] 中松博英.(河合): 粉体および粉末治金. 36. (1989)

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      1988 Annual Research Report
  • [Publications] H.Murakami.(吉田): Advanced Ceramic Material. 3. 423-426 (1988)

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      1988 Annual Research Report
  • [Publications] K.Terashima.(吉田): Applied Physics Letters. 52. 1274-1276 (1988)

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      1988 Annual Research Report
  • [Publications] 稲村.(金丸): 材料. 37. 83-86 (1988)

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      1988 Annual Research Report
  • [Publications] Masao Takahashi.(金丸): Proc.International Meetings Advanced Mater.

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      1988 Annual Research Report
  • [Publications] T.Terashima.(坂東): Jpn.J.Appl.Phys.27. L91-L93 (1988)

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      1988 Annual Research Report
  • [Publications] R.Kanno.(坂東): Mat.Res.Bull.22. 1525-1532 (1988)

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      1988 Annual Research Report
  • [Publications] H.Itoh.: J.Mater.Sci.23. 43-47 (1988)

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      1988 Annual Research Report
  • [Publications] H.Itoh: J.Mater.Sci. (1989)

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      1988 Annual Research Report
  • [Publications] 若槻雅男 編集 瀬高信雄,難波義捷,松永正久,若槻雅男: "人造ダイヤモンド技術ハンドブック(第I編第1章、I及びIII節を担当)" サイエンスフォーラム, 1989

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      1988 Annual Research Report

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