超分子ローター構造を利用した物性開拓

• Project Area: New Frontier in Materials Science Opened by Molecular Degrees of Freedom
• Project/Area Number: 21110503
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Tohoku University (2010); Hokkaido University (2009)
• Principal Investigator: 芥川 智行 東北大学, 多元物質科学研究所, 教授 (60271631)
• Project Period (FY): 2009 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000); Fiscal Year 2010: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000); Fiscal Year 2009: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
• Keywords: 分子性結晶 / 強誘電体 / 分子モーター / 超分子 / 導電性 / 金属錯体 / クラウンエーテル / 分子機械 / 強誘電本 / 分子磁性 / 分子ローター / 誘電率 / アダマンタン

Research Abstract

分子性結晶内に、分子の揺らぎや回転の自由度を導入したシステムは、結晶格子の柔らかさを利用した新規な物性開拓の場を提供する。本研究では、1R,2R-cyclohexanediammonium(CHDA^<2+>)-(crown ethers)_2カチオン構造中のCHDA^<2+>の振り子運動及びp-cyanomethylanilinium(CMAni^+)-[18]crown-6カチオンのコンフォメーション変化がもたらす構造相転移について検討した。
結晶中の分子運動が誘電応答に表れる系として、(CHDA^<2+>)([18]crown-6)_2[Ni(dmit)_2]^-_2(1)及び(CHDA^<2+>)(benzo[18]crown-6)_2[Ni(dmit)_2]^-_2(2)を作製した。CHDA^<2+>は、二つbenzo[18]crown-6分子にサンドイッチ型で挟まれ、水素結合相互作用により超分子カチオン構造を形成している。CHDA^<2+>ジカチオンは、二つの-NH_3^+基のN-N軸を回転軸として振り子運動を行う。結晶の誘電率の温度-周波数依存性から、振り子運動の方向に対応する測定で、誘電応答が観測された。ポテンシャルエネルギー計算から、非対称な運動空間の存在が示唆され、分子揺らぎが熱的に活性化される事が判明した。(CMAni^+)([18]crown-6)[Ni(dmit)_2](3)結晶では、153Kに構造相転移が出現した。CMAni^+カチオンのフェニル基の回転運動とp-位のcyanomethyl(-CH_2CN)基の振り子運動が関与した構造相転移を新規に見出した。分子コンフォメーションに自由度のある超分子カチオン構造を利用する事で、分子揺らぎに対応した構造相転移現象が実現できた。

Research Products

• [Journal Article] Supramolecular cations of the m-fluoroanilinium(dibenzo[18]crown-6) in ferromagnetic salt (2011)
  • Author(s): Toru Endo, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura
  • Journal Title: Dalton Transactions Volume: 40 Pages: 1491-1496
  • Peer Reviewed
• [Journal Article] Ferromagnetic coupling of [Ni(dmit)_2]^- anions in (m-fluoroanilinium)(dicyclohexano[18]crown-6)[Ni(dmit)_2] (2010)
  • Author(s): Tomoyuki Akutagawa, Daisuke Sato, Qiong Ye, Shin-ichiro Noro, Takayoshi Nakamura
  • Journal Title: Dalton Transactions Volume: 39 Pages: 2191-2193
  • Peer Reviewed
• [Journal Article] Conformational Polymorph of o-Aminoanilinium(dibenzo[18]crown-6) Supramolecules in [Ni(dmit)_2]^- Salts (2010)
  • Author(s): Tomoyuki Akutagawa, Hiroyuki Koshinaka, Qiong Ye, Shin-ichiro Noro, Jun Kawamata, Hiroshi Yamaki, Takayoshi Nakamura
  • Journal Title: Chemistry An Asian Journal Volume: 5 Pages: 520-529
  • Peer Reviewed
• [Journal Article] Excited state intramolecular proton transfer (ESIPT) in six-coordinated zinc(II)-quinoxaline complexes with ligand hydrogen bonds : their fluorescent properties sensitive to axial positions (2010)
  • Author(s): Ken-ichi Sakai, Sami Takahashi, Ataru Kobayashi, Tomoyuki Akutagawa, Takayoshi Nakamura, Masaaki Dosen, Masako Kato, Umpei Nagashim
  • Journal Title: Dalton Transactions Volume: 39 Pages: 1989-1995
  • Peer Reviewed
