2012 Fiscal Year Final Research Report
Creation of novelπ-conjugated molecules based on phthalocyanines
| Project Area | Emergence of highly elaborated pai-space and its function |
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| Project/Area Number |
20108007
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Tohoku University |
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Principal Investigator |
KOBAYASHI Nagao 東北大学, 大学院・理学研究科, 教授 (60124575)
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| Co-Investigator(Kenkyū-buntansha) |
SHIMIZU Soji 東北大学, 大学院・理学研究科, 講師 (70431492)
FUKUDA Takamitsu 大阪大学, 大学院・理学研究科, 講師 (40344741)
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| Project Period (FY) |
2008 – 2012
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| Keywords | 構造・機能材料 / 超分子化学 / 複合材料・物性 |
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| Research Abstract |
In this research, syntheses of novel phthalocyanine analogues, which were perturbed by several manners, such as distortion of planar structures of phthalocyanines and expansion of their π-conjugated systems, were investigated. Novel properties arising from control of arrangement of these π-conjugated molecules were also investigated. In addition, under the collaboration in this scientific research on innovative areas, analyses on electronic structures of π-conjugated molecules, which were synthesized by other members, were carried out using magnetic circular dichroism spectroscopy.
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Research Products
(25 results)
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[Journal Article] Effects of Carbon-Metal-Carbon Linkages on the Optical, Photophysical, and Electrochemical Properties of Phosphametallacycle-Linked Coplanar Porphyrin Dimers2012
Author(s)
Matano, Y,; Matsumoto, K.; Hayashi H.; Nakao Y.; Kumpulainen, T.; Chukharev, V.; Tkachenko, N.V.; Lemmetyinen, H.; Shimizu, S.; Kobayashi, N.; Sakamaki, D.; Ito, A.; Tanaka, K.; Imahori, H
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Journal Title
J, Am. Chem. Soc
Volume: Vol.134
Pages: 1825-1839
DOI
Peer Reviewed
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[Journal Article] Gold (II) Phthalocyanine Revisited: Synthesis and Spectroscopic Properties of Gold (III) Phthalocyanines and an Unprecedented Ring-Contracted Phthalocyanine Analogue2012
Author(s)
Y Wong, E, W.; Miura, A.; Wright, M, D.; Walsby, C, J.; Shimizu, S.; Kobayashi, N.; Leznoff, D,B
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Journal Title
Chem. Eur. J
Volume: Vol.18
Pages: 12404-12410
DOI
Peer Reviewed
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