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1991 Fiscal Year Final Research Report Summary

Crystallization Mechanizm of Polymers

Research Project

Project/Area Number 02302079
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 高分子物性・高分子材料(含機械材料)
Research InstitutionYamagata University

Principal Investigator

HIKOSAKA Masamichi  Yamagata University, Associate Professor, 工学部, 助教授 (60087103)

Co-Investigator(Kenkyū-buntansha) TAKAMIZAWA Kichiro  Kyusyu University, Professor, 工学部, 教授 (10037707)
TODA Akihiko  Kyoto Univeristy, Research Associte, 理学部, 助手 (70201655)
MIYAJI Hideki  Kyoto University, Assoicate Professor, 理学部, 助教授 (90025388)
TANAKA Hajime  The Univerisyt of Tokyo, Associate Professor, 生産技術研究所, 助教授 (60159019)
OHIGASHI Hiroji  Yamagata University, Professor, 工学部, 教授 (90185372)
Project Period (FY) 1990 – 1991
KeywordsCrystallization / Chain sliding diffusion / Lateral growth / Thickening growth / Nucleus / Spherulite / Polymer / Epitaxial growth
Research Abstract

1) Crystalizathion from the melt : It is found that polymer single crystlas are formed through new thickening growth and well known lateral growth mechanisms. Thickening growth rate (U) increased with increase of degree of supercooling. These findings indicates that sliding diffusion of polymer chains takes important role in polymer crystallization mechanism. Crystallization temperature deyiendence of shape of single crystals was explained by competing of nucleation rate and traveling velocity of a nucleus.
2) Crystallization from the solution : Important role of absorption of polymer chains in crystallization and possibility of nucleation of three dimensional nucleus were shown.
3) Crystallization of spherulites : Origin of spherulite formation was explained by generation of screw dislocation induced by misfit between two sectors with differently oriented folds. Lateral growth rate at very high degree of supercooling was observed and it could not be well explained by conventional nucleation theory, which requires some new explanation.
4) Other studies : Co-crystallization and crystalization of multi-component system were studied, which showed that competition of crystallization and segregation of components reduces various morphologies. It is found that crystallization and subsequent solid-solid phase transformation introduces "frozed" defects within a crystal.

  • Research Products

    (75 results)

All Other

All Publications (75 results)

  • [Publications] 彦坂 正彦,奥居 徳昌: "高分子集合体の形成と性質(1)" 共立出完, 15 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 彦坂 正道: "結晶成長ハンドブック" 共立出完, 2 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 尾山 外茂男: "高分子学会編 高分子機態材料シリ-ズ,第3巻「高分子集合体の形成と性質」,序論" 共立出版株式会社, 10 (1992)

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      「研究成果報告書概要(和文)」より
  • [Publications] 高見沢 橄一郎: "融解現象 「高分子機能材料」シリ-ズ 第3巻 高分子学会編" 共立出版社,

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      「研究成果報告書概要(和文)」より
  • [Publications] A.E.Tonelli,M.A.Gomez,H.Tanaka,F.C.Schilling,M.H.Cozine,A.J.Lovinger,F.A.Bovey: "Advances in Chemistry Series 227-Polymer Characterization,Physical Property,Spectroscopic and Chromatographic Methods" American Chemical Society, 43 (1990)

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  • [Publications] A.E.Tonelli,M.A.Gomez,H.Tanaka,M.H.Cozine: "Solid State NMR of Polymers" Prenum Press, 25 (1991)

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  • [Publications] 大東 弘二(分担執筆): "弾性波素子技術ハンドブック" 日本学術振興会第150委員会編 オ-ム社, 562 (1991)

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  • [Publications] 大東 弘二(分担執筆): "機能性高分子材料 第5巻 電子機能性材料" 高分子学会編 共立出版, (1992)

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  • [Publications] M. Hikosaka: "Unified Theory of the Nucleation Theory of Folded Chain Crystals and Extended Chain Crystals of Polymers (II) Origin of FCC and ECC" Polymer. 31. 458-468 (1990)

