芳香族性の新たな物性指標を指向したアザポルフィリノイドの創出

• Project Area: pi-System Figuration: Control of Electron and Structural Dynamism for Innovative Functions
• Project/Area Number: 15H01001
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyushu University
• Principal Investigator: 清水 宗治 九州大学, 工学研究院, 准教授 (70431492)
• Project Period (FY): 2015-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000); Fiscal Year 2016: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000); Fiscal Year 2015: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
• Keywords: 有機π電子系分子 / 芳香族性 / アザポルフィリン / 磁気円偏光二色性スペクトル / 紫外可視吸収スペクトル

Outline of Annual Research Achievements

本研究では芳香族性の新たな物性指標を確立するために、①明瞭なQ帯吸収の発現を指向したアザポルフィリン類縁体の合成と②MCD分光法を用いた光吸収特性と電子構造の相関解明を重点課題として研究を行っている。研究計画２年目である本年度は１年目に得られた合成研究の知見を基に、ポルフィリンのメゾ位の元素を炭素あるいは窒素以外の元素に置き換えた類縁体の合成に挑戦した。アザポルフィリンの合成前駆体であるジブロモジピリンの反応性を利用することで、5位と15位に酸素を有する5,15-ジオキサポルフィリンの合成に世界で初めて成功した。この新規ポルフィリン類縁体は酸素の非共有電子対が環状π共役系に組み込まれることで、全体として20π電子系を有しており、それに起因して、弱いながらも明確なヒュッケル反芳香族性を示すことを明らかにした。この分子の興味深い反芳香族性は今後も本領域公募研究において、継続して行う予定である。また合成の観点からも、この5,15-ジオキサポルフィリン合成法は他の含酸素ポルフィリン類縁体の合成へと展開可能であると考えており、現在、これを利用した環拡張類縁体の合成研究を展開している。①ではこれ以外にアザポルフィリン類のπ共役面としての平滑性に着目した集積体の合成研究についても行った。外部刺激応答部位として、テトラチアフルバレン（TTF）を組み込むことで、TTF部位の酸化に伴い、分子配向が制御可能な集積体の創出に成功しており、現在、その諸物性の解明を行っている。②においては領域内共同研究として、ノルコロール二量体のMCDスペクトルについて、理論的な解釈を行ったほか、①で合成した新規アザポルフィリン類縁体についても測定を行った。

Research Progress Status

28年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

28年度が最終年度であるため、記入しない。

Research Products

• [Int'l Joint Research] National Taiwan University(Taiwan)
• [Int'l Joint Research] National Taiwan University(Taiwan)
• [Journal Article] Phenylene-Bridged Expanded Porphyrazines (2017)
  • Author(s): Fumiya Iizuka, Yuto Kage, Nagao Kobayashi, Hiroyuki Furuta, Soji Shimizu
  • Journal Title: ChemPlusChem Volume: 印刷中 Issue: 7 Pages: 1021-1024
  • DOI: 10.1002/cplu.201600482
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Recent Advances in Subporphyrins and Triphyrin Analogues: Contracted Porphyrins Comprising Three Pyrrole Rings (2017)
  • Author(s): Soji Shimizu
  • Journal Title: Chemical Reviews Volume: 117 Issue: 4 Pages: 2730-2784
  • DOI: 10.1021/acs.chemrev.6b00403
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Polymeric Self-Assemblies with Boron-Containing Near-Infrared Dye Dimers for Photoacoustic Imaging Probes (2017)
  • Author(s): K. Miki, A. Enomoto, T. Inoue, T. Nabeshima, S. Saino, S. Shimizu, H. Matsuoka, K. Ohe
  • Journal Title: Biomacromolecules Volume: 18 Issue: 1 Pages: 249-256
  • DOI: 10.1021/acs.biomac.6b01568
  • Peer Reviewed
• [Journal Article] Supramolecular Dimeric Structures of Pyrazole-containing Meso-Oxo Carbaphlorin Analogues (2016)
  • Author(s): Ishida, M.; Fujimoto, H.; Morimoto, T.; Mori, S.; Toganoh, M.; Shimizu, S.; Furuta, H.
