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Electron Transfer Phenomena between Hetero Atoms and Their Characteristics and Applications

Research Project

Project/Area Number 63303009
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionOKAYAMA University

Principal Investigator

TORII Sigeru  Okayama University Professor, 工学部, 教授 (70032927)

Co-Investigator(Kenkyū-buntansha) YAMAMOTO Hisashi  Nagoya University Professor, 工学部, 教授 (10135311)
MORO-OKA Yoshihiko  Tokyo Institute of Technology Professor, 資源化学研究所, 教授 (70016731)
NAKAI Takeshi  Tokyo Institute of Technology Professor, 工学部, 教授 (90016717)
MURAI Shinji  Osaka University Professor, 工学部, 教授 (00029050)
UTIMOTO Kiitiro  Kyoto University Professor, 工学部, 教授 (90025958)
大辻 吉男  大阪府立大学, 工学部, 教授 (20081341)
Project Period (FY) 1988 – 1989
Project Status Completed (Fiscal Year 1989)
Budget Amount *help
¥12,800,000 (Direct Cost: ¥12,800,000)
Fiscal Year 1989: ¥4,800,000 (Direct Cost: ¥4,800,000)
Fiscal Year 1988: ¥8,000,000 (Direct Cost: ¥8,000,000)
KeywordsElectron transfer / Organometalic complex / Bimetal Redox System / Electroorganic Reactions / Photoelectron Transfer reaction / Metal Complex-catalyzed Reaction / Enantioselective Reaction / Chiral Catalyst / 光誘起電子移動反応
Research Abstract

Electron transfer between different elements has been intensively investigated from mechanistic and synthetic view points. The present cooperative research covers (1) electron transfer in two and three component metal redox systems, (2) electron transfer between organometalic complexes and organic compounds, (3) photo- and electrochemically induced electron transfer reactions, and (4) their synthetic applications. In the first category, newly designed two and three components metal redox systems, e.g., Ti/Zn, Ni/Zn, Nb/Zn, Ta/Zn, Pb/Al, Ti/Al, and Ni/Pb/Al may provide potential electron transfer systems, each of which can promote the characteristic carbon-carbon bond making reactions. The electron transfer systems comprising transition metal complexes and organic compounds have opened unique entries to various highly selective functionalization of olefins and silyl compounds. Electron transfer reaction between enzyme complexes in biological system has been also investigated using porphyrin dimmer linked by polymethylene diamide bond as a model system. On the other hand, under the plioto- and electrochemical conditions, the combinations of metal and organic redoxes, e.g., heteroaromatic o-quinones/NADH, copper complex/allyl halides, phenanthrene/group 4B metal complexes, and copper(II) salts/vinyl bromides, have been found to work as an efficient electron transfer system. The above mentioned electron transfer reactions can be applied successfully to various synthetic purposes, particularly, to enantio- and diastereoselective carbon-carbon bond formation, e.g., asymmetric [2+2]cycloaddition, asymmetric glyoxylate-ene reaction, oxygenation and hydrosilylation of olefins, cyclization of eneynes and diynes, rotamer distribution controlled C=C face differentiation, chirafity transfer of L-valine to homoallylamines and others.

Report

(3 results)
  • 1989 Annual Research Report   Final Research Report Summary
  • 1988 Annual Research Report
  • Research Products

    (141 results)

All Other

All Publications (141 results)

