動的面不斉を有する超分子型不斉触媒の創製

• Project Area: Precise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions
• Project/Area Number: 16H01016
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Nagoya University
• Principal Investigator: 逢坂 直樹 名古屋大学, 工学研究科, 講師 (80726331)
• Project Period (FY): 2016-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000); Fiscal Year 2017: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000); Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
• Keywords: 超分子化学 / キラリティ / らせん構造

Outline of Annual Research Achievements

本研究課題では、動的ならせん分子・超分子の特徴を最大限に活かし、触媒部位を組み込んだキラル構造体の構築、さらには、精密不斉反応場の構築を見据えた分子設計指針の確立を目指し、以下の成果を得た。
3位に動的に光学活性ならせんペプチド鎖を導入したビピリジン（bpy）誘導体の3’位と、ペプチド側鎖間をラクタムブリッジにより分子内架橋した動的に軸性キラルなbpy誘導体を新規に設計・合成した。分子内架橋前後のbpy誘導体の核磁気共鳴（NMR）測定を行なったところ、分子内架橋を施すことで、bpy部位の軸不斉とらせんペプチド鎖の左右のらせん反転速度が、NMRの時間尺度より著しく遅くなり、さらに、bpy部位の軸不斉が遠隔制御されることも見出した。また、bpy部位のN,N’-ジオキシド化がジアステレオ選択的に進行することを明らかにするとともに、生成した２種類のジアステレオマーの単離にも成功した。単離した2種類のジアステレオマーのうち、一方の軸不斉を有するbpy N,N’-ジオキシド誘導体の動的ならせんペプチド鎖部位が、溶媒により、右巻きからなるホモキラルならせん構造から、ペプチド鎖中にらせん反転部位を有し、右巻きらせんと左巻きらせんセグメントの両方からなるヘテロキラルならせん構造へとスイッチングすることを見出すとともに、このスイッチングが溶媒によるbpy N,N’-ジオキシド部位とらせんペプチド鎖間での分子内水素結合のON-OFFスイッチングを介して起こることも明らかにした。

Research Progress Status

29年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

29年度が最終年度であるため、記入しない。

Research Products

• [Int'l Joint Research] Harbin Engineering University(中国)
• [Journal Article] Allosteric regulation of metal-binding sites inside an optically-active helical foldamer and its tubular assemblies (2018)
  • Author(s): Kawabata, S.; Ousaka, N.; Yashima, E.
  • Journal Title: Chem. Commun. Volume: 54 Issue: 19 Pages: 2417-2420
  • DOI: 10.1039/c8cc00728d
  • Peer Reviewed
• [Journal Article] Double-Stranded Helical Oligomers Covalently Bridged by Rotary Cyclic Boronate Esters (2017)
  • Author(s): Iida, H.; Ohmura, K.; Noda, R.; Iwahana, S.; Katagiri, H.; Ousaka, N.; Hayashi, T.; Hijikata, Y.; Irle, S.; Yashima, E.
  • Journal Title: Chem. Asian J. Volume: 12 Issue: 8 Pages: 927-935
  • DOI: 10.1002/asia.201700162
  • Peer Reviewed
• [Journal Article] Chirality Control and Its Memory at Microphase-Separated Interface of Self-Assembled Chiral Block Copolymers for Nanostructured Chiral Materials (2017)
  • Author(s): Li, M.-C.; Ousaka, N.; Wang, H.-F.; Yashima, E.; Ho, R.-M.
  • Journal Title: ACS Macro Lett. Volume: 6 Issue: 9 Pages: 980-986
  • DOI: 10.1021/acsmacrolett.7b00493
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Alkali Metal Ion-enhanced Threading of a Perylenediimide-bound Polymer Chain through a Double-stranded Spiroborate Helicate with a Bisporphyrin Unit (2017)
  • Author(s): Ousaka, N.; Yamamoto, S.; Hayashi, N.; Li, M.-C.; Ho, R.-M.; Yashima, E.
