Theoretical Studies on State Change of Enzymatic and Catalytic Species and Activity Control

2016 Fiscal Year Annual Research Report

• Project Area: Stimuli-responsive Chemical Species for the Creation of Functional Molecules
• Project/Area Number: 24109014
• Research Institution: Kyushu University
• Principal Investigator: 吉澤 一成 九州大学, 先導物質化学研究所, 教授 (30273486)
• Project Period (FY): 2012-06-28 – 2017-03-31
• Keywords: 量子化学 / 生体関連化学 / 金属酵素 / 電子物性 / 酵素反応

Outline of Annual Research Achievements

新学術領域「感応性化学種が拓く新物質科学」のA04班の計画班長として本研究に参画し、酵素触媒反応種の状態変化と活性制御に関する理論的研究を推進した。酵素触媒反応の原動力となる金属活性種の構造と反応性について探索するため、実験研究者との共同研究体制の下に量子化学計算および分子力学計算による理論研究を展開した。理論計算化学は、実験的に観測困難な化学種の構造、反応、物性の研究に極めて有効な手段であり、最近の最先端研究における理論計算の役割は極めて重要である。本研究では理論計算化学の立場から、高周期典型元素と遷移元素を活性中心にもつ酵素反応系およびモデル系を対象として、実在系に生成する感応性化学種の発見に努めた。また、大規模量子化学計算を用いて活性中心の周辺環境や反応過程に応じて状態を変化させる感応性化学種の発見と、それらが受ける摂動メカニズムの解明に寄与した。本研究では、とくに金属酵素と関連するモデル錯体について、酸化反応などの生体模倣反応やタンパク質間相互作用の機構を領域内の実験グループと連携して研究を行った。密度汎関数法やQM/MM法により現実系の大規模計算を行い、酵素触媒反応種の構造と分光学的研究を行った。反応過程で生成する中間体のスピン状態変化およびタンパク質中での電子移動が、金属の関与する酵素触媒反応を理解するための鍵となることを明らかにした。実験による不安定活性種の観測は困難なため、量子化学計算は有効な研究手段となることを示した。平成28年～29年には46報の原著論文を報告した。その内、複数のグループとの領域内共同研究は16報の論文として発表され、領域内共同研究の推進に貢献した。

