Superhydrophobic and Superhydrophilic Surfaces Induced by Photoirradiation

2010 Fiscal Year Final Research Report

• Project Area: New Horizons of Photochromism: Customized Molecular Design and Novel Applications
• Project/Area Number: 19050012
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Ryukoku University
• Principal Investigator: UCHIDA Kingo Ryukoku University, 理工学部, 教授 (70213436)
• Project Period (FY): 2007 – 2010
• Keywords: フォトクロミズム / ジアリールエテン / 表面形状変化 / 超撥水性 / 超親水性

Research Abstract

By alternate irradiation with UV and visible light, reversible formation of micrometer sized crystals with different shapes corresponding to open-and closed-ring isomers of photochromic diarylethenes was observed accompanied with superhydrophobic and superhydrophilic property of the surface. Controlling the temperature after UV irradiation enabled the size-control of the crystals, and photo-control of lotus and petal effects of wetting was performed.

Research Products

• [Journal Article] Photoinduced Reversible Topographical Changes on Diarylethene Microcrystalline Surface with Bio-mimetic Wetting Properties (2011)
  • Author(s): N.Nishikawa, A.Uyama, T.Kamitanaka, H.Mayama, Y.Kojima, S.Yokojima, S.Nakamura, K.Tsujii, K.Uchida
  • Journal Title: Chem.Asian J. Vol.6,in press
  • Peer Reviewed
• [Journal Article] Reversible Photocontrol of Surface Wettability between Hydrophilic and Superhydrophobic Surfaces on an Asymmetric Diarylethene Solid Surface (2011)
  • Author(s): A.Uyama, S.Yamazoe, S.Shigematsu, M.Morimoto, S.Yokojima, H.Mayama, Y.Kojima, S.Nakamura, K.Uchida
  • Journal Title: Langmuir Vol.27, No.10 Pages: 6395-6400
  • Peer Reviewed
• [Journal Article] One-Color Reversible Control of Photochromic Reactions in a Diarylethene Derivative : Three-photon Cyclization and Two-photon Cycloreversion by Near IR Femtosecond Laser Pulse at 1.28 μm (2011)
  • Author(s): K.Mori, Y.Ishibashi, H.Matsuda, S.Ito, Y.Nagasawa, H.Nakagawa, K.Uchida, S.Yokojima, S.Nakamura, M.Irie, H.Miyasaka
  • Journal Title: J.Am.Chem.Soc. Vol.133, No.8 Pages: 2621-2625
  • Peer Reviewed
• [Journal Article] Phototunable Diarylethene Microcrystalline Surfaces : Lotus and Petal Effects upon Wetting (2010)
  • Author(s): K.Uchida, N.Nishikawa, N.Izumi, S.Yamazoe, H.Mayama, Y.Kojima, S.Yokojima, S.Nakamura, K.Tsujii, M.Irie
  • Journal Title: Angew.Chem., Int.Ed. Vol.49, No.34 Pages: 5942-5944
  • Peer Reviewed
• [Journal Article] Light-controlled Selective Metal Deposition on a Photochromic Diarylethene Film-Toward New Applications in Electronics and Photonics (2010)
  • Author(s): Y.Sesumi, S.Yokojima, S.Nakamura, K.Uchida, T.Tsujioka
  • Journal Title: Bull.Chem.Soc.Jpn.(Selected as "BCSJ Award Article") Vol.83, No.7 Pages: 756-761
  • Peer Reviewed
• [Journal Article] Unusual Photochromic Behavior of C3-Methoxy-Substituted Bis(2-thienyl)-perfluorocyclopentene (2009)
  • Author(s): K.Uchida, H.Sumino, Y.Shimobayashi, Y.Ushiogi, A.Takata, Y.Kojima, S.Yokojima, S.Kobatake, S.Nakamura
  • Journal Title: Bull.Chem.Soc.Jpn. Vol.82, No.11 Pages: 1441-1446
  • Peer Reviewed
• [Journal Article] Photoisomerization of Azobenzene Gel by Pulsed Laser Irradiation (2009)
  • Author(s): K.Uchida, S.Yamaguchi, H.Yamada, M.Akazawa, T.Katayama, Y.Ishibashi, H.Miyasaka
  • Journal Title: Chem.Commun. No.29 Pages: 4420-4422
  • Peer Reviewed
