白色発光を設計した元素ブロックの鎖状希土類錯体の創成

• Project Area: Creation of Element-Block Polymer Materials
• Project/Area Number: 15H00760
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Aoyama Gakuin University
• Principal Investigator: 長谷川 美貴 青山学院大学, 理工学部, 教授 (70306497)
• Project Period (FY): 2015-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000); Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000); Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
• Keywords: 希土類錯体 / 発光スペクトル / 分子磁石 / 鎖型錯体 / 希土類 / 鎖状錯体

Outline of Annual Research Achievements

(1)ヘリカルな分子構造を有する希土類元素ブロックの磁気特性:希土類イオンに対し、2個のビピリジンをエチレンジアミンで架橋した配位子Lは6座でヘリカルに配位する。Eu, Tb, Gd, NdおよびHoイオンの場合に同様の分子構造を有し、LのUV励起により光アンテナとして機能し、分子内エネルギー移動を介したff発光を示す。GdLは、L自身の蛍光および燐光を理解するために重要である。すなわち、これらの一連の錯体はLの励起三重項状態を経由したエネルギー移動過程によりff発光を示す。同様の方法で、Dyを中心金属にした錯体DyLを合成した。この錯体は、先の一連の錯体と同様にヘリカルな分子構造を有する。この錯体の磁気特性に関する実験を行ったところ、単分子磁石として機能することが明らかになった。同様の実験をNdLおよびTbLについても行ったところ、TbLは常磁性であり、NdLは単分子磁石としての特性を示すことがわかった。本研究ではヘリカルな分子構造が単核金属錯体として電子スピン緩和が遅い系を構築できることを見出した。
(2)重水素化配位子を有する発光性希土類元素ブロックの合成と多型形成による発光寿命解析:希土類の発光消光の原因の一つに、分子内や溶媒の振動の倍音と共鳴消光が挙げられる。重水素化した1,10-フェナントロリンDphenのEuあるいはTb錯体は多型を形成し、その比率が軽水素phenの場合と異なることを報告している. 元素ブロックとして、これらの発光を厳密に解析していくと、発光減衰曲線は2成分の発光種として解析した時に最適であり、それらの比率は、以前報告した放射光X線粉末回折測定から得られた多型の比率と対応することが証明された。すなわち、Eu錯体の多型形成比率がEuの発光種の帰属を実験的に相関させることができた。同様の方法により、Gd錯体とTb錯体も帰属を行うことができた。

Research Progress Status

28年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

28年度が最終年度であるため、記入しない。

Research Products

• [Int'l Joint Research] Technical Univeristy of Vienna(Austria)
• [Int'l Joint Research]
• [Journal Article] Solar-Pumping Upconversion of Interfacial Coordination Nanoparticles (2017)
  • Author(s): A. Ishii*, M. Hasegawa*
  • Journal Title: Scientific Reports Volume: 7 Issue: 1 Pages: 41446-41446
  • DOI: 10.1038/srep41446
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Impact of Phenyl Groups on Oxygen-bridged V-shaped Organic Semiconductors (2017)
  • Author(s): C. Mitsui, W. Kubo, Y. Tanaka, M. Yamagishi, T. Annaka, H. Dosei, M. Yano, K. Nakamura, D. Iwasawa, M. Hasegawa, T. Takehara, T. Suzuki, H. Sato, A. Yamano, J. Takeya, T. Okamoto*
  • Journal Title: Chemistry Letters Volume: 46 Issue: 3 Pages: 338-341
  • DOI: 10.1246/cl.161015
  • NAID: 130005436525
  • Peer Reviewed
• [Journal Article] Copper(II), Nickel(II) and Cobalt(II)/(III) (pyridine-2-yl)-1,2,4-triazol-3-yl]methane (2017)
  • Author(s): A. N. Gusev, V. F. Shul'gin, I. O. Ryush, M. Hasegawa, M. A. Kiskin, N. N. Efinov, K. A. Lyssenko, I. L. Eremenko, W. Linert*
  • Journal Title: Europian Journal of Inorganic Chemistry Volume: 2017 Issue: 3 Pages: 704-712
  • DOI: 10.1002/ejic.201601107
  • Peer Reviewed
• [Journal Article] Polymorphism-based luminescence of lanthanide complexes with a dueterated 1,10-phenanthroline (2017)
  • Author(s): S. Ogata, A. Ishii, C.L.Lu, T.Kondo, N.Yajima, M. Hasegawa*
