遷移金属配位圏でのシリル転位を引き金とする脱カルコゲン触媒反応の開発

• Project Area: Stimuli-responsive Chemical Species for the Creation of Functional Molecules
• Project/Area Number: 25109538
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Osaka City University
• Principal Investigator: 中沢 浩 大阪市立大学, 大学院理学研究科, 教授 (00172297)
• Project Period (FY): 2013-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000); Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2013: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
• Keywords: シリル基転位反応 / 結合切断 / 鉄錯体触媒 / 脱水素縮合反応 / 脱硫反応 / 鉄カルベン錯体

Outline of Annual Research Achievements

遷移金属配位圏内でのシリル基転位が鍵反応となり、通常では切断の困難な結合の切断を触媒的に進行させる反応を行ってきた。今までに有機ニトリルのC-CN結合切断、シアナミドのN-CN結合切断、シアナーとのO-CN結合切断、シリルシアニドのSi-CN結合切断を達成してきた。また、鉄錯体触媒存在下での二級チオアミドとヒドロシランの反応においては、強いC=S結合切断に加えて水素移動反応も同時に進行することを報告している。
本年度は鉄錯体触媒共存下、イミン(RN=CHPh)とヒドロシラン(HSiEt3)の反応を調べ、N-シリルアミン((R)(Et3Si)NCH2Ph)が生成することを見出した。我々は先に二級チオアミドとヒドロシランとの反応でイミンとアミンが生成することを報告したが、その反応機構は明らかではなかった。本研究成果を踏まえると、まずイミンが生成し、それがさらにヒドロシランと反応してN-シリルアミンが生成するという段階的反応で最終的にアミンが生成することが明らかとなった。これらの研究成果はHeteroatom Chemistry, 2014, 25, 607-611に掲載された。
また、鉄錯体触媒を用いて、シランとアルコールからシリルエーテルが生成することも見出し、報告した。シリルエーテルは有用な化合物であり、専らクロロシランとアルコールから合成されている。しかしこの方法では塩が副生成物として生じる。これに対して本研究で見出した反応は脱水素縮合反応であるので、副生成物は水素分子のみであり、クリーンな反応である。また触媒として環境にやさしい鉄錯体を用いている。これらの研究成果はInorg. Chim. Acta, 2015に掲載が決定している。

Research Progress Status

26年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

26年度が最終年度であるため、記入しない。

Research Products

• [Journal Article] Evaluation of the sigma-Donation from Group 11 Metals(Cu, Ag, Au) to Silane, Germanium, and Stannane Based on the Experimental / Theoretical Systematic Approach (2015)
  • Author(s): H. Kameo, T. Kawamoto, D. Bourissou, S. Sakaki, H. Nakazawa
  • Journal Title: Organometallics Volume: 34
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Dehydrogenative Coupling of Alcohol with Hydrosilane Catalyzed by an Iron Complex (2015)
  • Author(s): K. Fukumoto, M. Kasa, H. Nakazawa
  • Journal Title: Inorg. Chim. Acta Volume: 未定 Pages: 219-221
  • DOI: 10.1016/j.ica.2015.02.019
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] TiCl4-promoted Condensation of Methyl Acetoacetate, Isobutyraldehyde, and Indole: A Theoretical and Experimental Study (2015)
  • Author(s): A. Renzetti, A. Marrone, S. Gerard, J. Sapi, H. Nakazawa, N. Re, A. Fontana
  • Journal Title: Physical Chemistry Chemical Physics Volume: 未定
  • Peer Reviewed
• [Journal Article] Synthesis, Structure and Reactivity of Ruthenium(0) Indane Complex fac-[Ru(NCMe)3(CO)2(InX3)] (X = Cl, Br) (2015)
  • Author(s): M. Itazaki, M. Ito, H. Nakazawa
  • Journal Title: Eur. J. Inorg. Chem. Volume: 未定 Issue: 12 Pages: 2033-2036
  • DOI: 10.1002/ejic.201500112
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Coordination of a Triphosphine-Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au+→Si Interaction (2015)
  • Author(s): P. Gualco, S. Mallet-Ladeira, H. Kameo, H. Nakazawa, L. Maron, A. Amgoune, D. Bourissou
  • Journal Title: Organometallics Volume: 34
  • Peer Reviewed
