2013 Fiscal Year Final Research Report
Precise Design and Control of Hierarchical Nanointerface Consisting of Molecular Building Blocks
| Project Area | Coordination Programming - Science of Molecular Superstructures for Chemical Devices |
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| Project/Area Number |
21108005
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kumamoto University |
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Principal Investigator |
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| Project Period (FY) |
2009-07-23 – 2014-03-31
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| Keywords | 自己組織化 / ナノ界面 / 走査型プローブ顕微鏡 / 単分子膜 / 金属配位結合 / ナノクラスター / 超分子 |
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| Research Abstract |
The research project was focused on design and creation of characteristic two- and three-dimensional nanoarchitechtures based on the "bottom-up assembly" at solid surfaces and on characterization of those adlayers using in situ scanning tunneling microscopy. We succeeded in forming a redox-active adlayer consisting of bisterpyridine derivative and cobalt ions, controlling the sizes and distributions of Pt and Pd nanoclusters on a highly ordered adlayer of polycyclic aromatic hydrocarbons, and constructing supramolecular assembly of fullerenes onto platinum(II) ocataethylporphyrin adlayer. The interfacial coordination programming was demonstrated at solid/liquid interface.
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Research Products
(38 results)
