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Evaluation of Structure-Controlled Polysiloxane Functoionality Materials

Research Project

Project/Area Number 63850184
Research Category

Grant-in-Aid for Developmental Scientific Research (B).

Allocation TypeSingle-year Grants
Research Field 高分子合成
Research InstitutionNagoya University

Principal Investigator

KAWAKAMI Yusuke  Nagoya University Associate Professor, 工学部, 助教授 (80109280)

Co-Investigator(Kenkyū-buntansha) TOYOSHIMA Nobuyuki  Menicon, Ltd., Researcher, 研究員
Project Period (FY) 1988 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥7,000,000 (Direct Cost: ¥7,000,000)
Fiscal Year 1990: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1989: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1988: ¥3,300,000 (Direct Cost: ¥3,300,000)
Keywordsmolecular design / polysiloxane / contact lens / gas permeable Membrane / liquid crystalline / relaxation time / oligosiloxane / conformation / オリゴシロキサン / 立体規則性ポリマ- / 気体透過膜 / ポリシロキサン / ポリエ-テル / 構造一機能相関 / 拡散係数 / 緩和時間 / マクロマー / グラフト重合体 / 気体透過 / 高分子液晶 / 膜 / 表面修飾 / ガラス転移温度 / 側鎖の運動性 / スピンースピン緩和 / 立体規則性ポリマー
Research Abstract

1. Relationship between structure and permeation property was established by studying the relaxation property by solid state NMR. The established principle was applied to develop materials which can be used for contact lens.
2. Characteristic property of siloxane linkage was taken advantage in molecular designing liquid crystalline polymers. Polybutadiene with siloxane spacer and mesogenic groups was found as a new class of liquid crystalline polymers.
3. Polyoxetanes with cyanobiphenyl or fluorobiphenyl were found to be liquid crystalline polymers of new class. Specially fluorine substituents are interested from the view point of anionic polymerization. This tail group will make it possible to obtain well controlled structure of liquid crystalline polymers by anionic polymerization (macromolecules, Polym. Bull.).
4. Triphenylmethyl methacrylate having alkoxy, or alkyl substituent on one of the phenyl groups were synthesized. Polymers were obtained by radical, anionic, and asymmetric selective anionic polymerizations (Polym. J.).

Report

(4 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • 1988 Annual Research Report
  • Research Products

    (86 results)

All Other

All Publications (86 results)

  • [Publications] Y.Kawakami: "Polystyrenes with pーOligoーsiloxane,ーsilane,ーgermanosiloxane,ーgermane,orーstannane,as pーSubstitituents as Matererialsfor Oxygen Permeable Membrane." J.PoIym.SciーPoIym Chem.Ed.26. 1307-1314 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami: "Polynorbornenes with OligodimehyIsiloxanyl Substituents for Selectively Oxygen Permeable Membrane Material." Polym.J.20. 285-292 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.kawakami: "Effects of the Structure of pーOligodimethylsiloxanyl Substituents of Polystyrene on Glass Transition Temperature and Oxygen Permeability of the Polymer." Polym.J.20. 685-692 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Tsukahara: "Monolayers from Graft Copolymers Having Uniform Molecular Weight Branches." Polym.J.21. 959-963 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Nunomoto: "The Regioselectivity Control in Alkylation Reactions of Indoyl Ambident Anion." J.Chem.Soc.ーPerkin. 111-114 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami: "Relationships between Structure,Permeability and Glass Transition Temperature of Oligodimethylsiloxanyl Substituted Polymers." J.Memb.Sci. 50. 189-204 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami: "Synthesis and Polymerization of Mono pーAlkoxy Substituted Triphenylmethyl Methacrylate" polym.J.22. 705-718 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami: "Smectic Liquid Crystalline Polyoxetane with Novel Mesogenic Group." Polym.Bull.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami: "Synthesis of Liquid Crystalline Polymers with Polyoxetane Main Chain." Macromolecules.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami: "Synthesis of Dicarboxylic Functionalized Polysiloxane Macromer." Polym.Bull.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami: "Polymerizability of Isomerically Trimethylsilyl Substituted Styrene." Polym.J.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資: "機能設計の立場より、新しい機能性材料を" 高分子. 37. 39-39 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資: "マクロマ-の合成と応用" 高分子. 37. 264-267 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資: "マクロマ-を用いる機能性高分子の合成" 海外高分子研究. 34. 178-182 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資: "マクロマ-はどう応用されているか" MoI. 82-88 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資: "高分子模の気体透過機能設計" 表面. 28. 201-221 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 豊島 伸行: "酸素透過性コンタクトレンズ材料" 機能材料. 253-259 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Tsuruta: "Anionic Ringーopening Polymerization in “Comprehensive Polymer Science"" Pergamon, 457-466 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Tsuruta: "Anionic Ringーopening Polymerization in "Comprehensive Polymer Science″" pergamon, 489-500 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資(分担報筆): "マクロマ-の化学と工業" アイシピ-シ-, 419 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami(分担報筆): "Macromers in “Concise Encyclopedia Polymer Science and Engineering"" Wiley Interscience, 1341 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Kawakami: "Y.Yamashita Ed.,“Chemistry and Industry of Macromonomers"" Springel,

