格子不整合二次元ナノ界面における熱・電荷輸送の相関の解明と制御

• Project Area: Science of 2.5 Dimensional Materials: Paradigm Shift of Materials Science Toward Future Social Innovation
• Project/Area Number: 22H05469
• Research Category: Grant-in-Aid for Transformative Research Areas (A)
• Allocation Type: Single-year Grants
• Review Section: Transformative Research Areas, Section (II)
• Research Institution: Tokyo Metropolitan University
• Principal Investigator: 柳 和宏 東京都立大学, 理学研究科, 教授 (30415757)
• Project Period (FY): 2022-06-16 – 2024-03-31
• Project Status: Completed (Fiscal Year 2023)
• Budget Amount: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000); Fiscal Year 2023: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000); Fiscal Year 2022: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
• Keywords: 時間領域サーモリフレクタンス法 / 界面熱伝導 / 界面電気伝導 / 遷移金属ダイカルコゲナイド / 原子層 / 時間領域サーモリフレクタンス / 格子不整合界面 / インターカレーション / 熱輸送 / 電荷輸送 / 積層制御 / ファンデルワールス界面 / 熱電変換

Outline of Research at the Start

原子層物質を人為的に積層することにより形成される格子不整合な二次元ナノ界面は、顕著な断熱性を示す。この二次元界面は、高性能熱電変換や異方性熱輸送など新たな機能創出に繋がる可能性を秘めているが、その断熱性と電気伝導・熱起電力特性との関係は全く分かっていない。そこで本研究では、金を温度計金属として用いた時間領域サーモリフレクタンス法という申請者独自の熱輸送測定と、原子層積層技術・垂直デバイス作製技術を駆使し、系統的に界面構造を変化させた格子不整合二次元界面を対象に、その熱伝導・電気伝導の相関の解明し、また、熱起電力との関係を解き明かす為の端緒を得る。

Outline of Annual Research Achievements

申請者が有する金をトランスデューサとして活用した時間領域サーモリフレクタンス（TDTR）法を活用し、試料やデバイス構造に工夫を凝らすことにより格子不整合な２次元ナノ界面における熱伝導および電気伝導の解明（課題１）、および電気化学的に熱輸送を変調（課題２）することが可能であることを実証した。また、計測システムを改良し、顕微での計測が可能とさせ、単一ドメイン試料における熱伝導計測を達成した。課題１に関しては、化学気相法で合成された単層MoS2を４層積層した試料を作製し、金電極上への転写し、更に金電極をその上部に形成することにより、４層MoS2における熱伝導および電気伝導を計測することに成功した。有効熱伝導率は0.05 Wm^-1K^-1程の低熱伝導でありつつ、電気伝導率はバルクの１０分の１程度であることを明らかにした。また真空アニーリングによって、系統的に熱・電気コンダクタンスを増大可能であり、両者に一次の相関があることを明らかにした。理論計算により、層間距離の減少が主たる寄与であることが示唆されている。また課題２については、導電性ポリマー薄膜を対象として、イオンゲルを用いたイオンの電界による出し入れにより、熱伝導率が可逆的に変調されることを明らかにした。熱伝導は0.13 Wm^-1K^-1から0.23 Wm^-1K^-1程度へとイオンドーピングにより変調されることを明らかにした。導電性ポリマーにおける熱伝導の電界制御が可能であることを実証したはじめての例である。また顕微TDTR系を構築し、３層の単一ドメインMoS2における熱伝導率を決定することが可能であることを明らかにした。今後、積層角やヘテロ構造における熱・電荷輸送の相関の解明を可能とする計測手法の端緒を得た。

Research Progress Status

令和5年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和5年度が最終年度であるため、記入しない。

Research Products

• [Int'l Joint Research] Rice university/University of Utah(米国)
• [Int'l Joint Research] Heiderberg University(ドイツ)
• [Int'l Joint Research] ハイデルベルグ大学(ドイツ)
• [Int'l Joint Research] ライス大学(米国)
• [Journal Article] カーボンナノチューブの熱電応答 (2024)
  • Author(s): 柳和宏、山本貴博
  • Journal Title: 固体物理 Volume: 59 Pages: 5-15
  • Peer Reviewed
• [Journal Article] Thermoelectrics in thin films with van der Waals interfaces (2023)
  • Author(s): 柳 和宏
  • Journal Title: Oyo Buturi Volume: 92 Issue: 2 Pages: 79-83
  • DOI: 10.11470/oubutsu.92.2_79
  • ISSN: 0369-8009, 2188-2290
  • Year and Date: 2023-02-01
  • Peer Reviewed
• [Journal Article] Semiconducting Transition Metal Dichalcogenide Heteronanotubes with Controlled Outer-Wall Structures (2023)
