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金属酸化物クラスター配列制御による機能性イオン結晶の創製

Publicly Offered Research

Project AreaCoordination Programming - Science of Molecular Superstructures for Chemical Devices
Project/Area Number 24108709
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe University of Tokyo

Principal Investigator

内田 さやか  東京大学, 総合文化研究科, 准教授 (10361510)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywordsナノ材料 / 複合材料・物性 / 自己組織化 / 触媒化学プロセス / 触媒・化学プロセス
Research Abstract

資源の少ない我が国において、エネルギーや物質の有効利用を可能にする環境調和型かつ高機能な材料の開発は、重要な課題の一つである。本研究では、金属の核数と距離が精密に規定された金属酸化物クラスターの配列制御による機能性固体(吸着分離、吸蔵、触媒
、イオン伝導、磁性・電子材料)の構築を、サブナノ~ミクロンレベルで行うことを目的とした。当該領域「配位プログラミング」が目指す「機能階層的な超構造体を設計通り精密に組み上げる」、「分子機能を組織化して高効率出力するナノサイズ化学素子の開発」
という目的と合致する。平成25年度の主な成果として、(1)三次元細孔を有するイオン結晶の合成とアセチレン及び二酸化炭素の選択的吸着、(2)二次元層構造を有するイオン結晶の合成と無機ガス・低級炭化水素ガスの吸着分離、(3)ポストシンセシスにより細孔体積の増加と吸着量の増加、が挙げられる。(1)(2)と昨年度の成果により、イオン結晶における細孔構造の次元性の制御(1から3次元)に成功したことが最も大きなトピックスである。

Current Status of Research Progress
Reason

25年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

25年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (21 results)

All 2014 2013 2012 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (10 results) (of which Invited: 7 results) Book (1 results)

  • [Journal Article] Concerted Functions of Anions and Cations in a Molecular Ionic Crystal with Stable Three-Dimensional Micropores2014

    • Author(s)
      R. Kawahara, S. Uchida, N. Mizuno
    • Journal Title

      Inorganic Chemistry

      Volume: 53 Issue: 7 Pages: 36653661-36653661

    • DOI

      10.1021/ic4031574

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Selective Sorption and Unique Packing Geometries of Unsaturated Hydrocarbons and CO2 in a Fluorine-Substituted Organic-Inorganic Ionic Crystal2013

    • Author(s)
      S. Uchida, R. Kawahara, Y. Ogasawara, N. Mizuno
    • Journal Title

      Dalton Transaction

      Volume: 42 Issue: 45 Pages: 1620916215-1620916215

    • DOI

      10.1039/c3dt51458g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Porous Ionic Crystals Modified by Post-Synthesis of K2[Cr3O(OOCH)6(etpy)3]2[α-SiW12O40]8H2O through Single-Crystal-to-Single-Crystal Transformation2013

    • Author(s)
      S. Uchida, E. Takahashi, N. Mizuno
    • Journal Title

      Inorganic Chemistry

      Volume: 52 Issue: 16 Pages: 93209326-93209326

    • DOI

      10.1021/ic4008334

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enrichment of Tritiated Water Using Mesoporous Silica2013

    • Author(s)
      A. Taguchi, Y. Kato, Y. Torikai, M. Matsuyama, S. Uchida
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 179 Pages: 217233-217233

    • DOI

      10.1016/j.micromeso.2013.05.031

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cubic Cesium Hydrogen Silicododecatungstates with Anisotropic Morphology and Polyoxometalate Vacancies Exhibiting Selective Water Sorption and Cation-Exchange Properties2013

    • Author(s)
      Y. Ogasawara, S. Uchida, T. Maruichi, R. Ishikawa, N. Shibata, Y. Ikuhara, N. Mizuno
    • Journal Title

      Chemistry of Materials

      Volume: 25 Issue: 6 Pages: 905-911

    • DOI

      10.1021/cm3039448

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structural Characterization of Inorganic-Organic-Inorganic Hybrids of Dipalladium-Substituted y-Keggin Silicodecatungstates2013

    • Author(s)
      Tomohisa Hirano, Kazuhiro Uehara, Sayaka Uchida, Mitsuhiro Hibino, Keigo Kamata, Noritaka Mizuno
    • Journal Title

      Inorganic Chemistry

      Volume: 52 Issue: 5 Pages: 2662-2670

    • DOI

      10.1021/ic302703k

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Selective Sorption and Separation of CO2 from a Gas Mixture of CO2 and CH4 at Room Temperature by a Zeolitic Organic-Inorganic Ionic Crystal and Investigation of the Interaction with CO22012

