Design and development of hybrid system of dye/photocatalyst/biocatalyst for photoreduction of carbon dioxide

• Project Area: Creation of novel light energy conversion system through elucidation of the molecular mechanism of photosynthesis and its artificial design in terms of time and space
• Project/Area Number: 18H05174
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Research Institution: Osaka City University
• Principal Investigator: 天尾 豊 大阪市立大学, 複合先端研究機構, 教授 (80300961)
• Project Period (FY): 2018-04-01 – 2020-03-31
• Project Status: Completed (Fiscal Year 2019)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2019: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000); Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: 二酸化炭素還元 / 生体触媒 / 人工補酵素 / 半導体光触媒 / 可視光応答

Outline of Annual Research Achievements

本提案では，本新学術領域の骨子である「本質的かつ生産的な生物-化学融合領域の創成」を実現するために，国内外ではほとんど進められていない有機色素分子，半導体光触媒，生体触媒材料をそれぞれの研究領域の垣根を超えて複合化させ，それぞれの欠点を補うとともに特徴を最大限活用できる新規な二酸化炭素の光還元に資する材料構築を目的としている．本年度は酸化チタン（半導体光触媒）の光触媒機能とギ酸脱水素酵素（生体触媒）とを組み合わせた光駆動型二酸化炭素還元に基づくギ酸生成系を構築した．具体的には酸化チタン，メチルビオローゲン，トリエタノールアミン及びギ酸脱水素酵素をピロリン酸ナトリウム緩衝 液に加え，気相を二酸化炭素ガスで充填し，反応温度30℃で400 Wキセノンランプを照射した．その結果，光照射時間とともにギ酸生成が見られた．さらにこれまで広く可視光増感剤として利用されてきた水溶性亜鉛ポルフィリンを用いた従来の系と比較しても効率的にギ酸生成が達成できた．加えて，光触媒と二酸化炭素還元機能を有する生体触媒であるギ酸脱水素酵素とを複合化した「光触媒電極と生体触媒との複合化による極低バイアス二酸化炭素還元」の構築に着手し，水を電子源とした光駆動型二酸化炭素還元が達成できた．これらの成果は，生物-化学融合領域の創成に資する成果であり，すでに国際誌に掲載された．

Research Progress Status

令和元年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和元年度が最終年度であるため、記入しない。

Research Products

• [Journal Article] Photoelectrochemical CO2 Reduction to Formate with the Sacrificial Reagent Free System of Semiconductor Photocatalysts and Formate Dehydrogenase (2019)
  • Author(s): Tomoya Ishibashi, Masanobu Higashi, Shigeru Ikeda, Yutaka Amao
  • Journal Title: ChemCatChem Volume: 11 Issue: 24 Pages: 6227-6235
  • DOI: 10.1002/cctc.201901563
  • Peer Reviewed
• [Journal Article] Visible-light driven hydrogen production using chlorophyll derivatives conjugated with a viologen moiety in the presence of platinum nanoparticles (2019)
  • Author(s): Ikeyama Shusaku、Hizume Shota、Takahashi Tatsuya、Ogasawara Shin、Amao Yutaka、Tamiaki Hitoshi
  • Journal Title: Photochemical & Photobiological Sciences Volume: 18 Issue: 11 Pages: 2673-2681
  • DOI: 10.1039/c9pp00176j
  • Peer Reviewed
• [Journal Article] Selective Hydrogen Production from Formate Using Nanoparticle with Homogeneously Polymer-dispersed Platinum Clusters (2019)
  • Author(s): Yusuke Minami ,Yumiko Muroga ,Tomoko Yoshida , Yutaka Amao
  • Journal Title: Chemistry Letters Volume: 48 Issue: 8 Pages: 775-778
  • DOI: 10.1246/cl.190311
  • NAID: 130007687718
  • Peer Reviewed / Open Access
• [Journal Article] Double-Electron Reduced Diphenylviologen as a Coenzyme for Biocatalytic Building Carbon-Carbon Bonds from CO2 as a Carbon Feedstock (2019)
  • Author(s): Takayuki Katagiri, Yutaka Amao
  • Journal Title: ACS Sustainable Chemistry & Engineering Volume: 7 Issue: 10 Pages: 9080-9085
  • DOI: 10.1021/acssuschemeng.9b00081
  • Peer Reviewed
• [Journal Article] Electrochemical Evaluation for Multiple Functions of Pt loaded TiO2 Nanoparticles Deposited on a Photocathode (2019)
  • Author(s): Yosuke Kageshima, Takumi Fujita, Fumiaki Takagi, Tsutomu Minegishi, Katsuya Teshima, Kazunari Domen, Yutaka Amao, Hiromasa Nishikiori
  • Journal Title: ChemElectroChem Volume: 6 Issue: 18 Pages: 4859-4866
  • DOI: 10.1002/celc.201901453
  • Peer Reviewed
• [Journal Article] Light-driven CO2 Reduction to Formic Acid with a Hybrid System of Biocatalyst and Semiconductor Based Photocatalyst (2018)
  • Author(s): Ishibashi T.、Ikeyama S.、Ito M.、Ikeda S.、Amao Y.
