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Thermodynamic study of Multi-Component Calcium Ferrite

Research Project

Project/Area Number 63470050
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionKyushu University

Principal Investigator

ONO Yoichi  Kyushu University, Faculty of Engineering, Professor, 工学部, 教授 (20037732)

Co-Investigator(Kenkyū-buntansha) MAEDA Takayuki  Kyushu University, Faculty of Engineering, Research Associate, 工学部, 助手 (50150496)
Project Period (FY) 1988 – 1989
Project Status Completed (Fiscal Year 1989)
Budget Amount *help
¥5,600,000 (Direct Cost: ¥5,600,000)
Fiscal Year 1989: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1988: ¥4,600,000 (Direct Cost: ¥4,600,000)
KeywordsQuaternary Calcium Ferrite / Reduction Sequence / Reduction Equilibria / Magnetite / Wustite / 固体電解質 / 平衡ガス組成 / 還元平衡 / 熱天秤 / ウスタイト / マグネタイト
Research Abstract

Three kinds of quaternary calcium ferrites, whose composition differed from each other, were synthesized from reagent grade powders and the reduction sequence and the equilibria of those samples with CO-CO_2 gas mixture were investigated and the following results were obtained.
(1) Three kinds of samples having different chemical compositions were fired at 1300゚C for one hour in the air. The result of the identification of constituent minerals, revealed that most part of the synthesized samples consisted of quaternary calcium ferrite.
(2) Quaternary calcium ferrite is reduced to iron by way of magnetite('Fe_3O_4') and wustite('FeO'), which contained CaO, SiO_2, and Al_2O_3. The reduction sequence of quaternary calcium ferrite is different from binary calcium ferrite.
(3) The reduction sequence of quaternary calcium ferrite is given by the following equations except for the initial reduction stage.
'Fe_3O_4'(s)+CO(g)=3'FeO'(S)+CO_2(g) (1)
'FeO'(s)+CO(g)=Fe(S)+CO_2(g) (2)
The equilibrium CO concentrations for the reduction of quaternary calcium ferrite were higher than those for the reduction of pure iron oxides. The lines of temperature-equilibrium CO-CO_2 gas composition for the reduction of quaternary calcium ferrite were in approximately parallel with those for the reduction of iron oxides. Depending on the composition of quaternary calcium ferrite, the values of the equilibrium CO concentration for the reactions (1) and (2) varied.

Report

(3 results)
  • 1989 Annual Research Report   Final Research Report Summary
  • 1988 Annual Research Report
  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] Yoichi ONO: "Reduction Equilibria of Multi-Component Calcium Ferrite with CO-CO_2 gas Mixture" Ironmaking Conference Proceedings. 48. 3-11 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 前田敬之: "4成分系カルシウムフェライトのCO-CO_2混合ガスによる還元平衡" 九州大学工学集報. 62. 697-704 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yoichi ONO et al.: "Reduction Equilibria of Multi-Component Calcium Ferrite with CO-CO_2 Gas Mixture" IRONMAKING CONFERENCE PROCEEDINGS, 48(1989), pp.3-11.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Takayuki MAEDA et al.: "Reduction Equilibria of Quaternary Calcium Ferrite with CO-CO_2 Gas Mixtures" Technology Reports of Kyushu University, 62(1989), pp.697-704.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Yoichi ONO: "Reduction Equilibria of Malti-Component Calcium Feirite with CO-CO_2 gas mixture" Ironmaking Conference Proceedings. 48. 3-11 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 前田敬之: "4成分系カルシウムフェライトのCOーCO_2混合ガスによる還元平衡" 九州大学工学集報. 62. 697-704 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 前田敬之: 鉄と鋼. 75. 416-423 (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] Yoichi Ono: Ironmaking Proceedings. (1989)

    • Related Report
      1988 Annual Research Report

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Published: 1988-04-01   Modified: 2016-04-21  

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