  • [Publications] Hideo TANAKA: "Reductive Addition of Polyhalomethanes and Their Related Compounds to Aldehydes and l,2ーElomonation of the Coupling Products in a Pb/Al Bimetal Redox System" J.ORG.CHEM. 54. 444-450 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo TANAKA: "Reduction Dimerization of Vinyl Halides in an Ni/Pb/Al Three Metal Redox System.A Facile Access to Terphenyl Derivatives" TETRAHEDRON LETT.30. 1261-1264 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo TANAKA: "Electroreductive“Barbier Type"Allylation of Imines with a Combination of a Pb(0)/Pb(II)Redox Mediator and Sacrifical Anode(Al)" TETRAHEDRON LETT.30. 4161-4164 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo,TANAKA: "A Facile Electroreductive Hydrocoupling of Imines in an Undivided Cell" SYNLETT. 51-52 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Joji OHSHITA: "PlatiumーCatalyzed Reactions of Phenylethyldisilanes" CHEM.EXPRESS,. 3. 179-182 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Mitsuo ISHIKAWA: "Siliconーcarbon Unsaturated Compounds XXIII.Transitionーmetalーcatalyzed Formation of Silenes from Vinyldisilanes" J.ORGANOMET.CHEM.363. C1-C3 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Joji OHSHITA: "SiliconーCarbon Unsaturated Compounds.24.Some Reactions of a Nickelasilacyclobutene" Organometallics. 8. 2050-2054 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kohei TAMAO: "Nickel(0)ーPromoted Cyclization Enynes with Isocyanides:A New Route to Polycyclic Cyclopentenone Skeletones" J.AM.CHEM.SOC.110. 1286-1288 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yoshihiko,ITO: "Palladiumーcatalyzed Coupling of NーSubstituted Isocyanide Dichlorides with Alkynyltin Compounds:New Shythesis of Dialykynylketones" Tetrahedron Lett.29. 5379-5382 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kohei TAMAO: "Nickel(0)ーPromoted Cyclization of 1,nーDiynes with Isocyanide:The First Pracical Synthesis of Polycyclic Iminocyclopentadienes" J.Org.Chem.54. 3517-3519 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yoshihiko ITO: "Synthesis of Unsymmetrical Dialkynyl Imines.Stepwise Coupling of Nーphenyl Phenylthioimidoyl Chloride with Alkynyltin Compounds" Chem.Lett.1261-1264 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko TAKAI: "Preparation of Alkylchromiun Reagents by Reducation of Alkyl Halides with Chromium(II)Chloride under Cabalt Catalysis" J.Org.Chem. 54. 4732-4734 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko TAKAI: "Preparation of βーHeteroーSubstituted Alkenylsilannes from Carboxylic Acid Derivaties" Synlett. 27-28 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko TAKAI: "Perparation of Alkenyl Sulfides and Enamines by Alkylidenation of Carboxylic Acid Derivatives" Tetrahdron Lett.30. 211-214 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko TAKAI: "Stereoselective Addition of αーChloro Allylic Chromium Reagents to Aldehydes" Tetrahedron Lett.30. 4389-4392 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yasutaka KATAOKA: "Reduction of Acetylenes to(Z)ーOlefins by Means of LowーValent Niobium of Tantalum" Tetrahedron Lett.31. 365-368 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yasutaka KATAOKA: "Preparation of 1ーNaphthols from Acetylenes and oーPhthalaldehyde Using LowーValent Tantalum and Niobium" Tetrahedron Lett.31. 369-372 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kenji UNEYAMA: "Generation and Reaction of 2,2,2ーTrifluoroー1ーPhenylsulfenylethyl Carbocation" Tetrahedron Lett.30. 2265-2266 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kenji UNEYAMA: "Trifluoroacetimidoyl Chlorides as a New Trifluoromethyl Building Block for Fluorinated Nitrogen Heterocycles" Tetrahedron Lett.30. 4821-4824 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Shinobu ITO: "Efficient NAD^+ーRegeneration System with Heteroaromatic oーQuinones and Molecular Oxygen" J.Chem.Soc.,Chem.Commun. 