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2010 Fiscal Year Annual Research Report

配位プログラミング-分子超構造体の科学と化学素子の創製

Administrative Group

Project AreaCoordination Programming - Science of Molecular Superstructures for Chemical Devices
Project/Area Number 21108001
Research InstitutionThe University of Tokyo

Principal Investigator

西原 寛  東京大学, 大学院・理学系研究科, 教授 (70156090)

Co-Investigator(Kenkyū-buntansha) 山元 公寿  東京工業大学, 資源化学研究所, 教授 (80220458)
Keywords配位化学 / 超構造界面 / クラスター / 超分子 / メゾスコピック
Research Abstract

錯体化学が培ってきたd軌道やf軌道が演出する多彩な結合と化学構造、物性、化学反応性の科学を主軸として「プログラミング」の概念に基づき、他の物質科学、界面化学ならびに電子工学分野などの周辺分野との結合、組み合わせによって、ナノ・メゾ領域の精密な構造からなる物質群(超構造体)の基礎科学をつくり上げ、それをもとに物理的、化学的、生物学的な入力信号を、他の出力信号に変換することによって新原理に基づく新機能をもつ、高性能な素子へ展開することを目指している。
平成22年度は第3回全体会議(東京、2010年6月)、第4回全体会議+第2回公開講演会(名古屋、2011年2月)を開催し、計画班、総括班での本領域推進に関する討論、共同研究の推進を行うとともに、領域外研究者との交流(本領域の広報および関連研究の発表)を行った。それぞれの会議では要旨集等を出版した。また、News Letterを毎月発行し、研究成果やトピックスを班員および関連研究者にメールで広く発信し、「配位プログラミング」の研究概念の普及に努めた。
外部に対しては、2010年9月の錯体化学国際会議でのシンポジウム、ヨルダンでのユーラシア会議でのシンポジウム、12月のPacifichem2010でのシンポジウム、日韓錯体化学シンポジウムなどを開催し、広く本研究領域の内容と成果を発信した。2011年には、フランス、レンヌでの日仏研究成果についてはすでに共同研究を含め、論文発表した。

  • Research Products

    (59 results)

All 2011 2010 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results) Presentation (39 results) Remarks (2 results)

  • [Journal Article] Complete solid state photoisomerization of bis(dipyrazolylstyrylpyridine)iron(II) to change magnetic properties2011

    • Author(s)
      Yuta Hasegawa, Kazuhiro Takahashi, Shoko Kume, Hiroshi Nishihara
    • Journal Title

      Chem.Commun

      Volume: 47 Pages: 6846-6848

    • Peer Reviewed
  • [Journal Article] Preferential carbene insertion into Ge-H vs.other heavier group 14 hydrides via samarium carbenoids2011

    • Author(s)
      Hitoshi Kondo, Yoshinori Yamanoi, Hiroshi Nishihara
    • Journal Title

      Chem.Commun.

      Volume: 47 Pages: 6671-6673

    • Peer Reviewed
  • [Journal Article] A Uniform Bimetallic Rhodium/Iron Nanoparticle Catalyst for the Hydrogenation of Olefins and Nitroarenes2011

    • Author(s)
      Ikuse Nakamula, Yoshinori Yamanoi, Takane Imaoka, Kimihisa Yamamoto, Hiroshi Nishihara
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 50 Pages: 5830-5833

    • Peer Reviewed
  • [Journal Article] Reversible On/Off Conductance Switching of Single Diarylethene Immobilized on a Silicon Surface2011

    • Author(s)
      Kazuki Uchida, Yoshinori Yamanoi, Tetsu Yonezawa, Hiroshi Nishihara
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Pages: 9239-9241

    • Peer Reviewed
  • [Journal Article] Expanding Family of π-Conjugated Trinuclear Dithiolenes : The Cases of Group 8 (Ru^<II>) and 10 (Ni^<II> and Pt^<II>) Metals2011

    • Author(s)
      Tetsuya Kambe, Satoru Tsukada, Ryota Sakamoto, Hiroshi Nishihara
    • Journal Title

      Inorg.Chem.

