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2008 Fiscal Year Annual Research Report

高次π空間の創発と機能開発

Administrative Group

Project AreaEmergence of highly elaborated pai-space and its function
Project/Area Number 20108001
Research InstitutionUniversity of Tsukuba

Principal Investigator

赤阪 健  University of Tsukuba, 大学院・数理物質科学研究科, 教授 (60089810)

Co-Investigator(Kenkyū-buntansha) 大須賀 篤弘  京都大学, 理学研究科, 教授 (80127886)
福住 俊一  大阪大学, 工学研究科, 教授 (40144430)
神取 秀樹  名古屋工業大学, 工学研究科, 教授 (70202033)
安蘇 芳雄  大阪大学, 産業科学研究所, 教授 (60151065)
磯部 寛之  東北大学, 理学研究科, 教授 (30302805)
Keywordsπ電子 / π曲面 / π空間 / 拡張π電子系 / 拡張π平面
Research Abstract

本領域研究では、π電子を持つ化合物に対し、電子や磁場等の影響や別の化合物が相互作用する状況下においてより広がりを持った、あるいは特徴が変わった、そして究極的には高度で複雑な秩序やシステムまでもが生じる場を高次π空間と定義し、この機能、物性、構造および反応機構を明らかにすることを目的としている。総括班は領域全体の研究方針の策定を行うと共に、研究計画および公募研究から格段な研究成果を得るためにそれらを総括し、領域の効率的かつ効果的な研究支援活動を行う。また、研究者の知的好奇心の単なる延長上の研究に陥ることなく、かつそれぞれの研究が有機的に連携するように適切な研究マネジメントを実践する。
研究開始の本年度は、領域研究のホームページを立ち上げ、研究内容、目標等を広く社会へ情報発信するための準備を整えた。また、公開シンポジウムを開催し、広い領域分野の研究者および一般社会の人々への領域研究の紹介を行い、参加者間の交流、情報交換を行った。さらに、情報発信の一つとして、ニュースレターの発行を行った。

  • Research Products

    (151 results)

All 2009 2008 Other

All Journal Article (103 results) (of which Peer Reviewed: 102 results) Presentation (39 results) Book (1 results) Remarks (6 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 2 results)

  • [Journal Article] High-valent manganese(v)-oxo porphyrin complexes in hydride transfer reactions2009

    • Author(s)
      June Yoon Lee, et.al.
    • Journal Title

      Chemical Communications 6

      Pages: 704-706

    • Peer Reviewed
  • [Journal Article] Reorganization energies of diprotonated and saddle-distorted porphyrins in Dhotoinduced electron-transfer reduction controlled by conformational distortion2009

    • Author(s)
      Tatsuaki Nakanishi, et.al.
    • Journal Title

      Journal of the American Chemical Society 131

      Pages: 577-584

    • Peer Reviewed
  • [Journal Article] Radical Coupling Reaction of Paramagnetic Endohedral Metallofullerene La@C_<82>2008

    • Author(s)
      Y. Takano, et.al.
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 16224-16230

    • Peer Reviewed
  • [Journal Article] Does Gd@C_<82> Have an Anomalous Endohedral Structure? Synthesis and Single Crystal X-ray Structure of the Carbene Adduct2008

    • Author(s)
      T. Akasaka, et.al.
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 12840-12841

    • Peer Reviewed
  • [Journal Article] Chemical Understanding of a Non-IPR Metallofullerene : Stabilization of Encaged Metals on Fused-pentagon Bonds in La_2@C_<72>2008

    • Author(s)
      X. Lu, et.al.
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 9129-9136

    • Peer Reviewed
  • [Journal Article] Metal Atoms Collinear with the Spiro Carbon of 6, 6-Open Adducts, M_2@C_<80>(Ad) (M = La and Ce, Ad = Adamantylidene)2008

    • Author(s)
      M. Yamada, et.al.
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 1171-1176

    • Peer Reviewed
  • [Journal Article] Addition of Adamantylidene to La_2@C_<78> : Isolation and Single-Crystal X-ray Structural Determination of the Monoadducts2008

    • Author(s)
      B. Cao, et.al.
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 983-989

    • Peer Reviewed
  • [Journal Article] Nanorods of Endohedral Metallofullerene Derivative2008

    • Author(s)
      T. Tsuchiya, et.al.
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 450-451

    • Peer Reviewed
  • [Journal Article] Bis-carbene Adducts of Non-IPR La_2@C_<72> : Localization of High Reactivity around Fused-pentagons and Toward Controllable Tuning of Electroc hemical Properties of Metallofullerenes2008

    • Author(s)
      X. Lu, et.al.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 8642-8645

    • Peer Reviewed
  • [Journal Article] Observation of ^<13>C NMR Chemical Shifts of Metal Carbides Encapsulated in Fullerenes : Sc_2C_2@C_<82>, Sc_2C_2@C_<84>, and Sc_3C_2@C_<80>2008

    • Author(s)
      Y. Yamazaki, et.al.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 7905-7908

    • Peer Reviewed
  • [Journal Article] [2+1]-Cycloaddition of Nitrene onto C_<60> Revisited : Interconversion between Aziridinofullerene and Azafulleroid2008

    • Author(s)
      T Nakahodo, et.al.
    • Journal Title

      Angew. Chem.,Int. Ed. 47

      Pages: 1298-1300

    • Peer Reviewed
  • [Journal Article] Excited-State and Photoelectrochemical Behavior of Pyrene-Linked Phen yleneethynylene Oligomer2008

    • Author(s)
      Y. Matsunaga, et.al.
    • Journal Title

      J. Phys. Chem. B 112

      Pages: 14539-14547

    • Peer Reviewed
  • [Journal Article] Spectroscopic and Theoretical Study of Endohedral Dimetallofullerene Having a Non-IPR Fullerene Cage : Ce_2@C_<72>2008

