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2012 Fiscal Year Final Research Report

Programmed emergence phenomena in oxide nanostructures

Planned Research

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Project AreaEmergent Chemistry of Nano-scale Molecular System
Project/Area Number 20111005
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionOsaka University

Principal Investigator

KAWAI Tomoji  大阪大学, 産業科学研究所, 特任教授(常勤) (20092546)

Co-Investigator(Kenkyū-buntansha) TANAKA Hiroyuki  大阪大学, 産業科学研究所, 助教 (20314429)
Co-Investigator(Renkei-kenkyūsha) YANAGIDA Takeshi  大阪大学, 産業科学研究所, 准教授 (50420419)
TANIGUCHI Masateru  大阪大学, 産業科学研究所, 准教授 (40362628)
Project Period (FY) 2008 – 2012
Keywords遷移金属酸化物 / ナノワイヤ構造 / 創発化学 / 高次ナノ構造 / 気液固反応法
Research Abstract

Three dimensional nanomechanism of structure formation through dynamic nonequilibrium process was elucidated based on a concept of the emergence chemistry for transition metal oxide and realized the high level nano structures. (1)Using the VLS reaction method through the metal catalyst, we elucidated dynamic nonequilibrium mechanism to make one dimension of transition metal oxide nanostructure. (2)We applied the sequential VLS reaction method to make the highly advanced nanostructure beyond the hierarchy and elucidated dynamic mechanism to enable the space positioning of the metal catalyst. (3)Using the dynamic nonequilibrium mechanism mentioned above, we built a process to perform positioning of the transition metal oxide materials which has a desired function at the desired position and extracted the functionality. Specifically, we realized a dynamic process in the limited nano-space where biological molecules pass through.

  • Research Products

    (57 results)

All 2013 2012 2011 2010 2009 2008 Other

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (37 results) Remarks (1 results)

  • [Journal Article] Crystal Plane Dependence of Critical Concentration for Nucleation on Hydrothermal ZnO Nanowires2013

    • Author(s)
      Y.He他12名
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Pages: 1197-1203

    • DOI

      DOI:10.1021/jp3113232

    • Peer Reviewed
  • [Journal Article] Pressure-Induced Evaporation Dynamics of Gold Nanoparticles on Oxide Substrate2013

    • Author(s)
      G.Meng他11名
    • Journal Title

      Phys. Rev. E

      Volume: 87 Pages: 012405

    • DOI

      DOI:10.1103/PhysRevE.87.012405

    • Peer Reviewed
  • [Journal Article] Dual Defects of Cation and Anion on Memristive Nonvolatile Memory of Metal Oxides2012

    • Author(s)
      K.Oka他7名
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 2535-2538

    • DOI

      DOI:10.1021/ja2114344

    • Peer Reviewed
  • [Journal Article] Facile and Scalable Methodology for Sublithographic Scale Uniform Nanowires by Ultra-Thin AAO Free-Standing Membrane2012

    • Author(s)
      G.Meng他13名
    • Journal Title

      RSC Adv

      Volume: 2 Pages: 10618-10623

    • DOI

      DOI:10.1039/C2RA21643D

    • Peer Reviewed
  • [Journal Article] Switching Properties of Titanium Dioxide Nanowire Memristor2012

    • Author(s)
      K.Nagashima他11名
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 51 Pages: 11PE09

    • DOI

      DOI:10.1143/JJAP.51.11PE09

    • Peer Reviewed
  • [Journal Article] Prominent Thermodynamical Interaction with Surroundings on Nanoscale Memristive Switching of Metal Oxides2012

    • Author(s)
      K.Nagashima他12名
    • Journal Title

      Nano Lett

      Volume: 12 Pages: 5684-5690

    • DOI

      DOI:10.1021/nl302880a

    • Peer Reviewed
  • [Journal Article] Fundamental Strategy for Creating VLS Grown TiO2 Single Crystalline Nanowires2012

    • Author(s)
      F.Zhuge他14名
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Pages: 24367-24372

