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1992 Fiscal Year Final Research Report Summary

Preparation of Excited Electron System and Its Dynamics

Research Project

Project/Area Number 01420006
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 固体物性
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

GOTO Takenari  東北大学, 理学部, 教授 (10004342)

Co-Investigator(Kenkyū-buntansha) TERASAKI Osamu  東北大学, 理学部, 助手 (30004401)
KAYANUMA Yosuke  東北大学, 理学部, 助教授 (80124569)
須藤 彰三  東北大学, 教養部, 助教授 (40171277)
NOZUE Yasuo  東北大学, 理学部, 助手 (60125630)
ITOH Tadashi  東北大学, 理学部, 助教授 (60004503)
SUTO Shozo  
Project Period (FY) 1989 – 1992
KeywordsOptical Properties / Spatial Confinement / Excited Electorn / Dynamics
Research Abstract

This research project consists of three studies. 1.Optical properties of PBI_2 microcrystals embedded in organic polymer.
Absorption spectra of ultra thin PbI_2 microcrystals embedded into E-MAA copolymer have been measured at low temperatures. From these results it is concluded that the translational motion of the exciton is size quantized. From the luminescence measurements, it is suggested that the binding energy of the exciton becomes very large both for the size confinement effect and the dielectric confinement effect by the surrounding polymer. Moreover, we have measured the hydropressure dependence of the exciton energy and the resonant Raman scattering as a function of the layer number.
these results clarify that the atomic bonding of the PbI_2 mono-,double-and triple-layer crystals changes to the ionic one. Recently, the exciton-surface and exciton phonon interactions are studied by the pump-probe experiments,and shrinkage of the exciton wave function by the magneto-optical meas … More urements. 2.Optical properties of CuCl fine particles embedded in NaCl crystal. Under the size selective excitation of the exciton band,the size dependence of the luminescence decay time has been measured. It is found that the exciton superradiance due to the giant oscillator strength effect is taken place in the fine particles. The temperature dependence of the luminescence band width suggests the exciton is scattered by acoustic phonons at low temperatures. 3.Electronic properties of PbI_2,HgI_2,BiI_3,Na,K,Rb Clusters in zeolite.
Quantum size effects of the exciton energy and the oscillator strength have been observed in the absorption spectra of PbI_2,HgI_2,BiI_3,clusters loaded in zeolite. In highly loaded PbI_2 clusters,the extremely high reflectivity is observed for the ordering of the cluster. In the zeolite containing Na,K,Rb,there appear absorption bands due to electronic tgransition between two levels of the cluster and a band due to the surface plasmon like formation. Especially,ferromagnetic phase is observed at about 3K in the zeolite containing K clusters with medium concentration. Less

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] 伊藤 正: "CuCl微結晶における励起子系の光物性とその光学非線形性" 固体物理. 24. 941-945 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 伊藤 正: "Size-Dependent Radiative Decay Time og Confined Excitons in CuCl Microcrystals." Solid State Commun.73. 271-274 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 湯子 康: "Quantum Size Effect on the Excitation Energy and the Oscillator Strength of PbI_2 Clusters in Zeolite." J.Phys.Soc.Jpn.60. 2090-2094 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 後藤 武生: "Size Quantization of Excitons in PbI_2 Microcrystallites." Solid State Commun.80. 331-334 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 野末 泰夫: "Ferromagnetism of Potassium Clusters Incorporated into Zeolite LTA." Phys.Rev.Lett.68. 3789-3792 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤 伸吾: "Pressure Effect on Excitons in PbI_2 Mictocrystallites." Solid State Commun.84. 1043-1045 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Itoh: "Optical Properties of Exciton Systems in CuCl microcrystais and Thier Optical Nonlinearities." Solid State Physics. 24. 941-945 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Itoh,M.Furumiya and T.Ikehara: "Size-Dependent Radiative Decay Time of Confined Excitons in CuCl Microcrystals." Solid State Commun. 73. 271-274 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z.K.Tang,Y.Nozue and T.Goto: "Quantum Size Effect on the Excitation Energy and the Oscillator Strength of PbI_2 Clusters in Zeolite." J.Phys.Soc.Jpn. 60. 2090-2094 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Goto and S.Staito: "Size Quantization of Excitons in PbI_2 Microcrystallites." Solid State Commun. 80. 331-334 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Nozue,T.Kodaira and T.Goto: "Ferromagnetism of Potassium Clusters Incorporated into Zeolite LTA." Phys.Rev.Lett. 68. 3789-3792 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Saito and T.Goto: "Pressure Effect on Excitons in PbI_2 Microcrystallites." Slid State Commun. 84. 1043-1045 (1992)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1994-03-24  

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