• [Journal Article] Yonemitsu-type Condensations Catalysed by Proline and Eu(OTf)3 (2014)
  • Author(s): A. Renzetti, E. Boffa, M. Colazzo, S. Gerard, J. Sapi, T.-H. Chan, H. Nakazawa, C. Villani, A. Fontana
  • Journal Title: RSC Adv. Volume: 4 Issue: 89 Pages: 47992-47999
  • DOI: 10.1039/c4ra08853k
  • Peer Reviewed
• [Journal Article] Can One σ*-Antibonding Orbital Interact with Six Electrons of Lewis Bases? Analysis of a Multiply Interacting σ* Orbital (2014)
  • Author(s): Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, and Hiroshi Nakazawa
  • Journal Title: Organometallics Volume: 33 Issue: 21 Pages: 5960-5963
  • DOI: 10.1021/om500951e
  • Peer Reviewed
• [Journal Article] Synthesis, Geometry, and Bonding Nature of Heptacoordinate Compounds of Silicon and Germanium Featuring Three Phosphine Donors (2014)
  • Author(s): H. Kameo, T. Kawamoto, S. Sakaki, D. Bourissou, H. Nakazawa
  • Journal Title: Organometallics Volume: 33 Issue: 22 Pages: 6557-6567
  • DOI: 10.1021/om500906f
  • Peer Reviewed
• [Journal Article] Si-CN Bond Cleavage of Silylcyanides by an Iron Catalyst. A New Route of Silylcyanide Formation (2014)
  • Author(s): A. Renzetti, N. Koga, H. Nakazawa
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 87 Issue: 1 Pages: 59-68
  • DOI: 10.1246/bcsj.20130206
  • NAID: 130004153265
  • Peer Reviewed
• [Journal Article] Synthesis of Fe-H/Si-H and Fe-H/Ge-H Bifunctional Complexes and Their Catalytic Hydrogenation Reaction toward Non-polar Unsaturated Organic Molecules (2014)
  • Author(s): 神谷昌宏、西口佳範、多田、板崎真澄、中沢浩
  • Journal Title: Organometallics Volume: 33 Issue: 7 Pages: 1532-1535
  • DOI: 10.1021/om5000562
  • Peer Reviewed
• [Journal Article] Effective Dehydrogenation of 2-Pyridylmethanol Derivatives Catalyzed by an Iron Complex (2014)
  • Author(s): 神谷昌宏、夛田亮介、板崎真澄、中沢浩
  • Journal Title: Chemical Communication Volume: 50(In press) Issue: 59 Pages: 7941-7944
  • DOI: 10.1039/c4cc01498g
  • Peer Reviewed
• [Journal Article] Selective Boryl Silyl Ether Formation in the Photoreaction of Bisboryloxide/Boroxine with Hydrosilane Catalyzed by a Transition-Metal Carbonyl Complex (2014)
  • Author(s): M. Ito, M. Itazaki, H. Nakazawa
  • Journal Title: J. Am. Chem. Soc. Volume: 136 Issue: 17 Pages: 6183-6186
  • DOI: 10.1021/ja500465x
  • Peer Reviewed
• [Journal Article] Transformation of RN=CHPh to R(R’3Si)NCH2Ph in the Catalytic Desulfurization of Secondary Thioamide with R’3SiH Promoted by an Iron Complex (2014)
  • Author(s): K. Fukumoto, A. Sakai, T. Murai, H. Nakazawa
  • Journal Title: Heteroatom. Chem. Volume: 24
  • Peer Reviewed
• [Journal Article] Si-C Bond Cleavage by Hydride Complexes of Rhodium and Iridium: Comparison of Si-C(sp2) and Si-C(sp3) Activation (2013)
  • Author(s): Hajime Kameo, Sho Ishii, Hiroshi Nakazawa
  • Journal Title: Dalton Transactions Volume: 42 Issue: 13 Pages: 4663-4669
  • DOI: 10.1039/c3dt32896a
  • Peer Reviewed
• [Journal Article] Catalytic Cycle for N-CN Bond Cleavage by Molybdenum Silyl Catalyst: A DFT Study (2013)
  • Author(s): A. A. Dahy, N. Koga, H. Nakazawa