• [Journal Article] Selective separation of larger molecules from Lewis base mixture by flexible one-dimensional Cu(II) coordination polymer with shape-recognizing space (2010)
  • Author(s): Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Chemical Communications Volume: 46 Pages: 3134-3136
  • Peer Reviewed
• [Journal Article] Orthogonality of Jahn-Teller axes in a dinuclear Cu(II) complex bridged by one F^- anion (2010)
  • Author(s): Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Chemical Communications Volume: 46 Pages: 4619-4620
  • NAID: 120005906982
  • Peer Reviewed
• [Journal Article] [18]crown-6 Rotator in Spin-Ladder Compound of m-Aminoanilinium([18]crown-6)[Ni(dmit)_2]^- (2010)
  • Author(s): Tomoyuki Akutagawa, Daisuke Sato, Ye Qiong, Toru Endo, Shin-ichiro Noro, Sadamu Takeda, Takayoshi Nakamura
  • Journal Title: Dalton Transactions Volume: 39 Pages: 8219-8227
  • Peer Reviewed
• [Journal Article] Asymmetrical [Ni(dmit)_2]^- Arrangements Induced by (1R,2R)-Cyclohexanediammonium-Crown Ether Supramolecules (2010)
  • Author(s): Qiong Ye, Tomoyuki Akutagawa, Toru Endo, Shin-ichiro Noro, Takayoshi Nakamura, Ren-Gen Xiong
  • Journal Title: Inorganic Chemistry Volume: 49 Pages: 8591-8600
  • Peer Reviewed
• [Journal Article] Zn_3(4-OOCC_6H_4PO_3)_2 : A polar metal phosphonate with pillared layered structure showing SHG-activity and large dielectric anisotropy (2010)
  • Author(s): Jin-Tang Li, Deng-Ke Cao, Tomoyuki Akutagawa, Li-Min Zheng
  • Journal Title: Dalton Transactions Volume: 39 Pages: 8606-8608
  • Peer Reviewed
• [Journal Article] Highly Polar 7,7-Bis(N,N-dimethylpiperazinium)-8,8-dicyanoquinodimethane in [Ni(dmit)_2]^- Salt ; Crystal Structure and Magnetic Properties (2010)
  • Author(s): Subbalakshmi Jayanty, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: CrystEngComm. Volume: 12 Pages: 4087-4090
  • Peer Reviewed
• [Journal Article] Polymorphism and Magnetism of cis-Cyclohexane-1, 4-diammonium)(Dicyclohexano [18]crown-6)_2[Ni(dmit)_2]_2 Salts (2010)
  • Author(s): Qiong Ye, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura, Ren-Gen Xiong
  • Journal Title: Cryst.Growth & Des Volume: 10 Pages: 4856-4860
  • Peer Reviewed
• [Journal Article] Electron transport in a gold nanoparticle assembly structure stabilized by a physisorbed porphyrin derivative (2010)
  • Author(s): Yuki Noda, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Phys.Rev.B. Volume: 82
  • NAID: 120002649886
  • Peer Reviewed
• [Journal Article] An Imidazolate- and Azide-Bridged Copper(II) Coordination Polymer Consisting of Alternating Di- and Mononuclear Units (2010)
  • Author(s): Ken-ichi Sakai, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Eur.J.Inorg.Chem Volume: 2010 Pages: 116-120
  • Peer Reviewed
• [Journal Article] Diverse structures and adsorption properties of quasi-Werner-type copper(II) complexes (2010)
  • Author(s): Shin-ichiro Noro, Tomonori Ohba, Katsuo Fukuhara, Yukiko Takahashi, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Dalton Transactions Volume: 40 Pages: 2268-2274