694-695 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko MIZUNO: "Generation of Organic Cations from Group 14 Organometallic Compounds via Photoinduced Electron Transfer in the Presence of Cu(II)Salt" Chem.Lett.229-232 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko MIZUNO: "Dual Regioselectivity in the Photoallylation of ElectronーDeficient Alkenes by Allylic Silanes" Chem.Lett.1507-1510 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko MIZUNO: "Photosubstitution of Dicyanobenzenes by Group 14 Organometallic Compounds via Photoinduced ElectronーTransfer.Addtive and Medium Effects on Photinduced Electron Transfer Reaction" Chem.Lett. 1833-1836 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko MIZUNO: "Photosilylation of ElectronーDeficient Alkenes by Use of Disilanes via Photoinduced ElectronーTransfer" Tetrahedron Lett.30. 3689-3692 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Akihiro SUZUKI: "Preparation and Properties of Reconstituted Myoglobins of with Chemically Modified Hemes." Journal of the Chemical SOciety of Japan. 505-511 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Masao TOKUDA: "An Efficient Electrochemical Coupling of Allylic Halides by Using a Copper Anode" Chem.Lett.945-948 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Masao TOKUDA: "Regioselectivity in Electrochemical Allylation of Carbonyl Compounds.A Synthesis of Egomaketone by Regioselective Allylation" J.Org.Chem.54. 5608-5613 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Tsugio KITAMURA: "Photolysis of βー(oーMethylthiophehyl)vinyl Bromides.A Versatile Synthesis of Benzo[b]thiophenes" Chem.Lett.1637-1638 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Koichi MIKAMI: "Various Chiral Dialkoxy Titanium Complexes as an Asymmetric Catalyst for Glyoxylateーene Reaction" Chem.Express. 4. 589-593 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Koichi MIKAMI: "Asymmetric GlyoxylateーEne Reaction Catalyzed by Chiral Titanium Complexes:A Practical Access to αーHydroxy Esters in High Enantiomeric Purities" J.Am.Chem.Soc.111. 1940-1941 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yujiro HAYASHI: "Asymmetric[2+2]Cycloaddition Reaction Catalyzed by a Chiral Titanium Reagent" Chem.Lett.793-796 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo KUROSAWA: "An Unusually Lower Barrier to Reductive Elimination of an 18ーElectron η^3ーAllyl(organo)nickel(II)Complex Than Those of a 16ーElectron η^3ーAllyl Counterpart and a 16ーElectron η^1ーAlly Isomer" J.Am.Chem.Soc.110. 6272-6273 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Toshiaki MURAI: "Cobalt Carbonyl Catalyzed Reactions of Cyclic Ethers with a Hydrosilane and Carbon Monoxide.A New Synthetic Reaction Equivalent to Nucleophilic Oxymethylation" J.Am.Chem.Soc.111. 7938-7946 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Takahiro HOSOKAWA: "Pd(II)Catalyzed Reactions of Olefins with Oxygen Nucleophiles" Journal of SYnthetic Organic Chemostry,Japan. 47. 636-648 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Seiki SAITO: "Rotamer Distribution Control and Double Michael Addition for Cyclopentance Annulation with Superb Selectivity" J.Am.Chem.Soc.111. 4533-4535 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka AKITA: "Metalーexchange Reaction on Cationic Diiron μーη^2ー(C,O)ーenolate Complexes" J.Organomet.Chem. 345. C9-C12 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka AKITA: "Oneーpot Synthesis of Transtition MetalーSubstitutedd Carboxylic Acid" J.Organomet.Chem.348. 91-94 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka AKITA: "Preparation of Homoーand Heterobimetallic μーη^2ー(C,C)ーKetene Complexes,FpCH_2COMLn,and Transformation of the Bridging Ketene Ligand into Various C2 Functional Groups" Organometallics. 7. 