  • Journal Title: Organometallics Volume: 32 Issue: 9 Pages: 2725-2735
  • DOI: 10.1021/om400179y
  • Peer Reviewed
• [Journal Article] Desulfurization and H-Migration of Secondary Thioamides Catalyzed by an Iron Complex to Yield Imindes and Their Reaction Mechanism (2013)
  • Author(s): K. Fukumoto, A. Sakai, K. Hayasaka, H. Nakazawa
  • Journal Title: Organometallics Volume: 32 Issue: 10 Pages: 2889-2892
  • DOI: 10.1021/om400304v
  • Peer Reviewed
• [Journal Article] Dehydrogenative Desulfurization of Thiourea Derivatives to Give Carbodiimides, Using Hydrosilane and an Iron Complex (2013)
  • Author(s): K. Hayasaka, K. Fukumoto, and H. Nakazawa
  • Journal Title: Dalton Trans. Volume: 42 Issue: 28 Pages: 10271-10276
  • DOI: 10.1039/c3dt50996f
  • Peer Reviewed
• [Journal Article] Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety (2013)
  • Author(s): Hajime Kameo, Hiroshi Nakazawa
  • Journal Title: Chemistry - An Asian Journal Volume: 8 Issue: 8 Pages: 1720-1734
  • DOI: 10.1002/asia.201300184
  • Peer Reviewed
• [Journal Article] Crystal Structure and Metal Atom Dynamics of the Dimethyl Stannane complex: {o-(Ph2P)C6H4}2Sn(CH3)2 (2013)
  • Author(s): Hajime Kameo, Hiroshi Nakazawa, Rolfe H. Herber
  • Journal Title: Journal of Molecular Structure Volume: 1054-1055 Pages: 321-325
  • DOI: 10.1016/j.molstruc.2013.10.002
  • Peer Reviewed
• [Presentation] Synthesis of Asymmetric 1,2-Bis(phosphino)ethane in the Hydrophosphination Reaction Catalyzed by an Iron Complex (2015)
  • Author(s): 勝部伸哉、板崎真澄、中沢 浩
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス（千葉県）
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] Selective Double-Hydrosilylation of Nitriles Catalyzed by an Iron Complex Containing Indium Trichloride (2015)
  • Author(s): 伊藤昌輝、板崎真澄、中島 覚、中沢 浩
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス（千葉県）
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] イリジウムヒドリド錯体によるGe-F結合の切断とその反応機構の研究 (2015)
  • Author(s): 池田耕己、亀尾 肇、中沢 浩、松坂裕之
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス（千葉県）
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] 高校化学グランドコンテストを通した化学の普及ならびに国際化への貢献 (2015)
  • Author(s): 中沢 浩
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス（千葉県）
  • Year and Date: 2015-03-26 – 2015-03-29
  • Invited
• [Presentation] Synthesis of Iron Complexes with Indium Trihalide and Their Catalytic Application to Selective Double-Hydrosilylation Reaction of Nitriles (2015)
  • Author(s): M. Ito, M. Itazaki, S. Nakashima, H. Nakazawa
  • Organizer: The 18th Osaka City University International Symposium
  • Place of Presentation: Osaka City University, Osaka, Japan
  • Year and Date: 2015-03-09
• [Presentation] Conversion of Vinylphosphines into Asymmetric 1,2-Bis(phosphino)ethanes Catalyzed by Iron Complexes (2015)
  • Author(s): S. Katsube, M. Itazaki, H. Nakazawa
  • Organizer: The 18th Osaka City University International Symposium
  • Place of Presentation: Osaka City University, Osaka, Japan
  • Year and Date: 2015-03-09
• [Presentation] イリジウムヒドリド錯体によるGe-F結合の切断 (2014)
