1992 Fiscal Year Annual Research Report

多核錯体,低次元錯体など集合構造をもつ新しい錯体の合成,および集合の化学的効果

Research Project

Project/Area Number	02303006
Research Institution	TOHOKU UNIVERSITY
Principal Investigator	伊藤翼東北大学, 理学部, 教授 (90007328)
Co-Investigator(Kenkyū-buntansha)	藤田純之佑名古屋大学, 理学部, 教授 (80004266) 中村晃大阪大学, 理学部, 教授 (80029404) 齋藤太郎東京大学, 理学部, 教授 (90011006) 海崎純男大阪大学, 理学部, 教授 (20089874) 大滝仁志岡崎国立共同研究機構, 分子科学研究所, 教授 (80022549)
Keywords	多核金属錯体 / 金属クラスター錯体 / 低次錯体 / 錯体集合体
Research Abstract	1.本年度は,3年間にわたって研究活動を進めてきた当総合研究(A)班の研究最終年度あたる。3年間の研究成果の報告会を,公開シンポジウムの形で平成4年11月12-13日の二日間,岡崎国立共同研究機構・分子科学研究所において開催した。全国から50名の参加者があり,19名の班員全員が研究成果について講演を行い活発な討論がなされた。講演要旨集を500部作成し参会者に配布したほか、関係する全国の研究者に配布した。 2.研究成果の具体的内容については,冊子体の研究成果報告書に詳しく述べたのでここでは省略するが、多核錯体の化学に加え錯体集合体の化学について著しい研究の進展がみられた。また,分子研大瀧班員から,ポルフィリン錯体の溶液内反応における反応中間体をstopped-flowEXAFS法により直接検出できたというきわめて興味深い最新の研究結果が上記の公開シンポジウムで報告された。 3.班会議においてこの研究分野の基礎化学における重要性が議論され,″重点領域研究″への申請や国際会議の開催などについて意見交換が行なわれた。

Research Products

(39 results)

All Other

All Publications (39 results)

