2016 Fiscal Year Final Research Report
Creation of stimuli-responsive metal complexes based on the ligand properties of low-coordinate boryl anion and their catalytic function
| Project Area | Stimuli-responsive Chemical Species for the Creation of Functional Molecules |
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| Project/Area Number |
24109012
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Nagoya University (2016)
Chuo University (2012-2015) |
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Principal Investigator |
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| Project Period (FY) |
2012-06-28 – 2017-03-31
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| Keywords | ホウ素 / 多座配位子 / 後周期遷移金属錯体 / 触媒反応 / アルカン / 脱水素 / 酸化 |
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| Outline of Final Research Achievements |
Throughout this research, we obtained the following research results. (1) Five kinds of ligands were newly added to the library of boron-containing pincer ligand by using a novel synthetic methods. (2) We have succeeded in synthesis of the corresponding complexes by introduction of platinum, ruthenium, rhodium, and iridium into the PBP ligands in the library and have elucidated their properties. (3) Hydrosilylation of alkene progresses with PBP platinum catalyst, hydrogenation of aldehyde proceeds with PBP ruthenium catalyst, and dehydrogenation of alkane and dimethylamine-borane proceeds with PBP iridium catalyst.
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| Free Research Field |
有機典型元素化学・有機金属化学・均一系触媒
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