  • Author(s): 池田耕己、亀尾 肇、中沢 浩、松坂裕之
  • Organizer: 第41回有機典型元素化学討論会
  • Place of Presentation: 宇部市文化会館文化ホール（山口県）
  • Year and Date: 2014-11-27 – 2014-11-29
• [Presentation] ホスフィンカルボキシアミド (RNHC(O)PR’2) とハロゲン間の水素結合形成を鍵とするかご状白金錯体の合成 (2014)
  • Author(s): 井関柾登、伊藤昌輝、板崎真澄、中沢 浩
  • Organizer: 第41回有機典型元素化学討論会
  • Place of Presentation: 宇部市文化会館文化ホール（山口県）
  • Year and Date: 2014-11-27 – 2014-11-29
• [Presentation] 第11族金属を有するメタラシラトランの系統的合成 (2014)
  • Author(s): 亀尾 肇、川本達也、中沢 浩
  • Organizer: 第18回ケイ素化学協会シンポジウム
  • Place of Presentation: ラフォーレ那須（栃木県）
  • Year and Date: 2014-10-17 – 2014-10-18
• [Presentation] 新規機能性無機材料開発を志向した遷移金属錯体触媒による選択的ホウ素－ケイ素結合形成反応の創製 (2014)
  • Author(s): 伊藤昌輝、板崎真澄、中沢 浩
  • Organizer: 第４回CSJ化学フェスタ2014
  • Place of Presentation: タワーホール船堀（東京都）
  • Year and Date: 2014-10-14 – 2014-10-16
• [Presentation] Electronic Influence of Coordination of Borane Ligand on Metal Center (2014)
  • Author(s): 亀尾 肇、松坂裕之、中沢 浩
  • Organizer: 第61回有機金属化学討論会
  • Place of Presentation: 九州大学（福岡県）
  • Year and Date: 2014-09-23 – 2014-09-25
• [Presentation] Achievement of Boron-Oxygen-Silicon Alignment Promoted by a Transition Metal Catalysis: Selective Synthesis of Boryl Silyl Ethers (2014)
  • Author(s): 伊藤昌輝、板崎真澄、中沢 浩
  • Organizer: 第61回有機金属化学討論会
  • Place of Presentation: 九州大学（福岡県）
  • Year and Date: 2014-09-23 – 2014-09-25
• [Presentation] 新しい超原子価構造を有する高周期14族化合物の合成 (2014)
  • Author(s): 川本達也、 亀尾 肇、中沢 浩
  • Organizer: 錯体化学会第64回討論会
  • Place of Presentation: 中央大学（東京都）
  • Year and Date: 2014-09-18 – 2014-09-20
• [Presentation] 鉄触媒を用いたヒドロホスフィン化によるビニルホスフィンの合成および中間体錯体の単離 (2014)
  • Author(s): 勝部伸哉、板崎真澄、神谷昌宏、中沢 浩
  • Organizer: 錯体化学会第64回討論会
  • Place of Presentation: 中央大学（東京都）
  • Year and Date: 2014-09-18 – 2014-09-20
• [Presentation] Desulfurization of Thioamide and Thiourea Promoted by an Iron Complex (2014)
  • Author(s): H. Nakazawa
  • Organizer: The 2nd Japan-UK Joint Symposium on Coordination Chemistry
  • Place of Presentation: Chuo University, Tokyo, Japan
  • Year and Date: 2014-09-16 – 2014-09-18
  • Invited
• [Presentation] Selective Hydrophosphination of Terminal Alkynes Catalyzed by an Iron Complex (2014)
  • Author(s): M. Itazaki, M. Kamitani, K. Katsube, C. Tamiya, H. Nakazawa
  • Organizer: 5th EuCheMS Chemistry Congress
  • Place of Presentation: Istanbul, Turkey
  • Year and Date: 2014-08-31 – 2014-09-04
• [Presentation] Selective B-O-Si Bond Formation Catalyzed by a Transition-Metal Complex (2014)
  • Author(s): M. Ito, M. Itazaki, H. Nakazawa
  • Organizer: 5th EuCheMS Chemistry Congress
  • Place of Presentation: Istanbul, Turkey
  • Year and Date: 2014-08-31 – 2014-09-04
• [Presentation] Catalytic Strong Bond Cleavage Triggered by Silyl Migration in a Coordination Sphere (2014)
  • Author(s): H. Nakazawa
  • Organizer: The 41st International Conference on Coordination Chemistry
  • Place of Presentation: Singapore, Singapore
  • Year and Date: 2014-07-21 – 2014-07-25
  • Invited
• [Presentation] Desulfurization of Thioamide by Hydrosilane via an Iron-Carbene Complex (2014)
  • Author(s): H. Nakazawa, K. Fukumoto, A. Sakai, T. Oya, K. Hayasaka