  • Journal Title: Supramol. Chem. Volume: 28 Issue: 1 Pages: 8-16
  • DOI: 10.1080/10610278.2016.1158408
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Stacked antiaromatic porphyrins (2016)
  • Author(s): Ryo Nozawa, Hiroko Tanaka, Won-Young Cha, Yongseok Hong, Ichiro Hisaki, Soji Shimizu, Ji-Young Shin, Tim Kowalczyk, Stephan Irle, Dongho Kim, Hiroshi Shinokubo
  • Journal Title: Nature Communications Volume: 7 Issue: 1 Pages: 13620-13620
  • DOI: 10.1038/ncomms13620
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Pyrene-Bridged Boron Subphthalocyanine Dimers: Combination of Planar and Bowl-Shaped -Conjugated Systems for Creating Uniquely Curved -Conjugated Systems (2016)
  • Author(s): Nakano, S.; Kage, Y.; Furuta, H.; Kobayashi, N.; Shimizu, S.
  • Journal Title: Chem. Eur. J Volume: 22 Issue: 23 Pages: 7706-7710
  • DOI: 10.1002/chem.201600548
  • Peer Reviewed
• [Journal Article] A novel isoindole-containing polyaromatic hydrocarbon unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin (2016)
  • Author(s): Yuta Shiina, Hideaki Karasaki, Shigeki Mori, Nagao Kobayashi, Hiroyuki Furuta, Soji Shimizu
  • Journal Title: Journal of Porphyrins and Phthalocyanines Volume: 20 Issue: 08n11 Pages: 1049-1054
  • DOI: 10.1142/s1088424616500541
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Rational Molecular Design Towards vis/NIR Absorption and Fluorescence using Pyrrolopyrrole aza-BODIPY and its Highly Conjugated Structures for Organic Photovoltaics (2015)
  • Author(s): S. Shimizu, T. Iino, A. Saeki, S. Seki, N. Kobayashi
  • Journal Title: Chemistry A European Journal Volume: 21 Issue: 7 Pages: 2893-2904
  • DOI: 10.1002/chem.201405761
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Asymmetric core-expanded aza-BODIPY analogues: facile synthesis and optical properties (2015)
  • Author(s): H. Liu, H. Lu, Z. Zhou, S. Shimizu, Z. Li, N. Kobayashi, Z. Shen
  • Journal Title: Chemical Communications Volume: 51 Issue: 9 Pages: 1713-1716
  • DOI: 10.1039/c4cc06704e
  • Peer Reviewed / Open Access
• [Journal Article] Cyclophanes Containing Bowl-Shaped Aromatic Chromophores: Three Isomers of anti-[2.2](1,4)Subphthalocyaninophane (2015)
  • Author(s): Q. Liu, S. Shimizu, N. Kobayashi
  • Journal Title: Angewandte Chemie International Edition Volume: 54 Issue: 17 Pages: 5187-5191
  • DOI: 10.1002/anie.201411510
  • Peer Reviewed
• [Journal Article] Ring-fused porphyrins: extension of π-conjugation significantly affects the aromaticity and optical properties of the porphyrin π-systems and Lewis acidity of the central metal ions (2015)
  • Author(s): Yuta Saegusa, Tomoya Ishizuka, Keiyu Komamura, Soji Shimizu, Hiroaki Kotani, Nagao Kobayashi, Takahiko Kojima
  • Journal Title: PCCP Volume: 17 Issue: 22 Pages: 15001-15011
  • DOI: 10.1039/c5cp01420d
  • NAID: 120007130097
  • Peer Reviewed