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  • [Publications] S. Rastogi, M. Hikosaka, H. Kawabata and A. Keller: "A Study on the Role of Mobile Phase in Polymer Crystallization" Proceedings of Symposium on Plolymers (Pune, India). 95-95 (1991)

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  • [Publications] S. Rastogi, M. Hikosaka, H. Kawabata and A. Keller: "The Role of Mobile Phase in the Crystalzation of PE (I) Metastability and Lateral Growth" Macromolecules. 24. 6384-6391 (1991)

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  • [Publications] S, Rastogi, M. Hikosaka, H. Kawabata and A. Keller: "New Trends in Polymer Crysalization Studies (II) The Role of Transient Mesophasein Polymer Crystallization" Macromolecular Chem. Symp.48/49. 103-114 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] M. Hikosaka: "Folded Chain- and Extende Chain-Crystals of Polymers" Hyomen. 29. 114-121 (1991)

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  • [Publications] M. Hikosaka, S. Rastogi, H. Kawabata and A. Keller: "Invesitigation on the Crystallization of PE under High Pressure : Role of Mobile Phase, Lamellar Thickening Growth, Phase Transformations and Morphology" J. Macromolec. Sci. Phys.(1992)

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  • [Publications] M. Hikosaka, K. Tsukijima, S. Rastogi and A. Keller: "Equilibrium Triple Point Pressure and P-T Phase Diagram of PE" Polymer. (1992)

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  • [Publications] M. Hikosaka, T. Kasahara, T. Ichijyo, S. Rastogi and A. Keller: "New Crystallization Mechanism of Polymers, lamellar Thickening Growth Mechanism" Polymer.

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      「研究成果報告書概要(欧文)」より
  • [Publications] A. Suzuki, H. Awano, M. Hikosaka and H. Ohigashi: "Structure and Morphology of LB Film of Phthalocyanine Derivatives" Thin Solid Film.

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  • [Publications] S. Rastogi, M. Hikosaka, H. Kawabata and A. Keller: "Recent Findings on Pressure Crystallization" Euro. Phys. Soc. Intern. Conf.Stockholm.

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      「研究成果報告書概要(欧文)」より
  • [Publications] A. Toda: "Growth of polyethylene single crystals from the melt : change in lateral habit and regime I-II transition," Colloid Polym. Sci.(1992)

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      「研究成果報告書概要(欧文)」より
  • [Publications] A. Toda, H. Miyaji, Y. Ogawa and K. Takamizawa: "Lateral habits of n-alkane single crystals," J. Mater. Sci.26. 2793-2796 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] A. Toda: "Rounded lateral habits of polyethylene single crystals," Polymer. 32. 771-780 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] H. Kawamura, M. Tsuji, A. Kawaguchi and K. Katayama: "TEM Study on Oriented Thin Films of Poly (aryl-ether-ether-ketone) (PEEK)," Bull. Inst. Chem. Res., Kyoto Univ.68. 41-52 (1990)

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      「研究成果報告書概要(欧文)」より
  • [Publications] K. J. Ihn, M. Tsuji, A. Kawaguchi and K. Katayama: "TEM Measurement of Lamellar Thickness in Polyethylene and Cycloparaffins by Staining with RuO_4," Bull. Inst. Chem. Res., Kyoto Univ.68. 30-40 (1990)

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  • [Publications] A. Kawaguchi, T. Okihara and K. Katayama: "Oriented Crystallization of Normal Long Chain Compounds on Polylefins," J. Cryst. Growth. 99. 1028-1032 (1990)

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  • [Publications] T. Okihara, A. Kawaguchi, M. Ohara and K. Katayama: "Subcell-Matched Epitaxy of Normal Long Chain Compounds on Polyethylene I. on the (110) plane," J. Cryst. Growth. 106. 318-332 (1990)

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      「研究成果報告書概要(欧文)」より
  • [Publications] T. Okihara, A. Kawaguchi, M. Ohara and K. Katayama: "Subcell-Matched Epitaxy of Normal Long Chain Compounds on Polyethylene II. on the (100) plane," J. Cryst. Growth. 106. 333-348 (1990)