  • Journal Title: Journal of Photochemistry and Photobiology A: Chemistry Volume: 334 Pages: 55-60
  • DOI: 10.1016/j.jphotochem.2016.10.031
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Large edge magnetism in oxidized few-layer black phosphorus nanomeshes (2017)
  • Author(s): Y. Nakanishi, A. Ishi, C. Ohata, D. Soriano, R. Iwaki, K. Nomura, M. Hasegawa, T. Nakamura, S. Katsumoto, S. Roche and J. Haruyama
  • Journal Title: Nano Res. Volume: 10 Issue: 2 Pages: 718-728
  • DOI: 10.1007/s12274-016-1355-8
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Alkylated oxygen-bridged V-shaped molecules: impacts of the substitution position and length of the alkyl chains on the crystal structures ad fundamental properties in aggregated forms (2017)
  • Author(s): C. Mitsui, T. Annaka, K. Nakamura, M. Mitani, D. Hashizume, K. Nakahara, M. Yamagishi, T. Ueno, Y. Tanaka, M. Yano, D. Iwasawa, M. Hasegawa, H. Sato, A. Yamano, J. Takeya, T. Okamoto
  • Journal Title: Polymer Journal Volume: 49 Issue: 1 Pages: 215-221
  • DOI: 10.1038/pj.2016.105
  • Peer Reviewed
• [Journal Article] Slow magnetic relaxation of lanthanide(III) complexes with a helical ligand (2016)
  • Author(s): H. Wada, S. Ooka, D. Iwasawa, M. Hasegawa*, and T. Kajiwara*
  • Journal Title: Magnetochemistry Volume: 2 Issue: 4 Pages: 43-54
  • DOI: 10.3390/magnetochemistry2040043
  • Peer Reviewed / Open Access
• [Journal Article] The Ethanol-induced Interfacial Reduction of a Europium Complex on SiO2 Nanoparticles (2016)
  • Author(s): A. Ishii, M. Hasegawa
  • Journal Title: Chemistry Letters Volume: 45 Pages: 1265-1267
  • NAID: 130005509530
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Quality Evaluation for Japanese Sake Using Taste Sensor with LB Films (2016)
  • Author(s): M. Hiroki, H. Uchida, Y. Hasegawa, M. Hasegawa
  • Journal Title: The Institute of Electrical Engineers Japan Transactions Volume: 4
  • NAID: 130005149056
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Mechanoresponsive liquid crystals exhibiting reversible luminescent color changes at ambient temperature (2016)
  • Author(s): M. Mitani, S. Ogata, S. Yamane, M. Yoshio, M. Hasegawa, and T. Kato
  • Journal Title: J. Mater. Chem. C Volume: 4 Issue: 14 Pages: 2751-2760
  • DOI: 10.1039/c5tc03578c
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Synthesis and characterization of a family of Fe(II) tetrazole complexes [Fe(C6mtz)6]X2 (X = BF4ˉ, ClO4ˉ, PF6ˉ) (2015)
  • Author(s): M. T.-Kryeziu, A. Caneschi, M. Fittipaldi, G. Spina, M. Lantieri, M. Weil, M. Hasegawa, and W. Linert
  • Journal Title: J. Coord. Chem. Volume: 68 Pages: 3457-3471
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] An Interfacial Europium Complex on SiO2 Nanoparticles: Reduction-Induced Blue Emission System (2015)
  • Author(s): A. Ishii and M. Hasegawa
