1991 Fiscal Year Annual Research Report

微量分析法の高度化のための分離化学的方法に関する研究

Research Project

Project/Area Number	02303005
Research Institution	Hiroshima University
Principal Investigator	熊丸尚宏広島大学, 理学部, 教授 (50033816)
Co-Investigator(Kenkyū-buntansha)	黒田六郎千葉大学, 工学部, 教授 (50009198) 赤岩英夫群馬大学, 工学部, 教授 (60008414) 河嶌拓治筑波大学, 化学系, 教授 (50041760) 鈴木信男東北大学, 理学部, 教授 (10006025) 多賀光彦北海道大学, 理学部, 教授 (90000778)
Keywords	状態判別 / 微量分析法 / イオン交換 / 分離化学 / 溶媒抽出 / 共同沈殿 / イオン浮選 / オンライン分離濃縮
Research Abstract	1. 状態判別を指向した高感度分析法の開発 (1)インダミン色素の生成反応におけるMn(II)の接触作用を利用する接触滴定法を確立した (河嶌)。 (2)III BーVI B族元素のGFーAASにおいてアルブミンとPd化合物の増感効果を調べ、船底塗料からの有機スズの溶出試験に応用した (松本)。 2. 化学種の分離・分別・濃縮に有効な特異的試薬・イオン交換体の開発 (1)2価6配位の金属イオンの選択的濃縮試薬としてポリピラゾリルボレ-トを合成し、実用化した(松井)。 (2)キトサンにジチオカルバメ-ト基を導入したDTDーキチンを合成し、Ag、Au、Cdなどの濃縮分離に適用した (寺田)。 (3)ヒドロキシル基をもつポリスチレン系キレ-ト樹脂を合成し、Sc、Y、希土類の捕集・分離への有効性を確認し、ペレット法による固体蛍光法、蛍光X線分析法に応用した (西川)。 3. 新しい観点に立つ溶媒抽出系の開発 (1)類縁元素の相互分離法を設計する手段としてHSAB則に基づいたキレ-ト抽出系に適用できる新しいパラ-メ-タを提案した (赤岩)。 (2)PとSiのヘテロポリ酸および陽イオン染料とのイオン会合体生成反応による高感度定量法を開拓した (本水)。 4. 新規なイオン交換・吸着・沈殿・共沈・浮選法の開発 (1)希土類元素をグルコラト錯体とするイオン干渉クロマトグラフィ-を確立した (黒田)。 (2)種々のメンブランフィルタ-へのCu(II)ーDTC錯体の捕集挙動とCu(II)の濃縮定量法を示した(多賀)。 (3)シュウ酸カルシウムの不足当量沈殿による超微量ランタノイドの選択的共沈分離法を開発した(鈴木)。 (4)高分子イオン浮選法によりイオン交換樹脂を浮選するイオン種の分離濃縮法を開拓した(康)。 5.高感度・高選択的計測のためのオンライン分離濃縮法の開発 (1)ケイ酸のシラン/オゾン化学発光法(藤原); オキシン担持カラム/ICP発光法、逆ミセルールミノ-リ系化学発光法、電気透析/イオン交換膜中和ーICなど(熊丸)を開拓した。

Research Products
(24 results)

All Other

All Publications (24 results)

