2016 Fiscal Year Final Research Report
Creation of Novel Catalysts Centered on the Coordination Diversity of Heavy Typical Elements
| Project Area | Stimuli-responsive Chemical Species for the Creation of Functional Molecules |
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| Project/Area Number |
24109013
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
SASAMORI Takahiro 京都大学, 化学研究所, 准教授 (70362390)
MIZUHATA Yoshiyuki 京都大学, 化学研究所, 助教 (30437264)
AGOU Tomohiro 京都大学, 化学研究所, 助教 (90466798)
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| Project Period (FY) |
2012-06-28 – 2017-03-31
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| Keywords | キレート配位子 / 低配位化学種 / 立体保護 / 触媒 / 高周期典型元素 |
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| Outline of Final Research Achievements |
To develop the novel catalysts utilizing the coordination/oxidation state diversity of heavy typical elements, the design, synthesis, and elucidation of the properties of novel low-valent heavy group 13 and 14 compounds and ligand systems containing heavy group 15 elements were investigated. We have revealed the synthesis of novel low-valent phosphorus ligands, the application of triphospha[3]radialene as a ligand, the synthesis of novel silyliumylidene species, novel transformation reactions using digermyne, and the activation of dihydrogen by aluminum compounds at ordinary temperatures and pressures.
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| Free Research Field |
有機元素化学
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