  • Peer Reviewed
• [Journal Article] Langmuir-Blodgett Films of Charge-Transfer Complexes : Ethylenedithio-Substituted Amphiphilic Bis-TTF Macrocycle and F_4TCNQ or Br_2TCNQ (2009)
  • Author(s): Toru Endo, Tomoyuki Akutagawa, Teppei Kajiwara, Keiko Kakiuchi, Yoko Tatewaki, Shin-ichiro Noro, Takayoshi Nakamura
  • Journal Title: Bull.Chem.Soc.Jpn. 82 Pages: 968-974
  • NAID: 10025126961
  • Peer Reviewed
• [Journal Article] Ferromagnetic and Antiferromagnetic Coupling of[Ni(dmit)_2]^- Anion Layers Induced by Cs^+_2(benzo[18]crown-6)_3 Supramolecule (2009)
  • Author(s): Tomoyuki Akutagawa, Kozo Shitagami, Masaki Aonuma, Shin-ichiro Noro, Takayoshi Nakamura
  • Journal Title: Inorganic Chemistry 48 Pages: 4454-4461
  • Peer Reviewed
• [Journal Article] Coordination polymers constructed from transition metal ions and organic N-containing heterocyclic ligands : Crystal structures and microporous properties (2009)
  • Author(s): Shin-ichiro Noro, Ssusumu Kitagawa, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Progress in Polymer Science 34 Pages: 240-279
  • Peer Reviewed
• [Journal Article] Doping effect of nonmagnetic impurity on the spin-Peierls-like transition in the quasi-one-dimensional(quasi-1D)spin system of 1-(4'-nitrobenzyl)pyridinium bis(maleonitriledithiolato)nickelate (2009)
  • Author(s): X.M.Ren, G.X.Liu, H.Xu, T.Akutagawa, T.Nakamura
  • Journal Title: Polyhedron 28 Pages: 2075-2079
  • Peer Reviewed
• [Journal Article] C Supramolecular Silver Polyoxometalate Architectures Direct the Growth of Composite Semiconducting Nanostructures (2009)
  • Author(s): C.Streb, R.Tsunashima, D.A.Mac Laren, T.McGlone, T.Akutagawa, T.Nakamura, A.Scandurra, B.Pignataro, N.Gadegaard, L.Cronin
  • Journal Title: Angew.Chem.Int.Ed. 48 Pages: 6490-6493
  • Peer Reviewed
• [Journal Article] Selective Gas Adsorption in One-Dimensional, Flexible Cu^<II> Coordination Polymers with Polar Units (2009)
  • Author(s): S.Noro, D.Tanaka, H.Sakamoto, S.Shimomura, S.Kitagawa, S.Takeda, K.Uemura, H.Kita, T.Akutagawa, T.Nakamura
  • Journal Title: Chem.Mater. 21 Pages: 3346-3355
  • Peer Reviewed
• [Journal Article] Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring-Shaped Polyoxometalate Cluster (2009)
  • Author(s): S.Noro, R.Tsunashima, Y.Kamiya, K.Uemura, H.Kita, L.Cronin, T.Akutagawa, T.Nakamura
  • Journal Title: Angew.Chem.Int.Ed. 48 Pages: 8703-8706
  • Peer Reviewed
• [Journal Article] Nonlinear Transport Phenomena in Highly One-Dimensional M^<III>(Pc)(CN)_2 Chains with π-d Interaction(M=Co and Fe and Pc=Phthalocyaninato) (2009)
  • Author(s): M.Ishikawa, S.Yamashita, T.Naito, M.Matsuda, H.Tajima, N.Hanasaki, T.Akutagawa, T.Nakamura, T.Inabe
  • Journal Title: J.Phys.Soc.Jpn. 78 Pages: 104709-104709
  • Peer Reviewed
