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2007 Fiscal Year Annual Research Report

蒼族窒化物半導体の点欠陥と発光ダイナミックスの研究

Planned Research

Project AreaOptoelectronics Frontier by Nitride Semiconductor -Ultimate Utilization of Nitride Semiconductor Material Potential-
Project/Area Number 18069001
Research InstitutionUniversity of Tsukuba

Principal Investigator

上殿 明良  University of Tsukuba, 大学院・数理物質科学研究科, 准教授 (20213374)

Co-Investigator(Kenkyū-buntansha) 秩父 重英  東北大学, 多元物質科学研究所, 教授 (80266907)
押山 淳  東京大学, 工学部, 教授 (80143361)
白石 賢二  筑波大学, 大学院・数理物質科学研究科, 教授 (20334039)
KeywordsGaN / AIN / InN / 点欠陥 / 光学測定 / 第一原理計算 / 陽電子消滅
Research Abstract

陽電子消滅を用いることにより,半導体や金属等の空孔型欠陥を感度良く非破壊で検出・同定することができる.本年度は,陽電子消滅や光学特性,電気的特性を測定することにより,不純物をドープしたGaNおよびInN膜の点欠陥,またイオン注入により導入された不純物と空孔型欠陥の関係について調べた.RF-MBEにより成長したMgドープInNの評価を行った結果,Mg濃度が上昇しても,キャリア濃度(n型)は10^<18>-10^<19>cm^<-3>であり,かつ空孔[In空孔(V_<In>)およびその複合体]が導入されることがわかった.また,Siをドープした場合も空孔型欠陥が導入された.一方,GaNでは,フェルミレベル効果により,SiをドープするとV_<Ga>が導入されるが,Mgではその濃度は著しく減少する.InNでもフェルミレベル効果が有効であるとすると,Mgドーピングに伴い,何らかのn型不純物(酸素等)ないしは自己格子欠陥が導入され,空孔が導入されていると考えられる.MOCVD成長したundoped GaNへ室温でSi,O,Beイオンを注入することにより導入された欠陥とその焼鈍挙動を調べた.この結果,焼鈍前の主な欠陥は打ち込みイオン種によらずV_<Ga>ないしはV_<Ga>V_Nであり,焼鈍により,欠陥は表面方向へ移動しながら,クラスタリングしてゆくことがわかった.点欠陥の焼鈍特性には,打ち込み初期に導入された欠陥量が大きく影響を与える.ただし,酸素注入では,酸素がイオン注入により導入された点欠陥ないしは焼鈍中に形成された2次欠陥と相互作用することにより、酸素-空孔複合体を形成する.一方Beイオン注入では,質量が軽いことから導入される欠陥量は少なく、複合体形成の効果も抑えられるため,理想的な不純物種であることがわかった.

  • Research Products

    (27 results)

All 2008 2007 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (15 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Improvement of Al-polar AlN layer quality by three-stage flow-modulation metalorganic chemical vapor deposition2008

    • Author(s)
      M.Takeuchi
    • Journal Title

      Applied Physics Express 1

      Pages: 021102 1-3

    • Peer Reviewed
  • [Journal Article] Optical properties of nearly stacking-fault-free m-plane GaN homoepitaxial films grown by metalorganic vapor phase epitaxy on low defect density free-standing GaN substrates2008

    • Author(s)
      S.F.Chichibu
    • Journal Title

      Applied Physics Letters 92

      Pages: 091912 1-3

    • Peer Reviewed
  • [Journal Article] Origin of localized excitations in In-containing three-dimensional bulk (Al,In,Ga)N alloy films probed by time-resolved photoluminescence and monoenergetic positron annihilation Techniques2007

    • Author(s)
      S.F.Chichibu
    • Journal Title

      Philosophical Magazine 87

      Pages: 2019-2039

    • Peer Reviewed
  • [Journal Article] Annealing properties of vacancy-type defects in ion-implanted GaN studied by monoenergetic positron beams2007