• [Journal Article] Photo-induced Reversible Topographical Changes of Photochromic Diarylethene Microcrystalline Surfaces (2009)
  • Author(s): N.Izumi, N.Nishikawa, S.Yokojima, Y.Kojima, S.Nakamura, S.Kobatake, M.Irie, K.Uchida
  • Journal Title: New J.Chem. Vol.33, No.6 Pages: 1324-1326
  • Peer Reviewed
• [Journal Article] Metal Atom Behavior on Photochromic Diarylethene Surfaces-Deposition Rate Dependence of Selective Mg Deposition (2009)
  • Author(s): T.Tsujioka, Y.Sesumi, S.Yokojima, S.Nakamura, K.Uchida
  • Journal Title: New J.Chem. Vol.33, No.6 Pages: 1335-1338
  • Peer Reviewed
• [Journal Article] Dynamic Chirality, Chirality Transfer and Aggregation Behavior of Dithienylethene Switches (2008)
  • Author(s): J.J.D.de Jong, P.van Rijn, T.D.Tiemersma-Wegeman, L.N.Lucas, W.R.Browne, R.M.Kellogg, K.Uchida, J.H.vanEsch, B.L.Feringa
  • Journal Title: Tetrahedron Vol.64, No.36 Pages: 8324-8335
  • Peer Reviewed
• [Journal Article] Theoretical Investigation on Photochromic Diarylethene; A Short Review (2008)
  • Author(s): S.Nakamura, S.Yokojima, K.Uchida, T.Tsujioka, A.Goldberg, A.Murakami, K.Shinoda, M.Mikami, T.Kobayashi, S.Kobatake, K.Matsuda, M.Irie
  • Journal Title: J.Photochem. Photobiol.A., Chem. Vol.200 Pages: 10-18
  • Peer Reviewed
• [Journal Article] Selective Metal Deposition on Photoswitchable Molecular Surfaces (2008)
  • Author(s): T.Tsujioka, Y.Sesumi, R.Takagi, K.Masui, S.Yokojima, K.Uchida, S.Nakamura
  • Journal Title: J.Am.Chem.Soc. Vol.130, No.32 Pages: 10740-10747
  • Peer Reviewed
• [Journal Article] Super Water-Repellent Fractal Surfaces of a Photochromic Diarylethene Induced by UV Light (2008)
  • Author(s): N.Izumi, T.Minami, H.Mayama, A.Takata, S.Nakamura, S.Yokojima, K.Tsujii, K.Uchida
  • Journal Title: Jpn.J.Appl.Phys. Vol.47, No.9 Pages: 7298-7302
  • Peer Reviewed
• [Journal Article] Photochromic Properties of Diarylethene Derivatives Having Benzofuran and Benzothiophene Rings Based on Regioisomers (2008)
  • Author(s): T.Yamaguchi, K.Uchida, M.Irie
  • Journal Title: Bull.Chem.Soc.Jpn. Vol.81, No.5 Pages: 644-652
  • Peer Reviewed
• [Journal Article] Photoresponsive Dithienylethene-urea Based Organogels with"Reversed" Behavior (2008)
  • Author(s): M.Akazawa, K.Uchida, J.J.D.de Jong, J.Areephong, M.Stuart, G.Caroli, W.R.Browne, B.L.Feringa
  • Journal Title: Org.Biomol.Chem. Vol.6, No.9 Pages: 1544-1547
  • Peer Reviewed
• [Journal Article] Photoresponsive Rolling and Bending of Thin Crystals of Chiral Diarylethenes (2008)
  • Author(s): K.Uchida, S.Sukata, Y.Matsuzawa, M.Akazawa, J.J.D.de Jong, N.Katsonis, Y.Kojima, S.Nakamura, J.Areephong, A.Meetsma, B.L.Feringa
  • Journal Title: Chem.Commun.(Selected as"Hot Article") No.3 Pages: 326-328
  • Peer Reviewed
• [Journal Article] Photochromism of 1,2-Bis(3-n-alkyl-1-benzothiophen-2-yl)perfluorocyclopentene Derivatives (2007)
  • Author(s): T.Yamaguchi, K.Uchida, M.Irie
  • Journal Title: Mol.Cryst.Liq.Cryst. Vol.474 Pages: 111-118
  • Peer Reviewed
• [Journal Article] Quantum Yields and Potential Energy Surfaces : a Theoretical Study (2007)
  • Author(s): S.Nakamura, T.Kobayashi, A.Takata, K.Uchida, Y.Asano, A.Murakami, A.Goldberg, D.Guillaumont, S.Yokojima, S.Kobatake, M.Irie
  • Journal Title: J.Phys.Org.Chem. Vol.20, No.11 Pages: 821-829
  • Peer Reviewed
• [Journal Article] (2007)
  • Author(s): A.Takata, S.Yokojima, H.Nakagawa, Y.Matsuzawa, A.Murakami, S.Nakamura, M.Irie, K.Uchida
