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2012 Fiscal Year Final Research Report

Development of new electronic and photonic devices by controlling the interface of molecular nano-system.

Planned Research

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Project AreaEmergent Chemistry of Nano-scale Molecular System
Project/Area Number 20111014
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionOsaka University

Principal Investigator

AKAI Megumi  大阪大学, 大学院・工学研究科, 助教 (50437373)

Co-Investigator(Kenkyū-buntansha) SAITO Akira  大阪大学, 大学院・工学研究科, 准教授 (90294024)
KUWAHARA Yuji  大阪大学, 大学院・工学研究科, 教授 (00283721)
Project Period (FY) 2008 – 2012
Keywords分子デバイス / ナノテクノロジー / 一分子科学 / キラリティ / 確率共鳴
Research Abstract

We investigated the emergence of new phenomena at a heterologous interface between well-controlled molecular assembly and good conductor materials. A coulomb blockade transport emerged in continuous polymer layer has been found, and its model was proposed. The investigation of circularly-polarized light emission from molecules adsorbed on solid surface provided a new finding of assembled chiral structure of a few molecules. Furthermore, we successfully achieved a development of new stochastic resonance device, which functions effectively in two terminals, by using multiple pass effect and redox phenomena of single molecule at interface.

  • Research Products

    (35 results)

All 2013 2012 2011 2010 2009 2008

All Journal Article (15 results) Presentation (18 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Verification of Thermal Effect produced by Irradiation for Scanning Tunneling Microscope combined with Brilliant Hard X-rays from Synchrotron Radiation2012

    • Author(s)
      A. Saito, Y. Tanaka, Y. Kohmura, M.Akai-Kasaya, T. Ishikawa, Y. Kuwahara, . and M. Aono
    • Journal Title

      Current Applied Physics

      Volume: 12 Pages: S52-S56

  • [Journal Article] Development and Application of Multiple-Probe Scanning Probe Microscopes2012

    • Author(s)
      Tomonobu Nakayama, Osamu Kubo, Yoshitaka Shingaya, Seiji Higuchi, Tsuyoshi Hasegawa, Chun-Sheng Jiang, Taichi Okuda, Yuji Kuwahara, Kazuhiro Takami, Masakazu Aono
    • Journal Title

      Adv. Mater

      Volume: 24, 13 Pages: 1675-1692

  • [Journal Article] Controlled chain polymerisation and chemical soldering for singlemolecule electronics2012

    • Author(s)
      Yuji Okawa, Megumi Akai-Kasaya, Yuji Kuwahara, Swapan K. Mandal and Masakazu Aono
    • Journal Title

      Nanoscale

      Volume: 4, 10 Pages: 3013-3028

  • [Journal Article] Electrical conduction of organic ultrathin films evaluated by an independently driven double-tip scanning tunneling microscope2011

    • Author(s)
      K Takami, S Tsuruta, Y Miyake, M.Akai-Kasaya, A Saito, M Aono and Y Kuwahara
    • Journal Title

      J. Phys.: Condens. Matter

      Volume: 23, 43 Pages: 434002 (6pp)

  • [Journal Article] STM-induced light emission from thin films of perylene derivatives on the HOPG and Au substrates2011

    • Author(s)
      Aya Fujiki, Yusuke Miyake, Yasushi Oshikane, Megumi Akai-Kasaya, Akira Saito and Yuji Kuwahara
    • Journal Title

      Nanoscale Research Letters

      Volume: 6 Pages: 347

  • [Journal Article] Enhanced Red-Light Emission by Local Plasmon Coupling of Au Nanorods in an Organic Light-Emitting Diode2011

    • Author(s)
      Takuya Tanaka, Yuji Totoki, Aya Fujiki, Nobuyuki Zettsu, Yusuke Miyake, Megumi Akai-Kasaya, Akira Saito, Takuji Ogawa, and Yuji Kuwahara
    • Journal Title

