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Application for Micro-electronics of Polymer/(Liquid Crystal) Hybrid Thin Films

Research Project

Project/Area Number 63850182
Research Category

Grant-in-Aid for Developmental Scientific Research

Allocation TypeSingle-year Grants
Research Field 高分子物性
Research InstitutionKyushu University

Principal Investigator

KAJIYAMA Tisato  Kyushu Univ., Eng., Professor, 工学部, 教授 (60037976)

Co-Investigator(Kenkyū-buntansha) KIKUCHI Motoko  Kyushu Univ. Eng., Research Assistant, 工学部, 教務員 (20183204)
KIKUCHI Hirotsugu  Kyushu Univ., Eng., Research Associate, 工学部, 助手 (50186201)
Project Period (FY) 1988 – 1989
Project Status Completed (Fiscal Year 1989)
Budget Amount *help
¥5,100,000 (Direct Cost: ¥5,100,000)
Fiscal Year 1989: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1988: ¥4,000,000 (Direct Cost: ¥4,000,000)
KeywordsLiquid Crystal / Light Scattering / Electro-optical Effect / Display Device / Self-supported Liquid Crystal Screen / 自己支持型液晶スクリ-ン / 高分子@液晶ハイブリッド型薄膜 / 光スイッチング / 電気ー光情報変換機能 / マイクロエレクトロニクス
Research Abstract

(1) Preparation and Aggregation Structure of Polymer/(Liquid Crystal) Hybrid Thin Films Polymer/(liquid crystal ;(LC)) hybrid thin films composed of amorphous polymers and cyanobiphenyl type LCs were prepared by casting from a mixture solution. It was clear from the morphological observation and the thermal measurement that the LC phase formed a continuous phase in three dimensional network structure of the matrix polymer. The size of LC domain was controlled by the kinetic parameters during preparation process.
(2) Electro-optical Effect of Polymer/LC Hybrid Thin Films When the polymer/LC composite formed a mutual interpenetrating structure, the hybrid thin film showed remarkable light scattering. A reversible (light scattering)-(light transmission) switching was observed under off-on applied electric field, respectively. It was newly proposed that a spatial distortion of the LC directors is required to exhibit a strong light scattering state. The dielectric analysis for the hybrid thin film revealed that the light switching speed was dependent on the magnitudes of dielectric constant and electric conductivity of the matrix polymer. The response characteristics of light switching of the hybrid thin film was successfully unproved on the basis of electric properties of the hybrid thin film. The polymer/LC hybrid thin film has unique advantages as electro-optical devices in comparison with a twisted-nematic display with respect to: 1)bright display, 2)wide viewing cone angle, 3)fast decay response, 4)large area and 5)flexible.

Report

(3 results)
  • 1989 Annual Research Report   Final Research Report Summary
  • 1988 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] T.Kajiyama: "Photo-driven Active Transport of Metal Cations through polymer/(Liquid Crystal)/(Azobenzene Crown Ether)Ternary Composite Thin Films" New Polymeric Mater.1. 99-106 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.kajiyama: "Molecular Filtration of Hydrocarbon Isomers through Polymer/(Liquid Crystal)composite Membranes" J.Macromol.Sci.,Chem.A25. 583-600 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 菊地裕嗣: "高分子/液晶/(光学活性クラウンエ-テル)三元複合薄膜によるアミノ酸塩光学異性体の選択輸送" 化学工学論文集. 15. 617-622 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Kajiyama: "Aggregation States and Electro-optical Properties Based on Light Scattering of Polymer/(Liquid Crystal)Composite Films" Chem.Lett.1989. 813-816 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Kajiyama: "Functional Properties of Thin Films of Polymer/(Liquid Crystal)Composites" Frontiers of Macromolecular Science. 505-510 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] A.Miyamoto: "(Light Scattering)-(Light Transmission )Switching of Self-supported Liquid Crystalline Films" New Polymeric Mater.3. (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Kajiyama: "Photo-driven Active Transport of Metal Cations through Polymer/(Liquid Crystal)/(Azobenzene Crown Ether) Ternary Composite Thin Films" New Polymeric Mater. 1, 99-106, 1988.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Kajiyama: "Molecular Filtration of Hydrocarbon Isomers through Polymer/(Liquid Crystal) Composite Membrane" J. Macromol. Sci., Chem. A25, 583-600, 1988.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] H. Kikuchi: "Enantioselective Transport of Amino Acid Salts through Polymer/(Liquid Crystal) Composite Thin Film Containing Chiral Crown Ether" Kagaku Kogaku Ronbunshu 15, 617-622, 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Kajiyama: "Aggregation States and Electro-optical Properties Based on Light Scattering of Polymer/(Liquid Crystal) Composite Films" Chem. Lett 1989, 813-816, 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T. Kajiyama: "Functional Properties of Thin Films of Polymer/(Liquid Crystal) Composites" Frontiers of Macromol. Sci. 505-510, 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] A. Miyamoto: "(Light Scattering)-(Light Transmission) Switching of Self-supported Liquid Crystalline Films" New Polymeric Mater. 3, 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] T.Kajiyama: "Photo-driven Active Transport of Metal Cations through Polymer/(Liquid Crystal)/(Azobenzene Crown Ether) Ternary Composite Thin Films" New Polymeric Mater. 1. 99-106 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Kajiyama: "Molecular Filtration of Hydrocarbon Isomers thropgh Polymer/(Liquid Crystal)Composite Membranes" J.Macromol.Sci.,Chem.A25. 583-600 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] 菊池裕嗣: "高分子/液晶/(光学活性クラウンエ-テル)三元複合薄膜によるアミノ酸塩光学異性体の選択輸送" 化学工学論文集. 15. 617-622 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Kajiyama: "Aggregation States and Electro-optical Properties Based on Light Scattering of Polymer/(Liquid Crystal)Composite Films" Chem.Lett.1989. 813-816 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Kajiyama: "Functional Properties of Thin Films of Polymer/(Liquid Crystal)Composites" Frontiers of Macromolecular Science. 505-510 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] A.Miyamoto: "(Light Scattering)-(Light Transmission)Switching of Self-supported Liquid Crystalline Films" New Polymeric Mater.3. (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Tisato Kajiyama: Journal of Membrane Science. 36. 243-255 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Tisato Kajiyama: New Polymeric Material. 1. 99-106 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Tisato Kajiyama: Journal of Macromolecular Science-Chem.A. A25. 583-600 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Tisato Kajiyama: Chemistry Letters. (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] Tisato Kajiyama: Chemistry Letters. (1989)

    • Related Report
      1988 Annual Research Report

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Published: 1988-04-01   Modified: 2016-04-21  

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