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      「研究成果報告書概要(欧文)」より
  • [Publications] K. J. Ihn, M. Tsuji, S. Isoda, A. Kawaguchi, K. Katayama, Y. Tanaka and H. Sato: "Comparative Study on the Folded-Chain Structure in Polyethylene and Cycloparaffins. 1. TEM Study on Molecular Orientation of Polyethylene on a Decorated Surface of Polyethylene and Cycloparaffin Single Crystals," Macromolecules. 23. 1781-1787 (1990)

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      「研究成果報告書概要(欧文)」より
  • [Publications] K. J. Ihn, M. Tsuji, S. Isoda, A. Kawaguchi and K. Katayama: "Comparative Study on the Folded-Chain Structure in Polyethylene and Cycloparaffins. 2. Energy Calculation on the Surface Decoration of (CH_2)_<36> and C_<36>H_<74> with polyethylene" Macromolecules. 23. 1788-1793 (1990)

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  • [Publications] A. Kawaguchi, T. Okihara, M. Ohara and K. Katayama: "Formation of Oriented Film of Long Chain Compounds on Polyloleffine Thin Films by Epitaxy" Kasen-Koensyu. 47. 1-28 (1990)

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  • [Publications] M. Tsuji, K. Katayamea: "Structural Study of Fibers by High Resolution Transmission Electron Microscopy" Seni-Gakkai-Shi. 46. 388-394 (1990)

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  • [Publications] A. Kawaguchi, T. Okihara, S. Murakami, M. Ohara, K. Katayama and J. Petermann: "Epitaxial Growth of Isotactic Polypropylene on Oriented Polyethylene from Solution," J. Polym Sci. : Part B : Polym. Phys.29. 683-690 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] T. Okihara, M. Tsuji, A. Kawaguchi and K. Katayama: "Crystal Structure of Stereocomplex of Poly (L-lactide) and Poly (D-lactide)," J. Macromol. Sci. -Phys.B30. 119-140 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] K. Katayama, M. Tsuji, A. Kawaguchi, K. J. Ihn and H. Kawamura: "Structure of Fibrous Polymers" Kasen-Koensyu. 48. 75-83 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] M. Tsuji, M. Tosaka, A. Kawaguchi, K. Katayama and M. Iwatsuki: "High-resolution Observation of Polymer Single Crystals with Superconducting Cryo-TEM," Bull. Inst. Chem. Res., Kyoto Univ.69. 117-126 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] A. Kawaguchi, S. Murakami, K. Katayama, M. Mihoichi and T. Ohta: "An Application of a New X-ray Diffraction System with Imaging Plates to Studies on the Deformation Behavior of Ultra-high Molecular Weight Polyethylene," Bull. Inst. Chem. Res., Kyoto Univ.69. 145-154 (1991)

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  • [Publications] A. Kawaguchi: "Epitaxy of Polymers" Hyomen. 30. 297-312 (1991)

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  • [Publications] K. J. Ihn, M. Tsuji, A. Kawaguchi and K. Katayama: "Polymorphism of a long-chain cycloparaffin (CH_2)_<120>," J. Electron Microsc. Tech.20. (1992)

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      「研究成果報告書概要(欧文)」より
  • [Publications] H. Miyaji: "Crystallization of Polymers" Nihon-Kessyo-Gakkaishi. 17. 95-98 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Toda, H. Miyaji, Y. Ogawa and Kan-Ichiro Takamizawa: "Lateral Habit of n-alkane Crystals." J. Mater. Sci.26. 2793-2796 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] K. Fukao, Y. Miyamoto and H. Miyaji: "Crossover Behaviour of Dielectric Relaxation in Isotactic Polystyrene : from Stretched Exponential Decay to Power Law Decay." J. Phys. Condens. Matter. 3. 5451-5456 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] H. Miyaji and Y. Takahashi: "Ferroelectric Polymers" Kobunnshi. 450-453 (1991)