      Applied Physics Express

      Volume: 4 Pages: 032105

  • [Journal Article] Numerical analysis on the optical role of nano-randomness on the Morpho butterfly's scale2011

    • Author(s)
      Akira Saito, Masaru Yonezawa, Junichi Murase, Saulius Juodkazis, Vygantas Mizeikis, Megumi Akai-Kasaya, and Yuji Kuwahara
    • Journal Title

      J. Nanosc. Nanotechnol

      Volume: 11, 4 Pages: 2785

  • [Journal Article] Charge-carrier injection into pentacene thin film formed on Si(111) probed by STM spectroscopy2011

    • Author(s)
      Megumi Akai-Kasaya, Noriko Shimada, Akira Saito and Yuji Kuwahara
    • Journal Title

      J. Nanosc. Nanotechnol

      Volume: 11, 4 Pages: 2867

  • [Journal Article] Molecular scale control of unbound and bound C60 for topochemical ultradense data storage in an ultrathin C60 film2010

    • Author(s)
      M. Nakaya, S. Tsukamoto, Y. Kuwahara, M. Aono and T. Nakayama
    • Journal Title

      Adv. Mater

      Volume: 22, 14 Pages: 1622-1625

  • [Journal Article] Direct observation of X-ray induced Atomic Motion using STM combined with Synchrotron Radiation2010

    • Author(s)
      A. Saito, T. Tanaka, Y. Takagi, H. Hosokawa, H. Notsu, G. Ohzeki, Y. Tanaka, Y. Kohmura, M. Akai-Kasaya, T. Ishikawa, Y. Kuwahara, S. Kikuta, and M. Aono
    • Journal Title

      J. Nanosc. Nanotechnol

      Volume: 11, 4 Pages: 2873-2881(9)

  • [Journal Article] Enhanced fluorescence by surface plasmon coupling of Au nanoparticles in an organic electroluminescence diode2010

    • Author(s)
      A. Fujiki, T. Uemura, N. Zettsu, M.Akai-Kasaya, A. Saito, and Y.Kuwahara
    • Journal Title

      Appl. Phys. Lett

      Volume: 96 Pages: 43307-43309

  • [Journal Article] ナノギャップ平坦電極と一次元分子細線2009

    • Author(s)
      赤井恵
    • Journal Title

      Electrochemistly

      Volume: 77 Pages: 894-898

  • [Journal Article] 誘電多層構造によるモルフォ蝶型発色膜の作製2009

    • Author(s)
      齋藤彰、宮村友輔、石川陽子、村瀬淳一、赤井恵、桑原裕司
    • Journal Title

      J. Vac. Soc. Jpn

      Volume: 52, 4 Pages: 218-223

  • [Journal Article] Formation of amorphous sapphire by a femtosecond laser pulse inducedmicro-explosion2009

    • Author(s)
      Vygantas Mizeikis, Shigeru Kimura, Nikolay V. Surovtsev, Vygandas Jarutis, Akira Saito, Hiroaki Misawa and Saulius Juodkazis
    • Journal Title

      Appl. Surf. Sci

      Volume: 255 Pages: 9745-9749

  • [Journal Article] 導電性高分子を用いた分子ワイヤ素子の開発2009

    • Author(s)
      赤井恵、桑原裕司
    • Journal Title

      化学工業

      Volume: 60 Pages: 227-232

  • [Presentation] Simulatio n analysis on the optical role of the various structural disorder in the Morpho butterfly's color2013

    • Author(s)
      Akira SAITO, M.Yonezawa, T.Shibuya, M.Akai-Kasaya,Y.Kuwahara
    • Organizer
      SPIE Smart Structures and Materials & Nondestructive Evaluation and Health Monitoring
    • Place of Presentation
      Town and Country Resort and Convention Center, San Diego, California, USA
    • Year and Date
      20130310-14
  • [Presentation] on-equilibrium structural fluctuation of one-dimensional polydiacetylene nanowire2013