    • DOI

      DOI:10.1021/jp308945b

    • Peer Reviewed
  • [Journal Article] Molecular Rotation in Self-Assembled Multidecker Porphyrin Complexes2011

    • Author(s)
      Hiro.Tanaka他5名
    • Journal Title

      ACS Nano

      Volume: 5 Pages: 9575-9582

    • DOI

      DOI:10.1021/nn203773p

    • Peer Reviewed
  • [Journal Article] Study on transport pathway in oxide nanowire growth by using spacing-controlled regular array2011

    • Author(s)
      A.Klamchuen他11名
    • Journal Title

      Appl. Phys. Lett

      Volume: 99 Pages: 193105(1-3)

    • DOI

      DOI:10.1063/1.3660246

    • Peer Reviewed
  • [Journal Article] Essential Role of Catalyst in Vapor-Liquid-Solid Growth of Compounds2011

    • Author(s)
      M.Suzuki他6名
    • Journal Title

      Phys. Rev. E

      Volume: 83 Pages: 061606(1-4)

    • DOI

      DOI:10.1103/PhysRevE.83.061606

    • Peer Reviewed
  • [Journal Article] Spatial Nonuniformity in Resistive-Switching Memory Effects of NiO2011

    • Author(s)
      K.Oka他6名
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133 Pages: 12482-12485

    • DOI

      DOI:10.1021/ja206063m

    • Peer Reviewed
  • [Journal Article] Intrinsic Mechanisms of Memristive Switching2011

    • Author(s)
      K.Nagashima他7件
    • Journal Title

      Nano Lett

      Volume: 11 Pages: 2114-2118

    • DOI

      DOI:10.1021/nl200707n

    • Peer Reviewed
  • [Journal Article] Dopant homogeneity and transport properties of impurity-doped oxide nanowires2011

    • Author(s)
      A.Klamchuen他9名
    • Journal Title

      Appl. Phys. Lett

      Volume: 98 Pages: 053107(1-3)

    • DOI

      DOI:10.1063/1.3549703

    • Peer Reviewed
  • [Journal Article] Interfacial Effect on Metal/Oxide Nanowire Junctions2010

    • Author(s)
      K.Nagashima他6名
    • Journal Title

      Applied Physics Letters

      Volume: 96 Pages: 073110(1-3)

    • DOI

      DOI:10.1063/1.3318257

    • Peer Reviewed
  • [Journal Article] Crucial Role of Doping Dynamics on Transport Properties of Sb-doped SnO2 Nanowires2009

    • Author(s)
      A.Klamchuen他6名
    • Journal Title

      Appl. Phys. Lett

      Volume: 95 Pages: 053105(1-3)

    • DOI

      DOI:10.1063/1.3318257

    • Peer Reviewed
  • [Journal Article] Specific Surface Effect on Transport Properties of MgO/NiO Heterostructured Nanowires2009

    • Author(s)
      K.Oka他8名
    • Journal Title

      Appl. Phys. Lett

      Volume: 95 Pages: 133110(1-3)

    • DOI

      DOI:10.1063/1.3237176

    • Peer Reviewed
  • [Journal Article] Non-volatile Bipolar Resistive Memory Switching in Single Crystalline NiO Heterostructured Nanowires2009

    • Author(s)
      K.Oka他4名
    • Journal Title

      J.Am.Chem.Soc

      Volume: 131 Pages: 3434-3435

    • DOI

      DOI:10.1021/ja8089922

    • Peer Reviewed
  • [Journal Article] Rapid fabrication of Teflon micropores for artificial lipid bilayer formation2009

    • Author(s)
      M.Kitta, Hiro.Tanaka, T.Kawai
    • Journal Title

      Biosensors and Bioelectronics

      Volume: 4 Pages: 518-522

    • DOI

      DOI:10.1016/j.bios.2009.08.021

    • Peer Reviewed
  • [Journal Article] Enhancement of Oxide VLS Growth by Carbon on Substrate Surface2008

    • Author(s)
      T.Yanagida他7名
    • Journal Title

      J. Phys. Chem. C

      Volume: 112 Pages: 18923-18926

    • DOI

      DOI:10.1021/jp8073893

    • Peer Reviewed
  • [Presentation] Mechanism of Bipolar and Unipolar Resistive Switching on Metal Oxide Nanowires2012