  • Author(s): Yomogida Yohei、Nagano Mai、Liu Zheng、Ueji Kan、Rahman Md. Ashiqur、Ahad Abdul、Ihara Akane、Nishidome Hiroyuki、Yagi Takashi、Nakanishi Yusuke、Miyata Yasumitsu、Yanagi Kazuhiro
  • Journal Title: Nano Letters Volume: 23 Issue: 22 Pages: 10103-10109
  • DOI: 10.1021/acs.nanolett.3c01761
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Engineering chirality at wafer scale with ordered carbon nanotube architectures (2023)
  • Author(s): Doumani Jacques、Lou Minhan、Dewey Oliver、Hong Nina、Fan Jichao、Baydin Andrey、Zahn Keshav、Yomogida Yohei、Yanagi Kazuhiro、Pasquali Matteo、Saito Riichiro、Kono Junichiro、Gao Weilu
  • Journal Title: Nature Communications Volume: 14 Issue: 1 Pages: 7380-7380
  • DOI: 10.1038/s41467-023-43199-x
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Structural Diversity of Single-Walled Transition Metal Dichalcogenide Nanotubes Grown via Template Reaction (2023)
  • Author(s): Y. Nakanishi, S. Furusawa, Y. Sato, T. Tanaka, Y. Yomogida, K. Yanagi, W. Zhang, H. Nakajo, S. Aoki, T. Kato, K. Suenaga, Y. Miyata
  • Journal Title: Advanced Materials Volume: 35 Issue: 46 Pages: 23066312306631-23066312306631
  • DOI: 10.1002/adma.202306631
  • Peer Reviewed / Open Access
• [Journal Article] Unified Quantification of Quantum Defects in Small-Diameter Single-Walled Carbon Nanotubes by Raman Spectroscopy (2023)
  • Author(s): Sebastian Finn L.、Becker Felicitas、Yomogida Yohei、Hosokawa Yuuya、Settele Simon、Lindenthal Sebastian、Yanagi Kazuhiro、Zaumseil Jana
  • Journal Title: ACS Nano Volume: 17 Issue: 21 Pages: 21771-21781
  • DOI: 10.1021/acsnano.3c07668
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis and optical properties of WS2 nanotubes with relatively small diameters (2023)
  • Author(s): Rahman Md. Ashiqur、Yomogida Yohei、Ahad Abdul、Ueji Kan、Nagano Mai、Ihara Akane、Nishidome Hiroyuki、Omoto Mikito、Saito Shigeki、Miyata Yasumitsu、Gao Yanlin、Okada Susumu、Yanagi Kazuhiro
  • Journal Title: Scientific Reports Volume: 13 Issue: 1 Pages: 16959-16959
  • DOI: 10.1038/s41598-023-44072-z
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Extreme Polarization Anisotropy in Resonant Third‐Harmonic Generation from Aligned Carbon Nanotube Films (2023)
  • Author(s): Zhu Song、Li Wenkai、Yu Shengjie、Komatsu Natsumi、Baydin Andrey、Wang Fakun、Sun Fangyuan、Wang Chongwu、Chen Wenduo、Tan Chuan Seng、Liang Houkun、Yomogida Yohei、Yanagi Kazuhiro、Kono Junichiro、Wang Qi Jie
  • Journal Title: Advanced Materials Volume: 35 Issue: 41 Pages: 2304082-2304082
  • DOI: 10.1002/adma.202304082
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Multilayer In-Plane Heterostructures Based on Transition Metal Dichalcogenides for Advanced Electronics (2023)