  • Journal Title: Chemistry Letters Volume: 46 Issue: 7 Pages: 970-972
  • DOI: 10.1246/cl.170271
  • NAID: 130005709482
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Chiral Template-Directed Regio-, Diastereo-, and Enantioselective Photodimerization of an Anthracene Derivative Assisted by Complementary Amidinium?Carboxylate Salt Bridge Formation (2017)
  • Author(s): Tanabe, J.; Taura, D.; Ousaka, N.; Yashima, E.
  • Journal Title: J. Am. Chem. Soc. Volume: 139 Issue: 21 Pages: 7388-7398
  • DOI: 10.1021/jacs.7b03317
  • NAID: 120006473522
  • Peer Reviewed / Open Access
• [Journal Article] Helix-in-Helix" Superstructure Formation through Encapsulation of Fullerene-Bound Helical Peptides within a Helical Poly(Methyl Methacrylate) Cavity (2017)
  • Author(s): N. Ousaka, F. Mamiya, Y. Iwata, Y. Nishimura, E. Yashima
  • Journal Title: Angew. Chem., Int. Ed. Volume: 56 Issue: 3 Pages: 791-795
  • DOI: 10.1002/anie.201611349
  • Peer Reviewed / Open Access
• [Journal Article] Helix-Helix Inversion of an Optically-Inactive π-Conjugated Foldamer Triggered by Concentration Changes of a Single Enantiomeric Guest Leading to a Change in the Helical Stability (2016)
  • Author(s): L. Liu, N. Ousaka, M. Horie, F. Mamiya, E. Yashima
  • Journal Title: Chem. Commun. Volume: 52 Issue: 79 Pages: 11752-11755
  • DOI: 10.1039/c6cc05753e
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Cobalt(II)-Salen-Linked Complementary Double-Stranded Helical Catalysts for Asymmetric Nitro-Aldol Reaction (2016)
  • Author(s): D. Taura, S. Hioki, J. Tanabe, N. Ousaka, E. Yashima
  • Journal Title: ACS Catal. Volume: 6 Issue: 7 Pages: 4685-4689
  • DOI: 10.1021/acscatal.6b01627
  • Peer Reviewed
• [Journal Article] Remarkable Acceleration of Template-Directed Photodimerisation of 9-Phenylethynylanthracene Derivatives Assisted by Complementary Salt Bridge Formation (2016)
  • Author(s): J. Tanabe, D. Taura, N. Ousaka, E. Yashima
  • Journal Title: Org. Biomol. Chem. Volume: 14 Issue: 46 Pages: 10822-10832
  • DOI: 10.1039/c6ob02087a
  • Peer Reviewed / Open Access
• [Journal Article] Construction of Covalent Organic Nanotubes by Light-Induced Cross-Linking of Diacetylene-Based Helical Polymers (2016)
  • Author(s): Kaho Maeda, Liu Hong, Taishi Nishihara, Yusuke Nakanishi, Yuhei Miyauchi, Ryo Kitaura, Naoki Ousaka, Eiji Yashima, Hideto Ito,* and Kenichiro Itami*
  • Journal Title: J. Am. hem. Soc. Volume: 138 Issue: 34 Pages: 11001-11008