    • Author(s)
      M. Yaniada, et.al.
    • Journal Title

      J. Plys. Chem. A 112

      Pages: 7627-7631

    • Peer Reviewed
  • [Journal Article] Isolation and Characterization of Carbene Derivatives of La@C_<82>(Cs)2008

    • Author(s)
      T. Akasaka, et.al.
    • Journal Title

      J. Phys. Chem. A 112

      Pages: 1294-1297

    • Peer Reviewed
  • [Journal Article] Simple Purification and Selective Enrichment of Metallic SWCNTs Produced Using the Arc-discharge Method2008

    • Author(s)
      Y. Maeda, et.al.
    • Journal Title

      Carbon 46

      Pages: 1563-1569

    • Peer Reviewed
  • [Journal Article] Preparation of Transparent and Conductive Thin Films of Metallic Single-walled Carbon Nanotubes2008

    • Author(s)
      Y. Maeda, et.al.
    • Journal Title

      J. Mater. Chem. 18

      Pages: 4189-4192

    • Peer Reviewed
  • [Journal Article] Synthesis of Selenylfullerene with Seleniumcontaining Dibenzo[b, g]cyclooctane Moiety2008

    • Author(s)
      T. Nakahodo, et.al.
    • Journal Title

      Tetrahedron Lett 49

      Pages: 2302-2305

    • Peer Reviewed
  • [Journal Article] Location of the Metal Atoms in Ce_2@C_<78> and its Bissilylated Derivative2008

    • Author(s)
      M. Yamada, et.al.
    • Journal Title

      Chem. Commun. 2008

      Pages: 558-560

    • Peer Reviewed
  • [Journal Article] Generation of Nitrene by the Photolysis of N-substituted Iminodibenzothiophene2008

    • Author(s)
      H. Morita, et.al.
    • Journal Title

      J. Org. Chem 73

      Pages: 7159-7163

    • Peer Reviewed
  • [Journal Article] Selective Adsorption of Cations on Single-walled Carbon Nanotubes : A Density Functional Theory Study2008

    • Author(s)
      D. Wang, et.al.
    • Journal Title

      Computational Materials Science 43

      Pages: 886-891

    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Co(II), Ni(II), and Cu(II) Complexes Containing an Eight-membered Disulfanenitrile Chelating Ring2008

    • Author(s)
      T. Fujii, et.al.
    • Journal Title

      Inorganica Chimica Acta 361

      Pages: 2540-2546

    • Peer Reviewed
  • [Journal Article] C_<60>(OH)_n-Assisted dispersion of single-walled carbon nanotubes2008

    • Author(s)
      Y. Maeda, et.al.
    • Journal Title

      Nano 3

      Pages: 455-459

    • Peer Reviewed
  • [Journal Article] 金属性単層カーボンナノチューブの分離法の開拓2008

    • Author(s)
      前田優、長谷川正、赤阪健、永瀬茂
    • Journal Title

      ケミカルエンジニアリング 53

      Pages: 363-369

  • [Journal Article] Synthesis of Directly and Doubly Linked Dioxobacteriochlorin Dimers2008

    • Author(s)
      Satoru Hiroto, et.al.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 16172-16173

    • Peer Reviewed
  • [Journal Article] Efficient Rhodium-Catalyzed Installation of Unsaturated Ester Functions onto Porphyrins : SiteSpecific Heck-Type Addition versus Conjugate Addition2008

    • Author(s)
      H. Baba, et.al
    • Journal Title

      Chem. Eur. J. 14

      Pages: 4256-4262

    • Peer Reviewed
  • [Journal Article] Photoelectrochemical Properties of Doubly β-Functionalized Porphyrin Sensitizers for Dye-Sensitized Nanocrystalline-TiO2 Solar Cells2008

    • Author(s)
      J. K. Park, et.al.
    • Journal Title

      J. Phys. Chem. 112

      Pages: 16691-16699

    • Peer Reviewed
  • [Journal Article] Effective Expansion of the Subporphyrin Chromophore Through Conjuga tion with meso-Oligo(1,4-phenyleneethynylene) Substituents : Octupolar Effect on Two-Photon Absorption2008

    • Author(s)
      Yasuhide Inokuma, et.al.
    • Journal Title

      Angew. Chem, Int., Ed. 47

      Pages: 4840-4843

    • Peer Reviewed
  • [Journal Article] meso-(4-(N, N-Dialkylamino)phenyl)Substituted Subporphyrins : Remarkab ly Perturbed Absorption Spectra and Enhanced Fluorescence by Intramo lecular Charge Transfer Interactions2008

    • Author(s)
      Yasuhide Inokuma, et.al.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 12234-12235

    • Peer Reviewed
  • [Journal Article] Unambiguous Identification of Mobius Aromaticity for mesoAryl-Substit uted [28]Hexaphyrins(1.1.1.1.1.1)2008

    • Author(s)
      Jeyaraman Sankar, et.al.
    • Journal Title

      J. Am Chem. Soc. 130

      Pages: 13568-13579

    • Peer Reviewed
  • [Journal Article] 3, 3' and 4, 4'-Biphenylene-Bridged Subporphyrin Dimers2008

    • Author(s)
      Yasuhide Inokuma, et.al.
    • Journal Title

      Org. Lett 10

      Pages: 5561-5564

    • Peer Reviewed
  • [Journal Article] 2,5-Thionylene-Bridged Triangular and Linear Porphyrin Trimers2008

    • Author(s)
      J. Song, et.al.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 6004-6007

    • Peer Reviewed
  • [Journal Article] Two-Dimensionally Extended Porphyrin Tapes : Synthesis and Shape-Dep endent Two-Photon Absorption Properties2008

