Creation of Novel π-Electron Molecules Based on Phthalocyanines

2010 Fiscal Year Self-evaluation Report

• Project Area: Emergence of highly elaborated pai-space and its function
• Project/Area Number: 20108007
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Tohoku University
• Principal Investigator: KOBAYASHI Nagao Tohoku University, 大学院・理学研究科, 教授 (60124575)
• Project Period (FY): 2008 – 2012
• Keywords: π電子 / 芳香族化合物 / 分光学 / 合成 / 構造

Research Abstract

(1)新規鉄及びコバルトフタロシアニン(Pc)を用いた触媒反応の開拓
(2)ピロールの替わりに6,7員環またはピレン環を導入したPc誘導体の合成と物性
(3)Pc誘導体の半分の単位を有するBODIPYの合成と物性
(4)フルオロアルキル基を有するサブフタロシアニンの物性と特性の評価

Research Products

• [Journal Article] Tuning the Physico-Electrochemical Properties of Novel Cobalt(II) Octa[(3, 5-biscarboxylate)phenyl] Phthalocyanine Complex Using Phenylamine- Functionalized SWCNTs. (2010)
  • Author(s): B.O.Agboola, K.I.Ozoemena, T.Nyokong, T.Fukuda, N.Kobayashi
  • Journal Title: Carbon 48 Pages: 763-773
  • Peer Reviewed
• [Journal Article] Re- examination of the Emission Properties of Alkoxy- and Thioalkyl-Substituted Phthalocya- nines. (2010)
  • Author(s): J.Mack, N.Kobayashi, M.J.Stillman
  • Journal Title: J.InorgBio.Chem. 104 Pages: 310-317
  • Peer Reviewed
• [Journal Article] Studies on the Hetero- geneous Electron Transport and Oxygen Reduction Reaction at Metal (Co, Fe) Octabutylsulphony- lphthalocyanines Supported on Multi-walled Carbon Nanotube Modified Graphite Electrode. (2010)
  • Author(s): S.A.Mamuru, K.I.Ozoemena, T.Fukuda, N.Kobayashi, T.Nyokong
  • Journal Title: Electrochim.Acta 55 Pages: 6367-6375
  • Peer Reviewed
• [Journal Article] Solubility of Trifluoroethoxyphthalocya- nines and -Subphthalocyanines in Liquid and Supercritical Carbon Dioxide. (2010)
  • Author(s): B.Das, E.Tokunaga, N.Shibata, N.Koba- yashi
  • Journal Title: J.Fluo.Chem. 131 Pages: 652-654
  • Peer Reviewed
• [Journal Article] A Discrete Quadruple-Decker Phthalocyanine. (2010)
  • Author(s): T.Fukuda, T.Biyajima, N.Kobayashi.
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 6278-6279
  • Peer Reviewed
• [Journal Article] Specific Cu2+-induced J-aggre- gation and Hg2+-induced fluorescence enhance- ment based on BODIPY. (2010)
  • Author(s): H.Lu, Z.Xue, J.Mack, Z.Shen, X.You, N.Kobayashi.
  • Journal Title: Chem.Commun. 46 Pages: 3565-3567
  • Peer Reviewed
• [Journal Article] Trifuluoro-Coating Improves the Axial Ligand Substitution of Subphthalo- cyanines. (2010)
  • Author(s): N.Shibata, B.Das, E.Tokunaga, M.Shiro, N.Kobayashi.
  • Journal Title: Chem.Eur.J. 16 Pages: 7554-7562
  • Peer Reviewed
• [Journal Article] Novel Homo and Heterobinuclear Ball-Type Phthalocyanines : Synthesis and Electrochemical, Electrical, EPR and MCD Spectral Properties. (2010)
  • Author(s): Z.Odabas, F.Dumludag.A.R.Ozkaya, S.Yama- uchi, N.Kobayashi, O.Bekaroglu.
  • Journal Title: Dalton Trans. 39 Pages: 8143-8152
  • Peer Reviewed
• [Journal Article] Aza- phenalene Phthalocyanines-Phthalocyanine Analogues Bearing Six-Membered Ring Units Instead of Five-Membered Ring Units. (2010)
  • Author(s): S.Shimizu, H.Zhu, N.Kobayashi
  • Journal Title: Chem.Eur.J. 16 Pages: 11151-11159
  • Peer Reviewed
• [Journal Article] Synthesis, Reactions, and Electronic Properties of 16 π-electron Octaisobutyltetra- phenylporphyrin. (2010)