• [Journal Article] Benzo[c,d]indole-Containing Aza-BODIPY Dyes: Asymmetrization-Induced Solid-State Emission and Aggregation-Induced Emission Enhancement as New Properties of a Well-Known Chromophore (2015)
  • Author(s): Soji Shimizu, Ai Murayama, Takuya Haruyama, Taku Iino, Shigeki Mori, Hiroyuki Furuta, Nagao Kobayashi
  • Journal Title: Chem. Eur. J. Volume: 21 Issue: 37 Pages: 12996-13003
  • DOI: 10.1002/chem.201501464
  • Peer Reviewed
• [Journal Article] Synthesis of A Tetrabenzotetraaza[8]circulene by "Fold-in" Oxidative Fusion Reaction (2015)
  • Author(s): Fengkun Chen, Yong Seok Hong, Soji Shimizu, Dongho Kim, Takayuki Tanaka, and Atsuhiro Osuka
  • Journal Title: Angewandte Chemie International Edition Volume: 54 Issue: 36 Pages: 10639-10642
  • DOI: 10.1002/anie.201505124
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Core-modified phthalocyanines and subphthalocyanines: a synthetic strategy towards core-modification and novel properties arising from the inner ring-expansion (2015)
  • Author(s): Soji Shimizu, Hiroyuki Furuta
  • Journal Title: Macroheterocycles Volume: 8 Issue: 4 Pages: 332-342
  • DOI: 10.6060/mhc151102s
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] Synthesis of Dinaphthosubtriazachlorin and its Chiroptical Properties (2017)
  • Author(s): 王叶梅，三浦瑛貴，古田弘幸，小林長夫，清水宗治
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2017-03-16
• [Presentation] 広帯域光吸収を示すピロロピロール-アザ-BODIPY二量体の合成および光学特性 (2017)
  • Author(s): 鹿毛悠冬，古田弘幸，清水宗治
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2017-03-16
• [Presentation] 含酸素ポルフィリン類縁体の合成 (2017)
  • Author(s): 西山彰秀，福田雅弥，森重樹，古田弘幸，清水宗治
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2017-03-16
• [Presentation] テトラチアフルバレン縮環フタロシアニン類縁体の合成と酸化還元特性 (2017)
  • Author(s): 日永田泰斗，古田弘幸，清水宗治
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2017-03-16
• [Presentation] N-混乱ポルフィリン-アザジピリン複合体の合成とその錯化挙動 (2017)
  • Author(s): 福田雅弥，清水宗治，古田弘幸
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2017-03-16
• [Presentation] TTF 縮環サブフタロシアニンを用いた超分子ポリマーの構築 (2017)
  • Author(s): 内原岬哉，古川貢，古田弘幸，清水宗治
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2017-03-16
• [Presentation] Synthesis of N-Confused Porphyrin-aza-Dipyrrin Hybrid and its Metal Complexes (2017)
  • Author(s): Soji Shimizu, Masaya Fukuda, Hiroyuki Furuta
  • Organizer: The 3rd International Symposium on π-System Figuration
  • Place of Presentation: Nagoya
  • Year and Date: 2017-01-27
  • Int'l Joint Research
• [Presentation] Supramolecular Polymer Formation of TTF-Annulated Subphthalocyanine (2017)
  • Author(s): Soji Shimizu, Koya Uchihara, Hiroyuki Furuta
  • Organizer: The 2nd International Symposium on Polymeric Materials Based on Element-Blocks
  • Place of Presentation: Kyoto
  • Year and Date: 2017-01-18
  • Int'l Joint Research
• [Presentation] TTF 縮環サブフタロシアニンを用いた超分子ポリマーの構築 (2017)