    • Author(s)
      Yasuyuki Nakamura, et.al.
    • Journal Title

      Chemistry. A European Journal 14

      Pages: 8279-8289

    • Peer Reviewed
  • [Journal Article] ProtonationTriggered Conformational Changes to Mobius Aromatic [32] Heptaphyrins(1.1.1.1.1.1.1)2008

    • Author(s)
      Shohei Saito, et.al.
    • Journal Title

      Angew. Chem., Int. Ed. 47

      Pages: 9657-9660

    • Peer Reviewed
  • [Journal Article] A Stable Radical Species from Facile Oxygenation of meso-Free 5, 10, 20, 25-Tetrakis (pentafluorophenvl)-Substituted [26]Hexaphvrin(1.1.1.1.1.1)2008

    • Author(s)
      Taro Koide, et.al.
    • Journal Title

      Angew. Chem., Int. Ed. 47

      Pages: 9661-9665

    • Peer Reviewed
  • [Journal Article] Pt(II) and Pt(IV)-Bridged Cofacial Diporphyrins via Carbon-Transition Metal a -Bonds2008

    • Author(s)
      Shigeru Yamaguchi, et.al.
    • Journal Title

      J. Am Chem. Soc. 130

      Pages: 14440

    • Peer Reviewed
  • [Journal Article] A meso-meso directly linked octameric porphyrin square2008

    • Author(s)
      Naoki Aratani, et.al.
    • Journal Title

      Chem. Commun

      Pages: 4067-4069

    • Peer Reviewed
  • [Journal Article] Synthesis and characterizations of free base and Cu(II) complex of a porphvrin sheet2008

    • Author(s)
      Yasuyuki Nakamura, et.al.
    • Journal Title

      Tetrahedron 64

      Pages: 11433-11439

    • Peer Reviewed
  • [Journal Article] ポルフィリン多量体の化学2008

    • Author(s)
      荒谷直樹、大須賀篤弘
    • Journal Title

      固体物理 43

      Pages: 809-820

    • Peer Reviewed
  • [Journal Article] Bay-Area Selective Thermal [4+2] and [4+4]Cycloaddition Reactions of Triply Linked Zn(II) Diporphyrin with o-Xylylene2008

    • Author(s)
      T. Tanaka, et.al.
    • Journal Title

      Chem. Eur. J. 14

      Pages: 204-211

    • Peer Reviewed
  • [Journal Article] Synthesis of Nanometer-scale Porphyrin Wheels of Variable Size2008

    • Author(s)
      T. Hori, et.al.
    • Journal Title

      Chem : Eur. J 14

      Pages: 582-595

    • Peer Reviewed
  • [Journal Article] Metalation of Expanded Porphyrins : A Chemical Trigger Used To Produce Molecular Twisting and M bius Aromaticity2008

    • Author(s)
      Y. Tanaka, et.al.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 681-684

    • Peer Reviewed
  • [Journal Article] Excitation Energy Migration Processes in Cyclic Porphyrin Arrays Probed by Single Molecule Spectroscopy2008

    • Author(s)
      J. Yang, et.al.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 1879-1884

    • Peer Reviewed
  • [Journal Article] Photofunctional nanomaterials composed of multiporphyrins and carbon-based π-electron accentors2008

    • Author(s)
      Shunichi Fukuzumi, et.al.
    • Journal Title

      Journal of Materials Chemistry 18

      Pages: 1427-1439

    • Peer Reviewed
  • [Journal Article] Fullerene-based supramolecular nanoclusters with poly[2-methoxy-5-(2'-ethylhexyloxy)-p-phenylenevinylene] for light energy conversion2008

    • Author(s)
      Taku Hasobe, et.al.
    • Journal Title

      Japanese Journal of Applied Physics 47

      Pages: 1223-1229

    • Peer Reviewed
  • [Journal Article] One-Step versus Stepwise Mechanism in Protonated Amino Acid-Promoted Electron-Transfer Reduction of a Quinone by Electron Donors and Two-Electron Reduction by a Dihydronicotinamide Adenine Dinucleotide Analogue Interplay between Electron Transfer and Hydrogen Bondin2008

    • Author(s)
      Junpei Yuasa, et.al.
    • Journal Title

      Journal of the America' Chemical Society 130

      Pages: 5808-5820

    • Peer Reviewed
  • [Journal Article] Mechanistic study on dimerization of acetylene with aNieuwland catalyst2008

    • Author(s)
      Takashi Tachiyama, et.al.
    • Journal Title

      Applied Organometallic Chemistry 22

      Pages: 205-210

    • Peer Reviewed
  • [Journal Article] Control of redox reactivity of flavin and pterin coenzymes by metal ion coordination and hydrogen bonding2008

    • Author(s)
      Shunichi Fukuzumi, et.al.
    • Journal Title

      Journal of Biological Inorganic Chemistry 13

      Pages: 321-333

    • Peer Reviewed
  • [Journal Article] Accelerating and decelerating effects of metal ions on electron-transfer reduction of quinones as a function of temperature and binding modes of metal ions to semiquinone radical anions2008

    • Author(s)
      Junpei Yuasa, et.al.
    • Journal Title

      Chemistry-A European Journal 14

      Pages: 1866-1874

    • Peer Reviewed
  • [Journal Article] Development of bioinspired artificial photosynthetic systems2008

    • Author(s)
      Shunichi Fukuzumi, et.al.
    • Journal Title

      Physical Chemistry Chemical Physics 10

      Pages: 2283-2297

    • Peer Reviewed
  • [Journal Article] Switchable antenna : a star-shaped ruthenium/osmium tetranuclear complex with azobis(bipyridine) bridging ligands2008

    • Author(s)
      Joe Otsuki, et.al.
    • Journal Title

      Chemistry-A European Journal 14

      Pages: 2709-2718

    • Peer Reviewed
  • [Journal Article] Bioinspired energy conversion systems for hydrogen production and storage2008