  • Journal Title: Chemistry Letters Volume: 47 Issue: 12 Pages: 1505-1508
  • DOI: 10.1246/cl.180731
  • NAID: 130007534746
  • Peer Reviewed / Open Access
• [Journal Article] Activation of the catalytic function of formaldehyde dehydrogenase for formate reduction by single-electron reduced methylviologen (2018)
  • Author(s): Ishibashi T.、Ikeyama S.、Amao Y.
  • Journal Title: New Journal of Chemistry Volume: 42 Issue: 23 Pages: 18508-18512
  • DOI: 10.1039/c8nj02211a
  • Peer Reviewed
• [Journal Article] Abnormal co-enzymatic behavior of a one-electron reduced bipyridinium salt with a carbamoyl group on the catalytic activity of CO2 reduction by formate dehydrogenase (2018)
  • Author(s): Ikeyama S.、Amao Y.
  • Journal Title: New Journal of Chemistry Volume: 42 Issue: 19 Pages: 15556-15560
  • DOI: 10.1039/c8nj03478h
  • Peer Reviewed
• [Journal Article] Photoredox systems with biocatalysts for CO2 utilization (2018)
  • Author(s): Amao Y.
  • Journal Title: Sustainable Energy & Fuels Volume: 2 Issue: 9 Pages: 1928-1950
  • DOI: 10.1039/c8se00209f
  • Peer Reviewed
• [Presentation] Visible-light driven CO2 reduction and utilization with biocatalyst and organic dye hybrid system (2019)
  • Author(s): Yutaka Amao
  • Organizer: National Taiwan University Special Lecture
  • Int'l Joint Research / Invited
• [Presentation] Visible-light driven C-H bond activation and carboxylation with CO2 in the system of bio/photo-hybrid catalysts (2019)
  • Author(s): Yutaka Amao
  • Organizer: 8th Asia-Pacific Congress in Catalysis (APCAT8)
  • Int'l Joint Research / Invited
• [Presentation] Optical sensing technology for CO2 visualization (2019)
  • Author(s): Yutaka Amao
  • Organizer: 7th Japanese-German Joint Seminar, Molecular Imaging Technology for Interdisciplinary Research
  • Int'l Joint Research / Invited
• [Presentation] Visible-Light Driven Carbon Dioxide Reduction to Methanol with Bio/Photocatalyst Hybrid System - Studies on the Interaction between Electron Mediator and Biocatalyst Based on Enzyme Kinetic Analysis (2019)
  • Author(s): Yutaka Amao
  • Organizer: 3rd International Solar Fuels Conference (ISF-3) and International Conference on Artificial Photosynthesis-2019 (ICARP2019)
  • Int'l Joint Research / Invited
• [Presentation] Visible Light Driven Carbon Dioxide Reduction to Methanol with Photo/Biocatalysts Hybrid System (2019)
  • Author(s): Yutaka Amao
  • Organizer: 18th Asian Chemical Congress (18th ACC)
  • Int'l Joint Research / Invited
• [Presentation] Visible-light driven C-H bond activation and carboxylation of CO2 with bio-/photocatalytic hybrid system (2019)
  • Author(s): Yutaka Amao, Takayuki Katagiri
  • Organizer: 4th Green and Sustainable Chemistry Conference 2019
  • Int'l Joint Research
• [Presentation] Biocatalytic carboxylation using CO2 as the C1 source by malic enzyme and diphenylviologen derivative as an artificial co-enzyme (2019)
