2015 Fiscal Year Final Research Report
Efficient Transformation of Hydrocarbons Based on the Development of Designed Reactive Species
| Project Area | Molecule Activation Directed toward Straightforward Synthesis |
|---|
| Project/Area Number |
22105006
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
|
| Allocation Type | Single-year Grants |
|---|
| Review Section |
Science and Engineering
|
|---|
| Research Institution | Tokyo Institute of Technology |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2010-04-01 – 2016-03-31
|
| Keywords | 有機化学 / 合成化学 |
|---|
| Outline of Final Research Achievements |
In the present study, innovative synthetic reactions were developed based on the generation of novel reactive transition metal species using easily available hydrocarbons as starting material. Various useful reactions such as carbon-carbon bond forming reactions based on electrophilic activation of alkynes and allenes, PSiP-pincer palladium catalyzed dehydrogenative borylations, rhodium catalyzed direct carboxylation of aromatic C-H bonds, and generation of alkyl radicals from aldehydes using cobalt-salen complexes, and so on were realized. Exploration of the mechanism of these reactions clarified further unique characteristics of these reactions.
|
| Free Research Field |
有機合成化学
|