  • DOI: 10.1021/jacs.6b05582
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Supramolecular Helical Systems: Helical Assemblies of Small Molecules, Foldamers, and Polymers with Chiral Amplification and Their Functions (2016)
  • Author(s): E. Yashima, N. Ousaka, D. Taura, K. Shimomura, T. Ikai, K. Maeda
  • Journal Title: Chem. Rev. Volume: 116, Issue: 22 Pages: 13752-13990
  • DOI: 10.1021/acs.chemrev.6b00354
  • Peer Reviewed / Open Access
• [Presentation] 動的らせんペプチド鎖を有するビピリジン誘導体の軸不斉遠隔制御 (2018)
  • Author(s): 宇留嶋彬央・ 逢坂直樹・ 八島 栄次
  • Organizer: 日本化学会 第98春季年会
• [Presentation] オリゴフェノール誘導体からなる二重らせんチタンヘリケートの合成とその可逆的な構造変換 (2018)
  • Author(s): 板倉学・ 田浦大輔・ 逢坂直樹・ 八島 栄次
  • Organizer: 日本化学会 第98春季年会
• [Presentation] 動的ならせんペプチドフォルダマーを有するキラル構造体の不斉遠隔制御 (2018)
  • Author(s): 逢坂直樹
  • Organizer: 日本薬学会第１３８年会
• [Presentation] 配位高分子化によるロジウム二核錯体のプロペラキラリティの制御 (2017)
  • Author(s): 岩田拓也, 逢坂直樹, 八島栄次
  • Organizer: 日本化学会 第97春季年会
  • Place of Presentation: 慶應義塾大学 日吉キャンパス
  • Year and Date: 2017-03-16
• [Presentation] st-PMMAが形成するらせん空孔へのフラーレン誘導体の不斉選択的包接 (2017)
  • Author(s): 間宮文彦・ 見波暁子・ 田浦大輔・ 逢坂直樹・ 八島栄次
  • Organizer: 第66回高分子学会年次大会
• [Presentation] 配位高分子化を駆動力としたロジウム二核錯体の動的なプロペラキラリティの制御 (2017)
  • Author(s): 岩田拓也・ 逢坂直樹・ 八島栄次
  • Organizer: 第66回高分子学会年次大会
• [Presentation] オリゴフェノール誘導体からなる二重らせんチタンヘリケートの合成とその可逆的な構造変換 (2017)
  • Author(s): 板倉学・ 長坂顕・ 服部智成・ 田浦大輔・ 逢坂直樹・ 八島栄次
  • Organizer: 第161回東海高分子研究会講演会 (2017年夏期合宿)
• [Presentation] 動的ならせんペプチド鎖を介したビピリジン誘導体の軸不斉遠隔制御と不斉触媒への応用 (2017)
  • Author(s): 宇留嶋彬央・ 逢坂直樹・ 八島 栄次
  • Organizer: 第66回 高分子討論会
• [Presentation] 配位超分子重合を介したロジウム二核錯体の動的なプロペラキラリティの制御 (2017)
  • Author(s): 岩田拓也・ 逢坂直樹・ 八島栄次
  • Organizer: 第66回 高分子討論会
• [Presentation] らせん空孔を有する光学活性高分子の合成とその超分子重合 (2017)
  • Author(s): 川端賢・ 逢坂直樹・ 八島栄次
  • Organizer: 第66回 高分子討論会
• [Presentation] アントラセンリンカーを導入したカルボン酸二量体の合成と不斉選択的光二量化反応 (2017)
  • Author(s): 堀本尚路・ 田中真人・ 田邉純樹・ 田浦大輔・ 逢坂直樹・ 八島栄次
  • Organizer: 第66回 高分子討論会
• [Presentation] 配位超分子重合によるロジウム二核錯体の動的なプロペラキラリティの制御 (2017)
  • Author(s): 岩田拓也・ 逢坂直樹・ 八島栄次
  • Organizer: 第48回 中部化学関係学協会支部連合秋季大会
• [Presentation] 2,6-置換アントラセンリンカーを有するカルボン酸二量体の不斉選択的光二量化反応 (2017)
  • Author(s): 堀本尚路・ 田中真人・ 田邉純樹・ 田浦大輔・ 逢坂直樹・ 八島栄次
  • Organizer: 第48回中部化学関係学協会支部連合秋季大会
• [Presentation] Enantioselective Encapsulation of Fullerene Derivatives within an Optically‐Active Helical st‐PMMA Cavity (2017)
  • Author(s): Mamiya, F.; Minami, A.; Taura, D.; Ousaka, N.; Yashima, E.