  • Author(s): Ogura Hiroto、Kawasaki Seiya、Liu Zheng、Endo Takahiko、Maruyama Mina、Gao Yanlin、Nakanishi Yusuke、Lim Hong En、Yanagi Kazuhiro、Irisawa Toshifumi、Ueno Keiji、Okada Susumu、Nagashio Kosuke、Miyata Yasumitsu
  • Journal Title: ACS Nano Volume: 17 Issue: 7 Pages: 6545-6554
  • DOI: 10.1021/acsnano.2c11927
  • Peer Reviewed
• [Journal Article] Photoemission Study of One-Dimensional Electronic States of (6,5), (6,6), and (7,4) Single-Walled Carbon Nanotubes (2023)
  • Author(s): Suzuki Ryousuke、Kakihara Ryusuke、Ishii Hiroyoshi、Miyahara Tsuneaki、Maniwa Yutaka、Yanagi Kazuhiro、Iwasawa Hideaki、Shimada Kenya、Namatame Hirofumi、Taniguchi Masaki
  • Journal Title: Journal of the Physical Society of Japan Volume: 92 Issue: 2 Pages: 024703-024703
  • DOI: 10.7566/jpsj.92.024703
  • Peer Reviewed
• [Journal Article] Continuous Color‐Tunable Light‐Emitting Devices Based on Compositionally Graded Monolayer Transition Metal Dichalcogenide Alloys (2022)
  • Author(s): Pu Jiang、Ou Hao、Yamada Tomoyuki、Wada Naoki、Naito Hibiki、Ogura Hiroto、Endo Takahiko、Liu Zheng、Irisawa Toshifumi、Yanagi Kazuhiro、Nakanishi Yusuke、Gao Yanlin、Maruyama Mina、Okada Susumu、Shinokita Keisuke、Matsuda Kazunari、Miyata Yasumitsu、Takenobu Taishi
  • Journal Title: Advanced Materials Volume: 34 Issue: 44 Pages: 2203250-2203250
  • DOI: 10.1002/adma.202203250
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Surfactant-Assisted Isolation of Small-Diameter Boron-Nitride Nanotubes for Molding One-Dimensional van der Waals Heterostructures (2022)
  • Author(s): Furusawa Shinpei、Nakanishi Yusuke、Yomogida Yohei、Sato Yuta、Zheng Yongjia、Tanaka Takumi、Yanagi Kazuhiro、Suenaga Kazu、Maruyama Shigeo、Xiang Rong、Miyata Yasumitsu
  • Journal Title: ACS Nano Volume: 16 Issue: 10 Pages: 16636-16644
  • DOI: 10.1021/acsnano.2c06067
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Unravelling the Complete Raman Response of Graphene Nanoribbons Discerning the Signature of Edge Passivation (2022)
  • Author(s): Milotti Valeria、Berkmann Claudia、Laranjeira Jorge、Cui Weili、Cao Kecheng、Zhang Yifan、Kaiser Ute、Yanagi Kazuhiro、Melle‐Franco Manuel、Shi Lei、Pichler Thomas、Ayala Paola
  • Journal Title: Small Methods Volume: 6 Issue: 8 Pages: 2200110-2200110
  • DOI: 10.1002/smtd.202200110
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Electric-field-induced metal-insulator transition and quantum transport in large-area polycrystalline MoS2 monolayers (2022)
  • Author(s): Ou Hao、Yamada Tomoyuki、Mitamura Masaya、Edagawa Yusuke、Matsuda Tatsuma D.、Yanagi Kazuhiro、Chen Chang-Hsiao、Li Lain-Jong、Takenobu Taishi、Pu Jiang
  • Journal Title: Physical Review Materials Volume: 6 Issue: 6 Pages: 064005-064005
  • DOI: 10.1103/physrevmaterials.6.064005
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Conserved axis-dependent conduction polarity in NaSnAs polycrystalline bulk sample for transverse thermoelectric application (2022)