    • Author(s)
      A.Uedono
    • Journal Title

      J. App. Phys. 102

      Pages: 084505(1-7)

    • Peer Reviewed
  • [Journal Article] Relation between Al vacancies and deep emission bands in AlN epitaxial films grown by Nh_3-source molecular beam epitaxy2007

    • Author(s)
      T.Koyama
    • Journal Title

      Appl. Phys. Lett 90

      Pages: 291914(1-3)

    • Peer Reviewed
  • [Journal Article] Atomic distribution in In_x Ga1-_xN single-quantum-wells studied by extended X-ray absorption fine structure2007

    • Author(s)
      T.Miyanaga
    • Journal Title

      Physical Review B 76

      Pages: 035314(1-5)

    • Peer Reviewed
  • [Journal Article] Radiative and nonradiative lifetimes in nonpolar m-plane In_x Ga1-_xN/GaN multiple quantum wells grown on GaN templates prepared by lateral epitaxial overgrowth2007

    • Author(s)
      T.Onuma
    • Journal Title

      Journal of Vacuum Science and Technology B 25

      Pages: 1524-1528

    • Peer Reviewed
  • [Journal Article] Quantum-confined Stark effects in the m-plane In0.15Ga0.85N/GaN multiple quantum well blue light-emitting diode fabricated on low defect density free-standing GaN substrate2007

    • Author(s)
      T. Onuuma
    • Journal Title

      Applied Physics Letters 91

      Pages: 181903 1-3

    • Peer Reviewed
  • [Journal Article] Impacts f dislocation bending and impurity incorporation on the local cathodoluminescence spectra of GaN grown by ammonotheramal method2007

    • Author(s)
      S.F.chichibu
    • Journal Title

      Applied Physics Letters 91

      Pages: 251911 1-3

    • Peer Reviewed
  • [Journal Article] Impact of strain on free-exciton resonamce energies in wurtzite AlN2007

    • Author(s)
      H.Ikeda
    • Journal Title

      Journal of Applied Physics 102

      Pages: 123707 1-5

    • Peer Reviewed
  • [Presentation] m面自立GaN基板上へのInGaN薄膜のMOVPE成長2008

    • Author(s)
      秩父重英
    • Organizer
      2008年春季応用物理学会
    • Place of Presentation
      千葉、日本
    • Year and Date
      2008-03-29
  • [Presentation] 低転位非極性m面InGaN/GaN多重量子井戸LDの光学利得2008

    • Author(s)
      尾沼猛儀
    • Organizer
      2008年春季応用物理学会
    • Place of Presentation
      千葉、日本
    • Year and Date
      2008-03-29
  • [Presentation] 塩基性鉱化剤を用いた安熱合成GaNエピタキシャル層の講造おおび発光特性2008

    • Author(s)
      秩父重英
    • Organizer
      2008年春季応用物理学会
    • Place of Presentation
      千葉、日本
    • Year and Date
      2008-03-27
  • [Presentation] 非極性m面InGaN量子井戸LEDの光学特性酸化亜鉛の相手を知るべく2007

    • Author(s)
      尾沼猛儀
    • Organizer
      平成19年度東北大学金属材料研究所ワークショップ「酸化亜鉛半導体テクノロジーの進歩」
    • Place of Presentation
      東北大学多元物質科学研究所
    • Year and Date
      2007-12-20
  • [Presentation] Correlation between the ciolet luminescence intensity and defect density in ALN epilayers grown by NH3 source molecular beam epitaxy2007

    • Author(s)
      S. F, Chichibu
    • Organizer
      The 34th International Symposium on Compound Semiconductors (ISCS 2007)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2007-11-17
  • [Presentation] Origin of edfect-insensitive emission probability in (Al, In, Ga)N alloy films containing In2007