  • Organizer: The 29th International Symposium on Chiral Discrmination (Chirality 2017)
  • Int'l Joint Research
• [Presentation] Diastereoselective N,N’-Dioxidation of 2,2’-Bipyridine Derivatives Bearing Dynamic Helical Peptides through Remote Stereocontrol of Their Dynamic Axial Chirality (2017)
  • Author(s): Urushima, A.; Ousaka, N.; Yashima, E.
  • Organizer: The 29th International Symposium on Chiral Discrmination (Chirality 2017)
  • Int'l Joint Research
• [Presentation] Control of Dynamic Propeller Chirality of Dirhodium Complexes via Coordination-Driven Supramolecular Polymerization (2017)
  • Author(s): Iwata, T.; Ousaka, N.; Yashima, E.
  • Organizer: The 29th International Symposium on Chiral Discrmination (Chirality 2017)
  • Int'l Joint Research
• [Presentation] Supramolecular Assembly of an Optically‐Active Helical Foldamer and Allosteric Regulation of Its Metal‐Binding Sites inside the Helical Cavity (2017)
  • Author(s): Kawabata, S.; Ousaka, N.; Yashima, E.
  • Organizer: The 29th International Symposium on Chiral Discrmination (Chirality 2017)
  • Int'l Joint Research
• [Presentation] Coordination-Driven Supramolecular Polymerization of Chiral Dirhodium Complexes (2017)
  • Author(s): Iwata, T.; Ousaka, N.; Yashima, E.
  • Organizer: 3rd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules?
  • Int'l Joint Research
• [Presentation] Supramolecular Assembly of a Helical Polymer and Its Cooperative Helix-to-Helix Transition (2017)
  • Author(s): Kawabata, S.; Ousaka, N.; Yashima, E.
  • Organizer: 3rd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules
  • Int'l Joint Research
• [Presentation] Enantioselective Photodimerization of a Carboxylic Acid Dimer Connected with an Anthracene Linker (2017)
  • Author(s): Horimoto, N.; Tanaka, M.; Tanabe, J.; Taura, D.; Ousaka, N.; Yashima, E.
  • Organizer: 3rd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules
  • Int'l Joint Research
• [Presentation] Remote Stereocontrol of Axial Chirality of Bipyridine Derivatives through Dynamic Helical Peptide Chains (2017)
  • Author(s): Urushima, A.; Ousaka, N.; Yashima, E.
  • Organizer: 7th TOYOTA Riken International Workshop on Chirality in Soft Matter
  • Int'l Joint Research
• [Presentation] Synthesis of Optically-Active Double-Staranded Bipyridine N,N'-Dioxide Helicates and Their Application to Asymmetric Reaction (2017)
  • Author(s): Ueda, M.; Suzuki, Y.; Nakamura, T.; Iida,H.; Ousaka, N.; Yashima, E.
  • Organizer: 7th TOYOTA Riken International Workshop on Chirality in Soft Matter
  • Int'l Joint Research
• [Presentation] Cooperative Helix-to-Helix Transition of a Helical Polymer and Its Supramolecular Assemblies (2017)
  • Author(s): Kawabata, S.; Ousaka, N.; Yashima, E.
  • Organizer: 7th TOYOTA Riken International Workshop on Chirality in Soft Matter
  • Int'l Joint Research
• [Presentation] Enantioselective Photodimerization of a Carboxylic Acid Dimer Linked by a 2,6-Substituted Anthracene Unit (2017)
  • Author(s): Horimoto, N.; Tanaka, M.; Tanabe, J.; Taura, D.; Ousaka, N.; Yashima, E.