• [Journal Article] Structure, Magnetism, and Ionic Conductivity of the Gigantic{Mo_<176>}-Wheel Assembly : Na_<15>Fe_3Co_<16>[Mo_<176>O_<528>H_3(H_2O)_<80>]Cl_<27>・450H_2O (2009)
  • Author(s): H.Imai, T.Akutagawa, F.Kudo, M.Ito, K.Toyoda, S.Noro, L.Cronin, T.Nakamura
  • Journal Title: J.Am Chem.Soc. 131 Pages: 13578-13579
  • Peer Reviewed
• [Journal Article] Ferroelectri city and polarity control in solid state flip-flop supramolecular rotators (2009)
  • Author(s): T.Akutagawa, H.Koshinaka, D.Sato, S.Takeda, S.Noro, H.Takahasi, R.Kumai, Y.Tokura, T.Nakamura
  • Journal Title: Nature Materials 8 Pages: 342-347
  • Peer Reviewed
• [Presentation] luoroadamantylammonium/Dibenzo[18]crown-6超分子を導入した[Ni(dmit)_2]塩の構造と物性 (2011)
  • Author(s): 厳寅男、芥川智行、野呂真一郎、中村貴義
  • Organizer: 化学系学協会北海道支部2011年冬季研究発表会
  • Place of Presentation: 北海道大学
• [Presentation] Pyridazinium/[18]crown-6誘導体超分子カチオンを含む[Ni(dmit)_2]塩の結晶構造 (2011)
  • Author(s): 劉尊奇、李玲、久保和也, 野呂真一郎、芥川智行、中村貴義
  • Organizer: 化学系学協会北海道支部2011年冬季研究発表会
  • Place of Presentation: 北海道大学
• [Presentation] イオンチャネル構造を有するLi_2([18]crown-6)_3[Ni(dmit)_2]_2(H_2O)_4塩の構造と物性 (2011)
  • Author(s): 今野大輔、原禎文、秋田素子、井上克也、芥川智行、中村貴義
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学
• [Presentation] スピンラダー構造を有する[Ph(NH_3)]([18]crown-6)[Ni(dmit)_2]塩へのキャリアドーピングと電気物性評価 (2011)
  • Author(s): 國塩和久、西原禎文、芥川智行、中村貴義、秋田素子、井上克也
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学
• [Presentation] ルビウムフタロシアニンダブルデッカー錯体-金ナノ粒子複合体の磁気特性 (2011)
  • Author(s): 野田祐樹・野呂真一郎・久保和也・芥川智行・中村貴義
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学
• [Presentation] 籠状金属酸化物クラスター内に閉じ込められた亜硫酸イオンの熱振動とサーモクロミズム (2011)
  • Author(s): 綱島亮・Long, De-Liang・Cronin, Leroy・石黒勝也・芥川智行・中村貴義
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学
• [Presentation] フルオロアダマンチルアンモニウム誘導体を利用した超分子ローター型強誘電体の作製 (2010)
  • Author(s): 厳寅男・野呂真一郎・芥川智行・中村貴義
  • Organizer: 北海道支部2010年夏季研究発表会
  • Place of Presentation: 函館高専
  • Year and Date: 2010-07-24
• [Presentation] (Anilinium誘導体)(benzo[18]crown-6)[MnCr(ox)_3]結晶における分子回転と磁性 (2010)
  • Author(s): 遠藤格・芥川智行・野呂真一郎・中村貴義
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪国際交流センター
• [Presentation] [Ni(dmit)_2]単結晶中に構築したフルオロアダマンチルアンモニウム超分子ローターの回転と誘電性・磁性 (2010)
  • Author(s): 厳寅男・野呂真一郎・芥川智行・中村貴義
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪国際交流センター
• [Presentation] Pyridazine/[18]crown-6誘導体超分子カチオンを含む[Ni(dmit)_2]塩の結晶構造と誘電性 (2010)
  • Author(s): 劉尊奇・李玲・野呂真一郎・芥川智行・中村貴義
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪国際交流センター
• [Presentation] 水素結合型レニウム混合原子価錯体の構造と性質 (2010)
  • Author(s): 小川直希・芥川智行・小向得優・田所誠
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪国際交流センター
• [Presentation] フタロシアニンダブルデッカー-金ナノ粒子集積体の量子伝導挙動 (2010)
  • Author(s): 野田祐樹, 野呂真一郎, 芥川智行, 中村貴義
  • Organizer: 分子科学討論会2010
  • Place of Presentation: 大阪大学豊中キャンパス
• [Presentation] 分子性結晶内の動的自由度と誘電物性 (2010)
  • Author(s): 芥川智行
  • Organizer: 名古屋大学グローバルCOEプログラム 第4回物質科学フロンティアセミナー
  • Place of Presentation: 名古屋大学
• [Presentation] 分子性結晶中の多彩な分子揺らぎと誘電応答 (2010)
  • Author(s): 芥川智行