    • Author(s)
      Shunichi Fukuzumi
    • Journal Title

      European Journal of Inorganic Chemistry 9

      Pages: 1351-1362

    • Peer Reviewed
  • [Journal Article] DNA cleavage induced by photoirradiation of coenzyme B12 and organocobaloximes without dioxygen2008

    • Author(s)
      Makiko Tanaka, et.al.
    • Journal Title

      Journal of Photochemistry and Photobiology, A : Chemistry 197

      Pages: 94-100

    • Peer Reviewed
  • [Journal Article] Intermolecular vs. intramolecular photoinduced electron transfer from nucleotides in DNA to acridinium ion derivatives in relation with DNA cleavage2008

    • Author(s)
      Makiko Tanaka, et.al.
    • Journal Title

      Journal of Photochemistry and Photobiology, A : Chemistry 197

      Pages: 206-212

    • Peer Reviewed
  • [Journal Article] Clarification of the Oxidation State of Cobalt Corroles in Heterogeneous and Homogeneous Catalytic Reduction of Dioxygen2008

    • Author(s)
      Karl M Kadish, et.al.
    • Journal Title

      Inorganic Chemistry 47

      Pages: 6726-6737

    • Peer Reviewed
  • [Journal Article] Bisorthodiynyl-arene C60 adducts on SnO2 films for photoelectrochemical cells2008

    • Author(s)
      Kenji Saito, et.al.
    • Journal Title

      Journal of Materials Chemistry 18

      Pages: 3237-3241

    • Peer Reviewed
  • [Journal Article] Androgynous Porphyrins. Silver(II) Quinoxalinoporphyrins Act as Both Good Electron Donors and Acceptors2008

    • Author(s)
      Shunichi Fukuzumi, et.al.
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 9451-9458

    • Peer Reviewed
  • [Journal Article] Deuterium kinetic isotope effects and H/D exchange in dimerization of acetylene with a Nieuwland catalyst in aqueous media2008

    • Author(s)
      Takashi Tachiyama, et.al.
    • Journal Title

      Journal of Physical Organic Chemistry 21

      Pages: 510-515

    • Peer Reviewed
  • [Journal Article] Exciplex Mediated Photoinduced Electron Transfer Reactions of Phthalocvanine-Fullerene Dyads2008

    • Author(s)
      Maria Niemi, et.al.
    • Journal Title

      Journal of Physical Chemistry A 112

      Pages: 6884-6892

    • Peer Reviewed
  • [Journal Article] Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source2008

    • Author(s)
      Yuichiro Hirai, et.al.
    • Journal Title

      Angewandte Chemie, International Edition 47

      Pages: 5772-5776

    • Peer Reviewed
  • [Journal Article] Response : Why had long-lived elec-trontransfer states of donorsubstituted 10-methylacridinium ions been overlooked? Formation of the dimer radical cations detected in the near-IR reeion2008

    • Author(s)
      Shunichi Fukuzumi, et.al.
    • Journal Title

      Physical Chemistry Chemical Physics 10

      Pages: 5159-5162

    • Peer Reviewed
  • [Journal Article] pH-Dependent isotope exchange and hydrogenation catalysed by watersoluble NiRu complexes as functional models for [NiFe]hydrogenases2008

    • Author(s)
      Bunsyo Kure, et.al.
    • Journal Title

      Dalton Transactions 35

      Pages: 4747-4755

    • Peer Reviewed
  • [Journal Article] Metal ion-coupled electron-transfer reduction of dioxygen2008

    • Author(s)
      Shunichi Fukuzumi
    • Journal Title

      Chemistry Letters 37

      Pages: 808-813

    • Peer Reviewed
  • [Journal Article] A discrete supramolecular conglomerate composed of two saddle-distorted zinc(II)-phthalocyanine complexes and a doubly protonated porphyrin withsaddle distortion undergoing efficient nhotoinduced electron transfer2008

    • Author(s)
      Takahiko Kojima, et.al.
    • Journal Title

      Angewandte Chemie, International Edition 47

      Pages: 6712-6716

    • Peer Reviewed
  • [Journal Article] A mechanistic dichotomy in concerted versus stepwise pathways in hydride and hydrogen transfer reactions of NADH analogues2008

    • Author(s)
      Junpei Yuasa, et.al.
    • Journal Title

      Journal of Physical Organic Chemistry 21

      Pages: 886-896

    • Peer Reviewed
  • [Journal Article] Hydrogen atom abstraction and hydride transfer reactions by iron(IV)-Oxo porphyrins2008

    • Author(s)
      Yu Jin Jeong, et.al.
    • Journal Title

      Angewandte Chemie, International Edition 47

      Pages: 7321-7324

    • Peer Reviewed
  • [Journal Article] Highly. Selective Synthesis of the Ring-B Reduced Chlorins by Ferric Chloride-Mediated Oxidation of Bacteriochlorins : Effects of the Fused Imide vs. Isocyclic Ring on Photophysical and Electrochemical Properties2008

    • Author(s)
      Liu Chao, et.al.
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 14311-14323

    • Peer Reviewed
  • [Journal Article] Control of Photoinduced Electron Transfer in Zinc Phthalocyanine-Perylenediimide Dyad and Triad by the Magnesium Ion2008

    • Author(s)
      Shunichi Fukuzumi, et.al.
    • Journal Title

      Journal of Physical Chemistry A 112

      Pages: 10744-10752

    • Peer Reviewed
  • [Journal Article] Corrole-Fullerene Dyads : Formation of Long-Lived Charge-Separated States in Nonpolar Solvents2008

    • Author(s)
      Francis DSouza, et.al.
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 14263-14272

    • Peer Reviewed
  • [Journal Article] Adiabatic Photoinduced Electron Transfer and Back Electron Transfer in a Series of Axially Substituted Silicon Phthalocvaniiie Triads2008