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  • [Publications] S. Suehiro, H. Miyaji and H. Hayashi: "Refractive Lens for X-ray Focus." Nature. 352. 385-386 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] K. Izumi, K. Omiya and H. Miyaji: "The deformation of the Nearly Perfect Crystals of Polydiacetylene (PTS)." Bull. Inst. Chem. Res. Kyoto Univ.69. 184-192 (1991)

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  • [Publications] Y. Miyamoto, K. Fukao, Y. Tanzawa and H. Miyaji: "Dependence of Fold Length on Crystallization Temperature in Syndiotactic Polystyrene." Rep. Progr. Polym. Phys. Japan. XXXVI. 113-116 (1991)

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  • [Publications] M. Hashimoto, A. Toda and H. Miyaji: "Isotropic Scattering in H_v Litht Scattering from Spherulite of Polymers." Polymer.

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  • [Publications] Y. Miyamoto, K. Fukao, Y. Tanzawa and h. Miyaji: "Dependence of Fold length on Crystallization Temperature in Syndiotactic Polystyrene," Rep. Prog. Polym. Phys. Jpn.34. 113-116 (1991)

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  • [Publications] Y. Miyamoto, Y. Tanzawa, H. Miyaji and H. Kiho: "Growth Rate of Isotactic Polystyrene Crystals in the Concentrated Solutions and Melt," Polymer. 33. (1992)

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  • [Publications] N, Okui: "Relationship between Melting Temperature, Maximum Crystallization Temperature and Glass Transition Temperature" Polymer. 31. 92-94 (1990)

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  • [Publications] N. Okui: "Maximum Crystal Growth Rate and its Corresponding State" Polymer Bull.23. 111-118 (1990)

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  • [Publications] N. Okui: "Relationship between Crystallization Temperature and Melting Temperature in Crystalline Materials" J. Mat. Sci.25. 1623-1631 (1990)

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  • [Publications] K. Tanaka, N. Okui and T. Sakai: "Molecular Orientation Behavior of Paraffin Thin Films Made by Vapor Deposition" Thin Solid Films. 196. 137-145 (1991)

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  • [Publications] A. Kubono, N. Okui, K. Tanaka, S. Umemoto and T. Sakai: "Highly Oriented Polyamide Thin Films Prepared by Vapor Deposition Polymerization" Thin Solid Films. 199. 385-393 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] T. Takeno, N. Okui, T. Kitoh, M. Muraoka, S. Umemoto and T. Sakai: "Preparation and Piezoelectricity of beta Form Poly (vinylidene fuloride) Thin Film bu Vapor Deposition" Thin Solid Films. 202. 205-211 (1991)

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      「研究成果報告書概要(欧文)」より
  • [Publications] T. Takeno, N. Okui, T. Kitoh, M. Muraoka, S. Umemoto and T. Sakai: "Prepartion and Electrical Properties of gamma Form Poly (vinylidene fuloride) Thin Film by Vapor Depoition in the Presence of Electric Field" Thin Solid Films. 202. 213-220 (1991)

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  • [Publications] K. Takamizawa and Y. Urabe: "Effect of Sample Weight on Micro DSC Measurements of Heptacosane" Chem. Lett.63-66 (1990)

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  • [Publications] K. Takamizawa: "Amorphouphous Polymers (Grass Transition)" Netsusokutei. 17. 149-150 (1990)

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  • [Publications] K. Takamizawa and H. Toratani: "Pressure Effect on Relations between Glass Transition Temperature and Freezing-in Rate for Polystyrene" Thermochim. Acta. 163. 325-330 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Toda, H. Miyaji, Y. Ogawa, and K. Takamizawa: "Lateral habits of n-alkane single crystals" J. Mater. Sci.26. 2793-2796 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Takamizawa and H. Toratani: "Application of a high pressure d. t. a. to study the pressureglassification of polystyrene" Polym. Commun.