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資: "高分子設計" 日刊工業明聞社,

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資(分担報筆): "高分子機能材料、気体分離材料" 高分子学会,

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資(分担報筆): "実験化学講座" 丸善、,

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 川上 雄資(分担執筆): "応用化学全書、分離機能材料" 朝倉書店,

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, H. Hisada, Y. Yamashita: "Polystyrenes with Oligosiloxane, silane, germanosiloxane, germane, or stannane, as Substituents as Materials for Oxygen Permeable Membrane." J. Polym. Sci. -Polym. Chem. Ed.26. 1307-1314 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, H. Toda, M. Higashino, Y. Yamashita: "Polynorbornenes with Oligodimethylsiloxanyl Substituents for Selectively Oxygen Permeable Membrane Material." Polym. J.20. 285-292 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, T. Sugisaka, Y. Yamashita: "Effects of the Structure of Oligodimethylsiloxanyl Substituents of Polystyrene on Glass Transition Temperature and Oxygen Permeability of the Polymer." Polym. J.20. 685-692 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Tsukahara, A. Hayakawa, Y. Tachibana, Y. Yamashita, R. Tatematsu: "Monolayers from Graft Copolymers Having Uniform Molecular Weight Branches." Polym. J.21. 959-963 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Nunomoto, Y. Kawakami, Y. Yamashita, H. Takeuchi, S. Eguchi: "The Regioselectivity Control in Alkylation Reactions of Indoyl Ambident Anion." J. Chem. Soc. -Perkin II. 1. 111-114 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, T. Sugisaka: "Relationships between Structure, Permeability and Glass Transition Temperature of Oligodimethylsiloxanyl Substituted Polymers." J. Memb. Sci.50. 189-204 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, A. Okada: "Synthesis and Polymerization of Mono p-Alkoxy Substituted Triphenylmethyl Methacrylate." Polym. J.22. 705-718 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, K. Takahashi: "Smectic Liquid Crystalline Polyoxetane with Novel Mesogenic Group." Polym. Bull.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, H. Hibino, K. Takahashi: "Synthesis of Liquid Crystalline Polymers with Polyoxetane Main Chain." Macromolecules.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, S. Saibara, H. Suzuki, T. Abe, Y. Yamashita: "Synthesis of Dicarboxylic Functionalized Polysiloxane Macromer." Polym. Bull.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami, Cairo Ruben Walter: "Polymerizability of Isomerically Trimethylsilyl Substituted Styrene." Polym. J.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: "New Materials by Molecular Design(in Japanese)" Kobunshi. 37. 39 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: "Synthesis and Application of Macromers(in Japanese)" Kobunshi. 37. 264-267 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: "Molecular Design of Functionality Polymers by Macromers(in Japanese)" Kaigai kobunshi kenkyu. 34. 178-182 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: "How Macromers are used in Molecular Design(in Japanese)" Mol. 82-88 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: "Design of Gas Permeability of Polymer Films(in Japanese)" Hyomen. 28. 207-221 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] N. Toyoshima, Y. Yamashita: "Materials for Highly Oxygen Permeable Contact Lens(in Japanese)" Kino zairyou. 253-259 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Tsuruta, Y. Kawakami: Pergamon. Anionic Ring-opening Polymerization in Comprehensive Polymer Science. Vol. 3.457, (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Tsuruta, Y. Kawakami: Pergamon. Anionic Ring-opening Polymerization in Comprehensive Polymer Science. Vol. 3.489, (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: Ai-Pi-Si. Chemistry and Industry of Macromers(in Japanese), (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: Wiley Interscience. Macromers in Concise Encyclopedia of Polymer Science and Engineering., 573 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: Springer. Y. Yamashita Ed., "Chemistry and Industry of Macromonomers",

