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1992 Fiscal Year Final Research Report Summary

Research of Physical Chemistry on Activity and Spin-Spin Interaction of Paramagnetic Molecular Species

Research Project

Project/Area Number 02303001
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 物理化学一般
Research InstitutionYokohama National University

Principal Investigator

HIGUCHI Jiro  Yokohama National University, Faculty of Engineering, Professor, 工学部, 教授 (20017875)

Co-Investigator(Kenkyū-buntansha) KUBOTA Shozo  Tohoku University, Institute for Chemical Reaction Science, Associate Professor, 反応化学研究所, 助教授 (80111318)
TAKUI Takeji  Osaka City University, Faculty of Science, Professor, 理学部, 教授 (10117955)
OBI Kinichi  Tokyo Institute of Technology, Faculty of Science, Professor, 理学部, 教授 (10016090)
HIROTA Noboru  Kyoto University, Faculty of Science, Professor, 理学部, 教授 (90093301)
IWAIZUMI Masamoto  Tohoku University, Institute for Chemical Reaction Science, Professor, 反応化学研究所, 教授 (70006295)
Project Period (FY) 1990 – 1992
KeywordsEPR / Radical / CIDEP / Spin Chemistry / Metal Complex / Lowest Excited Triplet State / Spin Polarization / Relaxation Rate
Research Abstract

Recently, the lnvestigations of paramagnetic molecolar species, lncluding excited molecules, make rapid progress by improving the experimental techniques.
Under such circumstances, the present co-operative research was undertaken. The main purpose of this is the establishment of the research system which makes possible to investirate the special characters on the electronic structure of each molecular species, from both the theoretical and the experimental viewpoints. By reexaming the experimental informations and the theoretical considerations, the fundamental parts in the research system of paramagnetic molecular species could be understood by focussing the reactivity, the dynamic behavior, and the spin-spin-interaction. Thus, the development of our research becomes with great possibilities in the near future. The present co-operative research group with nineteen investigators began to take charge of the following four partial subjects; (1) the improvement of chemical method for param … More agnetic molecular species in focussing the time-resolved and the frequency-resolved methods. (2) the problems on the spin-spin interaction of paramagnetic species produced in the excited state. (3) the reactivity and the spin-spin interaction of metal complexes, and (4) the reactivity of free radicals trapped in condensed phases. After that, the complete resolutions of the present problems were obtained in close co-operation among all the member of our group by the exchange of information and the mutual discussions. As a result, many fruitful investigations and internationally high-level papers have been published. The main partial subjects of these are described as follows: Development of quantitative analysis of CIDEP signals, taking the diffusion process into consideration; Methodologycal development for the purpose of completing the spin chemistry; Determination of molecular structure, dynamic behavior, and energy-transfer rate between the same molecular species; Detection of spin polarizalion produced in the ground state of metal complexes after photoexcitation; Evidence for unsymmetrical structure of o-cation radicals of linear alkanes; Evidence for the correlation between the rate of hydrogen-atom-abstraction from n-alkanes and the relaxation rate of their C-C bending vibralion. detected by the pulse EPR method. Less

  • Research Products

    (44 results)

All Other

All Publications (44 results)

