Construction of avalanche photochromic system

2010 Fiscal Year Final Research Report

• Project Area: New Horizons of Photochromism: Customized Molecular Design and Novel Applications
• Project/Area Number: 19050009
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyoto University (2008-2010); Kyushu University (2007)
• Principal Investigator: MATSUDA Kenji Kyoto University, 大学院・工学研究科, 教授 (80262145)
• Co-Investigator(Kenkyū-buntansha): FUKAMINATO Tuyoshi 九州大学, 大学院・工学研究院, 助教 (80380583) ; HASEGAWA Jun-ya 京都大学, 大学院・工学研究科, 講師 (30322168) ; HIGASHIGUCHI Kenji 京都大学, 大学院・工学研究科, 助教 (90376583)
• Project Period (FY): 2007 – 2010
• Keywords: ナノ材料 / 複合材料・物性 / 光物性 / 光スイッチ

Research Abstract

A diarylethene-pyrene-diarylethene triad were synthesized to investigate the photoinduced two-dimensional ordering change at a solution-HOPG interface. A new ordering appeared upon irradiation with UV light and returned to the original ordering upon subsequent irradiation with visible light. The new arrangement was assigned to the ordering of the closed-closed isomers.

Research Products

• [Journal Article] Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the SolidState (2011)
  • Author(s): T.Hirose, K.Higashiguchi, K.Matsuda
  • Journal Title: Chem.Asian J. 6 Pages: 1057-1063
  • Peer Reviewed
• [Journal Article] π-Conjugation of Two Nitronyl Nitroxides-Attached Diarylethenes (2011)
  • Author(s): S.Yokojima, T.Kobayashi, K.Shinoda, K.Matsuda, K.Higashiguchi, S.Nakamura
  • Journal Title: J.Phys.Chem.B 115 Pages: 5685-5692
  • Peer Reviewed
• [Journal Article] Theoretical Investigation on the Origin of the CD Signal Reversal for the Closed-ring Isomer of Diarylethene with Peripherical π-Conjugated Substituents (2010)
  • Author(s): T.Hirose, J.-y.Hasegawa, K.Matsuda
  • Journal Title: Chem.Lett. 39 Pages: 516-517
  • Peer Reviewed
• [Journal Article] Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains : Core-Chain Ratio Dependence on Supramolecular Structures (2009)
  • Author(s): T.Hirose, M.Irie, K.Matsuda
  • Journal Title: Chem.Asian J. 4 Pages: 58-66
  • Peer Reviewed
• [Journal Article] The Photochromic and Self-Assembling Properties of Diarylethenes Having Chiral Amphiphilic Chains at the Reactive Carbon Atoms (2009)
  • Author(s): T.Hirose, M.Irie, K.Matsuda
  • Journal Title: New J.Chem. 33 Pages: 1332-1334
  • Peer Reviewed
• [Journal Article] Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission : Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment (2009)
  • Author(s): T.Hirose, K.Matsuda
  • Journal Title: Chem.Commun. Pages: 5832-5834
  • Peer Reviewed
• [Journal Article] Control of the Photoreactivity of Diarylethene Derivatives by Quaternarization of the Pyridylethynyl Group (2008)
  • Author(s): K.Yumoto, M.Irie, K.Matsuda
  • Journal Title: Org.Lett. 10 Pages: 2051-2054
  • Peer Reviewed
• [Journal Article] Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution-HOPG Interface (2008)
  • Author(s): R.Arai, S.Uemura, M.Irie, K.Matsuda
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 9371-9379
  • Peer Reviewed
• [Journal Article] Temperature-Light Dual Control of Clouding Behavior of an Oligo(ethyleneglycol)-Diarylethene Hybrid System (2008)
  • Author(s): T.Hirose, M.Irie, K.Matsuda
  • Journal Title: Adv.Mater. 20 Pages: 2137-2141
  • Peer Reviewed
• [Journal Article] Photoswitching of Solvatochromism Using Diarylethenes with 2,5-Disubstituted3-Thienyl Unit (2007)
  • Author(s): N.Tanifuji, M.Irie, K.Matsuda
  • Journal Title: Chem.Lett. 36 Pages: 1232-1233
  • Peer Reviewed
• [Presentation] Self-Assembly and Photochromic Behavior of Diarylethenes Carrying Amphiphilic Side Chain (2010)
  • Author(s): K.Matsuda, T.Hirose
  • Organizer: 6th International Symposium on Organic Photochromism
  • Place of Presentation: Yokohama, Japan
  • Year and Date: 2010-10-19
• [Presentation] Photochromic Molecules for Switching Units (2009)
  • Author(s): K.Matsuda
  • Organizer: The 4th International Symposium on Atomic Technologies
  • Place of Presentation: Kobe, Japan
  • Year and Date: 2009-11-19
• [Presentation] Photoswitching of Diarylethene for Nanoscience (2009)
  • Author(s): K.Matsuda
  • Organizer: International Workshop on Organic Photoswitchable Multifunctional Materials
  • Place of Presentation: Shanghai, China
  • Year and Date: 2009-10-25
• [Presentation] Photochromic Molecule as an Information Processing Unit in Molecular Optoelectronics (2007)
  • Author(s): K.Matsuda
  • Organizer: 2007Korea-Japan Symposium on Frontier Photoscience Gyeongju
  • Place of Presentation: Korea
  • Year and Date: 2007-11-25
• [Book] 水中で組織化する両親媒性ジアリールエテンによる光誘起超分子環境変化とLCST転移挙動 (2008)
  • Author(s): 廣瀬崇至、松田建児
  • Total Pages: 39,113-117
  • Publisher: 光化学
• [Book] フォトクロミックメモリ 有機半導体デバイス
  • Author(s): 松田建児
  • Total Pages: 363-367
  • Publisher: オーム社