  • Organizer: The XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Royton Sapporo Hotel, Sapporo, Japan
  • Year and Date: 2014-07-13 – 2014-07-18
• [Presentation] Transfer Hydrogenation of Alkynes and Alkenes from Isopropyl Alcohol Catalyzed by an Fe-H/Si-H Bufunctional Complex and Their Mechanistic Studies (2014)
  • Author(s): Y. Nishiguchi, M. Kamitani, R. Tada, M. Itazaki, H. Nakazawa
  • Organizer: The XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Royton Sapporo Hotel, Sapporo, Japan
  • Year and Date: 2014-07-13 – 2014-07-18
• [Presentation] Single and Double Hydrophosphination of Terminal Acetylenes with Biarylphosphine Catalyzed by an Iron Complex (2014)
  • Author(s): M. Itazaki, M. Kamitani, S. Katsube, C. Tamiya, H. Nakazawa
  • Organizer: The XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Royton Sapporo Hotel, Sapporo, Japan
  • Year and Date: 2014-07-13 – 2014-07-18
• [Presentation] Si-CN Bond Cleavage of Silyl Cyanides by an Iron Catalyst. A New Route of Silyl Cyanide Formation (2014)
  • Author(s): A. Renzetti, N. Koga, H. Nakazawa
  • Organizer: The XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Royton Sapporo Hotel, Sapporo, Japan
  • Year and Date: 2014-07-13 – 2014-07-18
• [Presentation] Selective Single and Double Hydrophosphination of Alkyne Catalyzed by an Iron Complex (2014)
  • Author(s): H. Nakazawa
  • Organizer: The 20th International Conference on Phosphorus Chemistry
  • Place of Presentation: Dublin, Ireland
  • Year and Date: 2014-06-28 – 2014-07-02
  • Invited
• [Presentation] Selective Bond Cleavage Catalyzed by a Silyl Complex of a Transition Metal (2014)
  • Author(s): H. Nakazawa
  • Organizer: 247th American Chemical Society National Meeting
  • Place of Presentation: Dallas, USA
  • Invited
• [Presentation] 鉄シリル錯体とアミド化合物Ar2NCHE (E = S, O)による鉄カルベン錯体の合成と構造 (2014)
  • Author(s): 板崎真澄、筈谷真企、伊藤昌輝、橋本康弘、中沢 浩
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] 鉄触媒を用いた末端アルキンの選択的モノヒドロホスフィン化反応 (2014)
  • Author(s): 板崎真澄、勝部伸哉、神谷昌宏、中沢 浩
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] ジイミン誘導体を配位子とする鉄錯体によるアルケンのヒドロシリル化反応 (2014)
  • Author(s): 山本陽加、中沢 浩
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] Strong Bond Cleavage Reactions Triggered by Silyl Migration from a Transition Metal (2013)
  • Author(s): H. Nakazawa
  • Organizer: 36th Annual Meeting of the Brazilian Chemical Society
  • Place of Presentation: Aguas de Lindoia, Brazil
  • Invited
• [Presentation] Double Hydrophosphination of Alkynes Catalyzed by an Iron Complex (2013)
  • Author(s): H. Nakazawa, M. Kamitani, M. Itazaki, and C. Tamiya
  • Organizer: The 1st Japan-Taiwan-Singapore Joint Symposium on Coordination Chemistry
  • Place of Presentation: Osaka University
  • Invited
• [Presentation] Iron-catalyzed s-Bond Metathesis Reactions of Si-H and Si-CN Bonds. A New Route to Silylcyanides (2013)
  • Author(s): A. Renzetti, H. Nakazawa
  • Organizer: European Symposium on Organic Chemistry 2013
  • Place of Presentation: Marseille, France