    • Author(s)
      T.Kawai
    • Organizer
      2nd International Workshop on Resistive RAM
    • Place of Presentation
      Stanford University (Stanford, CA, USA)
    • Year and Date
      2012-10-09
  • [Presentation] Hetero-structured Metal Oxide Nanowires for Nanoelectronics2012

    • Author(s)
      T.Kawai
    • Organizer
      MFM-7
    • Place of Presentation
      Gamboa Rainforest Resort (Panama City, Panama)
    • Year and Date
      2012-08-07
  • [Presentation] General Strategy for Impurity Doping in VLS Growth of Semiconductor Metal Oxide Nanowires2012

    • Author(s)
      A.Klamchuen
    • Organizer
      2012 MRS Spring Meeting
    • Place of Presentation
      Moscone West Convention Center/Marriott Marquis (San Francisco, California, USA)
    • Year and Date
      2012-04-10
  • [Presentation] 創発原理に基づく新奇無機ナノワイヤ構造の創成2012

    • Author(s)
      柳田剛
    • Organizer
      分子ナノシステムの創発化学 第3回公開シンポジウム
    • Place of Presentation
      大阪科学技術センター(大阪府)
    • Year and Date
      2012-02-03
  • [Presentation] Ionic Transport Induced Nonvolatile Memory in a Single Oxide Nanowire2011

    • Author(s)
      T.Yanagida
    • Organizer
      ICE2011
    • Place of Presentation
      the University of New South Wales (Sydney, Australia)
    • Year and Date
      2011-12-14
  • [Presentation] Atomically controlled processing for Oxide Thin Films and Nanowires2011

    • Author(s)
      T.Kawai
    • Organizer
      ICE2011
    • Place of Presentation
      the University of New South Wales (Sydney, Australia)
    • Year and Date
      2011-12-13
  • [Presentation] NANOWIRED ReRAM2011

    • Author(s)
      T.Kawai
    • Organizer
      ICAMD 2011
    • Place of Presentation
      Ramada Plaza Jeju Hotel (Jeju, Korea)
    • Year and Date
      2011-12-08
  • [Presentation] Atomically controlled processing for Oxide Thin Films and Nanowires2011

    • Author(s)
      T.Kawai
    • Organizer
      ICAE 2011
    • Place of Presentation
      Ramada Plaza Jeju Hotel (Jeju, Korea)
    • Year and Date
      2011-11-08
  • [Presentation] Pt/TiO2/Pt極微メモリスタ素子特性の基底状態依存性2011

    • Author(s)
      長島一樹
    • Organizer
      2011年秋季 第72回 応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス(山形県)
    • Year and Date
      2011-09-01
  • [Presentation] ナノ制限空間を利用した不揮発性抵抗変化メモリ現象の動作メカニズム解析2011

    • Author(s)
      岡敬祐
    • Organizer
      2011年秋季 第72回 応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス(山形県)
    • Year and Date
      2011-09-01
  • [Presentation] メモリスタの物理起源2011

    • Author(s)
      長島一樹
    • Organizer
      2011年秋季 第72回 応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス(山形県)
    • Year and Date
      2011-08-30
  • [Presentation] NANOWIRED ReRAM for ADVANCED NANO-ELECTRONICS, NANO KOREA 20112011

    • Author(s)
      T.Kawai
    • Organizer
      The 9th International Nanotech Exhibition in Korea
    • Place of Presentation
      KINTEX (Goyang-si, Korea)
    • Year and Date
      2011-08-25
  • [Presentation] Intrinsic nature of nonvolatile resistive switching extracted by a single oxide nanowire2011

    • Author(s)
      K.Nagashima
    • Organizer
      ISSP 2011
    • Place of Presentation
      KRP (Kyoto)
    • Year and Date
      2011-07-08
  • [Presentation] Crucial role of impurity doping dynamics on transport properties of VLS grown SnO2 nanowires2011

