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Investigation of Solid-State Alloying in Transition Metal Binary Alloy Composite Films by High Resolution and Analytical Electron Microscopy.

Research Project

Project/Area Number 63460226
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 結晶学
Research InstitutionKobe University

Principal Investigator

YOSHIDA Kentaroh  Kobe Univ., Fac. Eng. Dept. Appl. Phys. associate professor, 工学部, 助教授 (60031085)

Co-Investigator(Kenkyū-buntansha) YAMADA Takashi  Kobe Univ., Fac. Eng. Dept. Appl. Phys. assistant, 工学部, 助手 (00112079)
Project Period (FY) 1988 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥6,600,000 (Direct Cost: ¥6,600,000)
Fiscal Year 1990: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1989: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1988: ¥3,200,000 (Direct Cost: ¥3,200,000)
KeywordsLong-period crystal lattice / Interface / Quasicrystal / Solid-state alloying / Composite double layer films / Mn-Bi alloy system / Metastable alloy phase / High resolution electron microscopy / 固体反応 / Mn〜Bi合金 / 溶融亞鉛メッキ鋼板 / 真空同時蒸着法 / 真空逐次蒸着法 / 長周期合金格子 / 電子ビ-ム真空蒸着 / 高分解能電子顕微鏡 / 電子顕微鏡結晶構造解析 / 真空蒸着膜 / 同時蒸着膜 / 極薄二重膜 / 12回対称準結晶 / 円柱形アトミック・クラスター
Research Abstract

In order to accelerate experiments more effectively, a high-vacuum-deposition apparatus equipped with an electron-beam-evaporator with a large capability was designed and constructed. It has been successfully used, since 1990, for preparing composite double layer thick films consisting of a Bi layer 5000 A and of a Mn layer 2000 A in thickness.
By co-deposition of Bi and Mn, it was found that non-crystalline alloy films are obtained when their composition is between 65 and 85 at% Mn. When warmed up at 180^゚C, crystallization of the "nucleation and grain growth" type takes place and obtained crystals have a new metastable hexagonal lattice of a = 19.97 A, c = 4.49 A. Atomic arrangement within this large lattice was determined from its electron diffraction patterns, high resolution electron micrographs and their computer simulation. In composite double layer Mn-Bi films prepared by successive deposition, as many as more than four kinds of new alloy phases were obtained by solid-state alloying due to low temperature heating below the melting point of Bi, although only one phase, ferromagnetic MnBi, is described to exist in the equilibrium phase diagram. They include a long-period tetragonal phase with a = 17.26 A, c = 10.21 A, and a quasicrystal having twelve-fold symmetry, which will have intimate structural relation to the long-period tetragonal phase.
Structure analysis of the metastable hexagonal phase is one of a few examples of performing the analysis only by electron microscopy. The quasicrystal with twelve-fold symmetry is the one first observed in the world and is now in press in Philosophical Magazine Letters. Atomic arrangement of the long-period tetragonal phase is being looked for referring to the sigma-phase structure and so on. Deposition experiment of Fe-Zn system was just started in an aim of making some contribution to industrial manufacturing of galvanized steel sheets.

Report

(4 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • 1988 Annual Research Report
  • Research Products

    (39 results)

All Other

All Publications (39 results)