      Volume: 50 Pages: 6856-6858

    • Peer Reviewed
  • [Journal Article] Cyclization of TEMPO Radicals Bound to Metalladithiolene Induced by SOMO-HOMO Energy-Level Conversion2010

    • Author(s)
      Tetsuro Kusamoto, Shoko Kume, Hiroshi Nishihara
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 529-531

    • Peer Reviewed
  • [Journal Article] Thioacetyl-Terminated Ferrocene-Anthraquinone Conjugates : Synthesis, Photo- and Electrochemical Prooerties Triggered by Protonation-Induced Intramolecular Electron Transfer2010

    • Author(s)
      Wen-Wei Zhang, Mio Kondo, Takako Fujita, Kosuke Namiki, Masaki Murata, Hiroshi Nishihara
    • Journal Title

      Molecules

      Volume: 15 Pages: 150-163

    • Peer Reviewed
  • [Journal Article] Acid-Base Responsive Photoelectric Conversion of a Hydroxyazobenzene-appended Bipyridine-Copper Complex System2010

    • Author(s)
      Satoshi Umeki, Shoko Kume, Hiroshi Nishihara
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 204-205

    • Peer Reviewed
  • [Journal Article] A new special pair model comprising meso-di-p-anisylaminoporphyrin : enhancement of visible-light absorptivities and quantification of electronic communication in mixed-valent cation radical2010

    • Author(s)
      Ryota Sakamoto, Michihiro Nishikawa, Takeshi Yamamura, Shoko Kume, Hiroshi Nishihara
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 2028-2030

    • Peer Reviewed
  • [Journal Article] A Photosensing System Composed of Photosystem I, Molecular Wire, Gold Nanoparticle, and Double Surfactants in Water2010

    • Author(s)
      Mariko Miyachi, Yoshinori Yamanoi, Yusuke Shibata, Hirokazu Matsumoto, Kazuo Nakazato, Masae Konno, Kohsuke Ito, Yasunori Inoue, Hiroshi Nishihara
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 2557-2559

    • Peer Reviewed
  • [Journal Article] Surface Junction Effects on the Electron Conduction of Molecular Wires2010

    • Author(s)
      Tomochika Kurita, Yoshihiko Nishimori, Fumiyuki Toshimitsu, Satoshi Muratsugu, Shoko Kume, Hiroshi Nishihara
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 4524-4525

    • Peer Reviewed
  • [Journal Article] Controlled Storage of Ferrocene Derivatives as Redox-Active Molecules in Dendrimers2010

    • Author(s)
      Yousuke Ochi, Mana Suzuki, Takane Imaoka, Masaki Murata, Hiroshi Nishihara, Yasuaki Einaga, Kimihisa Yamamoto
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 5061-5069

    • Peer Reviewed
  • [Journal Article] Versatile Synthesis of Blue Luminescent Siloles and Germoles and Hydrogen Bond-Assisted Color Alteration2010

    • Author(s)
      Yusuke Yabusaki, Norikazu Ohshima, Tetsuro Kusamoto, Hitoshi Kondo, Yoshinori Yamanoi, Hiroshi Nishihara
    • Journal Title

      Chem.Eur.J.

      Volume: 16 Pages: 5581-5585

    • Peer Reviewed
  • [Journal Article] Dual Emission Caused by Ring Inversion Isomerization of a 4-Methyl-2-pyridyl-pyrimidine Copper(I) Complex2010

    • Author(s)
      Michihiro Nishikawa, Kuniharu Nomoto, Shoko Kume, Keiichi Inoue, Makoto Sakai, Masaaki Fujii, Hiroshi Nishihara
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 9579-9581

    • Peer Reviewed
  • [Journal Article] Double Protonation of 1,5-Bis(triarylaminoethynyl)anthraquinone To Form a Paramagnetic Pentacyclic Dipyrylium Salt2010

    • Author(s)
      Koya Prabhakara Rao, Tetsuro Kusamoto, Fumiyuki Toshimitsu, Kiyotaka Inayoshi, Shoko Kume, Ryota Sakamoto, Hiroshi Nishihara
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 12472-12479

    • Peer Reviewed
  • [Journal Article] Molten matrix sputtering synthesis of water-soluble luminescent Au nanoparticles with a large Stokes shift2010