    • Author(s)
      A.Klamchuen
    • Organizer
      ISSP 2011
    • Place of Presentation
      KRP (Kyoto)
    • Year and Date
      2011-07-06
  • [Presentation] Resistive Switching in a Single Oxide Nanowire, Anhui Institute of Optics and Fine Mechanics2011

    • Author(s)
      T.Yanagida
    • Organizer
      Chinese Academy of Science Seminar
    • Place of Presentation
      Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Science (Hefei, China)
    • Year and Date
      2011-05-27
  • [Presentation] Nanotechnology for advanced devices---Thin film formation, nanofabrication and device application in electronics and biotechnology---2011

    • Author(s)
      T.Kawai
    • Organizer
      Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Science Seminar
    • Place of Presentation
      Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Science (Hefei, China)
    • Year and Date
      2011-05-27
  • [Presentation] Extraction of Localized Non-volatile Memory Switching using MgO/Cobalt Oxide Heterostructured Nanowire2010

    • Author(s)
      K.Nagashima
    • Organizer
      The 13th SANKEN International Symposium 2009 / The 8th SANKEN Nanotechnology Symposium / The 3rd SANKEN MSTEC Symposium / The 2nd SANKEN Alliance Symposium
    • Place of Presentation
      関西空港国際会議場 (Osaka)
    • Year and Date
      20100118-19
  • [Presentation] Redox Reactions of Non-volatile Bipolar Resistive Memory Switching in Single Crystalline NiO Heterostructured Nanowire2010

    • Author(s)
      K.Oka
    • Organizer
      The 13th SANKEN International Symposium 2009 / The 8th SANKEN Nanotechnology Symposium / The 3rd SANKEN MSTEC Symposium / The 2nd SANKEN Alliance Symposium
    • Place of Presentation
      関西空港国際会議場 (Osaka)
    • Year and Date
      20100118-19
  • [Presentation] Impurity induced mesostructures of Sb doped SnO2 Nanowires2010

    • Author(s)
      A.Klamchuen
    • Organizer
      The 13th SANKEN International Symposium 2009 / The 8th SANKEN Nanotechnology Symposium / The 3rd SANKEN MSTEC Symposium / The 2nd SANKEN Alliance Symposium
    • Place of Presentation
      関西空港国際会議場 (Osaka)
    • Year and Date
      20100118-19
  • [Presentation] Fabrication and magnetic properties of one and two dimensional metal oxides2010

    • Author(s)
      T.Kawai
    • Organizer
      11th Joint MMM-Intermag
    • Place of Presentation
      Washington Marriott Wardman Park (Columbia, USA)
    • Year and Date
      2010-01-22
  • [Presentation] Non-Volatile Resistive Switching Memory Effects In Single Oxide Nanowire2009

    • Author(s)
      T.Yanagida
    • Organizer
      WCU International Conference on Quantum Phases and Devices
    • Place of Presentation
      Konkuk University (Seoul, Korea)
    • Year and Date
      20091028-30
  • [Presentation] Self-Assembling Oxide Nanowires: Growth Mechanisms and the Impact on Transport Properties of Impurity-Doped Nanowires2009

    • Author(s)
      T.Yanagida
    • Organizer
      16th International Workshop on Oxide Electronics
    • Place of Presentation
      Palau Firal i de Congressos de Tarragona (Catalonia, Spain)
    • Year and Date
      20091005-06
  • [Presentation] Resistive Switching Phenomena in MgO/CO4 Core/shell Nanowires2009

    • Author(s)
      K.Nagashima
    • Organizer
      16th International Workshop on Oxide Electronics
    • Place of Presentation
      Palau Firal i de Congressos de Tarragona (Catalonia, Spain)
    • Year and Date
      20091005-06
  • [Presentation] Non-volatile Resistive Switching in Individual MgO/NiO Heterostructured Nanowire2009

    • Author(s)
      K.Oka
    • Organizer
      16th International Workshop on Oxide Electronics
    • Place of Presentation
      Palau Firal i de Congressos de Tarragona (Catalonia, Spain)
    • Year and Date
      20091005-06
  • [Presentation] Non-volatile Memory Switching using Atomically Controlled MgO/Co3O4 Heterostructured Nanowires2009