  • Author(s): Takayuki Katagiri, Shusaku, Ikeyama, Yutaka Amao
  • Organizer: Southeast Asia Catalysis Conference 2019 (SACC 2019)
  • Int'l Joint Research
• [Presentation] Hydrogen production based on formic acid decomposition with platinum nano particles dispersed by polyvinylpyrrolidone (2019)
  • Author(s): Yusuke Minami, Shusaku Ikeyama, Yutaka Amao
  • Organizer: The 8th World Hydrogen Technologies Convention (WHTC 2019)
  • Int'l Joint Research
• [Presentation] Hydrogen production from formic acid catalyzed by platinum nano particles dispersed by polyvinylpyrrolidone (2019)
  • Author(s): Yusuke Minami, Shusaku Ikeyama, Yutaka Amao
  • Organizer: The 23rd Annual Green Chemistry & Engineering Conference and 9th International Conference on Green and Sustainable Chemistry
  • Int'l Joint Research
• [Presentation] Biocatalytic carboxylation using CO2 as the C1 source by malic enzyme and diphenylviologen derivative as an artificial co-enzyme (2019)
  • Author(s): Takayuki Katagiri, Shusaku, Ikeyama, Yutaka Amao
  • Organizer: The 23rd Annual Green Chemistry & Engineering Conference and 9th International Conference on Green and Sustainable Chemistry
  • Int'l Joint Research
• [Presentation] Light-driven CO2 reduction to formate with the system of biocatalyst and semiconductor based photocatalyst (2019)
  • Author(s): Yutaka Amao, Tomoya Ishibashi, Shigeru Ikeda
  • Organizer: 17th International Conference on Carbon Dioxide Utilization - ICCDU 2019
  • Int'l Joint Research
• [Presentation] Selective CO2 reduction to formic acid with semiconductor photocatalyst and biocatalyst (2019)
  • Author(s): Tomoya Ishibashi, Shusaku Ikeyama, Yutaka Amao
  • Organizer: 8th Asia-Pacific Congress in Catalysis (APCAT8)
  • Int'l Joint Research
• [Presentation] Selective hydrogen production catalyzed by platinum nano particles dispersed by polyvinylpyrrolidone based on formate decomposition (2019)
  • Author(s): Yusuke Minami, Shusaku Ikeyama, Yutaka Amao
  • Organizer: 8th Asia-Pacific Congress in Catalysis (APCAT8)
  • Int'l Joint Research
• [Presentation] Carboxylation of organic molecule by CO2 with biocatalyst and double-electron reduced diphenylviologen derivative (2019)
  • Author(s): Takayuki Katagiri, Shusaku, Ikeyama, Yutaka Amao
  • Organizer: 8th Asia-Pacific Congress in Catalysis (APCAT8)
  • Int'l Joint Research
• [Presentation] Hybrid system of biocatalyst and semiconductor based photocatalyst for light-driven CO2 reduction to formate (2019)
  • Author(s): Yutaka Amao, Tomoya Ishibashi, Shigeru Ikeda
  • Organizer: 14th European Congress on Catalysis (EuropaCat 2019)
  • Int'l Joint Research
• [Presentation] Building carbon-carbon bond from CO2with malic enzyme and viologen derivative (2019)
  • Author(s): Takayuki Katagiri, Shusaku, Ikeyama, Yutaka Amao
  • Organizer: 4th EuCheMS Conference on Green and Sustainable Chemistry
  • Int'l Joint Research