• [Presentation] Bond Cleavage Reactions Triggered by Silyl Migration in a Coordination Sphere of a Transition Metal (2013)
  • Author(s): H. Nakazawa, M. Itazaki, K. Fukumoto
  • Organizer: 15th Asian Chemical Congress 2013
  • Place of Presentation: Singapore
  • Invited
• [Presentation] Selective Strong Bond Cleavage Catalyzed by a Transition Metal Complex (2013)
  • Author(s): H. Nakazawa
  • Organizer: XXIII Ukrainian Conference on Organic Chemistry
  • Place of Presentation: Chernivtsi, Ukraine
  • Invited
• [Presentation] Catalytic Hydrophosphination of Alkyne with Diarylphosphine Promoted by a Piano-Stool Iron Complex (2013)
  • Author(s): H. Nakazawa, M. Kamitani, M. Itazaki, C. Tamiya
  • Organizer: SILQCOM 2013-Polymat
  • Place of Presentation: Huatulco, Mexico
• [Presentation] Hydrosilylation of Alkynes Catalyzed by an Iron Complex (2013)
  • Author(s): H. Nakazawa
  • Organizer: The 2nd Japan-France Coordination Chemistry Symposium
  • Place of Presentation: Todaiji Culture Center, Nara, Japan
  • Invited
• [Presentation] Transfer Hydrogenation Reaction Catalyzed by Fe-H/Si-H Bifunctional Complexes and Consideration of the Catalytic Mechanism (2013)
  • Author(s): Masahiro Kamitani, Ryosuke Tada, Masumi Itazaki, Hiroshi Nakazawa
  • Organizer: The 2nd Japan-France Coordination Chemistry Symposium
  • Place of Presentation: Todaiji Culture Center, Nara, Japan
• [Presentation] Desulfurization of Secondary Thioamides and Thiourea Derivatives Induced by an Iron Complex (2013)
  • Author(s): Kazumasa Hayasaka, Kozo Fukumoto, Akane Sakai, Hiroshi Nakazawa
  • Organizer: The 2nd Japan-France Coordination Chemistry Symposium
  • Place of Presentation: Todaiji Culture Center, Nara, Japan
• [Presentation] Synthesis and Structure of Iron Carbene Complexes from an Iron Silyl Complex with NR2C(=E)H (E = O, S) (2013)
  • Author(s): Masumi Itazaki, Masaki Hazutani, Masaki Ito, Yasuhiro Hashimoto, Hiroshi Nakazawa
  • Organizer: The 2nd Japan-France Coordination Chemistry Symposium
  • Place of Presentation: Todaiji Culture Center, Nara, Japan
• [Presentation] Syntheses and Structures of Complexes Containing Group 8 Transition-Metal－Indium Bond(s) (2013)
  • Author(s): Masaki Ito, Masumi Itazaki, Hiroshi Nakazawa
  • Organizer: The 2nd Japan-France Coordination Chemistry Symposium
  • Place of Presentation: Todaiji Culture Center, Nara, Japan
• [Presentation] Synthesis of Platinum Complexes with 1,1ʹ-Ferrocenedichalcogenato Ligand and Their Reactivity (2013)
  • Author(s): Masumi Itazaki, Masato Iseki, Masaki Ito, Hiroshi Nakazawa
  • Organizer: The 2nd Japan-France Coordination Chemistry Symposium
  • Place of Presentation: Todaiji Culture Center, Nara, Japan
• [Presentation] Si-F Bond Cleavage Induced by Iridium Hydride Complexes (2013)
  • Author(s): H. Kameo, T. Kawamono, H. Nakazawa
  • Organizer: The 1st International Symposium for Young Chemists
  • Place of Presentation: Toko Hotel, Tokyo, Japan
• [Presentation] Selective Hydrophosphination of Therminal Arylacetylenes Catalyzed by an Iron Complex (2013)
