2013 Fiscal Year Final Research Report
Development of Functional Organic and Inorganic Materials through Hierarchical Molecular Programming
| Project Area | Coordination Programming - Science of Molecular Superstructures for Chemical Devices |
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| Project/Area Number |
21108014
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Meijo University (2013)
The University of Tokyo (2009-2012) |
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Principal Investigator |
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| Project Period (FY) |
2009-07-23 – 2014-03-31
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| Keywords | ハイブリッド / プログラム / 自己集合 / 超分子化学 / 階層構造 |
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| Research Abstract |
From an idea to create a molecular assembly with unprecedented properties, Prussian blue, one of the porous metal complexes, has been successfully incorporated in inner space of one-dimensional molecular assemblies generated in low molecular-weight gels. Tetrasubstituted ferrocene having pyridyl groups at 1,1 ', 3,3' positions was designed to form self-assembled nanotube structure with silver (I) and ions, which has a uniform diameter of about 9 nm. Once Ferrocenes in the nanotube structure were oxidized to form ferrocenium ions by adding a suitable oxidizing agent, the ring structure was cut from the tubular structure and the reverse transformation was possible by the reduction of the ferrocenium ions in the ring structure.
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[Journal Article]2014
Author(s)
T.Fukino, H.Joo, Y.Hisada, M.Obana, H. Yamagishi, T.Hikima, M.Takata, N.Fujita, T.Aida
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Journal Title
Science
Volume: 344
Pages: 499-504
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[Journal Article]2010
Author(s)
T.Fukino, N.Fujita, T.AidaT.Fukino, N.Fujita, T.Aida
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Journal Title
Org. Lett.
Volume: 12
Pages: 3074-3077
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[Journal Article]2010
Author(s)
P.Mukhopadhyay, N.Fujita, A.Takada, T.Kishida, M.Shirakawa, S.Shinkai
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Journal Title
Angew. Chem. Int. Ed
Volume: 49
Pages: 6338-6342
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[Journal Article]2009
Author(s)
A.Dawn, N.Fujita, S.Haraguchi, K.Sada, S.-i.Tamaru S.Shinkai
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Journal Title
Org. Biomol. Chem
Volume: 7
Pages: 4378-4385
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[Journal Article]2009
Author(s)
A.Dawn, N.Fujita, S.Haraguchi, K.Sada, S.Shinkai
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Journal Title
Chem. Commun.
Pages: 2100-2102
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