| Project/Area Number |
63550227
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
電子材料工学
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
TAKEZOE Hideo Tokyo Institute of Technology, Dept. of Organic and Polymeric Materials, Associate Professor, 工学部, 助教授 (10108194)
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| Co-Investigator(Kenkyū-buntansha) |
OUCHI Yukio Tokyo Institute of Technology, Dept. of Organic and Polymeric Materials, Researc, 工学部, 助手 (60194081)
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| Project Period (FY) |
1988 – 1989
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| Project Status |
Completed (Fiscal Year 1989)
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| Budget Amount *help |
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1989: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1988: ¥1,700,000 (Direct Cost: ¥1,700,000)
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| Keywords | ferroelectric liquid crystal / electroclinic effect / smectic A phase / electro optic effect / X-ray diffraction / layer structure / X線回折 / X線線回折 |
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| Research Abstract |
In the first year of this project, we obtained the results that not only the molecular tilt but also the layer deformation are induced in the electroclinic effect.
1. Using the cells whose layers are perpendicular to the glass surfaces, the X-ray diffraction experiments were carried out. The X-ray diffraction intensity was measured under an electric field as rotating the cell with the detector fixed at the Bragg angle of the inter layer spacing. With increasing the field, two peaks appeared at the symmetry positions and the separation became wide. This fact suggests that the chevron layer structure is formed by applying the field. It was confirmed that the layer tilt angle is nearly equal to the molecular tilt angle in the low field region.
2. The above experiment gives information about the layer deformation perpendicular to the glass surfaces. The microscope observation, however, suggests the existence of the layer deformation parallel to the surfaces. To confirm this, it is necessary to observe the transmission Laue pattern. For this purpose, we are trying to detect the Laue pattern using the cells composed with very thin glasses. At this moment, the diffuse scattering due to the glasses prevents the observation of the Laue spot.
3. Since the electroclinic effect is equivalent to the excitation of the soft mode in the paraelectric phase, we should observe the divergent increase of the dielectric constant as the temperature approaches to the phase transition point. We developed the automatic system for determining dielectric constant and confirmed the behavior.
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