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2010 Fiscal Year Final Research Report

Fabrication of metal nanostructure for the enhancement of optical fields and their applications for the control of photochemical reactions

Planned Research

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Project AreaStrong Photons-Molecules Coupling Fields for Chemical Reactions
Project/Area Number 19049001
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionHokkaido University

Principal Investigator

MISAWA Hiroaki  北海道大学, 電子科学研究所, 教授 (30253230)

Co-Investigator(Kenkyū-buntansha) JUODKAZIS Saulius  北海道大学, 電子科学研究所, 准教授 (80332823)
UENO Kosei  北海道大学, 電子科学研究所, 准教授 (00431346)
Co-Investigator(Renkei-kenkyūsha) MURAZAWA Naoki  北海道大学, 電子科学研究所, 助教 (40455621)
Project Period (FY) 2007 – 2010
Keywords金属ナノ構造 / 局在表面プラズモン / フォトニック結晶 / レーザープロセッシング
Research Abstract

We proposed the concept of “effective utilization of photons” in photochemistry for an increase in excitation probability. Metallic nanostructures showing near-field enhancement effects induced by localized surface plasmon resonance, which act as photochemical reaction fields, are focused on. We have verified the two-photon photopolymerization of negative photoresists on the closely spaced gold nanoparticles irradiated by a weak incoherent light source. We also demonstrated an efficient plasmonic photoelectric conversion by visible to near-infrared light using electrodes, in which gold nanoblocks were elaborately arrayed on the surface of a TiO_2 single crystal.

  • Research Products

    (34 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (11 results) Book (5 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 2 results)

  • [Journal Article] Hybrid states dynamics of gold nanorods/dye J-aggregate under strong coupling2011

    • Author(s)
      Y.-W. Hao, H.-Y. Wang, Y. Jiang, Q.-D. Chen, K. Ueno, W.-Q. Wang, H. Misawa, H.-B. Sun
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 50 Pages: 1-6

    • Peer Reviewed
  • [Journal Article] Homogeneous nano-patterning using plasmon assisted photolithography2011

    • Author(s)
      K. Ueno, S. Takabatake, K. Onishi, H. Itoh, Y. Nishijima, H. Misawa
    • Journal Title

      Appl. Phys. Lett.

      Volume: 99 Pages: 011107

    • Peer Reviewed
  • [Journal Article] Spectral properties and mechanism of instability of nanoengineered silver blocks2011

    • Author(s)
      L. Wang, W. Xiong, Y. Nishijima, Y. Yokota, K. Ueno, H. Misawa, G. Bi, J.-r. Qiu
    • Journal Title

      Opt. Express

      Volume: 19 Pages: 10640-10646

    • Peer Reviewed
  • [Journal Article] Direct imaging of nanogap-mode plasmon-resonant fields2011

    • Author(s)
      Y. Tanaka, H. Ishiguro, H. Fujiwara, Y. Yokota, K. Ueno, H. Misawa, K. Sasaki
    • Journal Title

      Opt. Express

      Volume: 19 Pages: 7726-7733

    • Peer Reviewed
  • [Journal Article] Anomalous light transmission from plasmonic capped nano-aperture2011

    • Author(s)
      K. Imura, K. Ueno, H. Misawa, H. Okamoto
    • Journal Title

      Nano Lett.

      Volume: 11 Pages: 960-965

    • Peer Reviewed
  • [Journal Article] Plasmonic antenna effects on photochemical reactions2011

    • Author(s)
      S. Gao, K. Ueno, H. Misawa
    • Journal Title

      Accounts. Chem. Res.

      Volume: 44 Pages: 251-260

    • Peer Reviewed
  • [Journal Article] Essential Nanogap Effects on Surface-Enhanced Raman Scattering Signals from Closely Spaced Gold Nanoparticles2011

    • Author(s)
      Y. Yokota, K. Ueno, H. Misawa
    • Journal Title

      Chem. Commun.