    • Author(s)
      Yuichi Shishino, Tetsu Yonezawa, Koji Kawai, Hiroshi Nishihara
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 7211-7213

    • Peer Reviewed
  • [Journal Article] Facile synthesis of hypersilylated aromatic compounds by palladium-mediated arylation reaction2010

    • Author(s)
      Aldes Lesbani, Hitoshi Kondo, Jun-ichi Sato, Yoshinori Yamanoi, Hiroshi Nishihara
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 7784-7786

    • Peer Reviewed
  • [Journal Article] Integrated Palladium-Catalyzed Arylation of Heavier Group 14 Hydrides2010

    • Author(s)
      Aldes Lesbani, Hitoshi Kondo, Yusuke Yabusaki, Misaki Nakai, Yoshinori Yamanoi, Hiroshi Nishihara
    • Journal Title

      Chem.Eur.J.

      Volume: 16 Pages: 13519-13527

    • Peer Reviewed
  • [Presentation] Modification of Hydrogen-terminated Silicon Surface with Redox Molecular Wires2011

    • Author(s)
      H.Nishihara, H.Maeda, J.Sendo, R.Sakamoto, Y.Yamanoi
    • Organizer
      Shikata Discussion 2011 International Symposium on Electroanalytical Chemistry
    • Place of Presentation
      Awaji, Awaji Yumebutai International Conference Center(招待講演)
    • Year and Date
      2011-05-28
  • [Presentation] Photosensing System Composed of Photosystem I and Molecular Wire on Electrode2011

    • Author(s)
      H.Nishihara, M.Miyachi, Y.Yamanoi, Y.Shibata, H.Matsumoto, K.Nakazato, M.Konno, K.Ito, Y.Inoue
    • Organizer
      The 9th Spring Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Turku, Finland(招待講演)
    • Year and Date
      2011-05-11
  • [Presentation] メソ位にアルキニル基を有する新規平面π拡張BODIPYの合成と物性2011

    • Author(s)
      日下心平、坂本良太、西原寛
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-29
  • [Presentation] トリフェニレンヘキサチオールを用いた9族金属環状三核錯体の合成と物性2011

    • Author(s)
      塚田学、坂本良太、西原寛
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-29
  • [Presentation] 巨大ピリジル亜鉛ポルフィリンによる三次元自己集合多積層膜の構築と性質2011

    • Author(s)
      利光史行、西原寛
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-29
  • [Presentation] メソ位にアルキニル基を有するジピリン錯体の合成と光・電気化学特性2011

    • Author(s)
      日下心平、坂本良太、西原寛
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-29
  • [Presentation] 配位プログラミングによる化学素子へのアプローチ2011

    • Author(s)
      西原寛
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川(招待講演)
    • Year and Date
      2011-03-28
  • [Presentation] 銅(I)錯体上のピリミジン環反転による分子内電子移動の可逆制御2011

    • Author(s)
      久米晶子、西原寛
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-26
  • [Presentation] 三角形ジチオラト三核錯体を骨格とするシート状π共役系物質の創製2011

    • Author(s)
      神戸徹也、坂本良太、西原寛
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-26
  • [Presentation] フェニルカルバゾール、ジエチニルフマル酸ジメチルを有する四重極子型有機分子の可視光光異性化と固体発光2011

    • Author(s)
      林幹大、坂本良太、西原寛
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-26
  • [Presentation] 刺激応答分子の創製とその精密配列による化学素子の開発2011

    • Author(s)
      西原寛
    • Organizer
      新学術領域研究「配位プログラミング-分子超構造体の科学と化学素子の創製」第2回公開シンポジウム第4回全体会議
    • Place of Presentation
      愛知
    • Year and Date
      2011-02-04
  • [Presentation] Surface Coordination Programming of Electro-Functional Molecular Wires2011

    • Author(s)
      西原寛
    • Organizer
      分子研研究会
    • Place of Presentation
      岡崎(招待講演)
    • Year and Date
      2011-01-08
  • [Presentation] Electron injection system regulated with a rotational motion on copper complex2010

    • Author(s)
      S.Kume, H.Nishihara
    • Organizer
      PACIFICHEM2010
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-16
  • [Presentation] Transiton metal-catalyzed arylation of tertiary silanes2010