[Publications] Yayoi Miyata: "Determination of Manganese by flow indection analysis based on its catalytic effect on the oxidative coupling reaction of 3ーmethylー2ーbenzothiazoline hydrazone with N,Nーdimethylaniline" Anal.Sci.7. 97-101 (1991)
[Publications] Tsutomu Katsura: "Enhancement effect of palladium and albumin on the sensitivities of group IIIBーVIB elements in graphite furnace atomic absorption spectrometry" Anal.Sci.8. 97-98 (1992)
[Publications] Shigekazu Tsurobou: "Liquieーliquid extraction of cinchona alkaloids by using some metal complexes of optically pure usnic acids" Anal.Chim.Acta. 248. 501-506 (1991)
[Publications] Kikuo Terada: "Preconcentration of trace elements by sorption" Anal.Sci.7. 187-198 (1991)
[Publications] Kazuhisa Moriyasu: "Chemical analysis of thortveitite from Oro,Mineyamaーcho,Nakaーgun,Kyoto prefecture,Japan," Bull.Chem.Soc.Jpn.64. 2908-2911 (1991)
[Publications] Yasoo Itoh: "Synergist induced potentiometric responese of liquid membranes containing chelating agents" Anal.Sci.7. 947-950 (1991)
[Publications] Shoji Motomizu: "Porous membrane permiation of halogens and its application to the determination of halide ions and residual chlorine by flow injection analysis" Anal.Chim.Acta.
[Publications] Rokuro Kuroda: "Ionーexchange chromatography of glycolatocomplexes of rare earths" Chromatographia. 32. 65 (1991)
[Publications] Mitsuhiko Taga: "Evaluation of copper(II)ーbinding of humic acids in peat using sulphopropylーsephadex Cー25 cation exchanger" Anal.Chim.Acta. 244. 281-288 (1991)
[Publications] Nobuo Suzuki: "Synergic extraction of lanthanoid(III) with 2ーthenoyltrifluoroacetone and triphenylarsine oxide in benzene" J.Radioanal.Nucl.Chem.149. 149-159 (1991)
[Publications] Tomozo Koh: "Spectrophotometric determination of sulfide at the 10^<ー6>mol 1^<ー1> level by Solvent extraction of Silver(I)with methylene blue" Anal.Sci.
[Publications] Kitao Fujiwara: "Flame spectrophotometric determination of borate based on diborane generation" Anal.Chim.Acta. 246. 413-419 (1991)
[Publications] Yasuaki Okamoto: "Electrodialysis preーtreatment system for ion chromatography of strongly acidic samples and its application to the determination of magnesium and calcium" J.Chromatogr.539. 221-224 (1991)
[Publications] Terufumi Fujiwara: "Catalytic behavior of iron(III)ー8ーquinolinol complex in the chemiluminescence reaction of luminol with hydrogen peroxide in reverse micelles" Chem.Lett.1991. 1137-1140 (1991)
[Publications] Imdadullah: "Chemiluminescence from the reaction of chlorauric acid with luminol in reverse micelles" Anal.Chem.63. 1348-1352 (1991)
[Publications] Yasuaki Okamoto: "Detrmination of cadmium by inductively coupled plasma atomic emission spectrometry after suctionーflow onーline preconcentration on 8ーquinolinolーloaded active carbon" Anal.Sci.7. 879-882 (1991)
[Publications] Etsuro Iwamoto: "Determination of tin by electrothermal atomic absorption spectrometry with a tungstenーcoated tube" J.Anal.At.Spectrom.7. (1992)
[Publications] Takahiro Kumamaru: "Measurements of isotope ratios of antimony and lead by hybride generation inductively coupled plasma mass spectrometry" Analyst[London].
[Publications] 河嶌拓治: "ポイント分析化学演習ー基礎と計算ー" 広川書店, (1992)
[Publications] 内海喩: "基礎教育分析化学実験〈第2版〉" 東京教学社, 261 (1992)
[Publications] 赤岩英夫: "分析化学" 丸善, (1991)
[Publications] 多賀光彦: "教養の現代化学" 三共出版, 160 (1991)
[Publications] 日本化学会編: "実験化学講座(第4版)、分析" 丸善, 509 (1991)
[Publications] 日本化学会編: "標準化学用語辞典" 丸善, (1991)

1991 Fiscal Year Annual Research Report

微量分析法の高度化のための分離化学的方法に関する研究

Principal Investigator

熊丸 尚宏 広島大学, 理学部, 教授 (50033816)

Research Products

[Publications] Yayoi Miyata: "Determination of Manganese by flow indection analysis based on its catalytic effect on the oxidative coupling reaction of 3ーmethylー2ーbenzothiazoline hydrazone with N,Nーdimethylaniline" Anal.Sci.7. 97-101 (1991)

[Publications] Tsutomu Katsura: "Enhancement effect of palladium and albumin on the sensitivities of group IIIBーVIB elements in graphite furnace atomic absorption spectrometry" Anal.Sci.8. 97-98 (1992)

