Mechanical function of photochromic surfaces

2010 Fiscal Year Final Research Report

• Project Area: New Horizons of Photochromism: Customized Molecular Design and Novel Applications
• Project/Area Number: 19050007
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Osaka Kyoiku University
• Principal Investigator: TSUJIOKA Tsuyoshi Osaka Kyoiku University, 教育学部, 教授 (30346225)
• Project Period (FY): 2007 – 2010
• Keywords: フォトクロミズム / メタル / 真空蒸着

Research Abstract

Selective metal deposition on an amorphous photochromic diarylethene surface was studied. Metals including Mg, Mn and Zn were deposited selectively on the surface depending on the isomerization state. A diarylethene crystal surface also showed selective Mg deposition. This originates in the softened effect of the crystal surface via UV irradiation. The metal undeposition effect for a variety of metals was observed on soft polymer surfaces.

Research Products

• [Journal Article] Selective metal deposition on photosensitive organic crystal surfaces (2011)
  • Author(s): T.Tsujioka
  • Journal Title: Journal of Materials Chemistry DOI:10.1039/C1JM11593F(in press)
  • Peer Reviewed
• [Journal Article] Metal deposition selectivity based on photochromism of a diarylethene film in an intermediate vacuum (2011)
  • Author(s): Y.Iwai, T.Tsujioka
  • Journal Title: Japanese Journal of Applied Physics in press
  • Peer Reviewed
• [Journal Article] Light-controlled metal deposition on photochromic polymer films (2010)
  • Author(s): T.Tsujioka, R.Takagi, T.Shiozawa
  • Journal Title: Journal of Materials Chemistry 20 Pages: 9623-9627
  • Peer Reviewed
• [Journal Article] Photocurrent detection method based on photoisomerization of a diarylethene layer for nondestructive readout of photochromic optical memory (2010)
  • Author(s): T.Tsujioka, I.Onishi, D.Natsume
  • Journal Title: Applied Optics 49 Pages: 3894-3899
  • Peer Reviewed
• [Journal Article] Light-controlled Selective Metal Deposition on a Photochromic Diarylethene Film -Toward New Applications in Electronics and Photonics (2010)
  • Author(s): Y.Sesumi, S.Yokojima, S.Nakamura, K.Uchida, T.Tsujioka
  • Journal Title: Bulletin of the Chemical Society of Japan(BCSJ award article) 83 Pages: 756-761
  • Peer Reviewed
• [Journal Article] Electrical functions of photochromic molecules, Journal of Photochemictry and Photobiology (2010)
  • Author(s): T.Tsujioka, M.Irie
  • Journal Title: C : Photochemistry Reviews 11 Pages: 1-14
  • Peer Reviewed
• [Journal Article] Efficient carrier separation from a photochromic diarylethene layer (2010)
  • Author(s): T.Tsujioka, M.Yamamoto, K.Shoji, K.Tani
  • Journal Title: Photochemical & Photobiological Sciences 9 Pages: 157-161
  • Peer Reviewed
• [Journal Article] Selective metal deposition for a structure with a thin intermediate layer on a photochromic diarylethene film (2009)
  • Author(s): K.Masui, R.Takagi, Y.Sesumi, S.Nakamura, T.Tsujioka
  • Journal Title: Journal of Materials Chemistry 19(20) Pages: 3176-3180
  • Peer Reviewed
• [Journal Article] Metal atom behavior on photochromic diarylethene surfaces-deposition rate dependence of selective Mg deposition (2009)
  • Author(s): T.Tsujioka, Y.Sesumi, S.Yokojima, S.Nakamura, K.Uchida
  • Journal Title: New Journal of Chemistry 33(6) Pages: 1335-1338
  • Peer Reviewed
• [Journal Article] Light-controlled selective metal deposition on photopolymer films (2009)
  • Author(s): T.Tsujioka, A.Matsui
  • Journal Title: Applied Physics Letters 94 Pages: 013302-1-3
  • Peer Reviewed
• [Journal Article] Metal patterning using maskless vacuum evaporation process based on selective deposition of photochromic diarylethene (2008)
