• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2011 Fiscal Year Final Research Report

Search for novel mesoporous materials

Planned Research

  • PDF
Project AreaNew Materials Science Using Regulated Nano Spaces -Strategy in Ubiquitous Elements
Project/Area Number 19051013
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionWaseda University

Principal Investigator

KURODA Kazuyuki  早稲田大学, 理工学術院, 教授 (90130872)

Co-Investigator(Kenkyū-buntansha) MOCHIZUKI Dai  東京工業大学, 大学院・理工学研究科, 助教 (90434315)
Project Period (FY) 2007 – 2011
Keywordsメソ多孔体 / ユビキタス元素 / ナノ空間 / 自己組織化 / 層状ケイ酸塩 / 無機有機ハイブリッド
Research Abstract

Various nanospace materials have been synthesized by using cage-like polyhedral oligomeric siloxanes as starting materials. This synthesis method is a new guideline for precise design for nanospace materials. The materials derived from polyhedral oligomeric siloxanes can be applied to different fields from conventional nanospace materials because of closed pores in polyhedral oligomeric siloxane molecules. Moreover, some materials have been synthesized in various nanospaces. It is found that the confined spaces affect the morphology and structures of obtained products.

  • Research Products

    (49 results)

All 2012 2011 2010 2009 2008 2007 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results) Presentation (26 results) Book (2 results) Remarks (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Polymorph control of calcium carbonate on the surface of mesoporous silica2012

    • Author(s)
      K.-M. Choi, K. Kuroda
    • Journal Title

      Cryst. Growth. Des.

      Volume: 12 Pages: 887-893

    • Peer Reviewed
  • [Journal Article] Dye-sensitized H_2 evolution over TiO_2 and SnO_2 nanoparticles Depending on Electron Donors2012

    • Author(s)
      Z. Conghong, M. M. Maitani, D. Mochizuki, E. Suzuki, Y. Wada
    • Journal Title

      Chem. Lett.

      Volume: 41 Pages: 423-424

    • Peer Reviewed
  • [Journal Article] A Spherosilicate Oligomer with Eight Stable Silanol Groups as a Building Block of Hybrid Materials2012

    • Author(s)
      K. Kawahara, H. Tachibana, Y. Hagiwara, K. Kuroda
    • Journal Title

      New J. Chem.

      Volume: 36 Pages: 1210-1217

    • Peer Reviewed
  • [Journal Article] Measurements of Accurate Temperatures in the Microwave Reactors2011

    • Author(s)
      D. Mochizuki, Y. Wada
    • Journal Title

      Mini-Rev. Org. Chem.

      Volume: 8 Pages: 294-298

    • Peer Reviewed
  • [Journal Article] Double function of tris(hydroxymethyl) aminomethane (THAM) for the preparation of colloidal silica nanospheres and the conversion to ordered mesoporous carbon2011

    • Author(s)
      K.-M. Choi, K. Kuroda
    • Journal Title

      Chem. Commun.

      Volume: 47 Pages: 10933-10935

    • Peer Reviewed
  • [Journal Article] Enhancement of Photoexcited Charge Transfer by {001} Facet-Dominating TiO_2 Nanoparticles2011

    • Author(s)
      M. M. Maitani, K. Tanaka, D. Mochizuki, Y. Wada
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 2 Pages: 2655-2659

    • Peer Reviewed
  • [Journal Article] Synthesis of mesostructureed silica from monoalkyl-substituted double five-ring unit2011

    • Author(s)
      A. Shimojima, H. Kuge, K. Kuroda
    • Journal Title

      J. Sol-Gel Sci.

      Volume: 13 Pages: 263-268

    • Peer Reviewed
  • [Journal Article] Formation of Reactive Microporous Networks from Alkoxysilylated Siloxane Cages2010

    • Author(s)
      Y. Hagiwara, A. Shimojima, K. Kuroda
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 83 Pages: 424-430

    • Peer Reviewed
  • [Journal Article] Self-Assembled Double Ladder Structure Formed Inside Carbon Nanotubes by Encapsulation of H_8Si_8O_<12>2009

    • Author(s)
      Z. Liu, S.-K. Joung, T. Okazaki, K. Suenaga, Y. Hagiwara, T. Ohsuna, K. Kuroda, Sumio Iijima
    • Journal Title