  • Organizer: 7th TOYOTA Riken International Workshop on Chirality in Soft Matter
  • Int'l Joint Research
• [Presentation] Synthesis of an Acylhydrazone-Linked Foldamer Bearing Optically Active Side-Chains and Its Self-Assembly Behavior (2016)
  • Author(s): S. Kawabata, N. Ousaka, E. Yashima
  • Organizer: 11th SPSJ International Polymer Conference (IPC2016)
  • Place of Presentation: Fukuoka, Japan
  • Year and Date: 2016-12-13
  • Int'l Joint Research
• [Presentation] 動的らせんペプチド鎖を有するビピリジン誘導体の軸性キラリティーの遠隔不斉制御 (2016)
  • Author(s): 宇留嶋彬央, 逢坂直樹, 八島栄次
  • Organizer: 第6回 CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2016-11-14
• [Presentation] 動的共有結合形成を介した光学活性フォルダマーの合成とその会合挙動 (2016)
  • Author(s): 川端賢, 逢坂直樹, 八島栄次
  • Organizer: 第6回 CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2016-11-14
• [Presentation] st-PMMA が形成するらせん空孔へのらせんペプチド鎖を有するフラーレン誘導体の包接 (2016)
  • Author(s): 間宮文彦, 岩田欣明, 逢坂直樹, 八島栄次
  • Organizer: 第25回ポリマー材料フォーラム
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2016-11-10
• [Presentation] 動的な共有結合による光学活性フォルダマーの合成とその会合挙動 (2016)
  • Author(s): 川端賢, 逢坂直樹, 八島栄次
  • Organizer: 第25回ポリマー材料フォーラム
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2016-11-10
• [Presentation] 一方向巻きのペプチド鎖を有するフラーレン誘導体を利用したst-PMMAのらせん誘起 (2016)
  • Author(s): 間宮文彦, 岩田欣明, 逢坂直樹, 八島栄次
  • Organizer: 第47回 中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 豊橋技術科学大学
  • Year and Date: 2016-11-05
• [Presentation] 光学活性ならせん空孔を有する新規フォルダマーの合成とその会合挙動 (2016)
  • Author(s): 川端賢, 逢坂直樹, 八島栄次
  • Organizer: 第47回 中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 豊橋技術科学大学
  • Year and Date: 2016-11-05
• [Presentation] Development of Cobalt(ll)-Salen-Linked Complementary Double Helical Catalysts for Asymmetric Reaction (2016)
  • Author(s): D. Taura, S. Hioki, J. Tanabe, N. Ousaka, E. Yashima
  • Organizer: 2016 International Symposium on Integrated Molecular / Materials Science & Engineering (IMSE 2016)
  • Place of Presentation: Qingdao, China
  • Year and Date: 2016-10-14
  • Int'l Joint Research
• [Presentation] Diastereoselective N,N'-dioxidation of Bipyridine Derivatives Bearing Dynamic Helical Peptide Chains (2016)
  • Author(s): A. Urushima, N. Ousaka, E. Yashima
  • Organizer: 2016 International Symposium on Integrated Molecular / Materials Science & Engineering (IMSE 2016)
  • Place of Presentation: Qingdao, China
  • Year and Date: 2016-10-14
  • Int'l Joint Research
• [Presentation] An Inclusion Complex Formation of a Double-Stranded Porphyrin Helicate with Various Aromatic Molecules (2016)
  • Author(s): T. Iwata, S. Yamamoto, N. Ousaka, E. Yashima
  • Organizer: 2016 International Symposium on Integrated Molecular / Materials Science & Engineering (IMSE 2016)
  • Place of Presentation: Qingdao, China
  • Year and Date: 2016-10-14
  • Int'l Joint Research
• [Presentation] Acid/Base-Triggered Unidirectional Spring-like Motion of Double-Stranded Spiroborate Helicates (2016)