  • Author(s): Omprakash Muthusamy、Usui Hidetomo、Yanagi Kazuhiro、Mizuguchi Yoshikazu、Goto Yosuke
  • Journal Title: Materials Today Communications Volume: 31 Pages: 103558-103558
  • DOI: 10.1016/j.mtcomm.2022.103558
  • Peer Reviewed
• [Journal Article] Heat and Charge Carrier Flow through Single-Walled Carbon Nanotube Films in Vertical Electrolyte-Gated Transistors: Implications for Thermoelectric Energy Conversion (2022)
  • Author(s): Ueji Kan、Muto Nobuhiro、Heimfarth Daniel、Matsuoka Yuya、Ichinose Yota、Yomogida Yohei、Yagi Takashi、Zaumseil Jana、Yanagi Kazuhiro
  • Journal Title: ACS Applied Nano Materials Volume: 5 Issue: 5 Pages: 6100-6105
  • DOI: 10.1021/acsanm.2c01687
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Structures and optical properties of thin tungsten oxide nanowires treated with poly(ethylene glycol) (2022)
  • Author(s): Rahman Md. Ashiqur、Yomogida Yohei、Nagano Mai、Tanaka Ryoga、Yanagi Kazuhiro
  • Journal Title: Japanese Journal of Applied Physics Volume: 61 Issue: SD Pages: SD1018-SD1018
  • DOI: 10.35848/1347-4065/ac528c
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Formation of a Two-Dimensional Electronic System in Laterally Assembled WTe Nanowires (2022)
  • Author(s): Shimizu Hiroshi、Pu Jiang、Liu Zheng、Lim Hong En、Maruyama Mina、Nakanishi Yusuke、Ito Shunichiro、Kikuchi Iori、Endo Takahiko、Yanagi Kazuhiro、Oshima Yugo、Okada Susumu、Takenobu Taishi、Miyata Yasumitsu
  • Journal Title: ACS Applied Nano Materials Volume: - Issue: 5 Pages: 6277-6284
  • DOI: 10.1021/acsanm.2c00377
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Hall effect in gated single-wall carbon nanotube films (2022)
  • Author(s): Yomogida Yohei、Horiuchi Kanako、Okada Ryotaro、Kawai Hideki、Ichinose Yota、Nishidome Hiroyuki、Ueji Kan、Komatsu Natsumi、Gao Weilu、Kono Junichiro、Yanagi Kazuhiro
  • Journal Title: Scientific Reports Volume: 12 Issue: 1 Pages: 101-101
  • DOI: 10.1038/s41598-021-03911-7
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Presentation] 格子不整合二次元ナノ界面における 熱・電荷輸送の相関の解明と制御 (2023)
  • Author(s): 柳和宏
  • Organizer: 2.5次元領域会議
• [Presentation] 導電性高分子におけるラメラ層間インターカレーションと熱輸送 (2023)
  • Author(s): 伊藤 駿一郎, 上治寛, 竹延 大志, 柳 和宏
  • Organizer: 2.5次元領域会議
• [Presentation] Correlation between heat flow and current by interface control of ultrathin films made from dry-transferred MoS2 (2023)
  • Author(s): S. Nakamura, K. Ueji, K. Zhou, H. Nishidome, T. Yagi, Y. Yomogida, Y. Miyata, K. Yanagi
  • Organizer: 2.5次元領域会議
• [Presentation] Thermoelectric properties of aligned single-walled carbon nanotubes thin film (2023)
  • Author(s): Shojiro Asatori, Rikuto Abe, Kan Ueji, Yohei Yomogida, Kazuhiro Yanagi
  • Organizer: The 23rd international conference on the Science and Applications of Nanotubes and Low-Dimensional Materials (NT23)
  • Int'l Joint Research