366-374 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka AKITA: "Modelling the PichlerーSchulz Mechanism by Catalytic Hydrosilylation of Acyl Metal Complexes" J.Chem.Soc.,Chem.Commun.527-529 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka AKITA: "Molecular Structure of Heterobimetallic μーη^2ー(C,C)ーKetene Complexes" J.Chem.Soc.Dalton Trans.1627-1630 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka AKITA: "MetalーExchange Reaction on Cationic Polyiron μ_3ーη^3ー(C,C,O)ーKetene and μーη^2ー(C,O)ーEnolate Complexes" Organometallics. 8. 687-693 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka AKITA: "Reactivities of Ketene Ligands on Polymetallic Systems" J.Mol.Catal.56. 107 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Akira Yanagusawa: "Double Alkylation ofα,βーUnsaturated Acetals.An Inverse Polarity Approach" J.Am.Chem.Soc.111. 366-368 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Sigeru TORII: "Topics in Current Chemistry,Vol.148" SpringerーVerlag,BarlinーHeidelberg, 41 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Sigeru TORII: "Organic Electrochemistry,3rd,Edition" Marcel Dekker,inc.,New York, (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo Tanaka: "Reductive Addition of Polyhalomethanes and Their Related Compounds to Aldehydes and 1,2-Elomonation of the Coupling Products in a Pb/Al Bimetal Redox System" J.ORG.CHEM.54. 444-450 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo Tanaka: "Reduction Dimerization of Vinyl Halides in an Ni/Pb/Al Three Metal Redox System. A Facile Access to Terphenyl Derivatives" TETRAHEDRON LETT., 30, 1261-1264(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo Tanaka: "Electroreductive "Barbier Type" Allylation of Imines with a Combination of a Pb(0)/Pb(II) Redox Mediator and Sacrificial Anode(Al)" TETRAHEDRON LETT., 30, 4161-4164(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo Tanaka: "A Facile Electroreductive Hydrocoupling of Imines in an Undivided Cell" SYNLETT, 1989, 51-52.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Joji Ohshita: "Platium-Catalyzed Reactions of Phenylethyldisilanes" CHEM.EXPRESS, Vol.3, No.3, pp.179-182(1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Mitsuo Ishikawa: "Silicon-carbon Unsaturated Compounds XXIII. Transition-metal-catalyzed Formation of Silenes from Vinyldisilanes" J.ORGANOMET.CHEM., 363, C1-C3(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Joji Ohshita: "Silicon-Carbon Unsaturated Compounds. 24. Some Reactions of a Nickelasilacyclobutene" ORGANOMETALICS, 8, 2050-2054(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kohei Tamao: "Nickel(0)-Promoted Cyclization Enynes with Isocyanides: A New Route to Polycyclic Cyclopentenone Skeletones" J.AM.CHEM.SOC., 110, 1286-1288(1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yoshihiko Ito: "Palladium-catalyzed Coupling of N-Substituted Isocyanide Dichlorides with Alkynyltin Compounds: New Synthesis of Dialykynylketones" TETRAHEDRON LETT., 29, 5379-5382(1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kohei Tamao: "Nickel(0)-Promoted Cyclization of 1,n-Diynes with Isocyanide: The First Practical Synthesis of Polycyclic Iminocyclopentadienes" J.ORG.CHEM., 54, 3517-3519(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yoshihiko Ito: "Synthesis of Unsymmetrical Dialkynyl Imines. Stepwise Coupling of N-Phenyl Phenylthioimidoyl Chloride with Alkynyltin Compounds" CHEM.LETT., 1989, 1261-1264.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko Takai: "Preparation of Alkylchromiun Reagents by Reduction of Alkyl Halides with Chromium(II) Chloride under Cabalt Catalysis" J.ORG.CHEM., 54, 4732-4734(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko Takai: "Preparation of beta-Hetero-Substituted Alkenylsilanes from Carboxylic Acid Derivatives" SYNLETT, 1989, 27-28.