  • Author(s): M. Ueda, Y. Suzuki, T. Nakamura, H. Iida, N. Ousaka, E. Yashima
  • Organizer: 2016 International Symposium on Integrated Molecular / Materials Science & Engineering (IMSE 2016)
  • Place of Presentation: Qingdao, China
  • Year and Date: 2016-10-14
  • Int'l Joint Research
• [Presentation] "Aggregation Behavior of an Optically Active Foldamer Linked by Dynamic Acylhydrazone Bonds " (2016)
  • Author(s): S. Kawabata, N. Ousaka, E. Yashima
  • Organizer: 2016 International Symposium on Integrated Molecular / Materials Science & Engineering (IMSE 2016)
  • Place of Presentation: Qingdao, China
  • Year and Date: 2016-10-14
  • Int'l Joint Research
• [Presentation] Synthesis of a Spiroborate-Based Double-Stranded Helicate Bearing Pyrenyl Units and Its Fluorescent Behavior (2016)
  • Author(s): C. Yokota, Y. Suzuki, K. Shimizu, H. Iida, D. Taura, N .Ousaka, E. Yashima
  • Organizer: 2016 International Symposium on Integrated Molecular / Materials Science & Engineering (IMSE 2016)
  • Place of Presentation: Qingdao, China
  • Year and Date: 2016-10-14
  • Int'l Joint Research
• [Presentation] 相補的な二重らせん構造を有する有機分子触媒の合成と不斉触媒反応への応用 (2016)
  • Author(s): 下村昂平, 田浦大輔, 逢坂直樹, 八島栄次
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学 横浜キャンパス
  • Year and Date: 2016-09-14
• [Presentation] キラルなテンプレートを用いたアントラセン誘導体の不斉選択的光二量化反応 (2016)
  • Author(s): 田邉純樹, 田浦大輔, 逢坂直樹, 八島栄次
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学 横浜キャンパス
  • Year and Date: 2016-09-14
• [Presentation] ビスポルフィリン部位を有する二重らせんホウ素ヘリケートのキラル認識とデラセミ化反応 (2016)
  • Author(s): 山本慎也, 飯田拡基, 逢坂直樹, 八島栄次
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学 横浜キャンパス
  • Year and Date: 2016-09-14
• [Presentation] 動的なアシルヒドラゾン結合を主鎖骨格に有する光学活性フォルダマーの合成とその会合挙動 (2016)
  • Author(s): 川端賢, 逢坂直樹, 八島栄次
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学 横浜キャンパス
  • Year and Date: 2016-09-14
• [Presentation] Enantioselective Encapsulation of Peptide-Bound Fullerene Derivatives within an Optically Active Helical st-PMMA Cavity (2016)
  • Author(s): F. Mamiya, Y. Iwata, N. Ousaka, E. Yashima
  • Organizer: The 28th International Symposium on Chiral Discrmination (Chirality 2016)
  • Place of Presentation: Heidelberg, Germany
  • Year and Date: 2016-07-24
  • Int'l Joint Research
• [Presentation] Self-Assembly of an Optically Active Helical Oligomer Linked by Dynamic Hydrazone Bonds (2016)
  • Author(s): S. Kawabata, N. Ousaka, H. Iida, E. Yashima
  • Organizer: The 28th International Symposium on Chiral Discrmination (Chirality 2016)
  • Place of Presentation: Heidelberg, Germany
  • Year and Date: 2016-07-24
  • Int'l Joint Research
• [Presentation] A Unique Inclusion-Complex Formation of an Optically Active Double-Stranded Porphyrin Helicate with Various Aromatic Molecules (2016)
  • Author(s): T. Iwata, S. Yamamoto, N. Ousaka, E. Yashima
  • Organizer: The 11th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC-2016)
  • Place of Presentation: Seoul, Koria