  • Author(s): Y.Yamamoto, Y.Hirata, M.Kodama, T.Yama- guchi, S.Matsukawa, K.Akiba, D.Hashizume, F.Iwasaki, A.Muranaka, M.Uchiyama, P.Chen, K.M.Kadish, N.Kobayashi.
  • Journal Title: J.Am.Chm.Soc. 132 Pages: 12627-12638
  • Peer Reviewed
• [Journal Article] Iron (II) Tetrakis(diaqua platinum)octa- carboxyphthalocyanine Supported on Multi-walled Carbon Nanotube Platform : An Efficient Functional Material for Enhancing Electron Transfer Kinetics and Electrocatalytic Oxidation of Formic Acid. (2010)
  • Author(s): S.A.Mamuru, K.I.Ozoemena, T.Fukuda, N.Kobayashi.
  • Journal Title: J.Mater.Chem. 20 Pages: 10705-10715
  • Peer Reviewed
• [Journal Article] Sub-Aza- Phenalenephthalocyanine : A Subphthalocyanine Ana- logue Bearing a Six-Membered Ring Unit. (2010)
  • Author(s): Hua.Zhu, S.Shimizu, N.Kobayashi.
  • Journal Title: Angew.Chem. 49 Pages: 8000-8003
  • Peer Reviewed
• [Presentation] Relationship between the Molecular Structures and Spectroscopic and Electrochemical Properties of Giant Aromatic Molecules. (2010)
  • Author(s): N.Kobayashi
  • Organizer: Pacifichem
  • Place of Presentation: Honolulu, Hawaii, USA(招待講演)
  • Year and Date: 20101215-20101220
• [Presentation] Relationship between the Symmetry of π-Systems and Excited State and the Electrochemical Properties of Tetraazaporphyrins. (2010)
  • Author(s): N.Kobayashi
  • Organizer: Pacifichem
  • Place of Presentation: Honolulu, Hawaii, USA(招待講演)
  • Year and Date: 20101215-20101220
• [Presentation] Synthesis and Properties of meso-oxoporphyrins. (2010)
  • Author(s): S.Shimizu, N.Kobayashi
  • Organizer: Pacifichem
  • Place of Presentation: Honolulu, Hawaii, USA
  • Year and Date: 20101215-20101220
• [Presentation] Azulenocyanine : A New Family of Phthalocyanines with Intense Near-IR Absorption. (2010)
  • Author(s): A.Muranaka, M.Yonehara, N.Kobayashi, M.Uchiyama
  • Organizer: Pacifichem
  • Place of Presentation: Honolulu, Hawaii, USA
  • Year and Date: 20101215-20101220
• [Presentation] Evaluation of the Structure and Antiaromaticity of 16π benzofused porphyrin zinc complex. (2010)
  • Author(s): S.Sugawara, Y.Hirata, S.Kojima, S.Matsukawa, D.Hashizume, J.Mack, N.Kobayashi, Y.Yamamoto.
  • Organizer: Pacifichem
  • Place of Presentation: Honolulu, Hawaii, USA
  • Year and Date: 20101215-20101220
• [Presentation] Novel Subporphyrins and Subphtha- locyanines. (2010)
  • Author(s): N.Kobayashi
  • Organizer: 11th Eurasia Conference on Chemical Sciences
  • Place of Presentation: Dead Sea, Jordan(招待講演)
  • Year and Date: 20101215-20101220
• [Book] Bottom-up Assembly(Supramolecular Nanostructures of Phthalocyanines and Porphyrins at Surfaces Based)(135) (2010)
  • Author(s): S.Yoshimoto, N.Kobayashi
  • Total Pages: 137-168
  • Publisher: Structure and Bonding
• [Book] Handbook of Porphyrin Science(Optically Active Porphyrin Systems Analyzed by Circular Dichroism.)(K.M.Kadish, K.M.Smith, and R.Guilard Eds.)(Vol.7) (2010)
  • Author(s): N.Kobayashi
  • Publisher: World Scientific, Singapore
• [Book] Handbook of Porphyrin Science(Electronic Absorption Spectra-Phthalocyanines.)(K.M.Kadish, K.M.Smith, and R.Guilard Eds.)(Vol.9) (2010)
  • Author(s): T.Fukuda, N.Kobayashi.
  • Publisher: World Scientific, Singapore