• [Presentation] Selective Hydrogen Production from Formate with Polyvinylpyrrolidone-coordinated Platinum Nanoparticles (2019)
  • Author(s): Yutaka Amao, Yusuke Minami
  • Organizer: 7th Asian Conference on Coordination Chemistry (ACCC7)
  • Int'l Joint Research
• [Presentation] 生体触媒による二酸化炭素の還元と分子への固定 (2019)
  • Author(s): 天尾 豊
  • Organizer: 第 57 回触媒研究懇談会
  • Invited
• [Presentation] 生体触媒を利用した二酸化炭素の物質変換 (2019)
  • Author(s): 天尾 豊
  • Organizer: 2019年度先端錯体工学研究会 (SPACC) 年会
  • Invited
• [Presentation] 生体触媒による二酸化炭素の利用と分子貯蔵 (2019)
  • Author(s): 天尾 豊
  • Organizer: 北海道大学大学院環境科学専攻講演会
  • Invited
• [Presentation] Biocatalytic carbon dioxide conversion to organic molecule (2019)
  • Author(s): 天尾 豊
  • Organizer: 錯体化学会第69回討論会
  • Invited
• [Presentation] CO2 fixation with malic enzyme and diphenylviologen derivative as a co-enzyme (2019)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 第10回触媒科学研究発表会
• [Presentation] Development of CO2 reduction system using TiO2 and formate dehydrogenase (2019)
  • Author(s): 石橋 知也, 池山 秀作, 東 正信、天尾 豊
  • Organizer: 第10回触媒科学研究発表会
• [Presentation] 生体触媒と二電子還元型ジフェニルビオローゲン誘導体を用いた二酸化炭素の有機分子への固定化 (2019)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 第8回JACI/GSCシンポジウム
• [Presentation] ポリビニルピロリドンで分散した白金ナノ微粒子によるギ酸分解に基づく選択的水素生成機構の解明 (2019)
  • Author(s): 南 祐輔、池山 秀作、天尾 豊
  • Organizer: 第124回触媒討論会
• [Presentation] 半導体光触媒とギ酸脱水素酵素を用いた水を電子源とする光駆動型二酸化炭素還元反応に関する研究 (2019)
  • Author(s): 石橋 知也, 池山 秀作, 東 正信、天尾 豊
  • Organizer: 第124回触媒討論会
• [Presentation] 生体触媒と人工補酵素ジフェニルビオローゲン誘導体を用いた二酸化炭素の固定化 (2019)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 第124回触媒討論会
• [Presentation] ポリビニルピロリドンを保護コロイドとして分散させた白金ナノ微粒子が触媒するギ酸分解に基づく選択的水素生成機構 (2019)
  • Author(s): 南 祐輔、池山 秀作、天尾 豊
  • Organizer: 第49回石油・石油化学討論会（山形大会）
• [Presentation] TiO2とギ酸脱水素酵素を用いた水を電子源とするCO2光還元系の開発 (2019)
  • Author(s): 石橋 知也, 池山 秀作, 東 正信、天尾 豊
  • Organizer: 第49回石油・石油化学討論会（山形大会）
• [Presentation] リンゴ酸酵素が触媒する二酸化炭素固定反応における多電子蓄積ジフェニルビオローゲン誘導体の機能に関する研究 (2019)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 第49回石油・石油化学討論会（山形大会）
• [Presentation] ポリビニルピロリドンで分散した白金微粒子が触媒するギ酸分解機構の分光法による検討 (2019)
  • Author(s): 南 祐輔、池山 秀作、天尾 豊
  • Organizer: 第38回水素エネルギー協会大会 (HESS大会)
• [Presentation] ギ酸脱水素酵素が触媒する二酸化炭素還元反応における二酸化炭素反応種の影響 (2019)
  • Author(s): 佐藤 涼平、池山 秀作、天尾 豊
  • Organizer: 日本化学会第100春季年会
• [Presentation] ギ酸分解に基づく水素生成を触媒する白金ナノ微粒子触媒の機構解明 (2019)
  • Author(s): 南 祐輔、池山 秀作、天尾 豊
  • Organizer: 日本化学会第100春季年会
• [Presentation] Effect of metal ion on the CO2 addition by malic enzyme with viologen derivative (2019)
  • Author(s): Takayuki Katagiri, Shusaku, Ikeyama, Yutaka Amao
  • Organizer: 日本化学会第100春季年会
• [Presentation] 半導体光触媒と生体触媒を用いた光駆動型二酸化炭素-ギ酸変換反応に関する研究 (2019)
  • Author(s): 石橋 知也、池山 秀作、天尾 豊
  • Organizer: 日本化学会第99春季年会
• [Presentation] 人工補酵素ジフェニルビオローゲン誘導体とリンゴ酸酵素による二酸化炭素を原料とした有機分子のカルボキシ化 (2019)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 日本化学会第99春季年会
• [Presentation] 二酸化炭素の有効利用に向けた人工光合成技術 (2019)