    • Author(s)
      Megumi Akai-Kasaya, Yuji Kuwahara, Masakazu Aono
    • Organizer
      The Symposium on Surface and Nano Science 2013 (SSNS'13)
    • Place of Presentation
      Hotel Jurin, Yamagata, Japan
    • Year and Date
      20130115-18
  • [Presentation] Nanoscale elemental analysis and applications using STM combined with brilliant hard X-rays2012

    • Author(s)
      Akira SAITO, T. Tanaka, H. Matsuno, H. Miki, Y. Furudate, Y. Takagi, M.Akai-Kasaya, Y. Tanaka, Y. Kohmura, T. Ishikawa, Y. Kuwahara and M. Aono
    • Organizer
      The 13th edition of Trends in Nanotechnology International Conference (TNT2012)
    • Place of Presentation
      Escuela Tecnica Superior de Ingenieros Industriales (ETSII Madrid - UPM)
    • Year and Date
      20120910-14
  • [Presentation] Reproduction & Applications of the Morpho-Butterfly's Specific Colors2012

    • Author(s)
      Akira SAITO, M.Yonezawa, T.Shibuya, K.Ishibashi, M.Akai-Kasaya, Y.Kuwahara
    • Organizer
      AsiaNANO 2012 (6th in the series of Asian Conference on Nanoscience & Nanotechnology )
    • Place of Presentation
      Crowne Plaza Lijiang Ancient Town Lijiang, Yunnan, China
    • Year and Date
      20120907-10
  • [Presentation] Nonlinear charge transport in two-dimensional polymer monolayer2012

    • Author(s)
      M. Akai-Kasaya, S. Nagano, A. Saito and Y. Kuwahara
    • Organizer
      AsiaNANO 2012 (6th in the series of Asian Conference on Nanoscience & Nanotechnology )
    • Place of Presentation
      Crowne Plaza Lijiang Ancient Town Lijiang, Yunnan, China
    • Year and Date
      20120907-10
  • [Presentation] Large area & high-speed reproduction of the Morpho butterfly's color for true practical applications2012

    • Author(s)
      Akira SAITO, M.Yonezawa, T.Shibuya, M.Akai-Kasaya, Y.Kuwahara
    • Organizer
      SPIE Smart Structures and Materials & Nondestructive Evaluation and Health Monitoring
    • Place of Presentation
      Town and Country Resort and Convention Center, San Diego, California, USA
    • Year and Date
      20120311-15
  • [Presentation] Nonlinear transport in two-dimensional polymer monolayer2012

    • Author(s)
      M. Akai-Kasaya, Y. Okuaki, S. Nagano, A. Saito and Y. Kuwahara
    • Organizer
      Symposium on Surface and Nano Science 2012
    • Place of Presentation
      Shizukuishi Prince Hotel, Shizukuishi, Shizukuishi, Iwate, Japan
    • Year and Date
      20120109-12
  • [Presentation] 局在表面プラズモン共鳴による有機 LEDの高効率化2012

    • Author(s)
      桑原 裕司
    • Organizer
      情報機構「プラズモン」セミナー
    • Place of Presentation
      江東区産業会館 2階第 5展示室
    • Year and Date
      2012-01-23
  • [Presentation] Large-area high-throughput reproduction of the Morpho butterfly's color by laser ablation for practical applications2011

    • Author(s)
      Akira SAITO, M.Yonezawa, J.Murase, M.Akai-Kasaya, Y.Kuwahara
    • Organizer
      SPIE Smart Nano-Micro Materials and Devices
    • Place of Presentation
      Swinburne University of Technology, Melbourne
    • Year and Date
      20111205-07
  • [Presentation] High Resolution Chemical Analyses using Synchrotron Radiation for Medical Applications2011

    • Author(s)
      A. Saito, G. Ohzeki, H. Matsuno, Y. Takagi, Y. Tanaka, Y. Kohmura, M. Akai-Kasaya, T. Ishikawa, Y. Kuwahara, and M. Aono
    • Organizer
      The 5th China Medical Biotech Forum, (CMBF-2011)
    • Place of Presentation
      Beijing International Convention Center, China
    • Year and Date
      20111107-09
  • [Presentation] Nano-scale Elemental Analysis and applications by Synchrotron-Radiation-based STM2011