    • Author(s)
      Y.Yamanoi, A.Lesbani, H.Kondo, H.Nishihara
    • Organizer
      PACIFICHEM2010
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-16
  • [Presentation] Pyrimidine ring inversion behaviors of a copper(I) complex containing 4-methyl-2-pyridyl-pyrimidine and their effects on the photoprocess2010

    • Author(s)
      M.Nishikawa, K.Nomoto, S.Kume, K, Inoue, M.Sakai, M.Fujii, H.Nishihara
    • Organizer
      PACIFICHEM2010I
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-16
  • [Presentation] Photoinduced coordinated pyrimidine ring inversion toward redox modulation of copper complex2010

    • Author(s)
      M.Nishikawa
    • Organizer
      Mini-Symposium On Coordination Programming 2010
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2010-11-02
  • [Presentation] Novel Metalladithiolene Multinuclear complexes with Electronic Communication2010

    • Author(s)
      S.Tsukada
    • Organizer
      Mini-Symposium On Coordination Programming
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2010-11-02
  • [Presentation] Coordination programming of electro-functional molecular wires on the surface2010

    • Author(s)
      H.Nishihara
    • Organizer
      11th Eurasia Conference on Chemical Sciences
    • Place of Presentation
      The Dead Sea, Jordan(招待講演)
    • Year and Date
      2010-10-09
  • [Presentation] 動的挙動を示す非対称ピリジルピリミジン銅錯体のレドックス特性と光物性2010

    • Author(s)
      西川道弘、久米晶子、西原寛
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-28
  • [Presentation] 架橋型スルホキシド部位を持つ多座型ルテニウム錯体の光応答性と電子移動特性2010

    • Author(s)
      鈴木翔子、久米晶子、西原寛
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-28
  • [Presentation] 有機フォトクロミック化合物と遷移金属錯体のインタープレイ2010

    • Author(s)
      坂本良太、西原寛
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-28
  • [Presentation] Coordination Programming of Electro-functional Molecular Wires on the Surface2010

    • Author(s)
      H.Nishihara
    • Organizer
      The 60th Symposium on Coordination Chemistry of Japan
    • Place of Presentation
      Osaka, Japan(招待講演)
    • Year and Date
      2010-09-28
  • [Presentation] Intramolecular Electron Handing through Coordination Mechanical Tools2010

    • Author(s)
      S.Kume, H.Nishihara
    • Organizer
      60th Anniversary Conference on Coordination Chemistry in Osaka, Japan
    • Place of Presentation
      Osaka, Japan(招待講演)
    • Year and Date
      2010-09-28
  • [Presentation] サマリウムカルベノイドを用いた14族水素化物へのアルキリデンの化学選択的導入法2010

    • Author(s)
      近藤仁志、山野井慶徳、西原寛
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-27
  • [Presentation] Double Ring Inversion of Bipyrimidine Derivatives Coordinated to Copper2010

    • Author(s)
      Y.Takara, T.Masui, M.Nishikawa, S.Kume, H.Nishihara
    • Organizer
      The 60th Symposium on Coordination Chemistry of Japan
    • Place of Presentation
      Osaka, Japan Tokyo
    • Year and Date
      2010-09-27
  • [Presentation] Photomagnetic Behavior of Iron(II) Spin Crossove Complexes Based on Stilbene-attached Dipyrazoylpiridine Ligands2010

    • Author(s)
      K.Takahashi, M.Nishikawa, Y.Hasegawa, S.Kume, H.Nishihara
    • Organizer
      The 60th Symposium on Coordination Chemistry of Japan
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2010-09-27
  • [Presentation] Electron Conduction through Molecular Wires Immobilized on the Electrode Surface2010

    • Author(s)
      H.Nishihara
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science NCSS2010
    • Place of Presentation
      Chiba, Japan Tokyo(招待講演)
    • Year and Date
      2010-09-21
  • [Presentation] Synthesis of nanoparticle network structures and their hydrogen storage properties2010

    • Author(s)
      Y.Yamamoto, Y.Yamanoi, H.Nishihara, A.Minoda, S.Oshima, Y.Kobori
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science NCSS2010
    • Place of Presentation
      Chiba, Japan Tokyo
    • Year and Date
      2010-09-20
  • [Presentation] メゾ位をジアリールアミノ基で置換したポリフィリンの電気化学・光化学特性2010

