Design of soft-supramolecular systems based on metal complexes

2010 Fiscal Year Self-evaluation Report

• Project Area: Emergent Chemistry of Nano-scale Molecular System
• Project/Area Number: 20111008
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyushu University
• Principal Investigator: KIMIZUKA Nobuo Kyushu University, 大学院・工学研究院, 教授 (90186304)
• Project Period (FY): 2008 – 2012
• Keywords: ナノ材料 / 複合材料・物性 / 超分子化学 / 自己組織化

Research Abstract

本研究は、分子の自己組織化に基づいてナノスケールの散逸構造を構築するための方法論を開拓し、分子システムにおける創発化学を具現化することを目的とする。従来の超分子化学や材料科学は、熱力学的平衡条件を暗黙の前提として展開されてきた。一方、非平衡系における分子集合により、ナノレベルの散逸構造や非線形現象を導き出すことは創発化学を開拓する上で本質的な問題である。

Research Products

• [Journal Article] Water/Ionic Liquid Inter faces as Fluid Scaffolds for Two-Dimensional Self-Assembly of Charged Nanospheres. (2011)
  • Author(s): T.Nakashima, N.Kimizuka
  • Journal Title: Langmuir 27(4) Pages: 1281-1285
  • Peer Reviewed
• [Journal Article] Aqueous Nanospheres Self-Assembled from Hyper branched Polymers and Silver Ions : Molecular Inclusion and Photoreduction Characteristics. (2010)
  • Author(s): M-a.Morikawa, K.Kim, H.Kinoshita, K.Yasui, Y.Kasai, N.Kimizuka
  • Journal Title: Macromolecules 43(2) Pages: 8971-8976
  • Peer Reviewed
• [Journal Article] Synthesis of Lipophilic Gold Nanosheetsby Using Reducing Stabilizers and Their Reversible Transformation between GoldenSolid. (2010)
  • Author(s): R.Kuwahara, K.Kuroiwa , N.Kimizuka
  • Journal Title: Chem.Lett. 39 Pages: 26-227
  • Peer Reviewed
• [Journal Article] Holey Gold Nanowires Formed by Photo conversion of Dissipative Nanostructures Emerged at the Aqueous-Organic Interface. (2009)
  • Author(s): T.Soejima, M.Morikawa, N.Kimizuka
  • Journal Title: Small 5(18) Pages: 2043-2047
  • Peer Reviewed
• [Journal Article] One-PotRoom-Temperature Synthesis of Single-Crystalline Gold Nanocorolla inWater. (2009)
  • Author(s): T.Soejima, N.Kimizuka
  • Journal Title: J.Am.Chem.Soc. 131(40) Pages: 14407-14412
  • Peer Reviewed
• [Presentation] Amphiphilic core-shell structured nano particles self-assembled fromhydrophobic hyperbranched polymers andsilver ions (2010)
  • Author(s): M-a.Morikawa, K.Kim, H.Kinoshita, K.Yasui, Y.Kasai, N.Kimizuka
  • Organizer: The 2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM2010)
  • Place of Presentation: Hawaii Convention Center, Honolulu, Hawaii, USA
  • Year and Date: 2010-12-17
• [Presentation] Self-assembly in softcoordination nanosystems (2010)
  • Author(s): N.Kimizuka
  • Organizer: The 2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM2010)
  • Place of Presentation: Hawaii Convention Center, Honolulu, Hawaii, USA
  • Year and Date: 2010-12-16
• [Presentation] Adaptive Self-Assembly in Coordination Nanoparticles of Nucleotides (2010)
  • Author(s): N.Kimizuka
  • Organizer: The 3rd International NanoBio 2010 Conference 2010
  • Place of Presentation: ETH Zurich, Switzerland
  • Year and Date: 2010-08-26
• [Presentation] Interfacial Self-Assembly for Dissipative- and Kinetically Controlled Nanostructures (2010)
  • Author(s): N.Kimizuka
  • Organizer: International Symposium on Macrocyclic and Supramolecular Chemistry : ISMSC
  • Place of Presentation: Nara Prefectural New Public Hall, Nara
  • Year and Date: 2010-06-10
• [Presentation] イオン液体/水界面における非平衡拡散プロセスを利用した超分子ナノファイバーの形成と形態制御 (2010)
  • Author(s): 森川全章・君塚信夫
  • Organizer: 新学術領域第1回公開シンポジウム
  • Place of Presentation: キャンパスプラザ京都
  • Year and Date: 2010-05-05
• [Presentation] 金属錯体を基盤とするソフト分子システムの開発 (2009)
  • Author(s): 君塚信夫
  • Organizer: 新学術領域全体会議
  • Place of Presentation: 札幌
  • Year and Date: 2009-08-21
• [Book] 超分子金属錯体 3.4.1 無限錯体とナノマテリアル化学 (2009)
  • Author(s): 君塚信夫
  • Total Pages: 319-331
  • Publisher: 三共出版
• [Book] Self-Assembly of Supramolecular Nano fibers (2008)
  • Author(s): Nobuo KIMIZUKA
  • Total Pages: 1-26
  • Publisher: Springer