  • Author(s): 板崎真澄、神谷昌宏、勝部伸哉、田宮千裕、中沢 浩
  • Organizer: 第60回有機金属化学討論会
  • Place of Presentation: 学習院大学
• [Presentation] Si-F Bond Cleavage Induced by Iridium Hydride Complexes (2013)
  • Author(s): 亀尾 肇、川本達也、中沢 浩
  • Organizer: 第60回有機金属化学討論会
  • Place of Presentation: 学習院大学
• [Presentation] 1,1'-フェロセンジカルコゲナト配位子を有する鉄三核錯体の酸化還元過程に関する理論化学的研究 (2013)
  • Author(s): 藤木さゆり、土田敦子、伊藤昌輝、板崎真澄、中沢 浩、鷹野景子
  • Organizer: 第７回分子科学討論会
  • Place of Presentation: 京都府民総合交流プラザ
• [Presentation] セレン架橋による高電子伝達能の発現：カルコゲン架橋型三核錯体の合成とその電気化学的性質 (2013)
  • Author(s): 伊藤昌輝、板崎真澄、山本健弥、市村彰男、中沢 浩
  • Organizer: 第３回CSJ化学フェスタ
  • Place of Presentation: タワーホール船堀
• [Presentation] 鉄錯体を用いた2級チオアミドおよびチオ尿素誘導体の脱硫脱水素反応の開発 (2013)
  • Author(s): 早坂和将、福本晃造、中沢 浩
  • Organizer: 第３回CSJ化学フェスタ
  • Place of Presentation: タワーホール船堀
• [Presentation] P→E (Si, Ge, Sn)相互作用を有する7配位14族元素化合物の合成と構 (2013)
  • Author(s): 川本達也、亀尾 肇、中沢 浩
  • Organizer: 第17回ケイ素化学協会シンポジウム
  • Place of Presentation: 箱根湯本
• [Presentation] ゲルミルおよびスタニルRh(III)錯体によるB-X (X = F, C)結合切断 (2013)
  • Author(s): 亀尾 肇、石井 翔、中沢 浩
  • Organizer: 第17回ケイ素化学協会シンポジウム
  • Place of Presentation: 箱根湯本
• [Presentation] ８族遷移金属－インジウム結合の考察：錯体の合成と構造 (2013)
  • Author(s): 伊藤昌輝、板崎真澄、中沢 浩
  • Organizer: 錯体化学会第63回討論会
  • Place of Presentation: 琉球大学
• [Presentation] ４級１４族元素化合物(SiR4, GeR4, SnR4)とCu, Ag, Auとの相互作用 (2013)
  • Author(s): 川本達也、亀尾 肇、中沢 浩
  • Organizer: 錯体化学会第63回討論会
  • Place of Presentation: 琉球大学
• [Presentation] Synthesis of a Rhodium Complex Featuring the Rh-H-B Linkage via a Hydride Migration from Rhodium to Borane: Study on the Electonic Deviation Induced by the Boron Moiety (2013)
  • Author(s): Hajime Kameo, Hiroshi Nakazawa
  • Organizer: 錯体化学会第63回討論会
  • Place of Presentation: 琉球大学
• [Presentation] モリブデン錯体を触媒としたボリルシリルエーテル合成反応 (2013)
  • Author(s): 伊藤昌輝、板崎真澄、中沢 浩
  • Organizer: 第40回有機典型元素化学討論会
  • Place of Presentation: 近畿大学
• [Presentation] 鉄錯体を用いたイミンとヒドロシランの反応 (2013)
  • Author(s): 西向淳吾、中井悠太、早坂和将、福本晃造、中沢 浩
  • Organizer: 第40回有機典型元素化学討論会
  • Place of Presentation: 近畿大学
• [Book] 高校生・化学宣言PART8～高校化学グランドコンテストドキュメンタリー～ (2015)
  • Author(s): 中沢 浩、松坂裕之
  • Total Pages: 230
  • Publisher: 遊タイム出版
• [Book] 高校生・化学宣言PART7～高校化学グランドコンテストドキュメンタリー～ (2013)
  • Author(s): 中沢 浩、松坂裕之
  • Total Pages: 224
  • Publisher: 遊タイム出版
• [Remarks] Coordination Chemistry Lab
  • URL: http://www.sci.osaka-cu.ac.jp/chem/cc/index.html
• [Remarks] Coordination Chemistry Lab
  • URL: http://www.sci.osaka-cu.ac.jp/chem/cc/index.html
• [Patent(Industrial Property Rights)] カルボジイミド化合物の製造方法 (2015)
  • Inventor(s): 中沢 浩
  • Industrial Property Rights Holder: 中沢 浩
  • Industrial Property Rights Type: 特許
  • Filing Date: 2015-01-08
  • Overseas
• [Patent(Industrial Property Rights)] カルボジイミド化合物の製造方法 (2014)
  • Inventor(s): 中沢 浩
  • Industrial Property Rights Holder: 東洋紡
  • Industrial Property Rights Type: 特許
  • Filing Date: 2014-02-12
• [Patent(Industrial Property Rights)] 有機ケイ素化合物の製造方法 (2014)
  • Inventor(s): 中沢 浩、五十嵐正安、中島裕美子、島田 茂、佐藤一彦
  • Industrial Property Rights Holder: 中沢 浩、五十嵐正安、中島裕美子、島田 茂、佐藤一彦
  • Industrial Property Rights Type: 特許
  • Filing Date: 2014-02-20