Research Progress Status

28年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

28年度が最終年度であるため、記入しない。

Research Products

• [Int'l Joint Research] El-Menoufia University(エジプト)
  • Country Name: EGYPT
  • Counterpart Institution: El-Menoufia University
• [Journal Article] Electrical conductivity of dithiophene-based diblock molecular Junctions (2017)
  • Author(s): A. El-Nahas, A. Gamea, M. M. El-Hendawy, and K. Yoshizawa
  • Journal Title: Comp. Theoret. Chem. Volume: 1099 Pages: 64-74
  • DOI: 10.1016/j.comptc.2016.11.012
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Anisotropic Change in Magnetic Susceptibility of a Dynamic Single Crystal of Cobalt(II) Complex (2017)
  • Author(s): Z.-S. Yao, S.-Q. Wu, Y. Kitagawa, S.-Q. Su, Y.-G. Huang, G.-L. Li, Z.-H. Ni, H. Nojiri, Y. Shiota, K. Yoshizawa, S. Kang, S. Kanegawa, O. Sato
  • Journal Title: Angew. Chem. Int. Ed. Volume: 56 Pages: 717-721
  • DOI: 10.1002/anie.201606165
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Acid-Base Properties of a Freebase Form of a Quadruply-Ring-Fused Porphyrin-Stepwise Protonation Induced by Rigid Ring-Fused Structure (2017)
  • Author(s): T. Ishizuka, Y. Saegusa, Y. Shiota, K. Yoshizawa, T. Kojima
  • Journal Title: J. Org. Chem. Volume: 82 (1) Pages: 322-330
  • DOI: 10.1021/acs.joc.6b02419
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Electrical Conductance and Diode-Like Behavior of Substituted Azulene (2017)
  • Author(s): A. El-Nahas, A. Staykov, K. Yoshizawa
  • Journal Title: Phys. Chem. C Volume: 121 (5) Pages: 2504-2511
  • DOI: 10.1021/acs.jpcc.6b10339
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Redox Potentials of Cobalt Corrinoids with Axial Ligands Correlate with Heterolytic Co-C Bond Dissociation Energies (2017)
  • Author(s): Y. Morita, K. Oohora, A. Sawada, T. Kamachi, K. Yoshizawa, T. Hayashi
  • Journal Title: Inorg. Chem. Volume: 56 (4) Pages: 1950-1955
  • DOI: 10.1021/acs.inorgchem.6b02482
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synergy of Electrostatic and van der Waals Interactions in the Adhesion of Epoxy Resin with Carbon-Fiber and Glass Surfaces (2017)
  • Author(s): K. Yoshizawa, T. Semoto, S. Hitaoka, C. Higuchi, Y. Shiota, and H. Tanaka
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 90 Pages: 500-505
  • DOI: 10.1246/bcsj.20160426
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] σ-CAM Mechanisms for the Hydrogenation of Alkenes by cis- and trans-Disilametallacyclic Carbonyl Complexes (M = Fe, Ru, Os): Experimental and Theoretical Studies (2017)
  • Author(s): K. Miyamoto, A. Tahara, Y. Sunada, H. Tutumi, R. Inoue, H. Tanaka, Y. Shiota, K. Yoshizawa, and H. Nagashima
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 99 Pages: in press
  • DOI: 10.1246/bcsj.20170004
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Thermodynamics and Photodynamics of a Monoprotonated Porphyrin Directly Stabilized by Hydrogen Bonding with Polar Protic Solvents (2017)
  • Author(s): W. Suzuki, H. Kotani, T. Ishizuka, K. Ohkubo, Y. Shiota, K. Yoshizawa, S. Fukuzumi, and T. Kojima
  • Journal Title: Chem. Eur. J. Volume: 23 (19) Pages: 4669-4679
  • DOI: 10.1002/chem.201606012
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Remarkable Catalytic Activity of Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes Bearing N-Heterocyclic Carbene-Based PCP-Pincer Ligand toward Nitrogen Fixation under Ambient Reaction Conditions (2017)
  • Author(s): A. Eizawa, K. Arashiba, H. Tanaka, S. Kuriyama, Y. Matsuo, K. Nakajima, K. Yoshizawa, Y. Nishibayashi
  • Journal Title: Nature Commun. Volume: 8 Pages: 14874/1-12
  • DOI: 10.1038/ncomms14874
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Phenylamine-functionalized mesoporous silica supported PdAg nanoparticles: a dual heterogeneous catalyst for the formic acid/CO2-mediated chemical hydrogen delivery/storage (2017)
  • Author(s): Kohsuke Mori, Shinya Masuda, Hiromasa Tanaka, K. Yoshizawa, Michel Che, and Hiromi Yamashita
  • Journal Title: Chem. Commun. Volume: 53 Pages: 4677-4680
  • DOI: 10.1039/C7CC00864C
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Persistent Four-Coordinate Iron-Centered Radical Stabilized by p-Donation (2016)
  • Author(s): Y. Sunada, S. Ishida, F. Hirakawa, Y. Shiota, K. Yoshizawa, S. Kanegawa, O. Sato, H. Nagashima, and T. Iwamoto