  • Journal Title: Sci. Rep. Volume: 5 Pages: 11714-11714
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Cation-Tuned Stimuli Responsive and Optical Properties of Supramolecular Hydrogels (2015)
  • Author(s): M. Yamanaka, K. Yanai, Y. Zama, J. Tsuchiyagaito, M. Yoshida, A. Ishii, and M. Hasegawa
  • Journal Title: Chem. Asian J. Volume: 10 Pages: 1299-1303
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 希土類錯体の開発と光機能：界面における錯形成を利用した発光性ナノ粒子の開発 (2015)
  • Author(s): 石井あゆみ, 長谷川美貴
  • Journal Title: 化学工業 Volume: 9 Pages: 18-22
• [Journal Article] 希土類金属錯体発光とその偏光発光発現 (2015)
  • Author(s): 長谷川美貴
  • Journal Title: 応用物理 Volume: 84 Pages: 736-739
  • NAID: 130007718815
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 禁制遷移を光らせる (2015)
  • Author(s): 長谷川美貴、石井あゆみ
  • Journal Title: 光アライアンス Volume: 26 Pages: 17-22
• [Presentation] バリンアミド骨格を導入したユウロピウム錯体の構造および光学キラル特性 (2017)
  • Author(s): 川口拓馬, 岩澤大地, 岩村崇高, 石井あゆみ, 野崎浩一, 長谷川美貴
  • Organizer: 日本化学会 第97春季年会
  • Place of Presentation: 慶応大学, 神奈川
  • Year and Date: 2017-03-16
• [Presentation] Upconversion luminescence of Tm/Yb oxide nanoparticles coordinated with anthraquinone dyes (2017)
  • Author(s): Miyu Komaba, Ayumi Ishii, Miki Hasegawa
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応大学, 神奈川
  • Year and Date: 2017-03-16
• [Presentation] Luminescence properties of the europium complex on the self-assembled monolayers, (2017)
  • Author(s): Masaaki Iwai, Ayumi Ishii, Miki Hasegawa
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応大学, 神奈川
  • Year and Date: 2017-03-16
• [Presentation] バリンアミド骨格を導入したユウロピウム錯体の構造および光学キラル特性 (2017)
  • Author(s): 川口拓馬, 岩澤大地, 岩村崇高, 石井あゆみ, 野崎浩一, 長谷川美貴
  • Organizer: 日本化学会 第97春季年会
  • Place of Presentation: 慶應義塾大学、神奈川
  • Year and Date: 2017-03-16
• [Presentation] リノール酸をカウンターアニオンとしたEu錯体の構造と発光特性 (2017)
  • Author(s): 小谷宗平, 石井あゆみ, 長谷川美貴
  • Organizer: 日本化学会 第97春季年会
  • Place of Presentation: 慶應義塾大学、神奈川
  • Year and Date: 2017-03-16
• [Presentation] 3.Luminescence spectra of amphiphilic europium complexes with various molecular size (2017)
  • Author(s): Shuhei Ogata, Ryota Tanabe, Ayumi Ishii, Miki Hasegawa
  • Organizer: 日本化学会 第97春季年会
  • Place of Presentation: 慶應義塾大学、神奈川
  • Year and Date: 2017-03-16
• [Presentation] Luminescent Element Blocks of Rare Earth Complexes with Helical Complexes (2017)
  • Author(s): Miki Hasegawa, Shuhei Ogata, Ayumi Ishii
  • Organizer: The 2nd International Symposium on Polymeric Materials Based on Element-Blocks
  • Place of Presentation: 60th Anniversary Hall, Kyoto Institute of Technology
  • Year and Date: 2017-01-18
• [Presentation] Molecular design strategies for the enhancement of the polarized luminescence of rare earth complexes (2016)
  • Author(s): Miki Hasegawa
  • Organizer: Phosphore Safari 2016
  • Place of Presentation: Hong Kong, China
  • Year and Date: 2016-11-28
  • Int'l Joint Research / Invited