    • Author(s)
      和田晴美、日下心平、坂本良太、西原寛
    • Organizer
      2010年電気化学秋季大会
    • Place of Presentation
      神奈川
    • Year and Date
      2010-09-02
  • [Presentation] ヘテロレドックス分子ワイヤの電子移動特性2010

    • Author(s)
      西森慶彦、前田啓明、利光史行、坂本良太、西原寛
    • Organizer
      2010年電気化学秋季大会
    • Place of Presentation
      神奈川
    • Year and Date
      2010-09-02
  • [Presentation] 界面での配位プログラミングによる電子機能性分子ワイヤの創製2010

    • Author(s)
      西原寛
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      茨城(招待講演)
    • Year and Date
      2010-08-30
  • [Presentation] Coordination Programming of Electro-Functional Molecular Wires on the Surface2010

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      8th China-Japan Joint Symposium on Metal Cluster Compounds
    • Place of Presentation
      Xi'an, China(招待講演)
    • Year and Date
      2010-08-11
  • [Presentation] 配位子の反転による動的挙動を示す非対称ピリジルピリミジン-phen型銅錯体の発光特性2010

    • Author(s)
      西川道弘、久米晶子、西原寛
    • Organizer
      第22回配位化合物の光化学討論会
    • Place of Presentation
      富山
    • Year and Date
      2010-08-04
  • [Presentation] 刺激応答分子の創製とその精密配列による化学素子の開発2010

    • Author(s)
      西原寛
    • Organizer
      新学術領域研究「配位プログラミング-分子超構造体の科学と化学素子の創製」第3回全体会議
    • Place of Presentation
      東京
    • Year and Date
      2010-06-04
  • [Presentation] Surface Junction Effects on the Electron Conduction of Molecular Wires2010

    • Author(s)
      H.Nishihara, T.Kurita, Y.Nishimori, F.Toshimitsu, S.Muratsugu, S.Kume
    • Organizer
      The 7th Asian Conference on Electrochemistry 2010I
    • Place of Presentation
      Kumamoto, Japan(招待講演)
    • Year and Date
      2010-05-21
  • [Presentation] Double Protonation of a Donor(D)-Acceptor(A)-Donor(D) Molecule, 1,5-Bis(triarylaminoethynyl)anthraquinone to Form a Novel π-Conjugated Pentacyclic Compoumd2010

    • Author(s)
      Koya Prabhakara Rao, T.Kusamoto, S.Kume, H.Nishihara
    • Organizer
      The 7th Asian Conference on Electrochemistry 2010I
    • Place of Presentation
      Kumamoto, Japan
    • Year and Date
      2010-05-21
  • [Presentation] A New Special Pair Model Comprising meso-Di-p-anisylaminoporphyrin : Enhancement of Visible-Light Absorptivities and Quantification of Electronic Communication in the Mixed-Valent Cation2010

    • Author(s)
      R.Sakamoto, M.Nishikawa, S.Kume, T.Yamamura, H.Nishihara
    • Organizer
      The 7th Asian Conference on Electrochemistry 2010
    • Place of Presentation
      Kumamoto, Japan
    • Year and Date
      2010-05-21
  • [Presentation] Creation of Novel Molecular Families with Bridged Donors by Multiple Annulation of Ring-Fused Lactones2010

    • Author(s)
      M.Hayashi, F.Toshimitsu, E.Sakamoto, S.Kume, H.Nishihara
    • Organizer
      2010 Tsinghua University at the University of Tokyo Symposium on Frontier Chemistry II
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2010-05-13
  • [Presentation] Coordination Programming of Electro-functional Molecular Wires on the Surface2010

    • Author(s)
      H.Nishihara
    • Organizer
      2010 Tsinghua University at the University of Tokyo Symposium on Frontier Chemistry II
    • Place of Presentation
      Tokyo, Japan(招待講演)
    • Year and Date
      2010-05-13
  • [Remarks]

    • URL

      http://coord-prog.chem.nagoya-u.ac.jp/

  • [Remarks]

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/inorg/index.html

URL: 

Published: 2013-06-26  

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