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1990 Fiscal Year Final Research Report Summary

Preparation of Heat Resistant Oxide Coatings by the Sol-Gel Process and Their Application to Surface Modification of Metal Sheets

Research Project

Project/Area Number 01850180
Research Category

Grant-in-Aid for Developmental Scientific Research (B).

Allocation TypeSingle-year Grants
Research Field 無機工業化学
Research InstitutionUniversity of Osaka Prefecture

Principal Investigator

MINAMI Tsutomu  Univ. Osaka Pref. , Prof., 工学部, 教授 (80081313)

Co-Investigator(Kenkyū-buntansha) KAWADA Yoshiyuki  Hyogo Univ. Teach. Ed. , Res. Assoc., 自然系, 助手 (90205542)
ADACHI Hirohiko  Hyogo Univ. Teach. Ed. , Prof., 自然系, 教授 (60029105)
MACHIDA Nobuya  Univ. Osaka Pref. , Res. Assoc., 工学部, 助手 (10190381)
TATSUMISAGO Masahiro  Univ. Osaka Pref. , Lect., 工学部, 講師 (50137238)
TOHGE Noboru  Univ. Osaka Pref. , Assoc. Prof., 工学部, 助教授 (00081315)
Project Period (FY) 1989 – 1990
KeywordsSol-gel process / Metal-alkoxide / Stabilizer / Oxide film / Metal sheet / Surface modification / Heat resistance / Water repellency
Research Abstract

The sol-gel process, which starts from metal-alkoxides, is one of the pomising processes for the preparation of coating films. This research project was carried out to develop the sol-gel process for the coating of oxide films on metal substrates and thereby to modify the properties of their surfaces. The following results were obtained.
1. The incorporation of methyl groups into SiO_2 coatings enabled to bend and press metal substrates without pealing of the coatings. The pre-treatment of the substrates with a solution of chromic acid and sulfuric acid improved the adhesion of SiO_2 coatings on the metal surfaces due to the formation of oxide layers.
2. ZrO_2 films were continuously coated on metal sheets using zirconium octylates as starting materials. Moreover, the incorporation of fluorine into ZrO_2 films brought about the good water repellency.
3. Highly hydrolyzable metal alkoxides, such as Al-alkoxides, were stabilized with beta-diketones and amines. The effects of stabilizer were however found to be greatly dependent on solvents.
4. PbTiO_3 -pbzro_3 ferroelectric films were prepared in an ambient atmosphere from alkoxides of Ti and Zr stabilized with acetylacetone.
5. Preparation conditions of passivation films in the MO-B<@D22@>D2O<@D23@>D2-SiO<@D22@>D2 (M=Mg, Zn) and P<@D22@>D2O<@D25@>D2-B<@D22@>D2O<@23@>D2-SiO<@D22@>D2 systems were examined. The films in the TiO<@D22@>D2-SiO<@D22@>D2 system were also found to have good weathering-resistance for glass substrates.
6. The addition of organic polymers to TiO_2-SiO_2 sols retarded the gelation and gave the gel films on which fine-patterning was possible with a stamper. This finding can be applied to the formation of pregrooves on glass substrates.
7. Ionic-conducting compound LiTi_2(PO_4)_3 was prepared at relatively low temperatures from alkoxides of Li and Ti and phosphoric acid. SiO_2 films containing H_3PMO_<12>O_<40> were also found to show a high proton-conduction.

  • Research Products

    (32 results)

All Other

All Publications (32 results)