[Publications] H.Sato,Yamagishi,and S.Kato: "Monte Carlo Simulations for rhe Interactions of Metal Complexes with the silicate sheets of a clay:Compareson of binding states between tris(1,10-phenanthroline)metal(II)and tres(2,2'-bipyridyl)metal(II)chelates" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)
[Publications] H.Sato,A.Yamagishi,and S.Kato: "Theorerical studies on racemic adsorption of tris(1,10-phenanthroline)metal(II)by a clay:Monte Carlo simulations" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)
[Publications] H.Sato,A.Yamagishi,ahd S.Kato: "Theoretical studies on racemic adsorption of tres(1,10-phenanthrolin)metal(II)by a clay:Monte Carlo simulations" J.Phys.Chem.,. 96. 9382-9387 (1992)
[Publications] M.Nakahanaka,T.Fuhihara, and,S.Kaizaki: "Sythesis and Z-Ray Structure of Novel Phenoxo Bridged Binuclear Complexes:Bis(μ-phenoxo)bis[bis(acetylacetonato)chromium(III)]Complex and Para-Substituted Phenoxo Analogues" Inorg.Chem.,. 31. 1315-1316 (1992)
[Publications] M.Nakafanada,T.Fujihara,N.Koine,andS.Kaizaki: "Synthesis and Characterization of L-tartrato Chromate(III)Complexes with Acetylactonate Ions" J.Chem.Soc.,Dalton Trans.,. 3423-3426 (1992)
[Publications] H.Ohtaki and Fukushima: "A Structural Study of Sarutared AQueors Solution of Some Alkail Halides by X-Ray Diffraction" J.Solution Chem.,. 21. 23-38 (1992)
[Publications] K.Ozutsumi,T.Takamuku,S.Ishiguro,and H.Ohtaki: "EXAFS and X-Ray Diffraction Studies on the Structure of the Tetrathiocyanatocadmate(II)Complex Ion Dimethyl Sulfoxide" Bull.Chem.Soc.Jpn.,. 65. 2104-2113 (1992)
[Publications] A.Miyamoto,H.Kobayashi,R.Kato,A.Kobayashi Y.Nishio,K Kajita,and W.Sesaki: "Metal Instability of(DMe-DCNQI)2Cu Induced by Uniaxial Stress and Enhancement of Electron Mass" Chem.Lett.,. 115-118 (1992)
[Publications] H.Tajima,S.Ikeda,A.Kobayashi,H.Kuroda,R.Kato and H.Kobayashi.: "Magnetoresistance of α-Et_2Me_2[Ni(dmit)_2]_2 Salt" Said State Commun.,. 82. 157-160 (1992)
[Publications] G.Saito,T.Komatsu,T.Nakamura,and H.Yamochi: "Design of Organic Superconductors Basec on BEDT-TTF" Mat.Res.Soc.,. 247. 483-494 (1992)
[Publications] G.Saito: "Organic Srperconductors Based on Sulfur and SElenium Compounds" Phosphrus,Sulfur,and Silecon.,. 67. 345-360 (1992)
[Publications] H.Kobayashi,N.Uryu,A.Tokiwa,T.Yamaguchi,Y.Sasaki,and T.Ito: "Magnctec Properties of Oxygen Centered Trinucear Ru(III)and Ph(III)" Bull.Chem.Soc.Jpn.,. 65. 198-202 (1992)
[Publications] D.Akashi,H.Kido,Y.Sasaki and T.Ito: "Preparation and Electrochemical Response of Poly(4-vinyl-pyrdine)-CoordinatedOxo-Acetato Triruthenium Cluster Film." Chem.Lett.,. 143-146 (1992)
[Publications] H.Takei,M.Koike,K.Imai,H.Sawa,and Y.Iye: "Growth and Properties of Li-deficient Lithium vanadium oxide singli ctystals" Materials Res.Bull.,. 27. 555-562 (1992)
[Publications] K.Imai,M.Koiki,H.sawa,and H.Takei: "Structural change in rhombohedral single ctystals Li_<1-x>VO_2(x=0.2)" J.Solid State Chem.,.
[Publications] M.Suzuku,Y.Hayashi,K.Munezawa,M.Suinaga,H.Senda,and A.Uehara: "Synthesid and Characterization of a Novel Dimer ofDi(μ-oxo)manganese Dimers with Two Coordinated Water Molecules in(III,IV,III,IV)Oxidation State" Chem.Lett.,. 1229-1932 (1991)
[Publications] Y.Hayashi,M.Suzuki,and A.Uehara: "(μ-Aikoxo)-diiron(II,II)Complexes of N,N,N,N'N'-Tetra-Kis(2-6-nethylpyridyl)nethyl)-1,3-diaminopropane-2-olate and Reversible Formation of the O_2-adduct" Chem.Lett.,. 91-94 (1992)
[Publications] K.Umakishi,A.Ichmura,I.Kinoshita,and S.Ooi: "The Dinuclear Palladium(II)Complex of Pyridine-2-thiol.synthesis,Structure and Electrochemistry" Inorg.Chem.,. 29. 4005-4010 (1990)
[Publications] T.Nishioka,I.Kinoshita,K.Kitano,and S.Ooi: "Synthesis of Lantern-type Dinucclear Mixed Metal Complex of Platinum(II)and Mickel(II)" Chem.Lett.,. 883-886 (1992)
[Publications] T.Shimada,M.Kodera,H.Okowa,and S.Kida: "Synthesis of 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-pctaaza-cyclohexatriacontane(L)and its Complex[Cu_4L(OH)_4](CIO_4)_4" J.Chem.Soc.DaltonTrans.,. 1121-1125 (1992)
[Publications] M.Tadakoro,H.Sakiyama,N.Matsumoto,M.kodera,H.Okawa,and S.Kida: "Tenplate Synthesis of Copper(II)-Lead(II)Complexes of New Binuceating Macrocycoes with Dissimilea Coordination Sites" J.Chem.Soc.Dalton Trans.,. 313-317 (1992)