    • Author(s)
      Luis.Martin-Gomis, et.al.
    • Journal Title

      Journal of Physical Chemistry C 112

      Pages: 17694-17701

    • Peer Reviewed
  • [Journal Article] Sequential Electron-Transfer and Proton-Transfer Pathways in Hydride-Transfer Reactions from Dihydronicotinamide Adenine Dinucleotide Analogues to Non-heme Oxoiron(IV) Complexes and pChloranil. Detection of Radical Cations of NADH Analogues in Acid-Promoted Hydride-Transfer Reactions2008

    • Author(s)
      Shunichi Fukuzumi, et.al.
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 15134-15142

    • Peer Reviewed
  • [Journal Article] Ruthenium(II) pyridylamine complexes with diimine Iigands showing reversible photochemical and thermal structural change2008

    • Author(s)
      Takahiko Kojima, et.al.
    • Journal Title

      Chemistry-A European Journal 14

      Pages: 8904-8915

    • Peer Reviewed
  • [Journal Article] Umpolung" Photoinduced Charge Separation in an Anion-bound Supramolecular Complex2008

    • Author(s)
      Jonathan L. Sessler, et.al.
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 15256-15257

    • Peer Reviewed
  • [Journal Article] Efficient catalytic decomposition of formic acid for the selective generation of H2 and H/D exchange with a watersoluble rhodium comolex in aaueous solution2008

    • Author(s)
      Shunichi Fukuzumi, et.al.
    • Journal Title

      ChemSusChem 1

      Pages: 827-834

    • Peer Reviewed
  • [Journal Article] Isolation and Crystal Structures of Both Enol and Keto Tautomer Intermediates in a Hydration of an Alkyne-Carboxylic Acid Ester Catalyzed by Iridium Complexes in Water2008

    • Author(s)
      Hironobu Kanemitsu, et.al.
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 17141-17147

    • Peer Reviewed
  • [Journal Article] Photoconductivity of Porphyrin Nanochannels Composed of Diprotonated Porphyrin Dications with Saddle Distortion and Electron Donors2008

    • Author(s)
      Tatsuaki Nakanishi, et.al.
    • Journal Title

      Chemistry of Materials 20

      Pages: 7492-7500

    • Peer Reviewed
  • [Journal Article] Metal Quinolinolate-Fullerene(s) Donor-Acceptor Complexes : Evidence for Organic LED Molecules Acting as Electron ponors in Photoinduced Electron-Transfer Reactions2008

    • Author(s)
      Francis D'Souza, et.al.
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 16959-16967

    • Peer Reviewed
  • [Journal Article] Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin2008

    • Author(s)
      Takahiko Kojima, et.al.
    • Journal Title

      Chemical Communications 48

      Pages: 6513-6515

    • Peer Reviewed
  • [Journal Article] (Pentamethylcyclopentadienyl)ruthenium π-complexes of metalloporphyrins : platforms with novel photo- and electrochemical properties2008

    • Author(s)
      Luciano Cuesta, et.al.
    • Journal Title

      Chemistry-A European Journal 14

      Pages: 10206-10210

    • Peer Reviewed
  • [Journal Article] Long-lived charge-separated states of simple electron donor-acceptor dyads using porphyrins and phthalocyanines2008

    • Author(s)
      Kei Ohkubo, et.al.
    • Journal Title

      Journal of Porphyrins and Phthalocyanines 12

      Pages: 993-1004

    • Peer Reviewed
  • [Journal Article] Proton shift upon oneelectron reduction in ruthenium(II)coordinated pterins2008

    • Author(s)
      Soushi Miyazaki, et.al.
    • Journal Title

      Angewandte Chemie, International Edition 47

      Pages: 9669-9672

    • Peer Reviewed
  • [Journal Article] Enhanced radical-scavenging activity of naturallyoriented artepillin C derivatives2008

    • Author(s)
      Sushma Manda, et.al.
    • Journal Title

      Chemical Communications 48

      Pages: 6610

    • Peer Reviewed
  • [Journal Article] Structural.Changes of Salinibacter Sensory Rhodopsin I upon Formation of the K and M Photointermediates2008

    • Author(s)
      D. Suzuki, et.al.
    • Journal Title

      Biochemistry 47

      Pages: 12750-12759

    • Peer Reviewed
  • [Journal Article] Functional Evaluation of Iron Oxypyriporphyrin in Protein Heme Pocket2008

    • Author(s)
      S. Neya, et.al.
    • Journal Title

      Inorg. Chem 47

      Pages: 10771-10778

    • Peer Reviewed
  • [Journal Article] FTIR Study of the L Intermediate of Anabaena Sensory Rhodopsin : Structural C hanges in the Cytoplasmic Region2008

    • Author(s)
      A. Kawanabe, et.al.
    • Journal Title

      Biochemistry 47

      Pages: 10033-10040

    • Peer Reviewed
  • [Journal Article] Ultrafast Pump-Probe Study of the Primary Photoreaction Process in pharaonis Halorhodopsin : Halide-Ion Dependence and Jsomerization Dynamics2008

    • Author(s)
      T. Nakamura, et.al.
    • Journal Title

      J. Phys. Chem B 112

      Pages: 12795-12800

    • Peer Reviewed
  • [Journal Article] Salinibacter Sensory Rhodopsin : Sensory Rhodopsin I-like Protein from a Eubacterium2008

    • Author(s)
      T. KitajimaIhara, et.al.
    • Journal Title

      J. Biol. Chem 283

      Pages: 23533-23541

    • Peer Reviewed
  • [Journal Article] Steric Constraint in the Primary Photoproduct of Sensory Rhodopsin II Is a prerequisite for Light-Signal Transfer to HtrII2008

    • Author(s)
      M. Ito, et.al.
    • Journal Title

      Biochemistry 47

      Pages: 6208-6215

    • Peer Reviewed
  • [Journal Article] Active Internal Waters in the Bacteriorhodopsin Photocycle. A Comparative Study of the L and M Intermediates at Room and Cryogenic Temperatures by Infrar ed Spectroscopy2008

