2016 Fiscal Year Final Research Report
Properties and Structural Control of Surface/Interface of Polymeric Materials based on Element-blocks
| Project Area | Creation of Element-Block Polymer Materials |
|---|
| Project/Area Number |
24102009
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
|
| Allocation Type | Single-year Grants |
|---|
| Review Section |
Science and Engineering
|
|---|
| Research Institution | Kobe University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
本郷 千鶴 神戸大学, 学内共同利用施設等, 助教 (10418767)
松本 拓也 神戸大学, 工学(系)研究科(研究院), 助教 (70758078)
小寺 賢 神戸大学, 工学(系)研究科(研究院), 助教 (80403301)
|
|---|
| Project Period (FY) |
2012-06-28 – 2017-03-31
|
| Keywords | 界面・表面 / 高分子構造 / 高分子物性 / 接着 / ゴム弾性 / 結晶弾性率 / 元素ブロック高分子 / 撥水 |
|---|
| Outline of Final Research Achievements |
Properties and structural control of surface/interface, mechanical properties, conductivity of various polymer based on element-blocks were investigated. As an element-block, fluorine, sulfur, silane were introduced into polymer in the main chain and/or side chains in this study. We could succeed to find peculiar outstanding novel properties as shown below:
1) Preparation of high water-repellent but high adhesive polymer surface with fluorine,2)Preparation of high molecular weight, high modulus, high water repellent polythiphene, 3) Synthesis of high elongation, high conductive polythiophene, These polymer/ phenomena have not yet observed, which could be only achieved using polymeric materials based on element-blocks.
In addition, many methods were employed to investigate 4) adhesion and polyolefin / polysilane interface. Polyolefin and polysilane are chemically quite different, but polysilane is a good adhesive to polyolefin, which was brought by thick interface (interphase).
|
| Free Research Field |
高分子物性
|