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko Takai: "Preparation of Alkenyl Sulfides and Enamines by Alkylidenation of Carboxylic Acid Derivatives" TETRAHEDRON LETT., 30, 211-214(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko Takai: "Stereoselective Addition of alpha-Chloro Allylic Chromium Reagents to Aldehydes" TETRAHEDRON LETT., 30, 4389-4392(1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yasutaka Kataoka: "Reduction of Acetylenes to (Z)-Olefins by Means of Low-Valent Niobium or Tantalum" TETRAHEDRON LETT., 31, 365-368(1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yasutaka Kataoka: "Preparation of 1-Naphthols from Acetylenes and o-Phthalaldehyde Using Low-Valent Tantalum and Niobium" TETRAHEDRON LETT., 31, 369-372 (1990).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kenji Uneyama: "Generation and Reaction of 2, 2, 2-Trifluoro-1-Phenylsulfenylethyl Carbocation" TETRAHEDRON LETT., 30, 2265-2266 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kenji Uneyama: "Trifluoroacetimidoyl Chlorides as a New Trifluoromethyl Building Block for Fluorinated Nitrogen Heterocycles" TETRAHEDRON LETT., 30, 4821-4824 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Shinobu Itoh: "Efficient NAD^T-Regeneration System with Heteroaromatic omicron-Quinones and Molecular Oxygen" J. CHEM. SOC., CHEM. COMMUN., 1989, 694-695.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko Mizuno: "Generation of Organic Cations from Group 14 Organometallic Compounds via Photoinduced Electron Transfer in the Presence of Cu(II)Salt" CHEM.LETT., 1988, 229-232.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko Mizuno: "Dual Regioselectivity in the Photoallylation of Electron-Deficient Alkenes by Allylic Silanes" CHEM.LETT., 1988, 1507-1510.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko Mizuno: "Photosubstitution of Dicyanobenzenes by Group 14 Organometallic Compounds via Photoinduced Electron-Transfer. Addtive and Medium Effects on Photoinduced Electron Transfer Reaction" CHEM.LETT., 1988, 1833-1836.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Kazuhiko Mizuno: "Photosilylation of Electron-Deficient Alkenes by Use of Disilanes via Photoinduced Electron-Transfer" TETRAHEDRON LETT., 30, 3689-3692 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Akihiro Suzuki: "Preparation and Properties of Reconstituted Myoglobins of with Chemically Modified Hemes." JOURNAL OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 505-511.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Masao Tokuda: "An Efficient Electrochemical Coupling of Allylic Halides by Using a Copper Anode" CHEM.LETT., 1988, 945-948.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Masao Tokuda: "Regioselectivity in Electrochemical Allylation of Carbonyl Compounds. A Synthesis of Egomaketone by Regioselective Allylation" J.ORG.CHEM., 54, 5608-5613 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Tsugio Kitamura: "Photolysis of beta-(o-Methylthiophehyl)vinyl Bromides. A Versatile Synthesis of Benzo[b]thiophenes" CHEM.LETT., 1988, 1637-1638.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Koichi Mikami: "Various Chiral Dialkoxy Titanium Complexes as an Asymmetric Catalyst for Glyoxylate-ene Reaction" CHEM.EXPRESS, 4, 589-593 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Koichi Mikami: "Asymmetric Glyoxylate-Ene Reaction Catalyzed by Chiral Titanium Complexes: A Practical Access to alpha-Hydroxy Esters in High Enantiomeric Purities" J.AM.CHEM.SOC., 111, 1940-1941 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yujiro Hayashi: "Asymmetric [2+2] Cycloaddition Reaction Catalyzed by a Chiral Titanium Reagent" CHEM.LETT., 1989, 793-796.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo Kurosaki: "An Unusually Lower Barrier to Reductive Elimination of an 18-Electron eta^3-Allyl(organo)nickel(II) Complex Than Those of a 16-Electron eta^3-Allyl Counterpart and a 16-Electron eta^1-Allyl Isomer" J.AM.CHEM.SOC., 110, 6272-6273 (1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Toshiaki Murai: "Cobalt Carbonyl Catalyzed Reactions of Cyclic Ethers with a Hydrosilane and Carbon Monoxide. A New Synthetic Reaction Equivalent to Nucleophilic Oxymethylation" J.AM.CHEM.SOC., 111, 7938-7946 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Takahiro Hosokawa: "Pd(II)-Catalyzed Reactions of Olefins with Oxygen Nucleophiles" J.SYNTH.ORG.CHEM.JPN., 47, 636-648 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Seiki Saito: "Rotamer Distribution Control and Double Michael Addition for Cyclopentane Annulation with Superb Selectivity" J.AM.CHEM.SOC., 111, 4533-4535 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka Akita: "Metal-exchange Reaction on Cationic Diiron mu-eta^2-(C,O)-enolate Complexes" J.ORGANOMET.CHEM., 345, C9-C12 (1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka Akita: "One-pot Synthesis of Transition Metal-Substituted Carboxylic Acid" J.ORGANOMET.CHEM.348, 91-94 (1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka Akita: "Preparation of Homo-and Heterobimetallic mu-eta^2-(C,C)-Ketene Complexes, FpCH_2COMLn, and Transformation of the Bridging Ketene Ligand into Various C2 Functional Groups" ORGANOMETALLICS, 7, 366-374 (1988).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka Akita: "Modelling the Pichler-Schulz Mechanism by Catalytic Hydrosilylation of Acyl Metal Complexes" J.CHEM.SOC., CHEM. COMMUN., 1989, 527-529.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka Akita: "Molecular Structure of Heterobimetallic mu-eta^2-(C,C)-Ketene Complexes" J.CHEM.SOC.DALTON TRANS., 1627-1630, 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka Akita: "Metal-Exchange Reaction on Cationic Polyiron mu3-eta^3-(C,C,O)-Ketene and mu-eta^2-(C,O)-Enolate Complexes" ORGANOMETALLICS, 8, 687-693 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Munetaka Akita: "Reactivities of Ketene Ligands on Polymetallic Systems" J.MOL.CATAL., 56, 107 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Akira Yanagisawa: "Double Alkylation of alpha, beta-Unsaturated Acetals. An Inverse Polarity Approach" J.AM.CHEM.SOC., 111, 366-368 (1989).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Hideo TANAKA: "Peductive Addition of Polyhalomethanes and Their Related Compounds to Aldehydes and 1,2-Elomonation of the Coupling Products in a Pb/Al Bimetal Redox System" J.ORG.CHEM.54. 444-450 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Hideo TANAKA: "Reduction Dimerization of Vinyl Hanyl Halides in an Ni/Pb/Al Three Metal Redox System.A Facile Access to Terphenyl Derivatives" TETRAHEDRON LETT.30. 1261-1264 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Hideo TANAKA: "Electroreductive"Barbier Type"Allylation of Imines with a Combination of a Pb(O)/Pb(II)Redox Mediator and Sacrificial Anode(Al)" TETRAHEDRON LETT.30. 4161-4164 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Hideo TANAKA: "A Facile Electroreductive Hydrocoupling of Imines in an Undivided Cell" SYNLETT. 51-52 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Joji OHSHITA: "Platium-Catalyzed Reactions of Phenylethyldisilanes" CHEM.EXPRESS,. 3. 179-182 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Mitsuo ISHIKAWA: "Silicon-carbon Unsaturated Compounds XXIII.Transition-metal-catalyzed Formation of Silenes from Vinyldisilanes" J.ORGANOMET.CHEM.363. C1-C3 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Joji OHSHITA: "Silicon-Carbon Unsaturated Compounds.24.Some Reactions of a Nickelasilacyclobutene" Organometallics. 8. 2050-2054 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kohei TAMAO: "Nickel(O)-Promoted Cyclization Enynes with Isocyanides:A New Route to Polycyclic Cyclopenone Skeletones" J.AM.CHEM.SOC.110. 1286-1288 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Yoshihiko ITO: "Palladium-catalyzed Coupling of N-Substituted Isocyanide Dichlorides with Alkynyltin Compounds:New Synthesis of Dialykynylketones" Tetrahedron Lett.29. 5379-5382 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kohei TAMAO: "Nickel(O)-Promoted Cyclization of 1,n-Diynes with Isocyanide:The First Practical Synthesis of Polycyclic Iminocyclopentadienes" J.Org.Chem.54. 