    • Author(s)
      V.A. LorenzFonfria, et.al.
    • Journal Title

      Biochemistry 47

      Pages: 4071-4081

    • Peer Reviewed
  • [Journal Article] Color Change of Proteorhodopsin by a Single Amino Acid Replacement at a Dis tant Cytoplasmic Loop2008

    • Author(s)
      M. Yoshitugu, et.al.
    • Journal Title

      Angew. Chem. hit. Ed 47

      Pages: 3923-3926

    • Peer Reviewed
  • [Journal Article] Protein-ProteinInteraction ofa pharaonis Halorhodopsin Mutant Forming a Complex with pharaonis Halobacterial Transducer Protein II Detected by Fourier Transform Infrared Spectroscopy2008

    • Author(s)
      Y. Furutani, et.al.
    • Journal Title

      Photochem. Photobio (in press)

    • Peer Reviewed
  • [Journal Article] Quantum Yields for the Light Adaptations in Anabaena Sensory Rhodopsin and Bacteriorhodopsin2008

    • Author(s)
      A. Wada, et.al.
    • Journal Title

      Chem. Phys. Lett 453

      Pages: 105-108

    • Peer Reviewed
  • [Journal Article] Structural Changes of Sensory Rhodopsin and its Transducer Protein Are Depend ent on the Protonated State of Asp762008

    • Author(s)
      Y. Furutani, et.al.
    • Journal Title

      Biochemistry 47

      Pages: 2875-2883

    • Peer Reviewed
  • [Journal Article] Structural Changes in the O-decay Accelerated Mutants of pharaonis Phoborhodopsin2008

    • Author(s)
      Y. Sudo, et.al.
    • Journal Title

      Biochemistry 47

      Pages: 2866-2874

    • Peer Reviewed
  • [Journal Article] Role of Phe1010 in LightInduced Structural Changes of the neol-L0V2 Domain of Adiantum2008

    • Author(s)
      A. Yamamoto, et.al.
    • Journal Title

      Biochemistry 47

      Pages: 922-928

    • Peer Reviewed
  • [Journal Article] Electronic Properties in a Five-Coordinate Azido Complex of Nonplanar Ion(III) Porphyrin : Revisiting to Quantum Mechanical Spin Admixing2008

    • Author(s)
      S. Neya, et.al.
    • Journal Title

      Bull Chem. Soc. Jpn 47

      Pages: 136-141

    • Peer Reviewed
  • [Journal Article] Substrate Effect of STMInduced Luminescence from Porphyrin Molecules2008

    • Author(s)
      H. W. Liu
    • Journal Title

      Thin Solid Films 516

      Pages: 2727-2730

    • Peer Reviewed
  • [Journal Article] Electronegative Oligothiophenes Based on Difluorodioxocyclopentene-Annelated Thiophenes : Synthesis, Properties, and n-Type FET Performances2008

    • Author(s)
      Y. Ie
    • Journal Title

      Org. Lett. 10

      Pages: 833-836

    • Peer Reviewed
  • [Journal Article] Electronegative Oligothiophenes Fully Annelated with Hexafluorocyclopentene : Sy nthesis, Properties, and Intrinsic Electron Mobility2008

    • Author(s)
      Y. Umemoto
    • Journal Title

      Org. Lett 10

      Pages: 1095-1098

    • Peer Reviewed
  • [Journal Article] フッ素化反応を基盤とする電子輸送性共役オリゴマーの開発と有機電界効果トランジスタへの応用2008

    • Author(s)
      家裕隆
    • Journal Title

      有機合成化学協会誌 66

      Pages: 504-514

    • Peer Reviewed
  • [Journal Article] Synthesis, Structure, and Properties of 2, 5, 8, 11, 14, 17-Hexamethyltriphenyleno [2, 1-b : 3, 4b' : 6, 5-b" : 7, 8b" : 10, 9b"" : 11, 12b""]hexathiophene2008

    • Author(s)
      M. Endou
    • Journal Title

      Heterocycles 76

      Pages: 1043-1048

    • Peer Reviewed
  • [Journal Article] Mono-and.penta-addition of enol silyl ethers to [60]fullerene2008

    • Author(s)
      E. Nakamura, et.al.
    • Journal Title

      Org. Lett 10

      Pages: 4923-4926

    • Peer Reviewed
  • [Journal Article] Imaging the passage of a single hydrocarbon chain through a nanopore2008

    • Author(s)
      M. Koshino. et.al.
    • Journal Title

      Nature Nanotech 3

      Pages: 595-597

    • Peer Reviewed
  • [Journal Article] A water-soluble fullerene vesicle alleviates angiotensin II induced oxidative ctracc in human umhilical vanmmc anrinthalial ralls2008

    • Author(s)
      R. Maeda, et.al.
    • Journal Title

      Hypertens. Res. 31

      Pages: 141-151

    • Peer Reviewed
  • [Presentation] 高次π空間の創発2009

    • Author(s)
      T. Akasaka
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      船橋市
    • Year and Date
      20090327-30
  • [Presentation] 地球温暖化対策としての人工光合成2009

    • Author(s)
      福住俊一
    • Organizer
      第89日日本化学会春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      20090327-30
  • [Presentation] Poly(3-hexylthiophene) field-effect transistors fabricated by slide coating method2009

    • Author(s)
      M. Karakawa
    • Organizer
      Fifth International Conference on Molecular Electronics and Bioelectronics (M&BE5)
    • Place of Presentation
      Miyazaki
    • Year and Date
      20090315-18
  • [Presentation] 赤外分光法による生体分子の機能発現過程の構造解析2009