[Publications] Shigekazu Tsurobou: "Liquieーliquid extraction of cinchona alkaloids by using some metal complexes of optically pure usnic acids" Anal.Chim.Acta. 248. 501-506 (1991)

[Publications] Kikuo Terada: "Preconcentration of trace elements by sorption" Anal.Sci.7. 187-198 (1991)

[Publications] Kazuhisa Moriyasu: "Chemical analysis of thortveitite from Oro,Mineyamaーcho,Nakaーgun,Kyoto prefecture,Japan," Bull.Chem.Soc.Jpn.64. 2908-2911 (1991)

[Publications] Yasoo Itoh: "Synergist induced potentiometric responese of liquid membranes containing chelating agents" Anal.Sci.7. 947-950 (1991)

[Publications] Shoji Motomizu: "Porous membrane permiation of halogens and its application to the determination of halide ions and residual chlorine by flow injection analysis" Anal.Chim.Acta.

[Publications] Rokuro Kuroda: "Ionーexchange chromatography of glycolatocomplexes of rare earths" Chromatographia. 32. 65 (1991)

[Publications] Mitsuhiko Taga: "Evaluation of copper(II)ーbinding of humic acids in peat using sulphopropylーsephadex Cー25 cation exchanger" Anal.Chim.Acta. 244. 281-288 (1991)

[Publications] Nobuo Suzuki: "Synergic extraction of lanthanoid(III) with 2ーthenoyltrifluoroacetone and triphenylarsine oxide in benzene" J.Radioanal.Nucl.Chem.149. 149-159 (1991)

[Publications] Tomozo Koh: "Spectrophotometric determination of sulfide at the 10^<ー6>mol 1^<ー1> level by Solvent extraction of Silver(I)with methylene blue" Anal.Sci.

[Publications] Kitao Fujiwara: "Flame spectrophotometric determination of borate based on diborane generation" Anal.Chim.Acta. 246. 413-419 (1991)

[Publications] Yasuaki Okamoto: "Electrodialysis preーtreatment system for ion chromatography of strongly acidic samples and its application to the determination of magnesium and calcium" J.Chromatogr.539. 221-224 (1991)

[Publications] Terufumi Fujiwara: "Catalytic behavior of iron(III)ー8ーquinolinol complex in the chemiluminescence reaction of luminol with hydrogen peroxide in reverse micelles" Chem.Lett.1991. 1137-1140 (1991)

[Publications] Imdadullah: "Chemiluminescence from the reaction of chlorauric acid with luminol in reverse micelles" Anal.Chem.63. 1348-1352 (1991)

[Publications] Yasuaki Okamoto: "Detrmination of cadmium by inductively coupled plasma atomic emission spectrometry after suctionーflow onーline preconcentration on 8ーquinolinolーloaded active carbon" Anal.Sci.7. 879-882 (1991)

[Publications] Etsuro Iwamoto: "Determination of tin by electrothermal atomic absorption spectrometry with a tungstenーcoated tube" J.Anal.At.Spectrom.7. (1992)

[Publications] Takahiro Kumamaru: "Measurements of isotope ratios of antimony and lead by hybride generation inductively coupled plasma mass spectrometry" Analyst[London].

[Publications] 河嶌 拓治: "ポイント分析化学演習ー基礎と計算ー" 広川書店, (1992)

[Publications] 内海 喩: "基礎教育 分析化学実験〈第2版〉" 東京教学社, 261 (1992)

[Publications] 赤岩 英夫: "分析化学" 丸善, (1991)

[Publications] 多賀 光彦: "教養の現代化学" 三共出版, 160 (1991)

[Publications] 日本化学会編: "実験化学講座(第4版)、分析" 丸善, 509 (1991)

[Publications] 日本化学会編: "標準化学用語辞典" 丸善, (1991)

熊丸尚宏広島大学, 理学部, 教授 (50033816)

[Publications] 河嶌拓治: "ポイント分析化学演習ー基礎と計算ー" 広川書店, (1992)

[Publications] 内海喩: "基礎教育分析化学実験〈第2版〉" 東京教学社, 261 (1992)

[Publications] 赤岩英夫: "分析化学" 丸善, (1991)

[Publications] 多賀光彦: "教養の現代化学" 三共出版, 160 (1991)