  • [Publications] Kentaroh Yoshida: "Further Investigation of the Basic Structure of Metastable Mn_3Bi by High Resolution Electron Microscopy and its Computer Simulation." Journal of Electron Microscopy. Vol.36. 139-150 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida: "NonーEquilibrium Alloy Phases in BiーMn Thin Films Prepared by Vacuum Depositions ーーー A Metastable Mn_3Bi and Other Long Period Crystal Lattices." Proceedings of JIMISー5 :Nonーequilibrium solid phases of Metals and Alloys,Suppl.to JIM.Vol.29.Vol.29. 135-138 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida: "LongーPeriod Crystal Lattices in Thin BiーMn Films Prepared by Successive and Simultaneous Vacuum Depositions." Applied SurFace Science. Vol.33/34. 516-524 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida: "SolidーState Alloying Reaction at the Interfaces of BiーMn Double Layer Thin Films." Proceedings of IVth AsiaーPacific Conference and Workshop on Electron Microscopy,(Bangkok,1988). 231-232 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 吉田,虔太郎: "二元合金の真空同時蒸着法と逐次蒸着法,=BiーMn系合金膜の場合=" 電子顕微鏡. Vol.23. 174-177 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida: "LongーPeriod Tetragonal Lattice Formation by SolidーState Alloying at the Interfaces of BiーMn Double Layer Thin Films." Acta Crystallographica. Vol.B45. 40-45 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Takashi Yamada: "use of Cartesian Coーordinates,〈〓,〓,〓〉,in the MultiーSlice simulation Program for High Resolution Electron Microscopy." Memoires of the Faculty of Engineering,Kobe university. No.36. 215-235 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Takashi Yamada: "A New Alloy Phase Produced in the CoーDeposited BiーMn Films in a Composition Range 50ー30 at% Mn." Proceedings of XIIth International Congress for Electron Microscopy (Seattle,1990). Vol.4. 1012-1013 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida: "Structure of LongーPeriod Tetragonal Lattice Formed by SolidーState Alloying in BiーMN Double Layer thin Films." Proceedings of XIIth International Congress for Electron Microscopy, (Seattle,1990). Vol.4. 160-161 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida: "Disordered Twin Boundary Regions in LongーPeriod Tetragonal BiーMn Films." Philosophical Magazine Letters. Vol.63. (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Takashi Yamada: "Composition Determination of Vacuum CoーDeposited MnーBi Thin Films by Means of Energy Dispersive Xーray Analysis." Memoires of the Faculty of Engineering, Kobe University. No.38. (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida, Takashi Yamada and Youta Furukawa: "Further investigation of the basic structure of metastable Mn_3Bi by high resolution electron microscopy and its computer simulation" J. Electron Microscopy. Vol. 36. 139-150 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida and Takashi Yamada: "Non-equilibrium alloy phases in Bi-Mn thin films prepared by vacuum depositions, - a metastable Mn_3Bi and other long period crystal lattices -" Proceedings of JIMTS-5 : NonーEquilibrium Solid Phase of Metals and Alloys, Supplement to JIM.Vol. 29. 135-138 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida and Takahashi Yamada: "Long-period crystal lattices in thin Bi-Mn alloy films prepared by successive and simultaneous vacuum depositions" Applied Surface Science. Vol. 33/34. 516-524 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida, Takashi Yamada and Yoshihisa Tanihuchi: "Solid-state alloying reaction at the interface of Bi-Mn double layer thin films," Proceedings of IVth Asia-Pacific Confer. & Workshop on Electron Microscopy. Bangkok. 231-232 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida and Takashi Yamada: "Simultaneous and successive vacuum depositions of binary alloys, --- for the case of Bi-Mn system as an example ---" Denshikenbikyo. Vol. 23. 174-177 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida, Takashi Yamada and Yoshihisa Taniguchi: "Long-period tetragonal lattice formation by solid-state alloying at the interfaces of Bi-Mn double layer thin films" Acta crystallographica. Vol. B45. 40-45 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Takashi Yamada, Youta Furukawa and Kentaroh Yoshida: "Use of Cartesian co-ordianate systems, <i, j, k> , in the multi-slice simulation program for high resolution electron microscopy" Memoires of the Faculty of Engineering, Kobe University. No36. 215-234 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Takashi Yamada & Kentaroh Yoshida: "A new alloy phase produced in the co-deposited Bi-Mn films in a composition range 50 - 30 at% Mn" Proceedings of the XIIth Intern. Congr. for Electron Microscopy, Seattle. Vol. 4. 