    • Author(s)
      神取秀樹
    • Organizer
      量子生体分子科学研究拠点形成に関するシンポジウム
    • Place of Presentation
      水戸
    • Year and Date
      20090219-20
  • [Presentation] 人工光合成材料2009

    • Author(s)
      福住俊一
    • Organizer
      SORSTシンポジウム(2)フレクシブルデバイス/マテリアルの未来像
    • Place of Presentation
      コクヨホール、東京
    • Year and Date
      20090212-13
  • [Presentation] Role of Internal Water Molecules in Bacteriorhodopsin : FTIR Study at Low and Room Temperatures2009

    • Author(s)
      H. Kandori, et.al.
    • Organizer
      6^<th> Asian Biophysics Association Symposium
    • Place of Presentation
      Hong Kong
    • Year and Date
      20090111-14
  • [Presentation] β、βージヒドロキシポルフィリンの合成および二量化反応2009

    • Author(s)
      廣戸聡、et.al.
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日本大学、船橋
    • Year and Date
      2009-03-30
  • [Presentation] カゴ型サブポルフィリンの合成と構造、及び物性2009

    • Author(s)
      猪熊泰英、et.al.
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日本大学、船橋
    • Year and Date
      2009-03-30
  • [Presentation] メゾーメゾ直接結合ポルフィリンーヘキサフィリンニ量体の合成と物性2009

    • Author(s)
      田中隆行、et.al.
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日本大学、船橋
    • Year and Date
      2009-03-30
  • [Presentation] 環拡張ポルフィリンのπ共役系変換反応2009

    • Author(s)
      斉藤尚平、et.at.
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日本大学、船橋
    • Year and Date
      2009-03-30
  • [Presentation] メゾフリーヘキサフィリンの金属錯体の合成と物性2009

    • Author(s)
      小出太郎、et.al.
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日本大学、船橋
    • Year and Date
      2009-03-30
  • [Presentation] 環外周部に炭素-金属結合を持つポルフィリンの合成2009

    • Author(s)
      山口滋、et.al.
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日本大学、船橋
    • Year and Date
      2009-03-29
  • [Presentation] トリアゾール環を用いたポルフイリン集合体の形成2009

    • Author(s)
      前田千尋、et.al.
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日本大学、船橋
    • Year and Date
      2009-03-27
  • [Presentation] Emergence of Highly Elaborated pi-Space : Endohedral Metallofullerenes2009

    • Author(s)
      T. Akasaka
    • Organizer
      College of Chemistry and Molecular Engineering, Peking University
    • Place of Presentation
      Beijing, China
    • Year and Date
      2009-03-23
  • [Presentation] Development of Tripodal Anchor Units Bearing Selenium Functional Groups and Characterization of Their Monolayers2009

    • Author(s)
      T. Hirose
    • Organizer
      The 12th SANKEN International Symposium
    • Place of Presentation
      Osaka Univ.
    • Year and Date
      2009-01-22
  • [Presentation] Synthesis and Properties of Branched Oligothiophenes Bearing Perylene Bis(dicarboximide) Groups2009

    • Author(s)
      T. Uto
    • Organizer
      The 12th SANKEN International Symposium
    • Place of Presentation
      Osaka Univ.
    • Year and Date
      2009-01-22
  • [Presentation] Synthesis of Pyridine-fused Porphyrinoid2008

    • Author(s)
      Sumito Tokuji, et.al.
    • Organizer
      10th KAIST-KYOTO Chemstry Symposium
    • Place of Presentation
      KAIST (Korea)
    • Year and Date
      20081210-13
  • [Presentation] 紅色細菌の光化学反応中心のプロトン取り込みに関わる水分子の検出2008

    • Author(s)
      岩田達也、et.al.
    • Organizer
      日本生物物理学会第46回年会
    • Place of Presentation
      福岡
    • Year and Date
      20081203-05
  • [Presentation] バクテリァのセンサーロドプシンに対する1アミノ酸の置換で実現した内向きのプロトンポンプ2008

    • Author(s)
      川鍋陽、et.al.
    • Organizer
      日本生物物理学会第46回年会
    • Place of Presentation
      福岡
    • Year and Date
      20081203-05
  • [Presentation] 光回復酵素およびクリプトクロムの光誘起構造変化の研究2008

    • Author(s)
      張宇、et.al.
    • Organizer
      日本生物物理学会第46回年会
    • Place of Presentation
      福岡
    • Year and Date
      20081203-05
  • [Presentation] ロドプシンのカーボンナノチューブへの内包2008

    • Author(s)
      川島崇睦、et.al.
    • Organizer
      日本生物物理学会第46回年会
    • Place of Presentation
      福岡
    • Year and Date
      20081203-05
  • [Presentation] ppRにウシロドプシンの第三ループを組み込んだキメラタンパク質の研究2008

    • Author(s)
      中妻亜弥、et.al.
    • Organizer
      日本生物物理学会第46回年会
    • Place of Presentation
      福岡
    • Year and Date
      20081203-05
  • [Presentation] D85N変異体を用いて解析したバクテリオロドプシンのシップ塩基部位の水素結合構造2008

    • Author(s)
      山田純也, et.al.
    • Organizer
      日本生物物理学会第46回年会
    • Place of Presentation
      福岡
    • Year and Date
      20081203-05
  • [Presentation] Homogeneous and Heterogeneoues Catalytic Reduction of Dioxygen Using Cobalt Corroles2008

    • Author(s)
      大久保敬
    • Organizer
      The 4^<th> Asian Biological Inorganic Chemistry Conference(AsBICIV)
    • Place of Presentation
      韓国・チェジュ島
    • Year and Date
      20081110-13
  • [Presentation] Metal Ion-Coupled Electron Transfer in Bioinspired ElectronTranafer Systems2008