    • Author(s)
      S. F, Chichibu
    • Organizer
      The 7th International Conference on Nitride Semiconductors (ICNS-7)
    • Place of Presentation
      Las Vegas, Necada, USA
    • Year and Date
      2007-09-20
  • [Presentation] Homoepitaxial growth of nearly stacking-fault-free m-plane (In, Ga)N films by metalorganic vapor phase using low defect density free-standing substrates2007

    • Author(s)
      S. F, Chichibu
    • Organizer
      The 7th International Conference on Nitride Semiconductors (ICNS-7)
    • Place of Presentation
      Las Vegas, Necada, USA
    • Year and Date
      2007-09-19
  • [Presentation] Quantum-confined Stark effects in nonpolar m-plane InxGa1-xN/GaN multiple quantum well light-emitting diodes fabricated on low defect density free-standing substrates2007

    • Author(s)
      T, Onuma
    • Organizer
      The 7th International Conference on Nitride Semiconductors (ICNS-7)
    • Place of Presentation
      Las Vegas, Necada, USA
    • Year and Date
      2007-09-18
  • [Presentation] Observation of well-resolved bound, free, and higher order excitons in AIN epilayers grown by metalorganic vapor phase epitaxy2007

    • Author(s)
      T, Onuma
    • Organizer
      The 7th International Conference on Nitride Semiconductors (ICNS-7)
    • Place of Presentation
      Las Vegas, Necada, USA
    • Year and Date
      2007-09-17
  • [Presentation] Correlation between the ciolet luminescence intensity and defect density in ALN epilayers grown by NH3 source molecular beam epitaxy2007

    • Author(s)
      T, Koyama
    • Organizer
      The 7th International Conference on Nitride Semiconductors (ICNS-7)
    • Place of Presentation
      Las Vegas, Necada, USA
    • Year and Date
      2007-09-17
  • [Presentation] 非極性InGaN量子井戸の空間分解CL評価2007

    • Author(s)
      秩父重英
    • Organizer
      第3回ナノマテリアル解析セミナー
    • Place of Presentation
      つくば国際会議場エポカル
    • Year and Date
      2007-09-14
  • [Presentation] AIN, GaNにおける貫通転位密度と点欠陥密度の関係2007

    • Author(s)
      秩父重英
    • Organizer
      2007年秋季応用物理学会
    • Place of Presentation
      北海道、日本
    • Year and Date
      2007-09-07
  • [Presentation] 陽電子消滅を用いた窒化物光半導体の空孔型欠陥の検出2007

    • Author(s)
      上殿明良・秩父重英
    • Organizer
      応用物理学会
    • Place of Presentation
      北海道工業大学
    • Year and Date
      2007-09-05
  • [Presentation] Correlation between Al cacancy concentration and intensities of deep cathodoluminescence bands in AIN epilayers grown by NH3-source molecular beam epitaxy2007

    • Author(s)
      S. F, Chichibu
    • Organizer
      26th Electronic Materials Symposium
    • Place of Presentation
      Shiga, Japan
    • Year and Date
      2007-07-06
  • [Presentation] Radiative and nonradiative processes in (Al, In, Ga)N alloy films2007

    • Author(s)
      S. F, Chichibu
    • Organizer
      14th Smiconducting and Insulating Materials Conference (SIMC-XIV)
    • Place of Presentation
      Fayetteville, Arkansas, USA
    • Year and Date
      2007-04-18
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/labo/chichibu/poster/poster.html

  • [Patent(Industrial Property Rights)] 紫外線窒化物半導体発光素子およびその製造方法2007

    • Inventor(s)
      秩父, 重英・尾沼, 猛儀・小山, 享宏・宗田, 孝之・池田, 大勝
    • Industrial Property Rights Holder
      東北大学・早稲田大学
    • Industrial Property Number
      2007-297191
    • Filing Date
      2007-11-15

URL: 

Published: 2010-02-04   Modified: 2016-04-21  

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