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  • [Publications] H. Saito, D. Tsutsumi and T. Inoue: "Temperature Dependence of the Flory Interaction Parameter in a Single-Phase Mixture of Poly (hydroxy ether of bisphenol-A) and Poly (ether sulfone)" Polymer J.28. 128 (1990)

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  • [Publications] T. Okada, H. Saito, M. Yamazaki and T. Inoue: "Effect of Nucleationg Agent on the Structure Development in Isotactic Polypropylene/Liquid paraffin Mixture" Polymer. 31. 469 (1990)

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  • [Publications] T. Okada, H. Saito and T. Inoue: "Nonlinear Crystal Growth in Mixture of Isotactic Polypropylene and Liquid Paraffin" Macromolecules. 23. 3865 (1990)

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  • [Publications] H. Saito, M. Matsuura and T. Inoue: "Depolarized Light Scattering Studies on Single-Phase Mixture of Diissimilar Polymers : Evidence for Local Ordering" J. Polym. Scie., Polym. Phys.29. (1991)

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  • [Publications] H. Saito, T. Okada, T. Hamane and T. Inoue: "Crystallization Kinetics in the Mixtures of Poly (vinylidene fluoride) and Poly (methyl methacrylate) : Two Step Diffusion Mechanism" Macromolecules. 24. 4446 (1991)

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  • [Publications] H. Saito, M. Takahashi and t. Inoue: "Chain Relaxation Behavior in Single-Phase Mixtures of Dissimilar Polymers" Macromolecules. 24. (1991)

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  • [Publications] H. Tanaka, A. J. Lovinger, and D. D. Davis: "Miscibility and Isomorphic Cocrystallization in Blends of Ferroelectric Copolymers of Vinylidene Fluoride and Trifluoroethylene" J. Polym. Sci. : Part B : Polym. Phys.28. 2183-2198 (1990)

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  • [Publications] C. Marco, J. G. Fatou, M. A. Gomez, H. Tanaka, and A. E. Tonelli: "Molecular Weight Effect on the Miscibility of Poly (ethylene oxide) and IsotacticPoly (methyl methacrylate) in Their Blends" Macromolecules. 23. 2183-2188 (1990)

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  • [Publications] H. Tanaka, T. Yokokawa, H. Abe, T. Hayashi, and T. Nishi: "Transition from Metastability to Instability in a Binary Liquid Mixture" Phys. Rev. Lett. 65. 3136-3139 (1990)

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  • [Publications] H. Tanaka, M. Thakur, M. A. Gomez, and A. E. Tonelli: "Study of the Correlation Between the Backbone Conformation and the Electronic Structures of Polydiacetylenes by Solid State ^<13>C NMR" Polymer. 30. 1834-1840 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Tanaka, T. Fujioka, and T. Nishi: "A New Method for Direct Determination of the Time Sequence of Nuculeation from Spatial Pattern Divided by Spherulites" Jpn. J. Appl. Phys. 30. L1310-L1313 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Nishi, H. Tanaka and T. Hayashi: "Pattern Formation and its Dysnamics of Polymers" Nihon-Butsuri-Gakkaishi. 12. 885-892 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Hikosaka and T. Okui: Kyoritsu-Shuppan. Crystallization of Polymers (Functional Polymers),

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Takamizawa: Kyoritsu-shuppan. Melting Phenomena (Functional Polymers),

    • Description
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  • [Publications] A. E. Tonelli, M. A. Gomez, H. Tanaka, F. C. Schilling, M. H. Cozine, A. J. Lovinger and F. A. Bovey: Polymer Characterization Physical Property, Spectroscopic and Chromatographic Methods. Solid-State Nuclear Magnetic Resonance, Differential Scanning Calorimetric, and X-ray Diffraction Studies of Polymers, 1990 (American Chemical Society, Washington)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. E. Tonelli, M. A. Gomez, H. Tanaka, and M. H. Cozine: Solid State NMR of Polymers. Solid State ^<13>C NMR Studies of the Structures, Conformations, and Dynamics of Semicrystalline Polymers, 81-105 (1991)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1993-03-16  

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