      Volume: 45 Pages: 3505-3507

    • Peer Reviewed
  • [Journal Article] Highly Controlled Surface-Enhanced Raman Scattering Analysis Chips Using Nano-Engineered Gold Blocks2011

    • Author(s)
      Y. Yokota, K. Ueno, H. Misawa
    • Journal Title

      Small

      Volume: 7 Pages: 252-258

    • Peer Reviewed
  • [Journal Article] Plasmon-assisted photocurrent generation from visible to near-infrared wavelength using a Au-nanorods/TiO_2 electrode2010

    • Author(s)
      Y. Nishijima, K. Ueno, Y. Yokota, K. Murakoshi, H. Misawa
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 1 Pages: 2031-2036

    • Peer Reviewed
  • [Journal Article] Nanogap-assisted surface plasmon nanolithography2010

    • Author(s)
      K. Ueno, S. Takabatake, Y. Nishijima, V. Mizeikis, Y. Yokota, H. Misawa
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 1 Pages: 657-662

    • Peer Reviewed
  • [Journal Article] Nano-textured metallic surfaces for optical sensing and detection applications2009

    • Author(s)
      Y. Yokota, K. Ueno, S. Juodkazis, V. Mizeikis, N. Murazawa, H. Misawa, H. Kasa, K. Kintaka, J. Nishii
    • Journal Title

      J. Photochem. Photobio. A; Chem

      Volume: 207 Pages: 126-134

    • Peer Reviewed
  • [Journal Article] Near-IR vibrational dynamics of periodic gold single and pair nanocuboids2009

    • Author(s)
      L. Wang, Y. Nishijima, K. Ueno, H. Misawa, N. Tamai
    • Journal Title

      Appl. Phys. Lett.

      Volume: 95 Pages: 053116

    • Peer Reviewed
  • [Journal Article] Nanoparticle-enhanced photopolymerization2009

    • Author(s)
      K. Ueno, S. Juodkazis, T. Shibuya, V. Mizeikis, Y. Yokota, H. Misawa
    • Journal Title

      J. Phys. Chem. C

      Volume: 113 Pages: 11720-11724

    • Peer Reviewed
  • [Journal Article] Spatially selective non-linear photopolymerization induced by the near-field of surface plasmons localized on rectangular gold nanorods2009

    • Author(s)
      N. Murazawa, K. Ueno, V. Mizeikis, S. Juodkazis, H. Misawa
    • Journal Title

      J. Phys. Chem. C

      Volume: 113 Pages: 1147-1149

    • Peer Reviewed
  • [Journal Article] Nanoparticle plasmon-assisted two-photon polymerization induced by incoherent excitation source2008

    • Author(s)
      K. Ueno, S. Juodkazis, T. Shibuya, Y. Yokota, V. Mizeikis, K. Sasaki, H. Misawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 130 Pages: 6928-6929

    • Peer Reviewed
  • [Presentation] 金ナノ粒子/酸化チタン単結晶電極の光電変換特性2012

    • Author(s)
      石旭、上野貢生、三澤弘明
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2012-03-26
  • [Presentation] Surface plasmon-assisted nanolithography with nanometric accuracy2012

    • Author(s)
      K. Ueno
    • Organizer
      SPIE Photonic West 2012
    • Place of Presentation
      The Moscone Center
    • Year and Date
      2012-01-23
  • [Presentation] プラズモン局在光電場を用いた局所2光子光化学反応2011

    • Author(s)
      上野貢生、大西広、伊藤弘子、三澤弘明
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎観光ホテル
    • Year and Date
      2011-09-07
  • [Presentation] 金ナノ構造/酸化チタン電極を用いたプラズモン電荷分離に基づく水の酸化反応2011

    • Author(s)
      西島喜明、上野貢生、小竹勇己、村越敬、井上晴夫、三澤弘明
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎観光ホテル
    • Year and Date
      2011-09-06
  • [Presentation] Quantitative Analysis of Plasmon-Assisted Two-Photon Photochromic Reactions on Gold Nanoparticles2010

