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1990 Fiscal Year Final Research Report Summary

Study of Hetero-junction of Lamellar Semiconductor/GaAs

Research Project

Project/Area Number 01550021
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Applied materials
Research InstitutionTokyo Metropolitan University

Principal Investigator

OKUMURA Tsugunori  Dept. of Tech. Tokyo Metropol. Univ. Prof., 工学部・電気工学科, 教授 (00117699)

Co-Investigator(Kenkyū-buntansha) SHIMURA Michiko  Dept. of Tech. Tokyo Metropol. Univ. Assoc. Prof., 工学部・電気工学科, 助教授 (60087294)
Project Period (FY) 1989 – 1990
KeywordsLamellar Semiconductor / Gallium Selenide / Gallium Telluride / Hetero-junction / ヘテロ接合
Research Abstract

Hetero-junction of lamellar semiconductor/GaAs was fabricated with vacuum deposition of GaTe or GaSe on GaAs wafers and its properties were evaluated from I-V and C-V measurements.
(1) Evaluation of GaTe/GaAs hetero-junction from resistivity of GaTe :
The resistivities of GaTe thin film (substrate : GaAs (111), and GaAs (100) -without dopant, and glass plate) were measured using van der Pauw's method and four-point probe method at room temperature. The resistivity decreased with crystallization of the film at substrate temperatures above 200 ^゚C. The film grown as lamella showed 20 ohm・cm, which was the same value as for the cleavage plane of GaTe single crystals. It is suggested that epitaxial growth takes place on GaAs (111) A surface, which consists only of Ga atom, due to chemical affinity of Te of GaTe to Ga in GaAs.
(2) Fabrication and evaluation of hetero-junction of GaSe/GaAs :
Formation of GaSe film was tried on GaAs (111) A and GaAs (100) with vacuum sublimation. Here, GaAs was used as substrate after passivation with ammonium sulfide. Lamellar GaSe film was obtained at substrate temperatures above 250^゚C. I-V and C-V measurements showed that the GaSe film behaved as p-type. The carrier densities were calculated to be 10^<17> cm^<-3>.

  • Research Products

    (11 results)

All Other

All Publications (11 results)

  • [Publications] Michiko SHIMURA, Takayuki YABE, Tsugunori OKUMURA: "TwoーDemensional Crystal Growth of GaTs Thin Films by Vacuum Deposition" The Momoirs of Fac.of Tech.Tokyo Metropol.Univ.No.40,. 91-98 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.SHIMURA,and K.NOBEYAMA: "Photoーintercalation of Cations in GaSe" DenkiーKagaku. 56. 1211-1212 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A. Gouskov, J. Camassel, and L. Gouskov: ""Growth and characterization of III-VI Layered crystals Like GaSe, GaTe, InSe, GaSe_<1-x>Te_x and Ga_xIn_<1-x>Se"" Prog. Crystal growth and Charact.Vol. 5. 323 (1982)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Kurtin, and C. A. Meas: ""Surface Barriers on Layer Semiconductors : GaS, GaSe, GaTe"" J. Phys. Chem. Solids. Vol. 30. 2007 (1969)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. M. Mancini, C. Manfredotti, A. Rizzo, and G. micocci: ""Vapour Growth of GaTe Single Crystals"" J. Crystal Growth. Vol. 21. 187 (1974)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J. Robertson: ""Electronic Structure of GaSe, GaS, InSe, and GaTe"" J. Phys. C : Solid State Phys.Vol. 12. 4777 (1979)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] F. Antonangeli, A. Balzarotti, E. Doni, R. Girlanda, V. Grasso, and M. Piacentini: ""X-ray Photoemision Spectrum of the III-VI Layered Compound GaTe in the Region of the Valence Bands"" Physica. 105B. 59 (1981)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] W. B. Pearson: ""The Crystal Structure of Semiconductors and a General Valence Rule"" Acta Cryst.Vol. 17. 1 (1964)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] C. Manfredotti, A. M. Mancini, R. Murri, A. Rizzo, and L. Vasenelli: "2 Electrical Properties of p-Type GaSe" Il Nuovo Cimento. Vol. 39. 257 (1977)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Ueno, T. Shimada, K. Sakai, and A. Koma: ""Heteroepitaxial Growth of Layered Transition Metal Dichalcogenides on Sulfur-terminated GaAs {111} Surfaces" Appl. Phys. Lett.Vol. 56. 327 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Wu, T. Toyoda, Y. Kawakami, S. Fujita, and S. Fujita: ""Metalorganic Molecular Beam Epitaxial Growth of ZnSe and ZnS on GaAs Substrate Pretreated with (NH_4)_2S_x Solution" J. J. Appl. Phys.Vol. 29. 144 (1990)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1993-08-12  

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