Development of hybridized pi-figuration of sphere and plane into superconductors and quantum magnets
Publicly Offered Research
| Project Area | pi-System Figuration: Control of Electron and Structural Dynamism for Innovative Functions |
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| Project/Area Number |
17H05139
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
プラシデス コスマス 大阪府立大学, 工学(系)研究科(研究院), 教授 (90719006)
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| Project Period (FY) |
2017-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2018: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
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| Keywords | Superconductivity / Spin liquids / Polyaromatic hydrocarbon / Quantum magnetism / Fullerenes / pi-electron systems / 強相関電子系 / 量子磁性 / 複合材料・物性 / フラーレン / 多環芳香族炭化水素 |
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| Outline of Annual Research Achievements |
We succeeded in establishing for the first time reproducible synthetic procedures of phase-pure highly-crystalline metal-doped PAHs, which emerge as candidates of new exotic electronic states of matter, including three-dimensional quantum spin liquids arising purely from carbon pi-electrons for the first time. Our methodology led to entirely new chemical approaches to produce intercalated PAHs with controlled oxidation states. The new synthetic routes allowed the isolation of unique materials, including the isolation of a S = 1/2 quantum spin-liquid state arising for the first time purely from pi-electrons. These results provide the seeds of new ideas to transform thinking about the scientific area of quantum magnetism in molecular systems and open a new branch of molecular science in the same way that, 10 years ago, the discovery of the Cs3C60 superconductor led to the renaissance of fullerene superconductivity.
As a direct application of our generic synthetic routes, we have now developed the synthesis of the first unsolvated alkali metal rubrene and tetracene phases. The crystal chemistry of the potassium rubrene phase contrasts with that of earlier structures allowing us to take the first step towards establishing structure-composition relationships in this class of materials. On the other hand, K2tetracene is isostructural with K2pentacene with the K+ cations residing in two sites that are not disordered due to the limited sites on which they can be accommodated.
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| Research Progress Status |
平成30年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
平成30年度が最終年度であるため、記入しない。
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Report
(2 results)
Research Products
(60 results)
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[Journal Article] π-electron S =1/2 quantum spin-liquid state in an ionic polyaromatic hydrocarbon2017
Author(s)
Takabayashi Y, Menelaou M, Tamura H, Takemori N, Koretsune T, Stefancic A, Klupp G, Buurma AJC, Nomura Y, Arita R,, Arcon D, Rosseinsky MJ, Prassides K
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Journal Title
Nature Chemistry
Volume: 9
Issue: 7
Pages: 635-643
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] Redox-controlled potassium intercalation into two polyaromatic hydrocarbon solids2017
Author(s)
F. D. Romero, M. J. Pitcher, C. I. Hiley, G. F. S. Whitehead, S. Kar, A. Y. Ganin, D. Antypov, C. Collins, M. S. Dyer, G. Klupp, R. H. Colman, K. Prassides and M. J. Rosseinsky
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Journal Title
Nature Chemistry
Volume: 9
Issue: 7
Pages: 644-652
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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