  • Author(s): 天尾豊
  • Organizer: 石灰石鉱業協会環境セミナー
  • Invited
• [Presentation] Visible-Light Driven C-H bond Activation and Carboxylation with CO2 Using Biocatalyst/Photocatalytic Dye Hybrid System (2018)
  • Author(s): 天尾豊
  • Organizer: 10th Asian Photochemistry Conference
  • Int'l Joint Research / Invited
• [Presentation] Visble-Light Driven Carboxylation with CO2 with The System of Biocatalyst And Photocatalytic Dye (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 7th Asia-Oceania Conference on Green and Sustainable Chemistry
  • Int'l Joint Research
• [Presentation] 還元型メチルビオローゲンを用いたホルムアルデヒド脱水素酵素によるギ酸‐ホルムアルデヒド変換反応における酵素速度論的解析 (2018)
  • Author(s): 石橋 知也、池山 秀作、天尾 豊
  • Organizer: 第48回石油・石油化学討諭会 (創立60周年記念東京大会)
• [Presentation] 二電子還元型ジフェニルビオローゲンを用いたリンゴ酸酵素が触媒する二酸化炭素固定化反応における速度論的解析 (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 第48回石油・石油化学討諭会 (創立60周年記念東京大会)
• [Presentation] 還元型メチルビオローゲンを用いたギ酸還元におけるホルムアルデヒド脱水素酵素の触媒活性の評価 (2018)
  • Author(s): 石橋 知也、池山 秀作、天尾 豊
  • Organizer: 第122回触媒討論会
• [Presentation] 二酸化炭素資源化のためのリンゴ酸酵素と新規人工補酵素との相互作用に関する速度論的考察 (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 第122回触媒討論会
• [Presentation] カルバモイル基を有するビオローゲンの一電子還元体のギ酸脱水素酵素のCO2 還元触媒活性に及ぼす効果 (2018)
  • Author(s): 池山 秀作、天尾 豊
  • Organizer: 第122回触媒討論会
• [Presentation] 生体触媒を利用した二酸化炭素の物質変換 (2018)
  • Author(s): 天尾豊
  • Organizer: 化学工学会第50回秋季大会
  • Invited
• [Presentation] Visible-Light Driven Carboxylation with CO2 in the Hybrid System of Biocatalyst and Photocatalytic Dye (2018)
  • Author(s): 天尾豊
  • Organizer: The 8th International IUPAC Conference on Green Chemistry (ICGC-8)
  • Int'l Joint Research
• [Presentation] Interaction between diphenylviologen derivative and malic enzyme for carbon-carbon bond formation from CO2 as a feedstock (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: The 8th International IUPAC Conference on Green Chemistry (ICGC-8)
  • Int'l Joint Research
• [Presentation] Enzyme Kinetic Analysis in Formate Reduction to Formaldehyde Using Aldehyde Dehydrogenase by One-Election Reduced Methylviologen (2018)
  • Author(s): 石橋 知也、池山 秀作、天尾 豊
  • Organizer: The 8th International IUPAC Conference on Green Chemistry (ICGC-8)
  • Int'l Joint Research
• [Presentation] 人工補酵素-ギ酸脱水素酵素系による炭酸ガスからのギ酸合成 (2018)
  • Author(s): 天尾豊
  • Organizer: 第70回日本生物工学会大会
  • Invited
• [Presentation] Visible light-driven building C-C bonds from CO2 as a feedstock with photosensitizer-biocatalyst hybrid system (2018)
  • Author(s): 天尾 豊、片桐 毅之、池山 秀作
  • Organizer: The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
  • Int'l Joint Research
• [Presentation] Kinetic studies of the interaction between diphenylviologen derivative as a novel co-enzyme and malic enzyme for building carbon-carbon bond from CO2 (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
  • Int'l Joint Research
• [Presentation] Selective formate reduction to formaldehyde with formaldehyde dehydrogenase and single‐electron reduced methylviologen (2018)