  • Journal Title: Chem. Sci. Volume: 7 Pages: 191-198
  • DOI: 10.1039/C5SC02601F
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Heterometallic FeIII/K coordination polymer with a wide thermal hysteretic spin transition around room temperature (2016)
  • Author(s): S. Kang, Y. Shiota, A. Kariyazaki, S. Kanegawa, K. Yoshizawa, and O. Sato
  • Journal Title: Chem. Eur. J. Volume: 22 Pages: 532-538
  • DOI: 10.1002/chem.201680262
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and Structure of a Water-soluble m-h1: h1-N2 Dinuclear RuII Complex with a Polyamine Ligand (2016)
  • Author(s): K. Yoshimoto, T. Yatabe, T. Matsumoto, A. Robertson, H. Nakai, H. Tanaka, T. Kamachi, Y. Shiota, K. Yoshizawa, K. Asazawa, H. Tanaka, and Seiji Ogo
  • Journal Title: Chem. Lett. Volume: 45 Pages: 3277-3284
  • DOI: 10.1039/C5DT04109K
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Intraprotein transmethylation via a CH3-Co(III) species in myoglobin reconstituted with a cobalt corrinoid complex (2016)
  • Author(s): K. Morita, K. Ohora, A. Sawada, K. Doitomi, T. Kamachi, K. Yoshizawa, Y. Hisaeda, and T. Hayashi
  • Journal Title: Dalton Trans. Volume: 45 Pages: 3277-3284
  • DOI: 10.1039/C5DT04109K
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A New Family of Anionic FeIII Spin Crossover Complexes Featuring a Weak-field N2O4 Coordination Octahedron (2016)
  • Author(s): K. Takahashi, K. Kawamukai, M. Okai, T. Mochida, T. Sakurai, H. Ohta, T. Yamamoto, Y. Einaga, Y. Shiota, and K. Yoshizawa
  • Journal Title: Chem. Eur. J. Volume: 22 Pages: 1253-1257
  • DOI: 10.1002/chem.201504883
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Crystal Structures and Coordination Behavior of Aqua- and Cyano-Co(III) Tetradehydrocorrins in the Heme Pocket of Myoglobin (2016)
  • Author(s): Y. Morita, K. Oohora, E. Mizohata, A. Sawada, T. Kamachi, K. Yoshizawa, T. Inoue, and T. Hayashi
  • Journal Title: Inorg. Chem. Volume: 55 Pages: 1287-1295
  • DOI: 10.1021/acs.inorgchem.5b02598
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] The chemistry of benzodisilacyclobutenes and benzobis(disilacyclobutene)s: New development of transition-metal-catalyzed reactions, stereochemistry and theoretical studies (2016)
  • Author(s): M. Ishikawa, A. Naka, and K. Yoshizawa
  • Journal Title: Dalton Trans. Volume: 45 Pages: 3210-3235
  • DOI: 10.1039/C5DT04569J
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Homogeneous Photocatalytic Water Oxidation with a Dinuclear Co(III)-Pyridylmethylamine Complex (2016)
  • Author(s): T. Ishizuka, A. Watanabe, H. Kotani, K. Satonaka, T. Wada, Y. Shiota, K. Yoshizawa, K. Ohara, K. Yamaguchi, S. Kato, S. Fukuzumi, and T. Kojima
  • Journal Title: Inorg. Chem. Volume: 55 Pages: 1154-1164
  • DOI: 10.1021/acs.inorgchem.5b02336
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Low-mode conformational search method with semiempirical quantum mechanical calculations: application to enantioselective organocatalysis (2016)
  • Author(s): T. Kamachi and K. Yoshizawa
  • Journal Title: J. Chem. Inf. Mod. Volume: 56 Pages: 347-353
  • DOI: 10.1021/acs.jcim.5b00671
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Possible Peroxo State of the Dicopper Site of Particulate Methane Monooxygenase from Combined Quantum Mechanics and Molecular Mechanics Calculations (2016)
  • Author(s): S. Itoyama, K. Doitomi, T. Kamachi, Y. Shiota, and K. Yoshizawa
  • Journal Title: Inorg. Chem. Volume: 55 Pages: 2771-2775
  • DOI: 10.1021/acs.inorgchem.5b02603
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Thermal behavior of benzobis(tetraethyldisilacyclobutene) (2016)
  • Author(s): A. Naka, K. Yoshizawa, and M. Ishikawa
  • Journal Title: Zeitschrift fur Naturforschung B Volume: 71 Pages: 227-230
  • DOI: 10.1515/znb-2015-0155
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Formation and high reactivity of anti-dioxo form of high-spin μ-oxodioxodiiron(IV) as the active species that cleavages strong C-H bonds (2016)
  • Author(s): M. Kodera, S. Ishiga, Y. Kawahara, T. Tsuji, K. Sakurai, Y. Hitomi, Y. Shiota, P. K. Sajith, K. Yoshizawa, K. Mieda, T. Ogura
  • Journal Title: Chem. Eur. J. Volume: 22 Pages: 5924-5936
  • DOI: 10.1002/chem.201600048