  • [Publications] M.Mukai,S.Yamauchi,N.Hirota,and J.Higuchi: "Time-Resolved EPR and Phosphorescence Studies of the Lowest Excited Triplet State od Benzil" J.Phys.Chem.96. 9328-9331 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Terazima,N.Hirota,H.Shinohara,and Y.Saito: "Time-Resolved EPR Investigation of Triplet State of C_<60> and C_<70>" Chem.Phys.Lett.195. 333-338 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ikoma,K.Akiyama,S.Tero-Kubota,and Y.Ikegami: "Structural Effeets on the Radiationless Transition from the T_1 States of Tropone Derivatives" J.Phys.Chem.97. 303-305 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Yagi,T.Kaneshima,M.Torii,M.Matsuo,and J.Higuchi: "Effects of Counterion on the Triplet States of Zinc(II) Complexes with 1,10-Phenanthroline and 2,9-Dimethyl- 1,10-Phenanthroline" Chem.Phys.Lett.197. 457-460 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kato,K.Sasano,M.Kimura,and S.Yamauchi: "Solid State Effect on the Phosphorescence Spectrum of Tris(3,3'-biisoquinoline) Ruthenium(II)" Chem.Lett.1887-1890 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Kawai,T.Okutsu,and K.Obi: "CIDEP in the Photsensitized Dissociation of Benzylchloride" Chem.Phys.Lett.198. 637-640 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Ohara,H.Murai,and K.Kuwata: "Time-Resolved ESR Studies on Photosensitized Reaction of Malcic Anhydride in Alcohols:CIDEP Memory Transfer in Spin-Adduct Formation" Bull.Chem.Soc.Jpn.65. 1672-1678 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Hanazaki,H.Murai,and K.Kuwata: "Photosensitized Triplet State of 1,3-Cyclodienes Detected by a Time-Resolved ESR Method" Chem.Phys.Lett.197. 67-71 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Fukui,K.Kojima,H.Ohya-Nishiguchi,and N.Hirota: "Mctal-Thiolate Bonding Properties:Single-Crystal ESR,Susceptibility,and Polarized Absorption Evidence for a Strong π Interaction in Tetrakis(thiophenolato)coblt(II)" Inorg.Chem.31. 1338-1344 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Hanaya and M.Iwaizumi: "EPR Studies of Photochemical Reactions of Hexacarbonylbis-(η^5-2,4-cyclopentadien-1-yl)ditungsten,〔CpW(CO)_3〕_2,with Quinones" J.Org.Chem.435. 337-345 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Kita,K.Uchida,R.Miyamoto,and M.Iwaizumi: "Spin-Spin Couplings in the Copper Acetate Hydrate Dimer Studied by Single Crystal ^<13>C-ENDOR for Zinc-Doped Copper Acetate Monohydrate" Chem.Lett.1329-1332 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Edihara,K.Tokoro,K.Imaeda,K.Sakurai,H.Masuda,T.Kawamura: "Complexes of Silver(I) with Bis(dealkyldithiocabamato)-Platinum(II) as Ligand:Synthesis and Structure of [Pt_3(S_2CNPr_2)_6Ag_2](BF_4)_2 and [Pt_3(S_2CNBu_2)_6Ag_2](ClO_4)_2" J.Chem.Soc.,Chem Commun.1591-1592 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Otuka,A.Sekine,Y.Ohashi,and Y.Kaizu: "The Crystal Water Affecting ^2E_9→ ^4A_<29> Relaxation in Tris(oxalato)chromate(III) Complexes" Bull.Chem.Soc.Jpn.65. 3378-3385 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Ishikawa,O.Ohno,Y.Kaizu,and H.Kobayashi: "Localized Orbital Study on the Electronic Structure of Phthalocyanine Dimers" J.Phys.Chem.96. 8832-8839 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Shiotani,K.Komaguti,J.Ohshita,M.Ishikawa,and L.Sjoqvist: "An Asymmetrically Distorted Structure of the 1-Methyl-silacycyclohexane Radical Cation:ESR Evidence" Chem.Phys.Lett.188. 93-99 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Komaguchi,M.Shiotani,M.Ishikawa,and K.Sasaki: "Structure and Ring-Puckering Molion of the σ-Localized Silacyclobutane Radical Cation:ESR Evidence." Chem.Phys.Lett.200. 580-586 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Toriyama and M.Okazaki: "Selectively Weakened C-C σ-Bond in Cation Radicals of Linear and Branched Pentanes as Studied by Electron Spin Resonance" J.Phys.Chem.96. 6986-6991 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ichikawa and H.Yoshida: "Selectivity of Alkyl Radical Formation form Branched Alkanes Studied by Electron Spin Resonance and Electron Spin Echo Spectroscopy" J.Phys.Chem.96. 7656-7661 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ichikawa: "Application of ESE Spectroscopy to the Study of Radical Reactions in Solids" Pure Appl.Chem.64. 841-846 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ichikawa and H.Yoshida: "Effect of Solid Phase on the Selectivity of Hydrogen Abstraction from n-Alkanes.An Electron Spin Resonance and Electron Spin Echo Study" J.Phys.Chem.96. 7661-7664 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Fujisaka,J.Takahashi,T.Shida,T.Bally,and K.Roth: "Novel Photochemical Reaction of C_8H_<10> Radical Cations" J.Phys.Chem.96. 2205-2210 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Shinohara,H.Sato,M.Ohkohchi,Y.Ando,T.Kodama,T.Shida,T.Kato,and Y.Saito: "Encapsulation of a Scandium Trimer in C_<82>" Nature. 357. 52-54 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. Mukai, S. Yamauchi, N. Hirota, and J. Higuchi: "Time-Resolved EPR and Phosphorescence Studies of the Lowest Excited Triplet State od Benzil" J. Phys. Chem.96. 