• [Presentation] 「光る」を知って光らせる：エネルギーを分子の世界でみてみよう (2016)
  • Author(s): 長谷川美貴
  • Organizer: 平成28年度第10回光エネルギーセミナー
  • Place of Presentation: 近畿大学、大阪
  • Year and Date: 2016-11-26
  • Invited
• [Presentation] 界面を分子制御した元素ブロックによる発光性希土類の機能制御 (2016)
  • Author(s): 長谷川美貴
  • Organizer: 島津新素材セミナー_元素ブロック
  • Place of Presentation: 早稲田大学、東京
  • Year and Date: 2016-11-25
  • Invited
• [Presentation] 希土類の判定な構造と発光のためのための分子設計と未来材料構築 (2016)
  • Author(s): 長谷川美貴
  • Organizer: 第11回学際領域における分子イメージングフォーラム
  • Place of Presentation: 宇宙航空研究開発機構（調布）
  • Year and Date: 2016-11-06
  • Invited
• [Presentation] ウニトゲのメソクリスタルを利用した希土類錯体の自己組織化と発光スペクトル (2016)
  • Author(s): 尾形周平, 田辺 凌太, 石井 あゆみ, 長谷川 美貴
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 慶応大学, 神奈川
  • Year and Date: 2016-09-15
• [Presentation] Enhanced luminescence of assembled amphiphilic Eu complexes in the mesocrystal of sea urchin spines (2016)
  • Author(s): Shuhei Ogata, Ryota Tanabe,Ayumi Ishii, Miki Hasegawa
  • Organizer: 錯体化学会第66回討論会
  • Place of Presentation: 福岡大学
  • Year and Date: 2016-09-10
• [Presentation] 界面Eu錯体を導入したナノ粒子の還元型発光機構 (2016)
  • Author(s): 石井あゆみ, 長谷川美貴
  • Organizer: 2016年光化学討論会
  • Place of Presentation: 東京大学
  • Year and Date: 2016-09-06
• [Presentation] Soichi Mizushima, Shogo Yamane, Masato Mitani, Junya Uchida, Shuhei Ogata, Ayumi Ishii, Takashi Kato, Miki Hasegawa (2016)
  • Author(s): The Luminescence Mechanism of a Ternary Tb Complex with Hexadentate Aromatic Ligand and Mesogenic Moiety
  • Organizer: 2016年光化学討論会
  • Place of Presentation: 東京大学
  • Year and Date: 2016-09-06
• [Presentation] ヒドロゲル希土類複合体の発光発現 (2016)
  • Author(s): 長谷川美貴, 石井あゆみ、山中正道
  • Organizer: 第28回配位化合物の光化学討論会
  • Place of Presentation: 京都工芸繊維大学
  • Year and Date: 2016-08-08
• [Presentation] 界面 Eu 錯体を導入した TiO2ナノ多孔膜の発光と光電変換機能 (2016)
  • Author(s): 石井あゆみ, 堺達郎、長谷川美貴
  • Organizer: 第28回配位化合物の光化学討論会
  • Place of Presentation: 京都工芸繊維大学
  • Year and Date: 2016-08-08
• [Presentation] ヘリカルなテルビウム錯体の液晶化に伴う発光増強と機構解明 (2016)
  • Author(s): 水島 颯一, 山根 祥吾, 三谷 真人, 内田 淳也, 尾形 周平, 石井 あゆみ, 加藤 隆史, 長谷川 美貴
  • Organizer: 第28回配位化合物の光化学討論会
  • Place of Presentation: 京都工芸繊維大学
  • Year and Date: 2016-08-08
• [Presentation] 重水素化 1,10-フェナントロリン希土類錯体の多形形成による励起エネルギー緩和過程 に関する研究 (2016)
  • Author(s): 尾形周平 , Lu Ling Cai, 近藤崇弘、矢島奈歩、石井あゆみ、長谷川 美貴
  • Organizer: 第28回配位化合物の光化学討論会
  • Place of Presentation: 京都工芸繊維大学
  • Year and Date: 2016-08-08
• [Presentation] Luminescence Properties of Praseodymium Complexes with a Series of Hexadentate N6-Ligands (2016)
  • Author(s): Miki Hasegawa, Shoya Sakurai, Masafumi Andrew Yamaguchi, Shuhei Ogata, Ayumi Ishii
  • Organizer: International Conference on Coordination Chemistry 2016
  • Place of Presentation: Brest, France
  • Year and Date: 2016-07-03
  • Int'l Joint Research
• [Presentation] 希土類錯体の分子設計と環境特異性による発光変調 (2016)
  • Author(s): 長谷川美貴
  • Organizer: 静岡大学理学部化学セミナー