      ACS Nano

      Volume: 3 Pages: 1160-1166

    • Peer Reviewed
  • [Journal Article] Mesostructured silica based delivery system for a drug with a peptide as a cell-penetrating vector2009

    • Author(s)
      C. Gao, I. Izquierdo-Barba, I. Nakase, S. Futaki, J. Ruan, K. Sakamoto, Y. Sakamoto, K. Kuroda, O. Terasaki, S. Che
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 122 Pages: 201-207

    • Peer Reviewed
  • [Journal Article] Properties of metal species in square-shape mesopores of KSW-2-based silica2009

    • Author(s)
      T. Kimura, S. Huang, A. Fukuoka, K. Kuroda
    • Journal Title

      J. Mater. Chem.

      Volume: 19 Pages: 3859-3866

    • Peer Reviewed
  • [Journal Article] Alkoxysililated-Derivatives of Double- Four-Ring Silicates as Novel Building Blocks of Silica-Based Materials2008

    • Author(s)
      Y. Hagiwara, A. Shimojima, K. Kuroda
    • Journal Title

      Chem. Mater.

      Volume: 20 Pages: 1147-1153

    • Peer Reviewed
  • [Journal Article] Oligomeric Alkoxysilanes Possessing Cage-like Hybrid as Cores: Designed Precursors of Nanohybrid Materials2008

    • Author(s)
      H. Kuge, Y. Hagiwara, A. Shimojima, K. Kuroda
    • Journal Title

      Chem. Asian J.

      Volume: 3 Pages: 600-606

    • Peer Reviewed
  • [Journal Article] Rational Design of Mesoporous Metals and Related Nanomaterials by a Soft-Templating Approach2008

    • Author(s)
      Y. Yamauchi, K. Kuroda
    • Journal Title

      Chem. Asian J.

      Volume: 3 Pages: 664-676

    • Peer Reviewed
  • [Journal Article] Pt Fibers with Stacked Donut-Like Mesospace by Assembling Pt Nanoparticles: Guided Deposition in Physically Confined Self-Assembly of Surfactants2008

    • Author(s)
      Y. Yamauchi, A. Takai, T. Nagaura, S. Inoue, K. Kuroda
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 130 Pages: 5426-5427

    • Peer Reviewed
  • [Journal Article] Mesoporous Platinum with Giant Mesocages Templated from Lyotropic Liquid Crystals Consisting of Diblock Copolymers2008

    • Author(s)
      Y. Yamauchi, A. Sugiyama, R. Morimoto, A. Takai, K. Kuroda
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 47 Pages: 5371-5373

    • Peer Reviewed
  • [Journal Article] Stepwise Silylation of Double-Four-Ring (D4R) Silicate into a Novel Spherical Siloxane with a Defined Architecture2008

    • Author(s)
      K. Kawahara, Y. Hagiwara, A. Shimojima, K. Kuroda
    • Journal Title

      J. Mater. Chem.

      Volume: 18 Pages: 3193-3195

    • Peer Reviewed
  • [Presentation] カゴ型ケイ酸8量体-アルキルトリメチルアンモニウム複合体の構造と形成条件2012

    • Author(s)
      河原一文, 長田師門, 新井貴子, 山田紘理, 黒田一幸
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都
    • Year and Date
      20120300
  • [Presentation] 層状ケイ酸塩層間への閉じ込めによるイリジウム錯体の振動エネルギー失活の抑制2012

    • Author(s)
      杉山元彦, 望月大, 米谷真人, 和田 雄二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      20120300
  • [Presentation] Synthesis of Cage-Type Silicates Located between Alkyltrimethylammonium Surfactant Layers2011

    • Author(s)
      K. Kawahara, S. Osada, T. Arai, K. Kuroda
    • Organizer
      International Conference of New Science Created by Materials with Nano Spaces: from Fundamentals to Applications
    • Place of Presentation
      宮城
    • Year and Date
      20111100
  • [Presentation] Synthesis of a Microporous Material Derived from Layered Silicate RUB-51 through Bidentate Silylation2011

    • Author(s)
      Y. Asakura, K. Kuroda
    • Organizer
      International Conference of New Science Created by Materials with Nano Spaces : from Fundamentals to Applications
    • Place of Presentation
      宮城
    • Year and Date
      20111100
  • [Presentation] Expansion Behavior of Mesostructured Silica via Swelling of Polymers Anchored on the Mesopore Surfaces2011