  • Author(s): 内原岬哉，古川貢，古田弘幸，清水宗治
  • Organizer: The 1st CMS-ExOM Joint Symposium
  • Place of Presentation: 福岡
  • Year and Date: 2017-01-17
• [Presentation] フッ素軸配位子を有するTTF縮環サブフタロシアニンを用いた超分子ポリマーの構築 (2016)
  • Author(s): 内原岬哉，古川貢、古田弘幸，清水宗治
  • Organizer: 第43回有機典型元素化学討論会
  • Place of Presentation: 仙台
  • Year and Date: 2016-12-08
• [Presentation] TTF縮環ケイ素フタロシアニン多量体の酸化還元による分子配列制御 (2016)
  • Author(s): 鹿毛悠冬，椎名祐太，小林長夫，古田弘幸，清水宗治
  • Organizer: 第43回有機典型元素化学討論会
  • Place of Presentation: 仙台
  • Year and Date: 2016-12-08
• [Presentation] TTF縮環フタロシアニン類縁体の分子配向制御 (2016)
  • Author(s): 清水宗治
  • Organizer: π造形科学 第三回公開シンポジウム
  • Place of Presentation: 仙台
  • Year and Date: 2016-10-21
• [Presentation] TTF縮環フタロシアニン類を基盤とした外部刺激応答性分子ワイヤの創出 (2016)
  • Author(s): 清水宗治，内原岬哉，古田弘幸
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 横浜
  • Year and Date: 2016-09-14
  • Invited
• [Presentation] ピロロピロール部位を組み込んだアザジピリン亜鉛錯体の合成および超分子ポリマー形成 (2016)
  • Author(s): 唐﨑秀朗，古田弘幸，清水宗治
  • Organizer: 第27回基礎有機化学討論会
  • Place of Presentation: 広島
  • Year and Date: 2016-09-01
• [Presentation] TTF縮環サブフタロシアニンを用いた超分子ポリマーの構築 (2016)
  • Author(s): 内原岬哉，古田弘幸，清水宗治
  • Organizer: 第27回基礎有機化学討論会
  • Place of Presentation: 広島
  • Year and Date: 2016-09-01
• [Presentation] アザジピリン様骨格を含むN-混乱ポルフィリン誘導体の合成とその錯化挙動 (2016)
  • Author(s): 福田雅弥，清水宗治，古田弘幸
  • Organizer: 第27回基礎有機化学討論会
  • Place of Presentation: 広島
  • Year and Date: 2016-09-01
• [Presentation] ピロロピロール-アザ-BODIPY二量体の合成および吸収スペクトルの広帯域化 (2016)
  • Author(s): 鹿毛悠冬，古田弘幸，清水宗治
  • Organizer: 第27回基礎有機化学討論会
  • Place of Presentation: 広島
  • Year and Date: 2016-09-01
• [Presentation] ピロロピロール-アザ-BODIPYの可視および近赤外領域における吸収特性制御 (2016)
  • Author(s): 鹿毛悠冬，森重樹，古田弘幸，清水宗治
  • Organizer: 有機合成化学協会九州山口支部 第28回若手研究者のためのセミナー
  • Place of Presentation: 福岡
  • Year and Date: 2016-08-27
• [Presentation] 外部及び内部に配位サイトを有するN-混乱ポルフィリン-アザ-ジピリン複合体の合成 (2016)
  • Author(s): 福田雅弥，清水宗治，古田弘幸
  • Organizer: 有機合成化学協会九州山口支部 第28回若手研究者のためのセミナー
  • Place of Presentation: 福岡
  • Year and Date: 2016-08-27
• [Presentation] TTF縮環サブフタロシアニンを用いた超分子ポリマーの構築 (2016)
  • Author(s): 内原岬哉，古田弘幸，清水宗治
  • Organizer: 有機合成化学協会九州山口支部 第28回若手研究者のためのセミナー
  • Place of Presentation: 福岡
  • Year and Date: 2016-08-27
• [Presentation] TTF縮環サブフタロシアニンの合成とその超分子構造の構築 (2016)
  • Author(s): 清水宗治
  • Organizer: 構造有機若手研究者 研究会2016
  • Place of Presentation: 札幌
  • Year and Date: 2016-07-30
• [Presentation] Design and Creation of Novel Porphyrinoids Based on the Structure-Property Relationship (2016)
  • Author(s): Soji Shimizu
  • Organizer: Ninth International Conference on Porphyrins and Phthalocyanines (ICPP-9)
  • Place of Presentation: Nanjing, China
  • Year and Date: 2016-07-03
  • Int'l Joint Research / Invited
• [Presentation] Synthesis of a N-Confused Porphyrin-aza-Dipyrrin Conjugate: a Porphyrin Analogue Bearing Exterior and Interior Coordination Sites (2016)