  • [Publications] 村上 メグミ: "CH_3Si(OC_2H_5)_3を出発原料としたステンレス鋼板へのSiO_2コ-ティング" 日本セラミックス協会学術論文誌. 97. 91-94 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Uchihashi: "Preparation of Amorphous Al_2O_3 Thlims from Stabilized AlーAlkoxide by the SolーGel Method" J.Ceram.Soc.Jpn.97. 396-399 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Izumi: "ZrO_2 Coating on Staliess Steel from OrganoーZirconim Compounds" J.Am.Ceram.Soc.72. 1465-1468 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 和泉 圭二: "ゾル-ゲル法によるステンレス鋼板へのZrO_2被履(解説)" 日新製鋼技報. 27-35 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 峠 登: "ゾル-ゲル法によるコ-ティング膜の作製(解説)" NEW GLASS. 4. 56-62 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Izumi: "Coating of FluorineーDoped ZrO_2 Films on Steel by the SolーGel Method" J.MonーCryst.Solids. 121. 344-347 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Matsuda: "Physical and Chemical Properties of TiO_2ーSiO_2 Films Derived from Poly(ethyene glycol)ーContatining Gels" J.Am.Ceram.Soc.73. 2117-2121 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Matsuda: "Pregrooving on Glass Disks by the SolーGel Method (Part 1)ーFormation and Evaluation of Pregrooved Glass Disks" SPIE Proc.SolーGel Optics. 1328. 62-70 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Matsuda: "Pregrooving on Glass Disks by the SolーGel Method (Part 2)ー Effects of the Addition of Organic Polymers on the Formation of Glass Films in the Sio_2ーTiO_2 System" SPIE Proc.SolーGel Optics. 1328. 71-79 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 和泉 圭二: "典がるセラミックス "ゾル-ゲル・セラミックス被履鋼板" (解説)" 金属「臨時増刊号」. 1-5 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N. Tohgo: "Prepartion of PbZrO_3ーPbTiO_3 Ferrolectric Thin Films by the SolーGel Process" J. Am. Ceram. Soc.74. 67-71 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 和泉 圭二: "ゾル-ゲル法によるフルオロアルキル基変性ZrO_2コ-ティング鋼板の撥水性" 日新鋼板技報. 13-21 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Matsuda: "Influences of Humidity and Temperature on Weathering of Glass Substrates Coated with SolーGel Derived Films" J.Ceram.Soc.Jpn.99. (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Matsuda: "Preparation of B_2O_5ーP_2O_5ーSiO_2 Coationg Films by the SolーGel Method" J.Mater.Sci.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Takezawa: "Effects of Stabilizing Agents on the Formation of Alumina Gels from AluminumーAlkoxides" J.Am.Ceram.Soc.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 南 努: "セラミックスデ-タブック'89" 工業製品技術協会, 464 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 南 努: "新無機材料科学" 化学同人, 196 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. Murakami: "SiO_2 Coating on Stainless Steal Sheets from CH_3Si(OC_2H_5)_3" J. Ceram. Soc. Jpn. ,. 97. 91-94 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Uchihashi: "Preparation of Amorphous Al_2O_3 Thin Films from Stabilized Al-Alkoxide by the Sol-Gel Method" J. Ceram. Soc. Jpn. ,. 97. 396-399 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Izumi: "ZrO_2 Coating on Stainless Steel Sheets from Organo-Zirconium Compounds" J. Am. Ceram. Soc.,. 72. 1465-1468 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Izumi: "ZrO_2 Coating on Stainless Steel Sheets by the Sol-Gel Method" Nisshin Seiko Giho,. 27-35 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Tohge: "Preparation of Coating Films by the Sol-Gel Process" NEW GLASS. 4. 56-62 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Izumi: "Coating of Fluorine-Doped ZrO_2 Films on Steel Sheets by the Sol-Gel Method" J. Non-Cryst. Solids. 121. 344-347 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Masuda: "Physical and Chemical Properties of TiO_2-SiO_2 Films Derived from Poly (ethylene glycol)-Containing Gels" J. Am. Ceram. Soc. ,. 73. 2117-2121 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Matsuda: "Pregrooving on Glass Disks by the Sol-Gel Method (Part 1)-Formation and Evaluation of Pregrooved Glass Disks" SPIE Proc. Sol-Gel Optics. 1328. 62-70 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Matsuda: "Pregrooving on Glass Disks by the Sol-Gel Method (part2)-Effects of the Addition of Origanic polymers on the Formation of Glass Films in the Sio_2-Tio_2 System" SPIE Proc. Sol-Gel Optics. 1328. 71-79 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Izumi: "Bendable Ceramic-Steel Sheets coated with Sol-Gel Ceramics" Kinzoku, Suppl.1-5 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Tohge: "Preparation of PbZrO_3-PbTiO_3 Ferroelectric Thin Films by Sol-Gel Process" J. Am. Ceram. Soc. ,. 74. 67-71 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Izumi: "Water Repellency of Steel Sheets Coated with Fluorine-Doped ZrO_2 Films by the Sol-Gel Method" Nisshin Seiko Giho. 13-21 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Matsuda: "Influences of Humidity and Temperature on Weathering of Glass Substrates Coated with Sol-Gel Derived Films" J. Ceram. Soc. Jpn.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Matsuda: "Preparation of B_2O_3-P_2O_5-SiO_2 Coating Films by the Sol-Gel Method" J. Mater. Sci.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Takezawa: "Effects of Stabilizing Agents on the Formation of Alumina Gels from Aluminum-Alkoxides" J. Am. Ceram. Soc.

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1993-08-12  

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