    • Author(s)
      C. Urata, Y. Tamura, Y. Yamauchi, K. Kuroda
    • Organizer
      International Conference of New Science Created by Materials with Nano Spaces: from Fundamentals to Applications
    • Place of Presentation
      宮城
    • Year and Date
      20111100
  • [Presentation] アナターゼ型酸化チタンナノ粒子の結晶面による光誘起電荷移動への影響2011

    • Author(s)
      田中恵多, 米谷真人, 望月大, 和田雄二
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      20110300
  • [Presentation] Selective formation of 3D networks from a vinylalkoxysilylated double-four- membered ring2010

    • Author(s)
      Y. Hagiwara, A. Shimojima, K. Kuroda
    • Organizer
      International Symposium on Zeolites and Microporous Crystals (ZMPC) 2010
    • Place of Presentation
      Tokyo
    • Year and Date
      20100800
  • [Presentation] マイクロ波加熱による銀を含む二元金属ナノ粒子の合成2010

    • Author(s)
      望月大, 滝沢翔平, 塚原保徳, 山内智央, 和田雄二
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      20100300
  • [Presentation] マイクロ波照射下における不均一触媒作用促進効果2009

    • Author(s)
      太田創之, 長南聡, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      第3回日本電磁波エネルギー応用学会シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      20091100
  • [Presentation] 新前駆体C_<10>H_<21>Si (OSi(OMe)_2CH_2CH_2Si(OMe)_3)_3の合成とシリカ-有機メソ構造体の創製2009

    • Author(s)
      今井崇人, 後藤良太, 下嶋敦, 黒田一幸
    • Organizer
      日本化学会第三回関東支部大会
    • Place of Presentation
      東京(ポスター)
    • Year and Date
      20090900
  • [Presentation] ジフェニルシラノール基を頂点に有する二重四員環シロキサンオリゴマーからのシロキサンネットワークの構築2009

    • Author(s)
      立花寛己, 河原一文, 萩原快朗, 黒田一幸
    • Organizer
      日本化学会第三回関東支部大会
    • Place of Presentation
      東京
    • Year and Date
      20090900
  • [Presentation] Ag-Cuどんぐり型ナノ粒子触媒によるアルコールの脱水素反応2009

    • Author(s)
      滝沢翔平, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20090900
  • [Presentation] C_<10>H_<21>Si(OSi(OMe)_2CH_2CH_2Si(OMe)_3)_3からのシリカ有機系メソ構造体の作製2009

    • Author(s)
      今井崇人, 後藤良太, 下嶋敦, 黒田一幸
    • Organizer
      日本ゾル-ゲル学会第7回討論会
    • Place of Presentation
      京都
    • Year and Date
      20090800
  • [Presentation] 二重四員環シロキサンオリゴマーの各末端にシラノール基を有する分子の固相重合によるシロキサンネットワークの構築2009

    • Author(s)
      立花寛己, 河原一文, 萩原快朗, 黒田一幸
    • Organizer
      日本ゾル-ゲル学会第7回討論会
    • Place of Presentation
      京都
    • Year and Date
      20090800
  • [Presentation] 層状ケイ酸塩のシリル化を利用したナノ空間設計2009

    • Author(s)
      望月大
    • Organizer
      ゼオライトフォーラム
    • Place of Presentation
      宮城県
    • Year and Date
      20090600
  • [Presentation] ゼオライト-イリジウム錯体ナノハイブリッドの発光特性と光触媒への応用2009

    • Author(s)
      望月大, 徐晨, 和田雄二
    • Organizer
      第29回光がかかわる触媒化学シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      20090600
  • [Presentation] Mesoporous Materials Composed of Silicates and Siloxane Oligomers2009

    • Author(s)
      K. Kuroda
    • Organizer
      STAC-3 (The Third International Conference on the Science and Technology for Advanced Ceramics)
    • Place of Presentation
      Yokohama
    • Year and Date
      20090600
  • [Presentation] ジフェニルエトキシシリル化二重四員環シロキサンオリゴマーを用いたシロキサンネットワークの構築2009

    • Author(s)
      立花寛己, 河原一文, 萩原快朗, 黒田一幸
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      20090300
  • [Presentation] シリカナノ空間に導入したカルボニル基を有する有機分子の光物性2008