3517-3519 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Yoshihiko ITO: "Synthesis of Unsymmetrical Dialkynyl Imines.Stepwise Coupling of N-Phenyl Phenylthioimidoyl Chloride with Alkynyltin Compounds" Chem.Lett.1261-1264 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko TAKAI: "Preparation of Alkylchromiun Reagents by Reduction of Alkyl Halides with Chromium(II)Chloride under Cabalt Catalysis" J.Org.Chem.54. 4732-4734 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko TAKAI: "Preparation of β-Hetero-Substituted Alkenylsilanes from Carboxylic Acid Derivatives" Synlett. 27-28 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko TAKAI: "Preparation of Alkenyl Sulfides and Enamines by Alkylidenation of Carboxylic Acid Derivatives" Tetrahedron Lett.30. 211-214 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko TAKAI: "Stereoselective Addition of α-Chloro Allylic Chromium Reagents to Aldehydes" Tetrahedron Lett.30. 4389-4392 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Yasutaka KATAOKA: "Reduction of Acetylenes to(Z)-Olefins by Means of Low-Valent Niobium or Tantalum" Tetrahedron Lett.31. 365-368 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Yasutaka KATAOKA: "Preparation of 1-Naphthols from Acetylenes and o-Phthalaldehyde Using Low-Valent Tantalum and Niobium" Tetrahedron Lett.31. 369-372 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kenji UNEYAMA: "Generation and Reaction of 2,2,2-Trifluoro-1-Phenylsulfenylethyl Carbocation" Tetrahedron Lett.30. 2265-2266 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kenji UNEYAMA: "Trifluoroacetimidoyl Chlorides as a New Trifluoromethyl Building Block for Fluorinated Nitrogen Heterocycles" Tetrahedron Lett.30. 4821-4824 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Shinobu ITO: "Efficient NAD^+-Regeneration System with Heteroaromatic o-Quinones and Molecular Oxygen" J.Chem.Soc.,Chem.Commun.694-695 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko MIZUNO: "Generation of Organic Cations from Group 14 Organometallic Compounds via Photoinduced Electron Transfer in the Presence of Cu(II)Salt" Chem.Lett.229-232 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko MIZUNO: "Dual Regioselectivity in the Photoallylation of Electron-Deficient Alkenes by Allylic Silanes" Chem.Lett.1507-1510 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko MIZUNO: "Photosubstitution of Dicyanobenzenes by Group 14 Organometallic Compounds via Photoinduced Electron-Transfer.Addtive and Medium Effects on Photoinduced Electron Transfer Reaction" Chem.Lett.1833-1836 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko MIZUNO: "Photosilylation of Electron-Deficient Alkenes by Use of Disilanes via Photoinduced Electron-Transfer" Tetrahedron Lett.30. 3689-3692 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Akihiro SUZUKI: "Preparation and Properties of Reconstituted Myoglobins of with Chemically Modified Hemes." Journal of the Chemical SOciety of Japan. 505-511 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Masao TOKUDA: "An Efficient Electrochemical Coupling of Allylic Halides by Using a Copper Anode" Chem.Lett.945-948 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Masao TOKUDA: "Regioselectivity in Electrochemical Allylation of Carbonyl Compounds.A Synthesis of Egomaketone by Regioselective Allylation" J.Org.Chem.54. 5608-5613 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Tsugio KITAMURA: "Photolysis of β-(o-Methylthiophehyl)vinyl Bromides.A Versatile Synthesis of Benzo[b]thiophenes" Chem.Lett.1637-1638 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Koichi MIKAMI: "Various Chiral Dialkoxy Titanium Complexes as an Asymmetric Catalyst for Glyoxylate-ene Reaction" Chem.Express. 4. 589-593 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Koichi MIKAMI: "Asymmetric Glyoxylate-Ene Reaction Catalyzed by Chiral Titanium Complexes:A Practical Access to α-Hydroxy Esters in High Enantiomeric Purities" J.Am.Chem.Soc.111. 