    • Author(s)
      K. Ueno, B. Wu, Y. Yokota, H. Misawa
    • Organizer
      6th Asian Photochemistry Conference 2010
    • Place of Presentation
      Wellington, New Zealand
    • Year and Date
      2010-11-17
  • [Presentation] プラズモン増強場における2光子フォトクロミック反応の定量測定2010

    • Author(s)
      上野貢生, 呉伯涛, 横田幸恵, 三澤弘明
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉大学
    • Year and Date
      2010-09-06
  • [Presentation] 制御されたナノギャップ金構造のプラズモン分光特性2010

    • Author(s)
      池谷伸太郎, 上野貢生, 村澤尚樹, 三澤弘明
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-27
  • [Presentation] 金属ナノ構造を用いた光局在場の創製と光化学反応への応用2010

    • Author(s)
      上野貢生
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学(招待講演)
    • Year and Date
      2010-03-18
  • [Presentation]2009

    • Author(s)
      池谷伸太郎, 上野貢生, 村澤尚樹, 西島喜明, 横田幸恵, ビガンタス ミゼイキス, サウリウス ヨードカジス, 三澤弘明
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-09
  • [Presentation] Electromagnetic field enhancement effects on nano-engineered gold particles2009

    • Author(s)
      K. Ueno, S. Juodkazis, V. Mizeikis, Y. Yokota, S. Takabatake, S. Ikegaya, H. Misawa
    • Organizer
      XXIV International Conference on Photochemistry ICP2009
    • Place of Presentation
      Toledo, Spain
    • Year and Date
      2009-07-21
  • [Presentation] Photochemical reactions on gold nanoparticles2009

    • Author(s)
      H. Misawa
    • Organizer
      215th ECS Meeting
    • Place of Presentation
      San Francisco Hilton
    • Year and Date
      2009-05-25
  • [Book] Strong photon-molecule coupling fields for chemical reactions, 392011

    • Author(s)
      K. Ueno, H. Misawa
    • Total Pages
      228-255
    • Publisher
      Photochemistry
  • [Book] 高効率な二光子励起を可能にする反応場の設計と作製,高効率二光子吸収材料の開発と応用(監修 渡辺敏行)2011

    • Author(s)
      上野貢生,三澤弘明(分担執筆)
    • Total Pages
      117-127
    • Publisher
      シーエムシー出版
  • [Book] 光アンテナ搭載光電変換を利用した高効率太陽電池の開発,プラズモニクスデバイス開発最前線2011

    • Author(s)
      三澤弘明,上野貢生(分担執筆)
    • Total Pages
      237-246
    • Publisher
      エヌ・ティー・エス
  • [Book] Molecular Electronic and Related Materials-Control and Probe with Ligh2010

    • Author(s)
      K. Ueno, S. Juodkazis, V. Mizeikis, H. Misawa
    • Total Pages
      261-280
    • Publisher
      Transworld Research Network
  • [Book] プラズモンナノ材料の最新技術2009

    • Author(s)
      上野貢生,,三澤弘明
    • Total Pages
      138-145
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://photomolecule.net/

  • [Patent(Industrial Property Rights)] フォトレジストパターンの作製方法2011

    • Inventor(s)
      上野貢生、三澤弘明
    • Industrial Property Rights Holder
      北海道大学
    • Industrial Property Number
      特許, PCT/JP2011/001192
    • Filing Date
      2011-03-01
    • Overseas
  • [Patent(Industrial Property Rights)] 光電変換装置、光検出装置、及び光検出方法2010

    • Inventor(s)
      三澤弘明、西島喜明、上野貢生、村越敬
    • Industrial Property Rights Holder
      北海道大学
    • Industrial Property Number
      特許, PCT/JP2010/065052
    • Filing Date
      2010-09-02
    • Overseas

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Published: 2013-07-31  

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