9328-9331 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Terazima, N. Hirota. H. Shinohara, and Y. Saito: "Time-Resolved EPR Investigation of Triplet State of C_<60> and C_<70>" Chem. Phys. Lett.195. 333-338 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Ikoma, K. Akiyama, S. Tero-Kubota, and Y. Ikegami: "Structural Effects on the Radiationless Transition from the T, States of Tropone Derivatives" J. Phys. Chem.97. 303-305 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Yagi, M. Torii, N. Yamauchi, T. Kaneshima, and J. Higuchi: "Effects of Conformation on the Luminescence Properies of 2,2'-Bipyridine and 2,2'-Biquinoline" Chem.Phys.Lett.187. 604-608 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kato, K. Sasano, M. Kimura, and S. Yamauchi: "Solid State Effect on the Phosphorescence Spectrum of Tris(3,3'-biisoquinoline) Ruthenium(II)" Chem. Lett.1887-1890 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Kawai, T. Okutsu, and K. Obi: "CIDEP in the Photsensitized Dissociation of Benzylchloride" Chem. Phys. Lett.198. 637-640 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Ohara, H. Murai, and K. Kuwata: "Time-Resolved ESR Studies on Photosensitized Reaction of Maleic Anhydride in Alcohols: CIDEP Memory Transfer in Spin Adduct Formation" Bull. Chem. Soc. Jpn.65. 1672-1678 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Hanazaki, H. Murai, and K. Kuwata: "Photosensitized Triplet State of 1,3-Cyclodienes Detected by a Time-Resolved ESR Method" Chem. Phys. Lett.197. 67-71 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Fukui, K. Kojima, H. Ohya-Nishiguchi, and N. Hirota: "Metal-Thiolate Bonding Properties: Single-Crystal ESR, Susceptibility, and Polarized Absorption Evidence for a Strong Pi Interaction in Tetrakis(thiophenolato)cobalt(II)" Inorg. Chem.31. 1338-1344 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Hanaya and M. lwaizumi: "EPR Studies of Photochemical Reactions of Hexacarbonylbis(eta^5-2,4-cyclopentadien-l-yl)ditungsten, [CpW(CO)^3]^2, with Quinones" J. Org. Chem.435. 337-345 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Kita, K. Uchida, R. Miyamoto, and M. Iwaizumi: "Spin-Spin Couplings in the Copper Acetate Hydrate Dimer Studied by Single Crystal ^<13>C-ENDOR for Zinc-Doped Copper Acetate Monohydrate" Chem. Lett.1329-1332 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Ebihara, K. Tokoro, K. Imacda, K. Sakurai, H. Masuda, and T. Kawamura: "Complexes of Silver(I) with Bis(dialkyldithiocabamato)- Platinum(II) as Ligand: Synthesis and Structure of [Pt_3(S_2CNPr_2)_6Ag_2](BF_4)_2 and [Pt_3(S_2CNBu_2)_6Ag_2](ClO_4)_2" J. Chem. Soc., Chem. Commun.1591-1592 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Otuka, A. Sekine, Y. Ohashi, and Y. Kaizu: "The Crystal Water Affecting ^2E_g*^4A_<20> Relaxation in Tris(oxalato)chromate(III) Complexes" Bull. Chem. Soc. Jpn.65. 3378-3385 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Ishikawa, O. Ohno, Y. Kaizu, and H. Kobayashi: "Localized Orbital Study on the Electronic Structure of Phthalocyanine Dimers" J. Phys. Chem.96. 8832-8839 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Shiotani, K. Komaguti, J. Ohshita, M. Ishikawa, and L. Sjoqvist: "An Asymmetrically Distorted Structure of the l-Methyl- silacycyclohexane Radical Cation: ESR Evidence" Chem. Phys. Lett.188. 93-99 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Komaguchi, M. Shiotani, M. Ishikawa, and K. Sasaki: "Structure and Ring-Puckering Motion of the sigma-Localized Silacyclobutane Radical Cation: ESR Evidence" Chem. Phys. Lett.200. 580-586 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Toriyama and M. Okazaki: "Selectively Weakened C-C sigma-Bond in Cation Radicals of Linear and Branched Pentanes as Studied by Electron Spin Resonance" J. Phys. Chem.96. 6986-6991 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Ichikawa and H. Yoshida: "Selectively of Alkyl Radical Formation from Branched Alkanes Studied by Electron Spin Resonance and Electron Spin Echo Spectroscopy" J. Phys. Chem.96. 7656-7661 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Ichikawa: "Application of ESE Spectroscopy to the Study of Radical Reactions in Solids" Pure Appl. Chem.64. 841-846 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Ichikawa and H. Yoshida: "Effect of Solid Phase on the Selectivity of Hydrogen Abstraction from n-Alkanes. An Electron Spin Resonance and Electron Spin Echo Study" J. Phys. Chem.96. 7661-7664 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Fujisaka, J. Takahashi, T. Shida, T. Bally, and K. Roth: "Novel Photochemical Reaction of C_8H_<10> Radical Cations" J. Phys. Chem.96. 2205-2210 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Shinohara, H. Sato, M. Ohkohchi, Y. Ando, T. Kodama, T. Shida, T. Kato, and Y. Saito: "Encapsulation of a Scandium Trimer in C_<82>" Nature. 357. 52-54 (1992)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1994-03-24  

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