    • Author(s)
      A. Saito, G. Ohzeki, H. Matsuno, Y. Takagi, Y. Tanaka, Y. Kohmura, M. Akai-Kasaya, T. Ishikawa, Y. Kuwahara, and M. Aono
    • Organizer
      Nano-S & T (BIT's 1st World Annual Congress)
    • Place of Presentation
      World Expo Center, Dalian, China
    • Year and Date
      20111023-26
  • [Presentation] 有機材料の電気伝導‐単結晶から単分子膜へ‐2011

    • Author(s)
      桑原裕司
    • Organizer
      「単分子エレクトロニクスの現状認識と近未来実現へ向けての中核体制構築」2011年度第2回研究会
    • Place of Presentation
      国際高等研究所, 京都
    • Year and Date
      20111021-22
  • [Presentation] Elemental Analysis at 1 nm Scale by STM combined with Highly Brilliant HardX-rays2011

    • Author(s)
      齋藤彰,野津浩史, 田中武拓, 高木康多,大関豪三,田中義人,香村芳樹,赤井恵,石川哲也, 辛埴, 桑原裕司, 青野正和
    • Organizer
      第66回物理学会年次大会
    • Place of Presentation
      富山大学
    • Year and Date
      20110922-24
  • [Presentation] Advances in Theoretical & Application Studies on the Specific Photonic Properties of Morpho-butterfly's Color2011

    • Author(s)
      Akira SAITO, J.Murase, M.Yonezawa, M.Akai-Kasaya, Y.Kuwahara
    • Organizer
      The 11th International Symposium. on biomimetic Materials Processing
    • Place of Presentation
      Nagoya Univ., Nagoya, Japan
    • Year and Date
      20110125-28
  • [Presentation] Applications of Morpho-butterfly's strange blue based on Nano-randomness2010

    • Author(s)
      A. Saito, J. Murase, M. Yonezawa, M. Akai-Kasaya and Y. Kuwahara
    • Organizer
      1st Korea-Japan Symposium on Surface Technology
    • Place of Presentation
      Songdo Park Hotel, Incheon, Korea
    • Year and Date
      20101125-26
  • [Presentation] Optical and transport properties in molecular nanosystems observed by STM-based techniques2010

    • Author(s)
      Y. Kuwahara, M. Akai-Kasaya, A. Saito
    • Organizer
      Trends in Nanotechnology (TNT) 2010
    • Place of Presentation
      International Iberian Nanotechnology Laboratory, Braga, Portugal
    • Year and Date
      20100906-10
  • [Presentation] 分子ナノシステムの物性探索と素子応用2010

    • Author(s)
      赤井恵
    • Organizer
      第65回物理学会年次大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-26
  • [Presentation] Metal transition of one-dimensional polymer nanowire2008

    • Author(s)
      M. Akai-Kasaya, Y. Kuwahara and M. Aono
    • Organizer
      International Workshop on Superconductivity in Diamond and Related Materials
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      20080707-09
  • [Patent(Industrial Property Rights)] 単一有機分子の酸化還元反応を利用した二端子多経路確率共鳴素子2012

    • Inventor(s)
      赤井恵、桑原裕司、松本卓也 、川合知二
    • Industrial Property Rights Holder
      大阪大学
    • Industrial Property Number
      特許、(K20120167)
    • Filing Date
      2012-08-30
  • [Patent(Industrial Property Rights)] 有機電界発光素子、および有機電界発光素子の製造方法2010

    • Inventor(s)
      是津信之、桑原裕司、植村隆文、藤喜彩、田中琢也、赤井恵
    • Industrial Property Rights Holder
      大阪大学
    • Industrial Property Number
      特許、PCT/JP2010/070882
    • Filing Date
      2010-11-24
    • Overseas

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Published: 2014-08-29   Modified: 2014-09-05  

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