[Publications] T.Kawamoto and Y.Kushi: "Ctystal and Moleculea structure of Tetra-palladium Cluster with a C,N,S-Tredentate Ligand" Chem.Lett.,. 1057-1059 (1992)
[Publications] T.Kawamoto and Y.Kushi: "Helical Bis[2-(ferrocanylethleneamino)benzenethiolato]Metal(II)Complexes(M=Ni,Zn or Pd)and a Related Mercury(II)Complex" J.Chem.Soc.Dalton Trans.,. 3137-3143 (1992)
[Publications] N.Sato and Y.Fukuda: "Anion Sensing Electrodes Based on Nicke(II)Mixed Ligand Complexes" Chem.Lett.,. 399-402 (1992)
[Publications] K.Yamada,K.Hore,and Y.Fukuda: "The Structure of(μ-Carbonato)bis[(acetylacetonato)(N,N,N'N'-Tetra-methylethylenedianine)nckel(II)][aqua(methanol)(acethlacetonato)(N,N,N',N'-tetramethylethylethylenediamine(mickel(II)]tetraphaphentlborate" Acta Cryst.,. (1993)
[Publications] K.Tsuge,S.Yajima,H.Imoto,T.Saito: "Synthesis of an Equilateral Trinagular Moltbdenum Cluster Complex[Mo_3(μ_3-S)_2(μ-S)_3(PMe_3)_6]with Elght Cluster Valence Electrons" J.Am.Chem.Soc.,. 114. 7910-7912 (1992)
[Publications] K.Tsuge.H.Imoto,T.Saito: "Synthesis of[Mo_4S_6(SH)_2(PME_3)_6]and [Mo_6S_<10>(SH)_2(PEt_3)_6]_6]Consisting of Fused Mo_3(μ_3-S)Cluster Units" Inorg.Chem.,. 23. 4715-4716 (1992)
[Publications] T.Yamaguchi,N.Nishimura,and T.Ito: "Triangular Platinum(II)ClusterComplexes[Pt_3(CH_3COO)_4(cdoh)_2(cdoh_2)]and [Pt_3(CH_3COO)_4(dmgh)_2(dmgH)_2(dmgH_2)](cdoH_2=cycohexanedionedioXime and dmgH_2=dimethyglyoXime)" J.Am.Chem.Soc.,. 115. (1993)
[Publications] Y.Sasaki,Y.Yoshida,A.Ohto,A.Tokiwa,T.Ito,H,Kobayashi,N.Uryu,andI.Mogi: "Mixed Chromium(III)-Ruthenuum(3)Trinuclear CompleX,[CrRu_2(μ_3-O)(μ-CH_3COO)_6(pyridine)_3]^+" Chem.Lett.,. 69-72 (1993)
[Publications] Y.Ozawa,A.Vazquez de Migiel,and K. Isobe: "μ-Methtlene Rhodium Complexes with SH Ligand:Synthesis and Structures of[Rh_2Cp^*_2(μ-CH_2)_2(μ-SH)Bph_4 and trans[Rh_2Cp^*=η^5-C_5ME_5)" J. Organomet.Chem.,. 433. 183-188 (1992)
[Publications] H.Akashi,K. Isobe,Y.Ozawa,and A. Yagasaki.,: "β-Methally6rhodium(III)Supported on a Vanadium Oxide Cluster:Synthesis,Structure,and Reaction" J.Cluster Sci.,. 2. 291-296 (1992)
[Publications] N.Ueyama: "Synthesis,Crysral Structure and Electronic properties of a 2Fe-2S Complex with a Buiky Yhiolato Ligand" J.Chem.Soc.,. 2723-2727 (1991)
[Publications] K.Mashima: "Rational Preparation and Characterization of a Tandem Tetrametal Clusters. Crystal Structure of Tetrakis(6-di-phenyphosphino-2-pyridonato)dimolybdenum" Chem.Lett.185-188 (1992)
[Publications] K.Nakagima,K.Kojima,M.Kojima,and J.Fuiita: "Preparation and Characterization of Optically Active Schiff Base-Oxo-vanadium(IV)and-Oxovanadium(IV)Coplexes and Catalytic Properteisa These Complexes on Asymmeteic Oxidation of Sulfed into Sulfoxides with Organic Hydroperoxides" Bull.Chem.Soc.jpn.,. 63. 2620-2630 (1992)
[Publications] C.Sasaki,K.Nakajina,M.Kojima,and J.Fujita: "Preparation and Characterization of Optically Active Quadridentate Schiff Base-Titanium(IV)Complexes and the Catalytic Properties of These Complexes on Asymmeteic Oxidation of Methyly Phenyl Sulfides with Organic HydroperoXides" Bull.Chem.Soc.Jph.64. 1318-1324 (1991)
[Publications] M.Kawano,C.Hoshimo,and K.Matsumoto: "Synthesis,Properties and Crystal Structure of a Novel μ-Hydragine-Bridged Mixed-Valonice Rutenium(II,III)Complex Stabilized by Hydrazine Hydrogen Bonds,[RuCI(TMP)_2]_2(μ-CI)(μ-CI)(μ-N_2H_4)(μ-S_2)(TMP=P(OM_e)_3" Inorg.Chem.,. 31. 5158-5159 (1992)
[Publications] H.Uemura,M.Kawano,T.Watenabe,T.matsumoto,and K.matsumoto: "Synyhesis and Crystal Structure of a Binuclear Rutenium Compound Comtaining[Ru^2(μ-S^5)(μ-S^<22>CNMe^2)(s^2CNMe^2\(CO)^2(PPh^3)^2]and[Ru2(μ-S6)(μ-S2CNMe2)(siCNMe2)(CO)2(PPh3)2]:The First RutheniumCom&3unds with Bridging S5 and S6 Ligands" Inorg.Chei.,. 31. 5137-5139 (1992)
[Publications] M.Munakata,S.Kitagawa,and K.Kawada: "Synthesis,Structures Formation Constants of Copper(I)Complexes with Alkynes and 1.10-Phenanthroline." J.Chem.Soc.,Dalton.Trans.,. 2225-2230 (1992)
[Publications] S.Kitagawa,M.Munakata,and T.Tanimura: "Synthesis of the Novel Infinete-Sheet and-Chain Copper(I)Complex Polymers,{[Cu(C^44H^4N^2)_<3/2>(CH_3CN)](PF_6)・0.5C_3H_6O}_∞and{[Cu(C_8H_<12>N_2)_3](ClO_4)_2}∞and Their X-ray Crystal Structures" Inorg.Chem.,. 31. 1714-1717 (1992)