  • Organizer: 第4回G-COE研究会「金属錯体の固体物性科学最前線-錯体化学と固体物性物理と生物物性の連携新領域創成をめざして-」
  • Place of Presentation: 東北大学
• [Presentation] Ferroelectric Supramolecular Rotators in Magnetic [Ni(dmit)_2] Salts (2010)
  • Author(s): Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: International Conference on Science and Technology of Synthetic Metals (ICSM2010)
  • Place of Presentation: Kyoto
• [Presentation] Crystal Structure and Magnetic Properties of (3-fluoro-4-methoxyanilinium)([18]crown-6)[Mn^<II>Cr^<III>(ox)_3] (2010)
  • Author(s): Toru Endo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: International Conference on Science and Technology of Synthetic Metals (ICSM2010)
  • Place of Presentation: Kyoto
• [Presentation] Fluoroadamantylammonium-Crown Ethers Supramolecular Rotators in [Ni(dmit)_2] Salts (2010)
  • Author(s): Y.Yan, S.Noro, T.Akutagawa, T.Nakamura
  • Organizer: International Conference on Science and Technology of Synthetic Metals (ICSM2010)
  • Place of Presentation: Kyoto
• [Presentation] Fabrication of Gold Nanoparticle Assemblies Connected by Double-decker Phthalocyanine Complex via van der Waals Interactions (2010)
  • Author(s): Y.Noda, S.Noro, T.Akutagawa, T.Nakamura
  • Organizer: International Conference on Nanoscopic Colloid and Surface Science (NCSS2010)
  • Place of Presentation: Tuskuba
• [Presentation] Structural Flexibility and Dielectric Responses of Supramolecules in [Ni(dmit)_2] Salts (2010)
  • Author(s): T.Akutagawa, Q.Ye, T.Nakamura
  • Organizer: The 10th Japan-China Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena (10JCJS)
  • Place of Presentation: Kyoto
• [Presentation] Design of Supramolecular Rotators in Solid State Toward Novel Functional Systems (2010)
  • Author(s): H.Ye, S.Noro, T.Akutagawa, T.Nakamura
  • Organizer: The 10th Japan-China Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena (10JCJS)
  • Place of Presentation: Kyoto
• [Presentation] Crystal Structures and Dielectric Response of (Pyridazine)([18]crown-6 derivatives)[Ni(dmit)_2] Salts (2010)
  • Author(s): Zunqi Liu, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: The 10th Japan-China Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena (10JCJS)
  • Place of Presentation: Kyoto
• [Presentation] molecular motion of Supramolecular Cations in Ferromagnetic Layer Structure of [MnCr(oxalate)_3] (2010)
  • Author(s): Toru Endo, Tomoyuki Akutagawa, Shin-ichiro Noro, Sadamu Takeda, Takayoshi Nakamura
  • Organizer: The 10th Japan-China Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena (10JCJS)
  • Place of Presentation: Kyoto
• [Presentation] Molecular Fluctuation and Dielectric Response in Flexible Supramolecular Complexes (2010)
  • Author(s): Tomoyuki Akutagawa
  • Organizer: International Symposium on Advanced Soft Materials
  • Place of Presentation: Kumamoto
• [Presentation] Ferroelectricity in magnetic [Ni(dmit)_2] salts (2010)