  • Year and Date: 2016-07-10
  • Int'l Joint Research
• [Presentation] Supramolecular Polymerization of Helical Foldamaers Linked by Dynamic Acylhydrazone Bonds (2016)
  • Author(s): S. Kawabata, N. Ousaka, E. Yashima
  • Organizer: The 11th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC-2016)
  • Place of Presentation: Seoul, Koria
  • Year and Date: 2016-07-10
  • Int'l Joint Research
• [Presentation] サレンマクロサイクルが有する動的な面性キラリティの遠隔制御と記憶 (2016)
  • Author(s): 間宮文彦, 岩田欣明, 逢坂直樹, 八島栄次
  • Organizer: 第5回 JACI/GSCシンポジウム
  • Place of Presentation: ANAクラウンプラザホテル神戸
  • Year and Date: 2016-06-02
• [Presentation] ペプチド鎖を有するビピリジン誘導体の遠隔不斉制御 (2016)
  • Author(s): 宇留嶋彬央, 逢坂直樹, 八島栄次
  • Organizer: 第5回 JACI/GSCシンポジウム
  • Place of Presentation: ANAクラウンプラザホテル神戸
  • Year and Date: 2016-06-02
• [Presentation] 有機触媒部位を導入した相補的二重らせん分子の合成と応用 (2016)
  • Author(s): 下村昂平, 田浦大輔, 逢坂直樹, 八島栄次
  • Organizer: 第65回 高分子学会年次大会
  • Place of Presentation: 神戸コンベンションセンター
  • Year and Date: 2016-05-25
• [Presentation] アントラセンの光二量化を利用した相補鎖のテンプレート合成 (2016)
  • Author(s): 田邉純樹, 田浦大輔, 逢坂直樹, 八島栄次
  • Organizer: 第65回 高分子学会年次大会
  • Place of Presentation: 神戸コンベンションセンター
  • Year and Date: 2016-05-25
• [Presentation] st -PMMAが形成するらせん空孔へのらせんペプチド鎖を有するフラーレン誘導体の包接挙動 (2016)
  • Author(s): 間宮文彦, 岩田欣明, 逢坂直樹, 八島栄次
  • Organizer: 第65回 高分子学会年次大会
  • Place of Presentation: 神戸コンベンションセンター
  • Year and Date: 2016-05-25
• [Presentation] ホストーゲスト相互作用を介した二重らせん型ポルフィリンヘリケートの特異な包接挙動 (2016)
  • Author(s): 岩田拓也, 山本慎也, 逢坂直樹, 八島栄次
  • Organizer: 第65回 高分子学会年次大会
  • Place of Presentation: 神戸コンベンションセンター
  • Year and Date: 2016-05-25
• [Presentation] Encapsulation of Peptide-Bound Fullerene Derivatives within an Optically Active Helical Cavity of Syndiotactic PMMA (2016)
  • Author(s): F. Mamiya, Y. Iwata, N. Ousaka, E. Yashima
  • Organizer: Molecular Chirality Asia 2016
  • Place of Presentation: Osaka, Japan
  • Year and Date: 2016-04-20
  • Int'l Joint Research
• [Presentation] Synthesis of Metal-Salen-Linked Complementary Double Helices and Their Application to Asymmetric Catalysis (2016)
  • Author(s): D. Taura, S. Hioki, J. Tanabe, N. Ousaka, E. Yashima
  • Organizer: Molecular Chirality Asia 2016
  • Place of Presentation: Osaka, Japan
  • Year and Date: 2016-04-20
  • Int'l Joint Research
• [Presentation] Remote Control of Axial Chirality in Bipyridine Derivatives Bearing Dynamic Helical Peptide Chains (2016)
  • Author(s): A. Urushima, N. Ousaka, E. Yashima
  • Organizer: Molecular Chirality Asia 2016
  • Place of Presentation: Osaka, Japan
  • Year and Date: 2016-04-20
  • Int'l Joint Research
• [Presentation] A Unique Inclusion-Complex Formation of a Double-Stranded Porphyrin Helicate with Functionalized Aromatic Molecules (2016)
  • Author(s): T. Iwata, S. Yamamoto, N. Ousaka, H. Iida, E. Yashima
  • Organizer: Molecular Chirality Asia 2016
  • Place of Presentation: Osaka, Japan
  • Year and Date: 2016-04-20
  • Int'l Joint Research