  • Place of Presentation: 静岡大学、静岡
  • Year and Date: 2016-06-15
  • Invited
• [Presentation] Isotope Effect on the Luminescence Mechanism of Lanthanide Complexes with Deuterated 1,10-Phenanthroline in the Solid State (2016)
  • Author(s): Shuhei Ogata, Ayumi Ishii, Miki Hasegawa
  • Organizer: Rare Earths 2016 in Sapporo
  • Place of Presentation: Hokkaido University, Sapporo
  • Year and Date: 2016-06-05
  • Int'l Joint Research
• [Presentation] Emission Enhancement Mechanism of Lanthanide Complexes Having Helical Molecular Structures in an Ionic Liquid (2016)
  • Author(s): Yuki Hasegawa, Miho Hatanaka, Ayumi Ishii, Miki Hasegawa
  • Organizer: Rare Earths 2016 in Sapporo
  • Place of Presentation: Hokkaido University, Sapporo
  • Year and Date: 2016-06-05
  • Int'l Joint Research
• [Presentation] Development of a Mixed Lanthanide Complex in Single Crystal with Dual Luminescence (2016)
  • Author(s): Daichi Iwasawa, Ayumi Ishii, Miki Hasegawa
  • Organizer: Rare Earths 2016 in Sapporo
  • Place of Presentation: Hokkaido University, Sapporo
  • Year and Date: 2016-06-05
  • Int'l Joint Research
• [Presentation] An Interfacial Eu Complex on a Mesoporous TiO2 Nano Film for Photo-emission and Photo-electric Conversion Devices (2016)
  • Author(s): Ayumi Ishii, Miki Hasegawa
  • Organizer: Rare Earths 2016 in Sapporo
  • Place of Presentation: Hokkaido University, Sapporo
  • Year and Date: 2016-06-05
  • Int'l Joint Research
• [Presentation] Circularly Polarized ff-Luminescence of Europium Complexes with L-Valine Amide Derivative of 2,2’-Bipyridine (2016)
  • Author(s): Takuma Kawaguchi, Daichi Iwasawa, Ayumi Ishii, Miki Hasegawa
  • Organizer: Rare Earths 2016 in Sapporo
  • Place of Presentation: Hokkaido University, Sapporo
  • Year and Date: 2016-06-05
  • Int'l Joint Research
• [Presentation] New Aspects to Keep the Molecular Structure and Luminescence of Helicate Lanthanide Complexes (2016)
  • Author(s): Miki Hasegawa
  • Organizer: Rare Earths 2016 in Sapporo
  • Place of Presentation: Hokkaido University, Sapporo
  • Year and Date: 2016-06-05
  • Int'l Joint Research
• [Presentation] 25.Reduction-Induced Blue Emission System of Interfacial Europium Complex on SiO2 Nanoparticles (2016)
  • Author(s): Ayumi Ishii, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] Circularly Polarized Luminescence of a Tetradentate Europium Complex with L-Valine Derivative (2016)
  • Author(s): Takuma Kawaguchi, Daichi Iwasawa, Munetaka Iwamura, Ayumi Ishii, Koichi Nozaki, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] Metal - to - Metal Energy Transfer in a Mixed Crystal with two lanthanide complexes (2016)
  • Author(s): Daichi Iwasawa, Ayumi Ishii, Kunihisa Sugimoto, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] Development of a fusion material of nacre layers dyed with green emissive terbium complexes (2016)