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: Asakura. Materials for Separation,

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: Nikkan Kogyo Shinbun. Macromolecular Design (in Japanese),

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: Kobunshi Gakkai. Gas Separation Material (in Japanese),

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Kawakami: Maruzen. Experimental Chemistry (in Japanese),

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Nunomoto: "The Regioselectivity Control in Alkylation Reactions of Indoyl Ambident Anion." J.Chem.Soc.Perkin II. ー. 111-114 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Kawakami: "Synthesis and Polymerization of MonoーpーalkoxyーSubstituted Triphenylmethyl Methacrylate." Polym.J.22. 705-718 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Kawakami: "StructureーPermeability,Glass Transition Temperature Relationships of Oligodimethylsiloxanyl Substituted Polymers." J.Memb.Sci.50. 189-205 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Kawakami: "Smectic Liquid Crystalline Polyoxetane with Noble Mesogenic Group." Polym.Bull.

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Kawakami: "Synthesis of Liquid Crystalline Polymers with Polyoxetane Main Chain." Macromolecules.

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Kawakami: "Synthesis of Dicarboxylic Functionalized Polysiloxane Macromer." Polym.Bull.

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Kawakami: "Polymerizability of Isomerically Trimethylsilyl Substituted Styrene." Polym.J.

    • Related Report
      1990 Annual Research Report
  • [Publications] 川上 雄資: "高分子膜の気体透過機能設計" 表面. 28. 207-221 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 豊島 伸行: "酸素透過性コンタクトレンズ材料" 機能材料. ー. 253-259 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Kawakami: "Concise Encyclopedia of Polymer Science and Engineering 一部執筆 Macromers" Wiley Interscience, 2 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 川上 雄資(分担執筆): "高分子機能材料 第2章 気体分離材料" 高分子学会,

    • Related Report
      1990 Annual Research Report
  • [Publications] 川上 雄資(分担執筆): "高分子設計" 日刊工業新聞社,

    • Related Report
      1990 Annual Research Report
  • [Publications] 川上雄資: "The Regioselectivity Control in Alkylation Reactions of Indoyl Ambident Anion" J.Chem.Soc.-Perkin II. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: "Structure-Permeability,Glass Transition Temperature Relationships of Oligodimethylsiloxanyl Substituted Polymets" J.Memb.Sci.(1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: "Synthesis and Polymerization of Mono p-Substituted Triphenylmethyl Methacrylate" Polym.J.(1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: "Liquid Crystalline Polymers with Polyoxetane Main Chain" Polym.Comm.

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: "Liquid Crystalline Polymwes with Jacketed Mesogen" Polym.Comm.

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: "Synthesis and Polymerizability of Isomerically Trimethylsilyl-substituted Styrene" Polym.J.

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: "マクロマ-とグラフト重合体の設計" Mo1. 82-88 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: "マクロマ-を用いる機能性高分子の合成" 海外高分子研究.

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: "高分子膜の気体透過機能設計" 表面. 28. 209-223 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資(分担執筆): "Comprehensive Polymer Science" Pergamon, 44 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資(分担執筆): "マクロマ-の化学と工業" アイピ-シ-, 40 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資(分担執筆): "応用化学全書、分離機能材料" 朝倉書店,

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資(分担執筆): "高分子機能材料" 高分子学会編,

    • Related Report
      1989 Annual Research Report
  • [Publications] 川上雄資: J.Polym.Sci.-Polym.Chem.Ed.26. 1307-1314 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 川上雄資: Polym.J.20. 285-292 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 川上雄資: Polym.J.20. 685-692 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 川上雄資: 高分子. 37. 39-39 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 川上雄資: 高分子. 37. 264-268 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 川上雄資: Mol.(1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] 川上雄資: 海外高分子研究. (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] Y.Kawakami: "Comprehensive Polymer Science" Pergamon Press, (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] T.Tsuruta: "Comprehensive Polymer Science" Pergamon Press, (1989)

    • Related Report
      1988 Annual Research Report

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Published: 1988-04-01   Modified: 2016-04-21  

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