  • Journal Title: J.Phys.Org.Chem. Vol.20, No.11 Pages: 998-1006
  • Peer Reviewed
• [Presentation] Photoisomerization of an Azobenzene Gel by Pulsed Lase Irradiation (2011)
  • Author(s): S.Sakiyama (K.Uchida)
  • Organizer: ChemComm International Symposium in Kyoto
  • Place of Presentation: 京都市、京都大学
  • Year and Date: 2011-05-16
• [Presentation] Photoinduced Isothermal Phase Changes of Triphenylene Derivatives Having Six Azobenzene Mesogens (2011)
  • Author(s): D.Tanaka (K.Uchida)
  • Organizer: ChemComm International Symposium in Kyoto
  • Place of Presentation: 京都市、京都大学
  • Year and Date: 2011-05-16
• [Presentation] Photoresponsive Bending of Thin Crystals of Chiral Diarylethenes (2011)
  • Author(s): A.Uyama (K.Uchida)
  • Organizer: ChemComm International Symposium in Kyoto
  • Place of Presentation: 京都市、京都大学
  • Year and Date: 2011-05-16
• [Presentation] Photo-induced Isothermal Phase Changes of Star-Shaped Azobenzenoid Triphenylenes between Col_h and SmA LC Phases (2010)
  • Author(s): K.Uchida
  • Organizer: 3rd Japanese-French Joint Seminar on Organic Photochromism
  • Place of Presentation: 横浜市、Nisseki Yokohama Hall
  • Year and Date: 2010-10-21
• [Presentation] Phototunable Diarylethene Microcrystalline Surfaces : Lotus and Petal Effects upon Wetting (2010)
  • Author(s): K.Uchida
  • Organizer: 6th International Symposium on Organic Photochromism
  • Place of Presentation: 横浜市、Nisseki Yokohama Hall
  • Year and Date: 2010-10-20
• [Presentation] Calamitic and Discotic Mesophases Formed by Kinetically Controlled Rod-Disc Alternation of Molecular Shape (2010)
  • Author(s): D.Tanaka (K.Uchida)
  • Organizer: 6th International Symposium on Organic Photochromism
  • Place of Presentation: 横浜市、Nisseki Yokohama Hall
  • Year and Date: 2010-10-18
• [Presentation] Photo-induced Reversible Topographical Changes on Diarylethene Microcrystalline Surfaces Showing Lotus and Petal Effects upon Wetting (2010)
  • Author(s): K.Uchida
  • Organizer: The 27th European Conference on Surface Science
  • Place of Presentation: オランダ王国、Groningen市
  • Year and Date: 2010-09-02
• [Presentation] Reversible Topographical Changes on Microcrystalline Surface of 1,2-Bis(2-methyl-5-phenyl thien-3-yl)perfluorocyclopentene by Alternate UV and Visible Light Irradiation (2010)
  • Author(s): A.Uyama (K.Uchida)
  • Organizer: The 27th European Conference on Surface Science
  • Place of Presentation: オランダ王国、Groningen 市
  • Year and Date: 2010-09-01
• [Presentation] Photoisomerization of Azobenzene Gel by Pulsed Laser Irradiation (2010)
  • Author(s): K.Uchida
  • Organizer: XXIII IUPAC Symposium on Photochemistry
  • Place of Presentation: イタリア、Ferrara 市
  • Year and Date: 2010-07-14
• [Presentation] Different Photochromic Property in Two types of Diarylethenes (2009)
  • Author(s): K.Uchida
  • Organizer: IKCOC-11(The Eleventh International Kyoto Conference on New Aspects of Organic Chemistry)
  • Place of Presentation: 京都市、Rihga Royal Hotel Kyoto
  • Year and Date: 2009-11-11
• [Presentation] 光により有機される超撥水性・超親水性表面、フォトクロミズムの攻究とメカニカル機能の創出 (2009)
  • Author(s): 内田欣吾
  • Organizer: 第4回公開シンポジウム(依頼公演)
  • Place of Presentation: 北海道札幌市、北海道大学
  • Year and Date: 2009-09-01
• [Presentation] Photo-induced Reversible Topographical Changes of Photochromic Diarylethene Microcrystalline Surface, New Horizons of Photochromism. (2008)
  • Author(s): K.Uchida
  • Organizer: From Design of Molecules to Applications.