  • Author(s): R.Takagi, K.Masui, S.Nakamura T.Tsujioka
  • Journal Title: Applied Physics Letters 93 Pages: 213304-1-3
  • Peer Reviewed
• [Journal Article] Selective Metal Deposition on Photo-switchable Molecular Surfaces (2008)
  • Author(s): T.Tsujioka, Y.Sesumi, R.Takagi, K.Masui, S.Yokojima, K.Uchida, S.Nakamura
  • Journal Title: Journal of American Chemical Society 130 Pages: 10740-10747
  • Peer Reviewed
• [Journal Article] Theoretical investigation on photochromic diarylethene : A short review (2008)
  • Author(s): S.Nakamura, S.Yokojima, K.Uchida, T.Tsujioka, A.Goldberg, A.Murakami, K.Shinoda, M.Mikami, T.Kobayashi, S.Kobatake, K.Matsuda, M.Irie
  • Journal Title: Journal of Photochemistry and Photobiology A 200 Pages: 10-18
  • Peer Reviewed
• [Presentation] Organic semiconductor memory using ring-closure reaction of diarylthene molecules by electrical carrier injection (2010)
  • Author(s): T.Tsujioka, T.Sasa, Y.Kakihara
  • Organizer: Third Japanese-French Joint Seminar on Organic Photochromism
  • Place of Presentation: 神奈川
  • Year and Date: 2010-10-21
• [Presentation] Light-controlled metal deposition using photochromic diarylethenes (2010)
  • Author(s): T.Tsujioka
  • Organizer: 6th Inthernational Symposium on Organic Photochromism
  • Place of Presentation: 神奈川
  • Year and Date: 2010-10-20
• [Presentation] Fine Pattern Preparation for Various Metals by using Selective Deposition on Photochromic Surfaces (2009)
  • Author(s): Y.Sesumi, S.Yokojima, K.Uchida, S.Nakamura, T.Tsujioka
  • Organizer: International Conference on Solid State Devices and Materials(SSDM2009)
  • Place of Presentation: 仙台
  • Year and Date: 2009-10-08
• [Presentation] Efficient Carrier Separation from Photochromic Memory (2009)
  • Author(s): T.Tsujioka, M.Yamamoto, K.Shoji, K.Tani
  • Organizer: International Symposium on Optical Memory
  • Place of Presentation: 長崎
  • Year and Date: 2009-10-06
• [Presentation] Light-controlled metal deposition on photochromic diarylethene doped polymers (2009)
  • Author(s): T.Tsujioka, R.Takagi, T.Shiozawa
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics (KJF-ICOMEP)
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2009-08-24
• [Presentation] Mg atom behavior at the deposition threshold for film formation on photochromic diarylethene films (2009)
  • Author(s): Y.Sesumi, S.Yokojima, S.Nakamura, K.Uchida, T.Tsujioka
  • Organizer: The 4th East Asia Symposium on Functional Dyes and Advanced Materials (EAS4)
  • Place of Presentation: 大阪
  • Year and Date: 2009-06-05
• [Book] 「次世代光メモリとシステム技術」第6章 1 「フォトクロミック分子の電子機能と関連メモリ技術」 (2009)
  • Author(s): 辻岡強(分担執筆)
  • Total Pages: 249
  • Publisher: (株)シーエムシー出版
• [Book] 第7章光ディスク 第一節「フォトクロミック分子を用いた高密度メモリ」(「最新 機能性色素大全集」) (2007)
  • Author(s): 辻岡強(分担執筆)
  • Total Pages: 207
  • Publisher: (株)技術情報協会
• [Remarks] ホームページ等
• [Remarks] 大阪教育大学リポジトリ
  • URL: http://ir.lib.osaka-kyoiku.ac.jp:8080/dspace/handle/123456789/2549
• [Remarks]
  • URL: http://ir.lib.osaka-kyoiku.ac.jp:8080/dspace/handle/123456789/2178
• [Remarks]
  • URL: http://ir.lib.osaka-kyoiku.ac.jp:8080/dspace/handle/123456789/2179
• [Remarks]
  • URL: http://ir.lib.osaka-kyoiku.ac.jp:8080/dspace/handle/123456789/2180
• [Patent(Industrial Property Rights)] 金属膜のパターン形成方法及び部材 (2009)
  • Inventor(s): 野殿光史、下中綾子、新納洋、辻岡強
  • Industrial Property Rights Holder: 三菱レイヨン株式会社
  • Industrial Property Number: 特許権,特願2009-272494
  • Filing Date: 2009-11-30
• [Patent(Industrial Property Rights)] 蒸着装置、及び金属蒸着物の製造方法 (2008)
  • Inventor(s): 中村振一郎、辻岡強
  • Industrial Property Rights Holder: 三菱化学株式会社
  • Industrial Property Number: 特許権,特願2008-076399
  • Filing Date: 2008-03-24