    • Author(s)
      望月大, 塚原保徳, 山内智央, 和田雄二
    • Organizer
      第24回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Year and Date
      20081100
  • [Presentation] Synthesis of Mesostructured Inorganic-Organic Hybrids from Amphiphilic Porphyrin Derivatives2008

    • Author(s)
      S. Nasu, K. Kuroda
    • Organizer
      6th International Mesostructured Materials Symposium 2008
    • Place of Presentation
      Belgium
    • Year and Date
      20080900
  • [Presentation] Selective Formation of Mesoporous Pt Nanorods and Nanotubes by Using Porous Anodic Aluminum Membranes2008

    • Author(s)
      A. Takai, Y. Yamauchi, K. Kuroda
    • Organizer
      6th International Mesostructured Materials Symposium 2008
    • Place of Presentation
      Belgium
    • Year and Date
      20080900
  • [Presentation] Bimetallic Nanoparticles Prepared by Microwave-Assisted Alcohol Reduction2008

    • Author(s)
      S. Takizawa, D. Mochizuki, Y. Tsukahara, T. Yamauchi, Y. Wada
    • Organizer
      Global Congress on Microwave Energy Applications 2008
    • Place of Presentation
      Otsu
    • Year and Date
      20080800
  • [Presentation] Synthesis of Mesostructured Inorganic-Organic Hybrids from Porphyrin Derivatives Possessing Amphiphilic Side Chains2008

    • Author(s)
      S. Nasu, K. Kuroda
    • Organizer
      17th International Conference on Photochemical Conversion and Storage of Solar Energy
    • Place of Presentation
      Australia
    • Year and Date
      20080700
  • [Presentation] Alkoxysilylated-Derivatives of Double-Four-Ring (D4R) Units as Novel Building Blocks of Silica Based Materials2008

    • Author(s)
      Y. Hagiwara, A. Shimojima, K. Kuroda
    • Organizer
      The 15^<th> International Symposium on Organosilicon Chemistry
    • Place of Presentation
      Korea
    • Year and Date
      20080600
  • [Presentation] ジシロキサンユニットをもつアルキルシロキサン系分子の合成とその自己組識化2008

    • Author(s)
      阪本樹, 櫻井美香子, 下嶋敦, 黒田一幸
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      20080300
  • [Presentation] エチレンオキシド鏡を層表面に固定化した層状ケイ酸塩-有機ナノ複合体の合成2007

    • Author(s)
      望月大, 黒田一幸
    • Organizer
      第51回粘土科学討論会
    • Place of Presentation
      北海道
    • Year and Date
      20070900
  • [Book] CSJ Current Review, 革新的な多孔質材料2010

    • Author(s)
      菅野陽将, 若林隆太郎, 黒田一幸
    • Total Pages
      63-69
    • Publisher
      化学同人
  • [Book] ハニカム構造の応用と機能-ハニカム構造材料からなのハニカム構造まで-2008

    • Author(s)
      浦田千尋, 黒田一幸
    • Total Pages
      208-227
    • Publisher
      シーエムシー出版
  • [Remarks] 研究室ホームページ黒田研究室

    • URL

      http://www.waseda.jp/sem-kuroda_lab/

  • [Remarks] 研究室ホームページ和田研究室

    • URL

      http://www.apc.titech.ac.jp/~ywada/wada/index.html

  • [Patent(Industrial Property Rights)] 金属ナノ粒子及びその製造方法並びに導電性インク2012

    • Inventor(s)
      和田雄二, 陳智, 望月大, 内田博, 篠崎研二, 冨田浩幸
    • Industrial Property Rights Holder
      昭和電工株式会社, 国立大学法人東京工業大学
    • Industrial Property Number
      特許権特願2012-051636
    • Filing Date
      2012-03-08
  • [Patent(Industrial Property Rights)] 炭化水素の製造方法2011

    • Inventor(s)
      野本英朗, 河野巧, 樋口雅一, 井上修治, 和田雄二, 鈴木榮一, 望月大, 米谷真人, 鯨井寛樹
    • Industrial Property Rights Holder
      新日鐵化学株式会社, 国立大学法人 東京工業大学
    • Industrial Property Number
      特許権特願2011-53410
    • Filing Date
      2011-03-10

URL: 

Published: 2013-07-31  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi