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2012 Fiscal Year Final Research Report

Functions of Highly Elaborated π-Space Based on the Synthesis of Extended π-Electron Systems and Application to Electronics

Planned Research

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Project AreaEmergence of highly elaborated pai-space and its function
Project/Area Number 20108004
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionOsaka University

Principal Investigator

ASO Yoshio  大阪大学, 産業科学研究所, 教授 (60151065)

Co-Investigator(Kenkyū-buntansha) KARAKAWA Makoto  大阪大学, 産業科学研究所, 助教 (80452457)
Project Period (FY) 2008 – 2012
Keywords拡張共役系 / 高分子構造・物性 / 有機エレクトロニクス / 先端機能デバイス / ナノ材料 / 分子エレクトロニクス
Research Abstract

With emphasizing the formation of highly elaborated π-space systems with efficient carrier-transporting function, a variety of novel materials have been developed and applied to organic and molecular electronics. Photo-functionalization and polymer extension of branched oligothiophenes, and synthesis of fluoroalkyl-functionalized systems and donor/acceptor type polymer materials have been achieved, and based of these materials organic thin-film transistors, switching devices, and high performance organic solar cells have been developed. Moreover, insulated molecular wires and tripodal anchor units for molecular electronics have been newly developed, and their functions and performances have been clarified.

  • Research Products

    (26 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (9 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Energy Level Modulation of HOMO, LUMO, and Band-Gap in Conjugated Polymers for Organic Photovoltaic Applications2013

    • Author(s)
      B.-G. Kim, X. Ma, C. Chen, Y. Ie, E. W. Coir, H. Hashemi, Y. Aso, P. F. Green, J. Kieffer, J. Kim
    • Journal Title

      Adv. Funct. Mater

      Volume: 23(4) Pages: 439-445

    • DOI

      DOI:10.1002/adfm.201201385

    • Peer Reviewed
  • [Journal Article] Buckminsterfullerene Derivatives Bearing a Fluoroalkyl Group for Use in Organic Photovoltaic Cells2012

    • Author(s)
      M. Karakawa, T. Nagai, T. Irita, K. Adachi, Y. Ie, Y. Aso
    • Journal Title

      J. Fluorine Chem

      Volume: 144 Pages: 51-58

    • DOI

      DOI:10.1016/j.jfluchem.2012.09.009

    • Peer Reviewed
  • [Journal Article] Air-Stable n-Type Organic Field-Effect Transistors Based on 4,9-Dihydro-s-indaceno[1,2-b:5,6-b']dithiazole-4,9-dione Unit2012

    • Author(s)
      Y. Ie, M. Ueta, M. Nitani, N. Tohnai, M. Miyata, H. Tada, Y. Aso
    • Journal Title

      Chem. Mater

      Volume: 24(16) Pages: 3285-3293

    • DOI

      DOI:10.1021/cm301985q

    • Peer Reviewed
  • [Journal Article] Synthesis, Properties, and Photovoltaic Performances of Donor.Acceptor Copolymers Having Dioxocycloalkene- Annelated Thiophenes As Acceptor Monomer Units2012

    • Author(s)
      Y. Ie, J. Huang, Y. Uetani, M. Karakawa, Y. Aso
    • Journal Title

      Macromolecules

      Volume: 45(11) Pages: 4564-457

    • DOI

      DOI:10.1021/ma300742r

    • Peer Reviewed
  • [Journal Article] Functional Oligothiophenes toward Molecular Wires in Single-Molecular Electronics2012

    • Author(s)
      Y. Ie, M. Endou, A. Han, R. Yamada, H. Tada, Y. Aso
    • Journal Title

      Pure Appl. Chem

      Volume: 84(4) Pages: 931-943

    • DOI

      DOI:10.1351/PAC-CON-11-10-26

    • Peer Reviewed
  • [Journal Article] Encapsulated Oligothiophenes having Electron-Affinity Characteristics2012

    • Author(s)
      M. Endou, Y. Ie, Y. Aso
    • Journal Title

      Chem. Commun

      Volume: 48(4) Pages: 540-542

    • DOI

      DOI:10.1039/c1cc14994f

    • Peer Reviewed
  • [Journal Article] The Frontiers of Quinoidal Stability in Long Oligothiophenes: Raman Spectra of Dicationic Polaron Pairs2011

    • Author(s)
      S. R. Gonzalez, Y. Ie, Y. Aso, J. T. L. Navarrete, J. Casado
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133(41) Pages: 16350-16353

    • DOI

      DOI:10.1021/ja2061903

    • Peer Reviewed
  • [Journal Article] Completely Encapsulated Oligothiophenes: Synthesis, Properties, and Single-Molecule Conductance2011

    • Author(s)
      Y. Ie, M. Endou, S. K. Lee, R. Yamada, H. Tada, Y. Aso
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 50(50) Pages: 11980-11984

    • DOI

      DOI:10.1055/s-0031-1290060

    • Peer Reviewed
  • [Journal Article] Electron-Transporting Oligothiophenes Containing Dicyanomethylene-Substituted Cyclopenta[b]thiophene: Chemical Tuning for Air Stability in OFETs2011

    • Author(s)
      Y. Ie, K. Nishida, M. Karakawa, H. Tada, Y. Aso
    • Journal Title

      J. Org. Chem

      Volume: 76(16) Pages: 6604-6610

    • DOI

      DOI:10.1021/jo200890b

    • Peer Reviewed
  • [Journal Article] Air-Stable n-Type Organic Field-Effect Transistors Based on Solution-Processable, Electronegative Oligomers Containing Dicyanomethylene-Substituted Cyclopenta[b]thiophene2011

    • Author(s)
      Y. Ie, K. Nishida, M. Karakawa, H. Tada, A. Asano, A. Saeki, S. Seki, Y. Aso
    • Journal Title

      Chem. Eur. J

      Volume: 17(17) Pages: 4750-4758

    • DOI

      DOI:10.1055/s-0030-1260621

    • Peer Reviewed
  • [Journal Article] Branched Polythiophene as a New Amorphous Semiconducting Polymer for an Organic Field-effect Transistor2011

    • Author(s)
      M. Karakawa, Y. Ie, Y. Aso
    • Journal Title

      Semicond. Sci. Technol

      Volume: 26 Pages: 034004(9pp)

    • DOI

      DOI:10.1088/0268-1242/26/3/034004

    • Peer Reviewed
  • [Presentation] Development of n-Type Organic Semiconductors Based on Fluoroalkyl- Substituted Conjugation Systems2012

    • Author(s)
      Yoshio Aso
    • Organizer
      The 20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      京都テルサ(京都市)
    • Year and Date
      2012-07-27
  • [Presentation] 電子受容性ユニット含む新規π 電子共役系の開発と有機エレクトロニクスへの応用2012

    • Author(s)
      安蘇芳雄
    • Organizer
      2012 PHyM シンポジウム
    • Place of Presentation
      東北大学(仙台市)
    • Year and Date
      2012-06-07
  • [Presentation] 分子エレクトロニクスに向けた分子材料開発と評価2011

    • Author(s)
      安蘇芳雄
    • Organizer
      第5回有機π電子シンポジウム
    • Place of Presentation
      ホテルアウィーナ大阪(大阪市)
    • Year and Date
      2011-11-26
  • [Presentation] Functionalized Oligothiophene Molecular Wires and Tripodal Anchoring Groups for Molecular Electronics2011

    • Author(s)
      Yoshio Aso
    • Organizer
      14th International Symposium on Novel Aromatic Compounds (ISNA-14)
    • Place of Presentation
      Oregon, USAYoshio Aso
    • Year and Date
      2011-07-28
  • [Presentation] Electronegative pi-Conjugated Oligomers for n-Channel OFET Materials2010

    • Author(s)
      Yoshio Aso
    • Organizer
      Symposium on Organic and Polymer Electronics
    • Place of Presentation
      Singapore
    • Year and Date
      2010-12-10
  • [Presentation] オリゴチオフェンの機能化分子設計とエレクトロニクス応用2010

    • Author(s)
      安蘇芳雄
    • Organizer
      第37回有機典型元素化学討論会
    • Place of Presentation
      室蘭市民会館ホール(室蘭市)
    • Year and Date
      2010-11-26
  • [Presentation] オリゴチオフェンの機能化分子設計とエレクトロニクス応用2010

    • Author(s)
      安蘇芳雄
    • Organizer
      日本化学会第4回関東支部大会 (2010)
    • Place of Presentation
      筑波大学(つくば市)
    • Year and Date
      2010-08-31
  • [Presentation] オリゴチオフェンの機能化分子設計とエレクトロニクス応用2010

    • Author(s)
      安蘇芳雄
    • Organizer
      第37回有機反応懇談会
    • Place of Presentation
      京都大学化学研究所(宇治市)
    • Year and Date
      2010-08-02
  • [Presentation] Branched Oligothiophenes: Synthesis, Properties and Electronic Applications2010

    • Author(s)
      Yoshio Aso
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2010-07-08
  • [Book] 拡張π電子共役系の創製に基づく高次π空間の機能とエレクトロニクス応用,赤阪 健/大須賀篤弘/福住俊一/神取秀樹監修「高次π空間の創発と機能開発」2013

    • Author(s)
      安蘇芳雄
    • Total Pages
      10-15
    • Publisher
      シーエムシー出版
  • [Book] 分子ワイヤ,松重和美/田中一義/和田恭雄監修「分子エレクトロニクスの基盤技術と将来展望」2009

    • Author(s)
      安蘇芳雄
    • Total Pages
      151-158
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://www.sanken.osaka-u.ac.jp/labs/omm/

  • [Patent(Industrial Property Rights)] 重合体、この重合体を用いた有機薄膜及び有機薄膜素子2012

    • Inventor(s)
      家 裕隆、黄 建明、安蘇芳雄、辛川 誠、上田将人
    • Industrial Property Rights Holder
      住友化学株式会社、国立大学法人大阪大学
    • Industrial Property Number
      特許、特願2012-196331
    • Filing Date
      2012-09-06
  • [Patent(Industrial Property Rights)] 化合物、並びに、該化合物を含有する有機半導体材料、有機半導体素子2012

    • Inventor(s)
      家 裕隆、陣内青萌、安蘇芳雄、寺井宏樹
    • Industrial Property Rights Holder
      住友化学株式会社、国立大学法人大阪大学
    • Industrial Property Number
      特許、特願 2012-193416
    • Filing Date
      2012-09-03
  • [Patent(Industrial Property Rights)] フラーレン誘導体2012

    • Inventor(s)
      安蘇芳雄、家 裕隆、辛川 誠、小島 彩、永井隆文、足達健二
    • Industrial Property Rights Holder
      ダイキン工業株式会社、国立大学法人大阪大学
    • Industrial Property Number
      特許、特願2012-34546
    • Filing Date
      2012-02-20

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Published: 2014-08-29  

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