1940-1941 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Yujiro HAYASHI: "Asymmetric[2+2]Cycloaddition Reaction Catalyzed by a Chiral Titanium Reagent" Chem.Lett.793-796 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Hideo KUROSAWA: "An Unusually Lower Barrier to Reductive Elimination of an 18-Electron η^3-Allyl(organo)nickerl(II)Complex Than Those of a 16-Electron η^3-Allyl Counterpart and a 16-Electron η^1-Allyl Isomer" J.Am.Chem.Soc.110. 6272-6273 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Toshiaki MURAI: "Cobalt Carbonyl Catalyzed Reactions of Cyclic Ethers with a Hydrosilane and Carbon Monoxide.A New Synthetic Reaction Equivalent to Nucleophilic Oxymethylation" J.Am.Chem.Soc.111. 7938-7946 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Takahiro HOSOKAWA: "Pd(II)-Catalyzed Reactions of Olefins with Oxygen Nucleophiles" Journal of Synthetic Organic Chemostry,Japan. 47. 636-648 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Seiki SAITO: "Rotamer Distribution Control and Double Michael Addition for Cyclopentane Annulation with Superb Selectivity" J.Am.Chem.Soc.111. 4533-4535 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Munetaka AKITA: "Metal-exchange Reaction on Cationic Diiron μ-η^2-(C,O)-enolate Complexes" J.Organomet.Chem.345. C9-C12 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Munetaka AKITA: "One-pot Synthesis of Transition Metal-Substituted Carbowylic Acid" J.Organomet.Chem.348. 91-94 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Munetaka AKITA: "Preparation of Homo-and Heterobimetallic μ-η^2-(C,C)-Ketene Complexes,FpCH_2COMLn,and Transformation of the Bridging Ketene Ligand into Various C2 Functional Groups" Organometallics. 7. 366-374 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Munetaka AKITA: "Modelling the Pichler-Schulz Mechanism by Catalytic Hydrosilylation of Acyl Metal Complexes" J.Chem.Soc.,Chem.Commun.527-529 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Munetaka AKITA: "Molecular Structure of Heterobimetallic μ-η^2-(C,C)-Ketene Complexes" J.Chem.Soc.Dalton Trans.1627-1630 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Munetaka AKITA: "Metal-Exchange Reaction on Cationic Polyiron μ_3-η^30(C,C,O)-Ketene and μ-η^2-(C,O)-Enolate Complexes" Organometallics. 8. 687-693 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Munetaka AKITA: "Reactivities of Ketene Ligands on Polymetallic Systems" J.Mol.Catal.56. 107 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Akira Yanagusawa: "Double Alkylation of α,β-Unsaturated Acetals.An Inverse Polarity Approach" J.Am.Chem.Soc.111. 366-368 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Sigeru TORII: "Topics in Current Chemistry,Vol.148" Springer-Verlag,Barlin-Heidelberg, 41 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] Sigeru TOTII: "Organic Electrochemistry,3rd Edition" Marcel Dekker,inc.,New York, (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kazuhiko Takai.: Tetrahedron Letters. 29. 1065-1068 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Koici Mikami.: Journal of the Chemical Society Chemical Communications. 1430-1431 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Hideo Tanaka.: Tetrahedron Letters. 29. 1721-1724 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Hideo Tanaka.: Tetrahedron Letters. 29. 3811-3814 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Akira Yanagisawa.: Journal of the American Chemical Society. 111. 366-368 (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] Koici Mikami.: Tetrahedron Letters. 30. 357-360 (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] Sigeru Torii.: "Topics in Current Chemistry,Vol.148" Springer-Verlag, 153-194 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Sigeru Torii.: "Organic Electrochemistry,3rd Edition" Marcel Dekker, (1989)

    • Related Report
      1988 Annual Research Report

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Published: 1988-04-01   Modified: 2016-04-21  

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