  • Author(s): Masaya Fukuda, Soji Shimizu, Hiroyuki Furuta
  • Organizer: Ninth International Conference on Porphyrins and Phthalocyanines (ICPP-9)
  • Place of Presentation: Nanjing, China
  • Year and Date: 2016-07-03
  • Int'l Joint Research
• [Presentation] Pyrrolopyrrole Aza-BODIPY Monomers and Dimers : Control of Absorption in the Far-red and NIR Regions (2016)
  • Author(s): Yuto Kage, Shigeki Mori, Hiroyuki Furuta, Soji Shimizu
  • Organizer: Ninth International Conference on Porphyrins and Phthalocyanines (ICPP-9)
  • Place of Presentation: Nanjing, China
  • Year and Date: 2016-07-03
  • Int'l Joint Research
• [Presentation] Synthesis of Novel aza-BODIPY Analogues from Lactams and Their Intriguing Optical and Electrochemical Properties (2016)
  • Author(s): Soji Shimizu
  • Organizer: Symposium of Fluoro-Boron-Silicon Dyes
  • Place of Presentation: Hangzhou, China
  • Year and Date: 2016-07-01
  • Int'l Joint Research / Invited
• [Presentation] TTF縮環サブフタロシアニンを用いた超分子ポリマーの構築 (2016)
  • Author(s): 内原岬哉，古田弘幸，清水宗治
  • Organizer: 第53回化学関連支部合同九州大会
  • Place of Presentation: 北九州
  • Year and Date: 2016-06-27
• [Presentation] TTF縮環サブフタロシアニンの合成及び酸化還元特性 (2016)
  • Author(s): 内原岬哉、古田弘幸、清水宗治
  • Organizer: 日本化学会 第96春季年会
  • Place of Presentation: 同志社、京田辺
  • Year and Date: 2016-03-24
• [Presentation] 内部縮環N-混乱ポルフィリンの合成と物性 (2016)
  • Author(s): 橘俊宏、石田真敏、戸叶基樹、清水宗治、古田弘幸
  • Organizer: 日本化学会 第96春季年会
  • Place of Presentation: 同志社、京田辺
  • Year and Date: 2016-03-24
• [Presentation] N-混乱ポルフィリン-アザ-BODIPY複合体の合成及び物性 (2016)
  • Author(s): 福田雅弥、清水宗治、古田弘幸
  • Organizer: 日本化学会 第96春季年会
  • Place of Presentation: 同志社、京田辺
  • Year and Date: 2016-03-24
• [Presentation] ピロロピロール-アザ-ジピリン金属錯体の合成及び物性 (2016)
  • Author(s): 唐﨑秀朗、古田弘幸、清水宗治
  • Organizer: 日本化学会 第96春季年会
  • Place of Presentation: 同志社、京田辺
  • Year and Date: 2016-03-24
• [Presentation] Synthesis of Novel Dimeric aza-BODIPY Analogues from Lactams and Their Intriguing Optical and Electrochemical Properties (2015)
  • Author(s): Soji Shimizu, Hideaki Karasaki, Yuto Kage, Hiroyuki Furuta
  • Organizer: The 10th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-10)
  • Place of Presentation: Kaohsiung, Taiwan
  • Year and Date: 2015-11-02
  • Int'l Joint Research / Invited
• [Presentation] Synthesis and Properties of Pyrrolopyrrole aza-BODIPY Toward Near-Infrared Absorption and Fluorescence (2015)
  • Author(s): Hideaki Karasaki, Hiroyuki Furuta, Soji Shimizu
  • Organizer: The 5th Junior International Conference on Cutting-Edge Organic Chemistry in Asia
  • Place of Presentation: Taipei, Taiwan
  • Year and Date: 2015-10-31
  • Int'l Joint Research
• [Presentation] ピロロピロール－アザ－BODIPY二量体の合成・物性 (2015)
  • Author(s): 鹿毛悠冬、清水宗治、森重樹、古田弘幸
  • Organizer: 第26回基礎有機化学会討論会
  • Place of Presentation: 愛媛大学、松山
  • Year and Date: 2015-09-24