  • Author(s): 石橋 知也、池山 秀作、天尾 豊
  • Organizer: The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
  • Int'l Joint Research
• [Presentation] Visible light-driven building carbon-carbon bond from CO2 as a feedstock with hybrid redox system of organic dye and biocatalys (2018)
  • Author(s): 天尾豊
  • Organizer: 2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology
  • Int'l Joint Research / Invited
• [Presentation] Catalytic function of aldehyde dehydrogenase for formic acid reduction by one‐electron reduced methylviologen as an artificial co-enzyme (2018)
  • Author(s): 石橋 知也、池山 秀作、天尾 豊
  • Organizer: 2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology
  • Int'l Joint Research
• [Presentation] Double-electron reduced diphenylviologen derivative as a novel co-enzyme for biocatalyst with the function of carbon-carbon bond formation from CO2 (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology
  • Int'l Joint Research
• [Presentation] Kinetic studies of the interaction between malic enzyme and diphenylviologen derivative for CO2 utilization (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: The 18th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC18)
  • Int'l Joint Research
• [Presentation] Selective formic acid reduction to formaldehyde with aldehyde dehydrogenase and reduced form of methylviologen as an artificial co-enzyme (2018)
  • Author(s): 石橋 知也、池山 秀作、天尾 豊
  • Organizer: The 18th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC18)
  • Int'l Joint Research
• [Presentation] Studies on the interaction between artificial co-enzyme based on diphenylviologen derivative and malic enzyme for CO2 utilization (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: The 22nd Annual Green Chemistry & Engineering Conference (GC&E)
  • Int'l Joint Research
• [Presentation] Evaluation of catalytic activity of malic enzyme for CO2 fixation by two-electron reduced form of diphenylviologen (2018)
  • Author(s): 片桐 毅之、池山 秀作、天尾 豊
  • Organizer: 触媒学会西日本支部第 9回触媒科学研究発表会
• [Presentation] Catalytic formate reduction using formaldehyde dehydrogenase by reduced form of methylviologen (2018)
  • Author(s): 石橋 知也、池山 秀作、天尾 豊
  • Organizer: 触媒学会西日本支部第 9回触媒科学研究発表会
• [Presentation] Visible-light driven building C-C bonds from CO2 with photosensitizer-biocatalyst system (2018)
  • Author(s): 天尾 豊、片桐 毅之、池山 秀作
  • Organizer: 3rd Green & Sustainable Chemistry Conference
  • Int'l Joint Research
• [Book] 生体触媒を利用した可視光で作動する二酸化炭素還元と資源化 (2018)
  • Author(s): 天尾豊
  • Total Pages: 222
  • Publisher: 触媒
• [Book] 生体触媒を用いた人工光合成 (2018)
  • Author(s): 天尾豊
  • Publisher: オプトロニクス
• [Book] 生体触媒を活用した光エネルギーを利用した二酸化炭素の資源化 (2018)
  • Author(s): 天尾豊
  • Publisher: ペトロテック
• [Remarks]
  • URL: https://www.recap.osaka-cu.ac.jp/site/amao/
• [Remarks] 大阪市立大学複合先端研究機構天尾研究室HP
  • URL: http://www.ocarina.osaka-cu.ac.jp/site/amao