1012-1013 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida and Takashi Yamada: "Structure of long-period tetragonal lattice formed by solid-state alloying in Bi-Mn double layer thin films" Proceedings of the XIIth Intern. Congr. for Electron Microscopy, Seattle. Vol. 4. 160-161 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida and Yshihisa Taniguchi: "Disordered twin boundary regions in long-period tetragonal Bi-Mn films" Philosophical Magazine Letters. Vol. 63 No. 3. (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Takashi Yamada and Kentaroh Yoshida: "Composition determination of vacuum co-deposited Mn-Bi thin films by means of energy dispersive X-ray analysis" Memoires of the Faculty of Engineering, Kobe University. No. 38. (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kentaroh Yoshida: "Production of Alloy Phases in BiーMn System by Vacuum Depositions & SolidーState Alloying,and their Structure Investigations by High Resolution Electron Microscopy." Supplement to Acta Crystallographica,Collected Abstracts of the XVth Congress and General Assembly of IUCr.,(Bordeaux,France).C386 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Kentaroh Yoshida: "Structure of LongーPeriod Tetragonal Lattice Fromed by SolidーState Alloying in BiーMn Souble Layer Thin Films." Proceedings of the XIIth Intern.Congress for Electron Microscopy,(Seattle,U.S.A.1990). 4. 160-161 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takashi Yamada: "A New Alloy Phase Produced in the CoーDeposited MnーBi Films in a Composition Range 50ー30 at% Mn." Proceedings of the XIIth Intern.Congress for Electron Microscopy,(Seattle,U.S.A.1990). 4. 1012-1013 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Kentaroh Yoshida: "Disordered Twin Boundary Regions in LongーPeriod Tetragonal BiーMn Films." Philosophical Magazine Letters. Vol.63. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takashi Yamada: "Composition Determination of Vacuum CoーDeposited MnーBi Thin Films by Means of Energy Dispersive Xーray Analysis" Memoires of the Faculty of Engineering,Kobe University.No.38. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Kentaroh Yoshida: "Long-Period Tetragonal Lattice Formation by Solid-State Alloying at the Interface of Bi-Mn Double Layer Thin Films." Acta Crystallographica. B45. 40-45 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Takashi Yamada: "Use of Cartesian Co-ordinate systems,〈〓〓〓〉,in the Multi-Slice Simulation Prograpm for High Resolution Electron Microscopy." Memoirs of the Faculty of Engineering,Kobe University. No.36. 215-234 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kentaroh Yoshida: "Production of Alloy Phases in Bi-Mn System by Vacuum Deposition Followed by Solid-State Alloying and Their Structure Investigations by High Resolution Electron Microscopy." Supplement to Acta Crystallographica,Proc.XVth Congress and General Assembly of IUCr.(Bordeaux,France,1990). (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kentaroh Yoshida: "Structure of Long-Period Tetragonal Lattice Formed by Solid-State Alloying in Bi-Mn Double Layer Thin Films." Proc.XIIth Intern.Congr.for Electron Microscopy(Seattle,U.S.A.1990). (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Takashi Yamada: "A New Alloy Phase Produced in the Co-Deposited Bi-Mn Films in a Composition Range 50-30 At% Mn." Proc.XIIth Intern.Congr.for Electron Microscopy(Seattle,U.S.A.1990). inpress (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Takashi Yamada: "エネルギ-分散型X線分光法による、同時蒸着Bi〜Mn薄膜の定量分析" Memoirs of the Faculty of Engineering,Kobe University. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Kentaroh Yoshida: Proceedings of the IVth Asia-Pacific Conference and Workshop on Electron Microscopy,Bangkok 1988. 231-232 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Kentaroh Yoshida: Applied Surface Science. 33/34. 516-524 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Kentaroh Yoshida: Proceedings of JIMIS-5:Non-Equilibrium Solid Phases of Metals and Alloys,Supplement to Trans.JIM.29. 135-135 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 吉田虔太郎: 電子顕微鏡. 23. 174-177 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Kentaroh Yoshida: Acta Crystallographica. B45. (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] 山田隆: MEMOIRS OF THE FACULTY OF ENGINEERING,KOBE UNIVERSITY. (1989)

    • Related Report
      1988 Annual Research Report

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Published: 1988-04-01   Modified: 2016-04-21  

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