    • Author(s)
      K.Nagashima
    • Organizer
      Second International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka University Nakanoshima Center (Osaka)
    • Year and Date
      2009-11-26
  • [Presentation] 今後の展開2009

    • Author(s)
      川合知二
    • Organizer
      2009年秋季 第70回 応用物理学会 学術講演会
    • Place of Presentation
      University of Toyama (Toyama)
    • Year and Date
      2009-09-09
  • [Presentation] Mechanism of Nonvolatile Bipolar Resistive Memory Switching in MgO/Co3O4 Nanowire and Multi-storage Memory Application2009

    • Author(s)
      K.Nagashima
    • Organizer
      5th Handai Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Osaka University (Osaka)
    • Year and Date
      2009-09-02
  • [Presentation] Crucial Role of Doping Dynamics on Transport Properties of Sb-Doped SnO2 Nanowires2009

    • Author(s)
      T.Yanagida
    • Organizer
      5th Handai Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Osaka University (Osaka)
    • Year and Date
      2009-09-02
  • [Presentation] Non-Volatile Resistive Memory Switching in Individual MgO/NiO Heterostructured Nanowire2009

    • Author(s)
      K.Oka
    • Organizer
      5th Handai Nanoscience and Nanotechnology, International Symposium
    • Place of Presentation
      Osaka University (Osaka)
    • Year and Date
      2009-09-02
  • [Presentation] Non-volatile Unipolar Memory Switching in TiO2 Heteronanowire2009

    • Author(s)
      K.Nagashima
    • Organizer
      ISSP 2009
    • Place of Presentation
      金沢国際ホテル (Kanazawa)
    • Year and Date
      2009-07-10
  • [Presentation] Non-volatile Bipolar Resistive Memory Switching in Single Crystalline NiO Heterostructured Nanowire2009

    • Author(s)
      K.Oka
    • Organizer
      ISSP 2009
    • Place of Presentation
      金沢国際ホテル (Kanazawa)
    • Year and Date
      2009-07-10
  • [Presentation] Metal Oxide Nanowires: Synthesis, Nano-properties and Device Applications2009

    • Author(s)
      T.Yanagida
    • Organizer
      ISSP 2009
    • Place of Presentation
      金沢国際ホテル (Kanazawa)
    • Year and Date
      2009-07-10
  • [Presentation] Metal Oxide Nanowires: Synthesis, Nano-properties and Non-volatile Memory Applications2009

    • Author(s)
      T.Yanagida
    • Organizer
      The 8th France-Japan Workshop on Nanomaterials
    • Place of Presentation
      NIMS (Tsukuba)
    • Year and Date
      2009-06-17
  • [Presentation] Nonvolatile Memory Effect in Heterostructured Nanowires of Metal Oxides2009

    • Author(s)
      K.Nagashima
    • Organizer
      The 8th France-Japan Workshop on Nanomaterials
    • Place of Presentation
      NIMS (Tsukuba)
    • Year and Date
      2009-06-17
  • [Presentation] Composite Nanostructures using Transition Metal Oxide Nanowires2009

    • Author(s)
      T.Kawai
    • Organizer
      ICCS15
    • Place of Presentation
      FEUP (Porto, Portugal)
    • Year and Date
      2009-06-15
  • [Presentation] Heterostructured Oxide Nanowires and Their Interface Properties2009

    • Author(s)
      T.Kawai
    • Organizer
      MRS Spring Meeting
    • Place of Presentation
      San Francisco Marriott (California, USA)
    • Year and Date
      2009-04-15
  • [Presentation] Heterostructured Oxide Nanowires and Their Interface Properties2009

    • Author(s)
      T.Kawai
    • Organizer
      MRS 2009 Spring Meeting
    • Place of Presentation
      Moscone West,San Francisco Marriott (San Francisco, USA)
    • Year and Date
      2009-04-15
  • [Remarks]

    • URL

      http://www.sanken.osaka-u.ac.jp/jp/organization/da/da_02.html

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Published: 2014-08-29  

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