• [Presentation] TTF縮環ケイ素フタロシアニン多量体の酸化還元による積層構造制御 (2015)
  • Author(s): 椎名祐太、清水宗治、古田弘幸、小林長夫
  • Organizer: 第26回基礎有機化学会討論会
  • Place of Presentation: 愛媛大学、松山
  • Year and Date: 2015-09-24
• [Presentation] ピロロピロール－アザ－BODIPY二量体の合成・物性 (2015)
  • Author(s): 鹿毛悠冬、清水宗治、森重樹、古田弘幸
  • Organizer: 有機合成化学協会九州山口支部 第27回若手研究者のためのセミナー
  • Place of Presentation: 九州大学、福岡
  • Year and Date: 2015-08-29
• [Presentation] Synthesis of Novel aza-BODIPY Analogues from Lactams and Their Intriguing Optical and Electrochemical Properties (2015)
  • Author(s): Soji Shimizu
  • Organizer: I SYMPOSIUM ON AROMATIC COMPOUNDS
  • Place of Presentation: Madrid, Spain
  • Year and Date: 2015-07-09
  • Int'l Joint Research / Invited
• [Presentation] Synthesis of Novel aza-BODIPY Analogues from a Schiff Base Formation Reaction of Lactams and Their Unique Optical and Electrochemical Properties (2015)
  • Author(s): Soji Shimizu, Taku Iino, Ai Murayama, Masamichi Tamada, Hideaki Karasaki, Nagao Kobayashi, and Hiroyuki Furuta
  • Organizer: 16th International Symposium on Novel Aromatic Compounds (ISNA-16)
  • Place of Presentation: Madrid, Spain
  • Year and Date: 2015-07-06
  • Int'l Joint Research
• [Presentation] Synthesis and Properties of Pyrrolopyrrole-Aza-BODIPY Dimer (2015)
  • Author(s): Yuto Kage, Taku Iino, Soji Shimizu, Shigeki Mori, Hiroyuki Furuta
  • Organizer: 16th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: Madrid, Spain
  • Year and Date: 2015-07-05
  • Int'l Joint Research
• [Presentation] ピロロピロール -アザ-BODIPY二量体の合成・物性 (2015)
  • Author(s): 鹿毛悠冬、清水宗治、森重樹、古田弘幸
  • Organizer: 日本化学会九州支部設立100周年記念国際シンポジウム ・第52回化学関連支部合同九州大会
  • Place of Presentation: 北九州国際会議場、北九州
  • Year and Date: 2015-06-27
• [Presentation] 近赤外吸収・発光を指向したピロロピロール-アザ-BODIPY類縁体の合成 (2015)
  • Author(s): 唐﨑秀朗、清水宗治、古田弘幸
  • Organizer: 日本化学会九州支部設立100周年記念国際シンポジウム ・第52回化学関連支部合同九州大会
  • Place of Presentation: 北九州国際会議場、北九州
  • Year and Date: 2015-06-27
• [Presentation] TTF-annulated Silicon Phthalocyanine and Redox Control of Molecular Alignment of Its μ-Oxo Oligomers (2015)
  • Author(s): Soji Shimizu, Yuta Shiina, Hiroyuki Furuta, Nagao Kobayashi
  • Organizer: 5th Georgian Bay International Conference on Bioinorganic Chemistry
  • Place of Presentation: Parry Sound, Ontario, Canada
  • Year and Date: 2015-05-19
  • Int'l Joint Research / Invited
• [Presentation] TTFの酸化還元を利用したケイ素フタロシアニン多量体の分子配列制御 (2015)
  • Author(s): 椎名祐太、清水宗治、小林長夫、古田弘幸
  • Organizer: 第25回記念万有福岡シンポジウム
  • Place of Presentation: 九州大学、福岡
  • Year and Date: 2015-05-16
• [Book] Recent advances in the chemistry of phthalocyanine as functional chromophores in Chemical Science of pi- Electron Systems (2015)
  • Author(s): Soji Shimizu, Nagao Kobayashi/ Eds. T. Akasaka, A. Osuka, S. Fukuzumi, H. Kandori
  • Total Pages: 777
  • Publisher: Springer
• [Remarks] 所属研究室ホームページ
  • URL: http://www.cstf.kyushu-u.ac.jp/~furutalab/