    • Author(s)
      R. Eguchi, S. Uchida, N. Mizuno, J. Phys.
    • Journal Title

      Chem. C,

      Volume: 116 Issue: 30 Pages: 16105-16110

    • DOI

      10.1021/jp305890s

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polyoxotungstate-Surfactant Layered Crystal toward Conductive Inorganic-Organic Hybrid2012

    • Author(s)
      T. Ito, N. Fujimoto, S. Uchida, J. Iijima, H. Naruke, N. Mizuno
    • Journal Title

      Crystals

      Volume: 2 Issue: 2 Pages: 362-373

    • DOI

      10.3390/cryst2020362

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and Dynamical Aspects of Alkylammonium Salts of a Silicodecatugstate as Heterogeneous Epoxidation Catalysts2012

    • Author(s)
      S. Uchida, K. Kamata, Y. Ogasawara, M. Fujita, *N. Mizuno
    • Journal Title

      Dalton. Trans.

      Volume: 41 Issue: 33 Pages: 9979-9983

    • DOI

      10.1039/c2dt30492a

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 二酸化炭素を見分ける!―多孔性イオン結晶の構築と機能開発2012

    • Author(s)
      水野哲孝, 内田さやか
    • Journal Title

      化学

      Volume: 67(6) Pages: 64-65

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] ポリオキソメタレートを基盤とした機能性イオン結晶の創製2013

    • Author(s)
      内田さやか
    • Organizer
      触媒学会埼玉地区講演会
    • Place of Presentation
      埼玉大学(埼玉県、さいたま市)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 金属酸化物の配列制御による有機―無機複合化イオン結晶の創製2012

    • Author(s)
      内田さやか
    • Organizer
      新学術領域研究若手合同シンポジウム「配位プログラム」×「融合マテリアル」
    • Place of Presentation
      東京大学(東京都、文京区)
    • Year and Date
      2012-12-20
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Creation of Functional Nanospace by Hierarchical Arrangement of Inorganic-Organic Units2012

    • Author(s)
      内田さやか
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県、富山市)
    • Year and Date
      2012-09-21
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] シリコタングステートアルキルアンモニウム塩の構造・動的挙動と不均一系酸化触媒能2012

    • Author(s)
      内田さやか・鎌田慶吾・小笠原義之・藤田恵・水野哲孝
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県、富山市)
    • Year and Date
      2012-09-21
    • Related Report
      2012 Annual Research Report
  • [Presentation] Structural Flexibility in Organic-Inorganic Ionic Crystals: Effect on Sorption Properties2012

    • Author(s)
      Sayaka Uchida, Ryo Eguchi, Noritaka Mizuno
    • Organizer
      International Symposium on Zeolites and MicroPorous Crystals (ZMPC2012)
    • Place of Presentation
      Aster Plaza(広島県、広島市)
    • Year and Date
      2012-07-28
    • Related Report
      2012 Annual Research Report
  • [Presentation] 多孔性イオン結晶の構築と機能の開拓

    • Author(s)
      内田さやか
    • Organizer
      女性化学者奨励賞受賞講演、日本化学会第94春季年会
    • Place of Presentation
      名古屋大学、名古屋、愛知県
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Hierarchically-Assembled Porous Ionic Crystals

    • Author(s)
      Sayaka Uchida
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学、名古屋、愛知県
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Crystal Structure-Function Relationships in Porous Organic-Inorganic Ionic Crystals

    • Author(s)
      Sayaka Uchida
    • Organizer
      The 12th Conference of the Asian Crystallographic Association
    • Place of Presentation
      香港科技大学、香港、中国
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] フッ素イオンを導入したイオン性結晶の合成及び不飽和炭化水素と二酸化炭素の吸着分離

    • Author(s)
      川原良介、内田さやか、水野哲孝
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学、那覇、沖縄県
    • Related Report
      2013 Annual Research Report
  • [Presentation] ポリオキソメタレートを基盤とした分子性イオン結晶の設計による機能性材料の開発

    • Author(s)
      内田さやか
    • Organizer
      平成25年度触媒学会・触媒工業交流サロン
    • Place of Presentation
      日本化学会化学会館、東京、東京都
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] 触媒年鑑「触媒技術の動向と展望 2013」2013

    • Author(s)
      内田さやか
    • Publisher
      触媒学会監修
    • Related Report
      2012 Annual Research Report

URL: 

Published: 2013-05-15   Modified: 2019-07-29  

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