• [Presentation] THERMAL AND ELECTRICAL CONDUCTIVITY THROUGH ULTRATHIN FILMS MADE FROM DRY-TRANSFERRED TRANSITION (2023)
  • Author(s): K. Ueji, K. Zhou, S. Nakamura, H. Nishidome, T. Yagi, Y. Yomogida, Y. Miyata, K. Yanagi
  • Organizer: The 23rd international conference on the Science and Applications of Nanotubes and Low-Dimensional Materials (NT23)
  • Int'l Joint Research
• [Presentation] Thermoelectrics at controlled nanotube and 2D interfaces (2023)
  • Author(s): Kazuhiro Yanagi
  • Organizer: PIRE-JUNCTION workshop
• [Presentation] Correlation between thermal and electrical conductance across the interfaces of stacked transition metal dichalcogenides (2023)
  • Author(s): K. Ueji1, K. Zhou1, S. Nakamura1, H. Nishidome1, T. Yagi2, Y. Yomogida1, Y. Miyata1, K. Yanagi1
  • Organizer: 応用物理学会フォノンエンジニアリング研究会 第7回研究会
• [Presentation] Correlation between heat flow and electrical current across 4 layered MoS2 (2023)
  • Author(s): Sota Nakamura, K. Ueji, K. Zhou, S. Saito, H. Nishidome, T. Yagi, T. Shiga, T. Yamamoto Y. Yomogida, Y. Miyata, K. Yanagi
  • Organizer: MNC conference 2023
  • Int'l Joint Research
• [Presentation] 人工積層したMoS2薄膜の面直方向電荷輸送・熱輸送のアニーリング効果 (2023)
  • Author(s): 上治 寛、チョウ カイヤオ、 中村 颯太、 齋藤 滋輝、 西留 比呂幸、 八木 貴志、 蓬田 陽平、 宮田 耕充、 柳 和宏
  • Organizer: 第84回応用物理学会秋季学術講演会
• [Presentation] モノドメイン積層界面における熱流と電流の相関 (2023)
  • Author(s): 朝鳥 祥史郎, 上治 寛, 中村 颯太, 斎藤 滋輝, 牧野 恭敬, 金子 嘉彦, 八木 貴志, 蓬田 陽平, 宮田 耕充, 柳 和宏
  • Organizer: 2nd workshop of Quantum material research center
• [Presentation] モノドメイン積層界面における熱流と電流の相関 (2023)
  • Author(s): 朝鳥 祥史郎, 上治 寛, 中村 颯太, 斎藤 滋輝, 牧野 恭敬, 金子 嘉彦, 八木 貴志, 蓬田 陽平, 宮田 耕充, 柳 和宏
  • Organizer: 2.5次元領域会議
• [Presentation] 単層カーボンナノチューブ薄膜における面直方向熱電性能評価 (2023)
  • Author(s): 齋藤 滋輝，金子 嘉彦, 上治 寛, 蓬田 陽平, 八木 貴志, 柳 和宏
  • Organizer: 第７１回春季応用物理学会学術講演会
• [Presentation] Correlation between Charge and Heat flows across two dimensional van der Waals interfaces (2023)
  • Author(s): Kazuhiro Yanagi
  • Organizer: ATIナノカーボン研究会
  • Invited
• [Presentation] Thermoelectric figure of merit of aligned and Fermi-level tuned carbon nanotubes (2023)
  • Author(s): Kazuhiro Yanagi
  • Organizer: US-Japan meeting
  • Int'l Joint Research / Invited
• [Presentation] ナノチューブの階層制御と熱電物性 (2023)
  • Author(s): 柳和宏
  • Organizer: 日本物理学会 第78回年次大会
  • Invited
• [Presentation] Thermoelectric performance of single walled carbon nanotubes (2023)
  • Author(s): Kazuhiro Yanagi
  • Organizer: ISSP Regular Workshop
  • Int'l Joint Research / Invited
• [Presentation] ナノチューブの構造制御と物性 (2023)
  • Author(s): 柳和宏
  • Organizer: 第73回化合物新磁性材料専門研究会
  • Invited
• [Presentation] 構造が精密に制御されたファンデルワールス界面の 熱電物性解明にむけた計測技術開発 (2023)
  • Author(s): 柳和宏
  • Organizer: ATF conference ナノカーボン研究会
  • Invited
• [Presentation] ナノカーボン系の熱電応答 ～基礎から社会実装まで～ (2023)
  • Author(s): 柳和宏、山本貴博
  • Organizer: 第６６回FNTG総合会議
  • Invited