  • Author(s): Takahiro Kondo, Ayumi Ishii, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] Investigation of Luminescent Lanthanide Complexes Associated with the Molecular Symmetry (2016)
  • Author(s): Naho Yajima, Ayumi Ishii, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] Linearly Polarized Luminescence of Europium Complexes in the Langmuir-Blodgett film (2016)
  • Author(s): Kazuki Kondo, Ayumi Ishii, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] Luminescence Behavior of Helical Terbium Complexes with Mesogenic Ligands (2016)
  • Author(s): Soichi Mizushima, Shogo Yamane, Masato Mitani, Junya Uchida, Shuhei Ogata, Ayumi Ishii, Takashi Kato, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] Emission Enhancement of a Europium Complex Having a Helical Molecular Structure in Ionic Liquids (2016)
  • Author(s): Yuki Hasegawa, Ayumi Ishii, Miho Hatanaka, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] Luminescence of lanthanide complexes with deuterated phenanthroline (2016)
  • Author(s): Shuhei Ogata, Ayumi Ishii, C. L. Lu, Takahiro Kondo, Naho Yajima, Miki Hasegawa
  • Organizer: International Symposium on Lanthanide Coordination Chemistry
  • Place of Presentation: Aoyama Gakuin University, Kanagawa
  • Year and Date: 2016-06-04
  • Int'l Joint Research
• [Presentation] デブリ衝突により発光色が変調する希土類化合物の開発への挑戦と現状 (2016)
  • Author(s): 長谷川美貴
  • Organizer: 宇宙科学談話会（第40回）
  • Place of Presentation: 宇宙航空研究開発機構（相模原）
  • Year and Date: 2016-03-09
  • Invited
• [Presentation] Fusion materials of lanthanide complexes with luminescence (2015)
  • Author(s): Miki Hasegawa
  • Organizer: Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-15
  • Int'l Joint Research / Invited
• [Presentation] 「光る」を知って光らせる：希土類発光のための錯体設計と未来材料への展開 (2015)
  • Author(s): 長谷川美貴
  • Organizer: 北陸先端大 マテリアルサイエンス系 研究科セミナー
  • Place of Presentation: 北陸先端科学技術大学院大学
  • Year and Date: 2015-11-20
  • Invited
• [Presentation] Lanthanides' Luminescence in Molecules (2015)
  • Author(s): Miki Hasegawa
  • Organizer: Fusion Materials Symposium 2015
  • Place of Presentation: 東京大学
  • Year and Date: 2015-09-19
  • Int'l Joint Research / Invited
• [Presentation] 希土類を用いた融合マテリアルの発光機能創成 (2015)
  • Author(s): 長谷川美貴
  • Organizer: 高分子討論会
  • Place of Presentation: 東北大学
  • Year and Date: 2015-09-15
  • Invited
• [Remarks] 青山学院大学理工学部・化学生命科学科 長谷川美貴研究室
  • URL: http://www.chem.aoyama.ac.jp/Chem/ChemHP/inorg2/
• [Remarks] 青山学院大学理工学部 長谷川美貴
  • URL: http://www.agnes.aoyama.ac.jp/bio/faculty/hasegawa.html
• [Remarks] 青山学院大学 長谷川美貴研究室
  • URL: http://www.chem.aoyama.ac.jp/Chem/ChemHP/inorg2/
• [Patent(Industrial Property Rights)] コアシェル型Ln錯体ナノ粒子 (2017)
  • Inventor(s): 長谷川美貴、石井あゆみ
  • Industrial Property Rights Holder: 長谷川美貴、石井あゆみ
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2017-065639
  • Filing Date: 2017-03-29