2016 Fiscal Year Final Research Report
Development of Synthetic Methods of Versatile Elements-block Polymers Based on Polymer Reactions
| Project Area | Creation of Element-Block Polymer Materials |
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| Project/Area Number |
24102007
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2012-06-28 – 2017-03-31
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| Keywords | 高分子合成 / 合成化学 / 高分子反応 / π共役高分子 / 元素ブロック / 機能性高分子 / 太陽電池 / 有機導体 |
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| Outline of Final Research Achievements |
π-Conjugated polymers possessing diverse elements and elements-blocks are attractive materials for advanced optoelectronic applications. Due to the highly reactive nature of the elements-containing building blocks, however, most of these materials are hardly accessible by the conventional synthetic methods such as the transition metal-catalyzed polycondensation technique.
We have established the synthesis method of novel π-conjugated polymers possessing various elements-blocks units by polymer reactions of regioregular organometallic polymers possessing reactive titanacyclopentadiene units with the electrophilic reagents possessing element-blocks. Their applications to opto-electronic devices have also been performed to demonstrate their excellent features originated from the elements-blocks.
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| Free Research Field |
高分子合成
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