2011 Fiscal Year Final Research Report
Study of the crystal structures of materials with having regulated nano spaces
| Project Area | New Materials Science Using Regulated Nano Spaces －Strategy in Ubiquitous Elements |
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| Project/Area Number |
19051015
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Nagoya University |
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Principal Investigator |
SAWA Hiroshi 名古屋大学, 工学研究科, 教授 (50215901)
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| Co-Investigator(Kenkyū-buntansha) |
AOYAGI Shinobu 名古屋市立大学, システム自然科学研究科, 准教授 (40360838)
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| Co-Investigator(Renkei-kenkyūsha) |
NISHIBORI Eiji 名古屋大学, 工学研究科, 准教授 (10293672)
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| Project Period (FY) |
2007 – 2011
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| Keywords | 放射光X線同折 / 配列ナノ空間物質 / 精密構造解析 / 電子密度解析 / フラーレン |
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| Research Abstract |
The precise structure analyses for the synthesized new materials in this project were performed using the synchrotron radiation X-rays diffraction technique at SPring-8. Electron density analysis using powder and single crystals diffraction were conducted for the purpose of clarifying the electronic state of functional materials, and for the revelation mechanism of quantum physical properties from a structural viewpoint. Especially we did the starting work of the single crystal diffractometer introduced on March 2008, and established measurement technology and the analysis technique. We performed the cooperative research such as the series of clathrate compounds and Li@C_<60> fullerene in this project.
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Research Products
(14 results)
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[Journal Article] Spin-Orbital Short-Range Order on a Honeycomb-Based Lattice2012
Author(s)
S. Nakatsuji, K. Kuga, K. Kimura, R. Satake, N. Katayama, F. Nishibori, H. Sawa, R. Ishii, M. Hagiwara, F. Bridges, T. U. Ito, W. Higemoto, Y. Karaki, M. Halim, A. A. Nugroho, J. A. Rodriguez-Rivera, M. A. Green, C. Broholm
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Journal Title
Science
Volume: vol. 336 no. 6081
Pages: 559-563
DOI
Peer Reviewed
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[Journal Article] A layered ionic crystal of polar Li@C_<60> superatoms2010
Author(s)
S. Aoyagi, E. Nishibori, *H. Sawa, K. Sugimoto, M. Takata, Y. Miyata, R. Kitaura, H. Shinohara, H. Okada, T. Sakai, Y. Ono, K. Kawachi, K. Yokoo, S. Ono, K. Omote, Y. Kasama, S. Ishikawa, T. Komuro, and H. Tobita
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Journal Title
Nature Chem.
Volume: 2
Pages: 678-683
DOI
Peer Reviewed
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[Journal Article] Bis-Carbene Adducts of Non-IPR La_2@C_<72>: Localization of High Reactivity around Fused Pentagons and Electrochemical Properties2008
Author(s)
X. Lu, H. Nikawa, T. Tsuchiya, Y. Maeda, M. 0. Ishitsuka, T. Akasaka, M. Toki, H. Sawa, Z. Slanina, N. Mizorogi, and S. Nagase
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Journal Title
Bis-Carbene Angew. Chem. Int. Ed.
Volume: 47
Pages: 8642-8645
DOI
Peer Reviewed
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