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Superior Thermoelasticity and Shape-Memory Nanopores in a Porous Supramolecular Organic Framework (2016)
  • Author(s): Y.-G. Huang, Y. Shiota, M.-Y. Wu, S.-Q. Su, Z.-S. Yao, S. Kang, S. Kanegawa, G.-L. Li, S.-Q. Wu, T. Kamachi, K. Yoshizawa, M.-C. Hong, and Osamu Sato
  • Journal Title: Nature Commun. Volume: 7 Pages: 11564/1-8
  • DOI: 10.1038/ncomms11564
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] First-Principals Calculations of Electron Transport Through Azulene (2016)
  • Author(s): A. El-Nahas, A. Staykov, and K. Yoshizawa
  • Journal Title: J. Phys. Chem. C Volume: 120 Pages: 9043-9052
  • DOI: 10.1021/acs.jpcc.6b00767
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Interplay between Theory and Experiment for Ammonia Synthesis by Transition Metal Complexes (2016)
  • Author(s): H. Tanaka, Y. Nishibayashi, and K. Yoshizawa
  • Journal Title: Acc. Chem. Res. Volume: 49 Pages: 987-995
  • DOI: 10.1021/acs.accounts.6b00033
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Unsymmetrical PNP-Pincer Type Phosphaalkene Ligands Protected by a Fused-Ring Bulky Eind Group: Synthesis and Applications to Rh(I) and Ir(I) Complexes (2016)
  • Author(s): H. Taguchi, D. Sasaki, K. Takeuchi, S. Tsujimoto, T. Matsuo, H. Tanaka, K. Yoshizawa, and F. Ozawa
  • Journal Title: Organometallics Volume: 35 Pages: 1526-1533
  • DOI: 10.1021/acs.organomet.6b00113
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Computational Study of Cyclobutane-1,3-diylidene Dicarbenes: Ground-State Spin Multiplicity and New Strategy Toward the Synthesis of Bicyclo[1.1.0]but-1(3)-enes (2016)
  • Author(s): Y. Fujita, M. Abe, Y. Shiota, T. Suzuki, and K. Yoshizawa
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 89 Pages: 955-964
  • DOI: 10.1246/bcsj.20160051
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] The Role of Coulombic Interactions for Spin Crossover Behaviors and Crystal Structural Transformation in Novel Anionic Fe(III) Complexes from a π-Extended ONO Ligand (2016)
  • Author(s): S. Murata, K. Takahashi, T. Sakurai, H. Ohta, T. Yamamoto, Y. Einaga, Y. Shiota, K. Yoshizawa
  • Journal Title: Crystals Volume: 6 Pages: 49-64
  • DOI: 10.3390/cryst6050049
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Computational Mutation Study on the Role of Catalytic Residues in Coenzyme B12-Dependent Diol Dehydratase (2016)
  • Author(s): K. Doitomi, T. Kamachi, T. Toraya, and K. Yoshizawa
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 89 Pages: 955-964
  • DOI: 10.1246/bcsj.20160083
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Energetic Mechanism of Cytochrome c - Cytochrome c Oxidase Electron Transfer Complex Formation under Turnover Conditions Revealed by Mutational Effects and Docking Simulation (2016)
  • Author(s): W. Sato, S. Hitaoka, K. Inoue, M. Imai, T. Saio, T. Uchida, K. Shinzawa-Itoh, S. Yoshikawa, K. Yoshizawa, and K. Ishimori
  • Journal Title: J. Biol. Chem. Volume: 291 Pages: 15320-15331
  • DOI: 10.1074/jbc.M115.708065
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Catalytic transformation of molecular dinitrogen into ammonia and hydrazine by using iron-dinitrogen complexes bearing anionic PNP-pincer ligand (2016)
  • Author(s): S. Kuriyama, K. Arashiba, K. Nakajima, Y. Matsuo, H. Tanaka, K. Ishii, K. Yoshizawa, and Y. Nishibayashi
  • Journal Title: Nature Commun. Volume: 7 Pages: 12181/1-9
  • DOI: 10.1038/ncomms12181
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Mechanistic Insights into C-H Oxidations by Ruthenium(III)-Pterin Complexes: Impact of Basicity of the Pterin Ligand and Electron Acceptability of the Metal Center on the Transition States (2016)
  • Author(s): H. Mitome, T. Ishizuka, H. Kotani, Y. Shiota, K. Yoshizawa, T. Kojima
  • Journal Title: J. Am. Chem. Soc. Volume: 138 Pages: 9508-9520
  • DOI: 10.1021/jacs.6b03785
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] An Azulene-Fused Tetracene Diimide with a Small HOMO-LUMO Gap (2016)
  • Author(s): T. Koide, M. Takesue, T. Murafuji, K. Satomi, Y. Suzuki, J. Kawamata, K. Terai, M. Suzuki, H. Yamada, Y. Shiota, K. Yoshizawa, and F. Tani
  • Journal Title: ChemPlusChem Volume: 2016 Pages: 81-86
  • DOI: 10.1002/cplu.201600356
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt-Dinitrogen Complexes Bearing Anionic PNP-Pincer Ligand (2016)
  • Author(s): S. Kuriyama, K. Arashiba, H. Tanaka, Y. Matsuo, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Pages: 14291-14295
  • DOI: 10.1002/anie.201606090
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Azaferrocene-Based PNP-type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation (2016)
  • Author(s): S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, K. Yoshizawa, and Y. Nishibayashi
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2016 Pages: 4856-4861
  • DOI: DOI:10.1002/ejic.201601051
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Ruthenium(III)-Oxyl Complex Bearing a Strong Radical Character (2016)
  • Author(s): Y. Shimoyama, T. Ishizuka, H. Kotani, Y. Shiota, K. Yoshizawa, K. Mieda, T. Ogura, T. Okajima, T. Kojima
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Pages: 14041-14045
  • DOI: 10.1002/anie.201607861
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Push-pull fluorenones and benzazulenequinones: unprecedented regioselective [4 + 2] and [2 + 2] cycloadditions of benzopentalenequinone derivative and alkynes bearing an aniline moiety (2016)
  • Author(s): S. Kato, T. Kijima, Y. Shiota, T. Yoshihara, S. Tobita, K. Yoshizawa, and Y. Nakamura
  • Journal Title: Tetrahedron Lett. Volume: 57 Pages: 4604-4607
  • DOI: 10.1016/j.tetlet.2016.09.002
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Thermally induced intra-carboxyl proton shuttle in a molecular rack-and-pinion cascade achieving macroscopic crystal deformation (2016)
  • Author(s): Y.-G. Huang, Y. Shiota, S.-Q. Su, S.-Q. Wu, Z.-S. Yao, G.-L. Li, S. Kanegawa, S. Kang, T. Kamachi, K. Yoshizawa, K. Ariga, and O. Sato
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Pages: 14628-14632
  • DOI: 10.1002/anie.201607886
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Directional Electron Transfer in Crystals of [CrCo] Dinuclear Complexes Achieved by a Chirality-Assisted Preparative Method (2016)
  • Author(s): S. Kanegawa, Y. Shiota, S. Kang, K. Takahashi, H. Okajima, A. Sakamoto, T. Iwata, H. Kandori, and K. Yoshizawa, and O. Sato
  • Journal Title: J. Am. Chem. Soc. Volume: 138 (43) Pages: 14170-14173
  • DOI: 10.1021/jacs.6b05089
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Platinum(0) Complex with a Square Planar Geometry (2016)
  • Author(s): K. Takeuchi, H. Taguchi, I. Tanigawa, S. Tsujimoto, T. Matsuo, H. Tanaka, K. Yoshizawa, and F. Ozawa
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Pages: 15347-15350
  • DOI: 10.1002/anie.201609515
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Direct Conversion of Methane to Methanol by Metal-Exchanged ZSM-5 Zeolite (Metal = Fe, Co, Ni, and Cu) (2016)
  • Author(s): M. H. Mahyuddin, A. Staykov, Y. Shiota, and K. Yoshizawa
  • Journal Title: ACS Catal. Volume: 6 Pages: 8321-8331
  • DOI: 10.1021/acscatal.6b01721
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Theoretical Study of the Catalytic Hydrogenation of Alkenes by a Disilaferracyclic Complex: Can the Fe-Si s-Bond-assisted Activation of H-H Bonds Allow Development of an Efficient Catalysis of Iron? (2016)
  • Author(s): A. Tahara, H. Tanaka, Y. Sunada, Y. Shiota, K. Yoshizawa, and H. Nagashima
  • Journal Title: J. Org. Chem. Volume: 81 Pages: 10900-10911
  • DOI: 10.1021/acs.joc.6b01961
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] TiO2-Supported Re as a General and Chemoselective Heterogeneous Catalyst for Hydrogenation of Carboxylic Acids to Alcohols (2016)
  • Author(s): T. Toyao, S. M. A. H. Siddiki, A. S. Touchy, W. Onodera, K. Kon, Y. Morita, T. Kamachi, K. Yoshizawa, and K. Shimizu
  • Journal Title: Chem. Eur. J. Volume: 23 Pages: 1001-1006
  • DOI: 10.1002/chem.201604762
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] Quantum Chemical Studies for the Development of Innovative Catalysts (2016)
  • Author(s): 吉澤 一成
  • Organizer: ANSCSE 20
  • Place of Presentation: Kasetsart University（タイ）
  • Year and Date: 2016-07-27 – 2016-07-29
• [Presentation] 接着の分子論 (2016)
  • Author(s): 吉澤 一成
  • Organizer: 新学術領域研究第5回公開シンポジウム
  • Place of Presentation: 東広島芸術文化ホールくらら小ホール（東広島市）
  • Year and Date: 2016-05-19
• [Remarks] 研究業績
  • URL: http://trout.scc.kyushu-u.ac.jp/yoshizawaJ/publications.html