  • Author(s): Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: PacificChem2010
  • Place of Presentation: Honolulu Hawaii USA
• [Presentation] Supramolecular functional systems in electrically active molecular assemblies (2010)
  • Author(s): Takayoshi Nakamura, Toru Endo, Shin-ichiro Noro, Tomoyuki Akutagawa
  • Organizer: PacificChem2010
  • Place of Presentation: Honolulu Hawaii USA
• [Presentation] Dielectric properties of ferromagnetic (fluoroanilinium)([18]crown-6)[MnCr(ox)_3] salts (2010)
  • Author(s): Toru Endo, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura
  • Organizer: PacificChem2010
  • Place of Presentation: Honolulu Hawaii USA
• [Presentation] Dipole Rotator in Ferroelectric[Ni(dmit)_2]Salts (2009)
  • Author(s): 芥川智行
  • Organizer: Global-COE International Conference on Perspectives in Organic-Inorganic Hybrid Conductors and Molecule-Based Magnets
  • Place of Presentation: Tohoku University(仙台市)
  • Year and Date: 2009-09-11
• [Presentation] Ferroelectricity Arising From Molecular Rotators in Magnetic[Ni(dmit)_2]Salts (2009)
  • Author(s): 芥川智行, 中村貴義
  • Organizer: ISCOM2009 The 8th international symposium on crystalline organic metals, superconductors, and ferromagnets
  • Place of Presentation: Niseko Hilton Village(ニセコ町)
• [Presentation] Dielectric Properties and Supramolecular Rotators in[Ni(dmit)_2]Salts (2009)
  • Author(s): 芥川智行, 中村貴義
  • Organizer: The 2nd Asian Conference on Coordination Chemistry
  • Place of Presentation: Nanjin, China
• [Presentation] Crystal Structures of[MnIICrIII(ox)3]Salts with o-Fluoroanilinium/([18]crown-6 or Dicyclohexano[18]crown-6)Supramolecular Cations (2009)
  • Author(s): 遠藤格, 野呂真一郎, 芥川智行, 中村貴義
  • Organizer: The 2nd Asian Conference on Coordination Chemistry
  • Place of Presentation: Nanjin, China
• [Presentation] 固相超分子ローター構造の設計と誘電物性の制御 (2009)
  • Author(s): 芥川智行
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学(長崎市)
• [Presentation] 巨大リング状及びボール状金属酸化物と両親媒性有機分子との複合構造の合成と性質 (2009)
  • Author(s): 野呂真一郎, 芥川智行, 中村貴義
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学(長崎市)
• [Presentation] Anilinium 誘導体/[18]crown-6超分子カチオンを含む[Mn_<II>Cr_<III>(ox)_3]錯体の結晶構造と磁性 (2009)
  • Author(s): 遠藤格, 野呂真一郎, 芥川智行, 中村貴義
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学(長崎市)
• [Presentation] アダマンチルアミン誘導体-クラウンエーテル超分子構造を含む[Ni(dmit)_2]塩の構造と物性 (2009)
  • Author(s): Qing Ye, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学(長崎市)
• [Presentation] 混合原子価ポリオキサメタレート化合物の材料化 (2009)
  • Author(s): 芥川智行
  • Organizer: 東北大学G-COE研究会 金属錯体の固体物性科学最前線
  • Place of Presentation: 東北大学(仙台市)
• [Book] 界面コロイド科学の辞典 (2010)
  • Author(s): 芥川智行, 中村貴義
  • Publisher: 丸善
• [Book] 配位空間の化学-最新技術と応用-:誘電物性 (2009)
  • Author(s): 芥川智行・中村貴義
  • Total Pages: 15
  • Publisher: シーエムシー出版
• [Book] 有機強誘電体の新展開 (2009)
  • Author(s): 芥川智行
  • Total Pages: 2
  • Publisher: 化学と工業
• [Book] 超分子サイエンス&テクノロジー (2009)
  • Author(s): 芥川智行・中村貴義
  • Total Pages: 9
  • Publisher: NTS出版