    • Author(s)
      福住俊一
    • Organizer
      The 4^<th> Asian Biological Inorganic Chemistry Conference(AsBICN)
    • Place of Presentation
      韓国・チェジュ島
    • Year and Date
      20081110-13
  • [Presentation] Construction of Conglomerates Composed of a Saddle-DistortedMetalloporphyrin and Heteronolvoxometalates2008

    • Author(s)
      横山温和
    • Organizer
      The International Workshop on Molecular Information and Dynamics 2008
    • Place of Presentation
      台湾
    • Year and Date
      20081110-12
  • [Presentation] Elongation of Charge-Separation Lifetime of Zinc Quinoxalino- porphyrin-Gold Quinoxalinoporahyrin by Binding of Scandium Ion2008

    • Author(s)
      大久保敬
    • Organizer
      The 5^<th> Asian-Oceanian Photochemistry Conference
    • Place of Presentation
      中華人民共和国・北京市
    • Year and Date
      20081101-05
  • [Presentation] Artificial Photosynthetic Svstems2008

    • Author(s)
      福住俊一
    • Organizer
      太陽光エネルギーの有効利用に関するワークショップ
    • Place of Presentation
      大阪市立大学文化交流センター
    • Year and Date
      2008-12-15
  • [Presentation] 塗布製膜n型OFET材料としてのジフルオロジオキソシクロペンテン縮環チオフェンを含む共役オリゴマーの開発2008

    • Author(s)
      岡部誠
    • Organizer
      第35回有機典型元素化学討論会
    • Place of Presentation
      八王子市
    • Year and Date
      2008-12-11
  • [Presentation] 様々な官能基を有する三脚型アンカーユニットの合成と単分子膜の評価2008

    • Author(s)
      廣瀬智哉
    • Organizer
      第2回有機π電子系シンポジウム
    • Place of Presentation
      広島市
    • Year and Date
      2008-12-05
  • [Presentation] アクセプター部位としてペリレンビスイミド基を持つ分岐型オリゴチオフェンの合成と物性2008

    • Author(s)
      宇都俊彦
    • Organizer
      第2回有機π電子系シンポジウム
    • Place of Presentation
      広島市
    • Year and Date
      2008-12-05
  • [Presentation] New Fullerene World Opened by Functionalization with Main Group Element Compounds2008

    • Author(s)
      T. Akasaka
    • Organizer
      Polish Academy of Sciences
    • Place of Presentation
      Lodz, Poland
    • Year and Date
      2008-11-27
  • [Presentation] 人工光合成の物理化学研究2008

    • Author(s)
      福住俊一
    • Organizer
      中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-11-08
  • [Presentation] ナノカーボンの新展開 : 金属内包フラーレン2008

    • Author(s)
      T. Akasaka
    • Organizer
      有機金属部会平成20年度第3回例会
    • Place of Presentation
      仙台市
    • Year and Date
      2008-10-30
  • [Presentation] New Progress in Nanocarbon Science : Endohedral Metallofullerene2008

    • Author(s)
      T. Akasaka
    • Organizer
      Plenary Lecture at Faculty of Chemical Engineeri ng, Nanjing University of Science and Technology
    • Place of Presentation
      Nanjing, China
    • Year and Date
      2008-09-08
  • [Presentation] New Progress in Nanocarbon Science : Endohedral Metallofullerene2008

    • Author(s)
      T. Akasaka
    • Organizer
      The Yong Hae Kini Lectureship, Korean Institute of Science and Technology
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2008-09-03
  • [Presentation] A New Approach for Nano-Device Applications-More is Different in Metallofullerenes2008

    • Author(s)
      T. Akasaka
    • Organizer
      NIMS Week 2008
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2008-07-15
  • [Presentation] A New Approach for Nano-Device Applications -More is Different in Metallofullerenes2008

    • Author(s)
      T. Akasaka
    • Organizer
      University of California at Davis
    • Place of Presentation
      Dayis, USA
    • Year and Date
      2008-07-01
  • [Presentation] New Progress in Chemistry of Nanocarbon : Endohedral Metallofullerenes2008

    • Author(s)
      T. Akasaka
    • Organizer
      Department of Chemistry, University of Compulte nse at Madrid
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2008-06-09
  • [Book] 電子共役系有機材料の創製・機能開発・応用「オリゴチオフェンの合成と機能」2008

    • Author(s)
      安蘇芳雄
    • Total Pages
      198-208
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

  • [Remarks]

    • URL

      http://kuchem.kyoto-u.ac.jp/shuyu/

  • [Remarks]

    • URL

      http://www.etchem.mls.eng.osaka-u.ac.jp/mlsetO10/fukuweb/index_j.html

  • [Remarks]

    • URL

      http://www.ach.nitech.ac.jp/~physchem/kandoti/index_j.html

  • [Remarks]

    • URL

      http://www.sanken.oska-u.jp/labs/omm/

  • [Remarks]

    • URL

      http://www.orgchem2.chem.tohoku.ac.jp/Main/Top.html

  • [Patent(Industrial Property Rights)] 分岐型化合物, これを用いた有機薄膜及び有機薄膜素子2009

    • Inventor(s)
      家裕隆, 宇都俊彦, 安蘇芳雄, 上田将人
    • Industrial Property Rights Holder
      大阪大学・住友化学株式会社
    • Industrial Property Number
      PCT/JP2009/050083
    • Filing Date
      2009-01-07
    • Overseas
  • [Patent(Industrial Property Rights)] 共役系化合物, 含窒素縮合環化合物, 倉窒素縮合環重合体, 有機薄膜及び有機薄膜素子2008

    • Inventor(s)
      安蘇芳雄, 家裕隆, 岡部誠, 二谷真司, 上田将人
    • Industrial Property Rights Holder
      大阪大学・住友化学株式会社
    • Industrial Property Number
      PCT/JP2008/071520
    • Filing Date
      2008-11-27
    • Overseas

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Published: 2010-06-11   Modified: 2016-04-21  

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