  • Place of Presentation: フランス、Arras 市
  • Year and Date: 2008-10-13
• [Presentation] Photo-responsive Bending of Tiny Crystals of Diarylethenes with Hydrogen Bonding Networks, Fπ8 (2008)
  • Author(s): Y.Matsuzawa (K.Uchida)
  • Organizer: the 8th International Symposium on Functional π-Electron Systems
  • Place of Presentation: オーストリア、Graz 市、Graz University of Technology
  • Year and Date: 2008-07-23
• [Presentation] Vapor Deposited Crystalline Patterning of Diarylethenes on Some Substrates, Fπ8 (2008)
  • Author(s): Y.Chaki (K.Uchida)
  • Organizer: the 8th International Symposium on Functional π-Electron Systems
  • Place of Presentation: オーストリア、Graz 市、Graz University of Technology
  • Year and Date: 2008-07-23
• [Presentation] Photoinduced Reversible Surface Morphology Changes of Photochromic Diarylethene Coating Films, Fπ8 (2008)
  • Author(s): K.Uchida
  • Organizer: the 8th International Symposium on Functional π-Electron Systems
  • Place of Presentation: オーストリア、Graz 市、Graz University of Technology
  • Year and Date: 2008-07-22
• [Presentation] Photoresponsive Rolling and Bending of Thin Crystals of Chiral Diarylethenes (2008)
  • Author(s): K.Uchida
  • Organizer: Fifth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
  • Place of Presentation: 滋賀県草津市、立命館大学
  • Year and Date: 2008-06-10
• [Presentation] Photoresponsive Dithienylethene-urea-based Organogels with Reversed Behavior (2008)
  • Author(s): M.Akazawa (K.Uchida)
  • Organizer: Fifth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
  • Place of Presentation: 滋賀県草津市、立命館大学
  • Year and Date: 2008-06-10
• [Presentation] Photoinduced Morphology Changes of Diarylethene Thin Film Surfaces (2007)
  • Author(s): K.Uchida
  • Organizer: International Symposium on Photochromism(ISOP-07)
  • Place of Presentation: カナダVancouver 市
  • Year and Date: 2007-10-08
• [Presentation] Photo-induced Phase Changes of Triphenylene Derivatives Connected Azobenzene Mesogens and Triphenylene Core by Ether Linkage (2007)
  • Author(s): H.Ishiguro (K.Uchida)
  • Organizer: International Symposium on Photochromism(ISOP-07)
  • Place of Presentation: カナダVancouver 市
  • Year and Date: 2007-10-07
• [Presentation] Photochromism of Vapor Deposited Crystalline Film of Diarylethenes having Chiral Substituents (2007)
  • Author(s): Y.Matsuzawa (K.Uchida)
  • Organizer: International Symposium on Photochromism(ISOP-07)
  • Place of Presentation: カナダVancouver 市
  • Year and Date: 2007-10-07
• [Book] 光機能性高分子材料の新たな潮流-最新技術とその展望- (2008)
  • Author(s): 内田欣吾(市村國宏)
  • Total Pages: 357(85-96)
  • Publisher: シーエムシー出版
• [Remarks] ホームページ等
  • URL: http://www.chem.ryukoku.ac.jp/uchida/index.html