2012 Fiscal Year Final Research Report
Construction of functionalized network architectures composed of molecular metal clusters
| Project Area | Emergent Chemistry of Nano-scale Molecular System |
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| Project/Area Number |
20111009
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Hokkaido University |
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Principal Investigator |
KONISHI Katsuaki 北海道大学, 大学院・地球環境科学研究院, 教授 (80234798)
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| Project Period (FY) |
2008 – 2012
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| Keywords | 結晶材料 / 自己組織化 / 分子認識 / 超分子 / クラスター / 発光材料 |
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| Research Abstract |
In this research, we aimed to create metal cluster-based assemblies with defined morphologies. For this purpose, we xplored synthetic routes to various fundamental cluster units having defined geometric structures and compositions. By taking the emergent principle in the formation and transformation of metal cluster species, we have succeeded in the syntheses of novel diphosphine-coordinated molecular gold clusters with unique geometric and optical features. We also studied the cluster functionalization and the construction of cluster assemblies.
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