Sequence Control of π-Electronic Compounds

2010 Fiscal Year Self-evaluation Report

• Project Area: Emergence of highly elaborated pai-space and its function
• Project/Area Number: 20108008
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: National Institute for Materials Science
• Principal Investigator: TASHIRO Kentaro National Institute for Materials Science, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (40332598)
• Project Period (FY): 2008 – 2012
• Keywords: 異種多核金属錯体 / ペプチド固相合成 / 強磁性 / ヘテロジャンクション

Research Abstract

π電子化合物が集合体として機能を発現するためには、構成要素である化合物の「並び方」(シークエンス)がきわめて重要となる。任意の配列が選択的に構築できれば、材料設計の自由度は格段に大きくなると期待される。本研究では、π電子化合物のシークエンス制御の新たな提案と利用に焦点をあてた取り組みを行い、材料設計の新たな分野を開拓する。

Research Products

• [Journal Article] Electron-or Hole-Transporting Nature Selected by Side-Chain-Directedπ-Stacking Geometry : Liquid Crystalline Fused Metalloporphyrin Dimers (2011)
  • Author(s): T.Sakurai, K.Tashiro, Y.Honsho, A.Saeki, S.Seki, A.Osuka, A.Muranaka, M.Uchiyama, J.Kim, S.Ha, K.Kato, M.Takata, T.Aida
  • Journal Title: J.Am.Chem.Soc. 133 Pages: 6537-6540
  • Peer Reviewed
• [Journal Article] Assembly and Manipulation of Rotatable Cerium Porphyrinato Sandwich Complexes on a Surface (2011)
  • Author(s): D.Ecija, W.Auwarter, S.Vijayaraghavan, K.Seufert, F.Bischoff, K.Tashiro, J.V.Barth
  • Journal Title: Angew.Chem.Int.Ed. 50 Pages: 3872-3877
• [Journal Article] Synthesis of Metal-Organic Complex Arrays (2011)
  • Author(s): P.Vairaprakash, H.Ueki, K.Tashiro, O.M.Yaghi
  • Journal Title: J.Am.Chem.Soc. 133 Pages: 759-761
  • Peer Reviewed
• [Journal Article] Chiroselective Assembly of a Chiral Porphyrin-Fullerene Dyad : Photoconductive Nanofiber with a Top-class Ambipolar Charge-Carrier Mobility (2010)
  • Author(s): Y.Hizume, K.Tashiro, R.Charvet, Y.Yamamoto, A.Saeki, S.Seki, T.Aida
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 6628-6629
  • Peer Reviewed
• [Presentation] Metal-Organic Complex Arrays (2011)
  • Author(s): K.Tashiro
  • Organizer: VNUHCM-UCLA MOF Symposium
  • Place of Presentation: Ho Chi Minh City, Viet Nam.
  • Year and Date: 2011-03-21
• [Presentation] MANA (2011)
  • Author(s): MOCAs, K.Tashiro
  • Organizer: International Symposium 2011
  • Place of Presentation: Tsukuba
  • Year and Date: 2011-03-02
• [Presentation] Precise Control of Supramolecular Interactions between Fullerenes and Metalloporphyrins : Applications for Molecular and Materials Sciences of Carbon Nanoclusters (2010)
  • Author(s): K.Tashiro
  • Organizer: Pacifichem 2010
  • Place of Presentation: Honolulu, USA
  • Year and Date: 2010-12-16
• [Presentation] Host-Guest Chemistry for the Separation of Fullerenes (2010)
  • Author(s): K. Tashiro
  • Organizer: Fullerene Silver Anniversary Symposium
  • Place of Presentation: Hersonissos, Greece
  • Year and Date: 2010-10-09
• [Presentation] Supramolecular Chemistry of Metal Bisporphyrinate Double-Decker Complexes with Fullerenes (2010)
  • Author(s): K. Tashiro
  • Organizer: Sixth International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Santa Ana Pueblo, USA
  • Year and Date: 2010-07-08
• [Presentation] Novel Approaches for Sequence Control in Covalent and Supramolecular Arrays (2009)
  • Author(s): K. Tashiro
  • Organizer: International Conference on Polymers and Advanced Materials
  • Place of Presentation: Huatulco, Mexico
  • Year and Date: 2009-11-23
• [Presentation] Controlled Self-Assembly ofπ-Electronic Moieties for Materials Engineering (2009)
  • Author(s): K.Tashiro
  • Organizer: International Symposium for Young Organic Chemists
  • Place of Presentation: Tsukuba
  • Year and Date: 2009-03-06
• [Presentation] Molecular Beyonds (2009)
  • Author(s): K. Tashiro
  • Organizer: MANA International Symposium 2009
  • Place of Presentation: Tsukuba
  • Year and Date: 2009-02-25
• [Book] 超分子サイエンス(ポルフィリン超分子レセプタ) (2009)
  • Author(s): 田代健太郎
  • Total Pages: 486-492
• [Book] パイ電子空間(ナノ空間材料の創成と応用) (2009)
  • Author(s): 田代健太郎
  • Total Pages: 29-34
• [Patent(Industrial Property Rights)] 金属錯体アレイとその製造法及び材料 (2010)
  • Inventor(s): 田代健太郎、Pothiappan Vairaprakash, 植木久憲, Omar M.Yaghi
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 物質特許,2010-038460
  • Filing Date: 2010-02-24