• [Presentation] Relationships betweenthe cross-plane electrical and thermal conductance in stacked van der Waals homo/heterostructures (2023)
  • Author(s): Kaiyao Zhou, Kan Ueji, Takahiko Endo, Yasumitsu Miyata, Rikuto Abe, Hiroyuki Nishidome, Sota Nakamura, YoheiYomogida, Kazuhiro Yanagi
  • Organizer: 2.5次元領域会議
• [Presentation] Investigation of the cross-plane electrical conductance in stacked multilayer van der Waals heterostructure withultralow thermal conductance (2023)
  • Author(s): Kaiyao Zhou, Kan Ueji, Takahiko Endo, Yasumitsu Miyata, Rikuto Abe, Hiroyuki Nishidome, Sota Nakamura, YoheiYomogida, Kazuhiro Yanagi
  • Organizer: he 64th Fullerenes-Nanotubes-Graphene General Symposium
• [Presentation] Out-of-plane heat and electrical flows in semiconducting single-walled carbon nanotube films with sp3 defects (2022)
  • Author(s): Kan Ueji, Yohei Yomogida, Takashi Yagi, Jana Zaumseil, Kazuhiro Yanagi
  • Organizer: MNC 2022: 35th International Microprocesses and Nanotechnology Conference
  • Int'l Joint Research
• [Presentation] Synthesis of relatively small-diameter WS2 nanotubes by sulfurization of poly(ethylene glycol) treated thin tungsten oxide nanowires (2022)
  • Author(s): Md. Ashiqur Rahman, Yohei Yomogida, Kan Ueji, Mai Nagano, Ryoga Tanaka, Yasumitsu Miyata and Kazuhiro Yanagi
  • Organizer: MNC 2022, 35th International Microprocesses and Nanotechnology Conference
  • Int'l Joint Research
• [Presentation] Thermal Conductivity of Single-walled Carbon Nanotube Films in Vertical Electrolyte-gated Transistors (2022)
  • Author(s): Kan Ueji, Nobuhiro Muto, Daniel Heimfarth, Yuya Matsuoka, Yota Ichinose, Yohei Yomogida, Takashi Yagi, Jana Zaumseil, Kazuhiro Yanagi
  • Organizer: NT22: The 22nd International Conference on the Science and Applications of Nanotubes and Low-Dimensional Materials
  • Int'l Joint Research
• [Presentation] Relationships between carrier density and thermal conductivity of single wall carbon nanotube thin films (2022)
  • Author(s): Kazuhiro Yanagi
  • Organizer: A3 symposium
  • Int'l Joint Research / Invited
• [Presentation] Ultra-Low Thermal Conductance across Hetero-Structured Four-Layered Van Der Waals Materials (2022)
  • Author(s): Kazuhiro Yanagi
  • Organizer: ECS meeting
  • Int'l Joint Research / Invited
• [Presentation] 格子不整合二次元ナノ界面における 熱・電荷輸送の相関の解明と制御 (2022)
  • Author(s): 朝鳥祥史郎、中村颯太、中西勇介、宮田耕充、蓬田陽平、上治寛、八木貴志、柳和宏
  • Organizer: 2.5次元領域会議
• [Presentation] Out-of-plane heat and electrical flows in semiconducting single-walled carbon nanotube film (2022)
  • Author(s): Kan Ueji, Yohei Yomogida, Takashi Yagi, Jana Zaumseil, Kazuhiro Yanagi
  • Organizer: ICOT2022: International Conference on Organic and Hybrid Thermoelectrics
• [Presentation] sp3欠陥を有する半導体型単層カーボンナノチューブ薄膜の面直方向の熱・電気特性 (2022)
  • Author(s): 上治 寛， 蓬田 陽平, 八木 貴志, Zaumseil Jana, 柳 和宏
  • Organizer: 第８３回応用物理学会秋期学術講演会