1992 Fiscal Year Annual Research Report

多核錯体,低次元錯体など集合構造をもつ新しい錯体の合成,および集合の化学的効果

Principal Investigator

伊藤 翼 東北大学, 理学部, 教授 (90007328)

Research Products

[Publications] H.Sato,Yamagishi,and S.Kato: "Monte Carlo Simulations for rhe Interactions of Metal Complexes with the silicate sheets of a clay:Compareson of binding states between tris(1,10-phenanthroline)metal(II)and tres(2,2'-bipyridyl)metal(II)chelates" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)

[Publications] H.Sato,A.Yamagishi,and S.Kato: "Theorerical studies on racemic adsorption of tris(1,10-phenanthroline)metal(II)by a clay:Monte Carlo simulations" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)

[Publications] H.Sato,A.Yamagishi,ahd S.Kato: "Theoretical studies on racemic adsorption of tres(1,10-phenanthrolin)metal(II)by a clay:Monte Carlo simulations" J.Phys.Chem.,. 96. 9382-9387 (1992)

[Publications] M.Nakahanaka,T.Fuhihara, and,S.Kaizaki: "Sythesis and Z-Ray Structure of Novel Phenoxo Bridged Binuclear Complexes:Bis(μ-phenoxo)bis[bis(acetylacetonato)chromium(III)]Complex and Para-Substituted Phenoxo Analogues" Inorg.Chem.,. 31. 1315-1316 (1992)

[Publications] M.Nakafanada,T.Fujihara,N.Koine,andS.Kaizaki: "Synthesis and Characterization of L-tartrato Chromate(III)Complexes with Acetylactonate Ions" J.Chem.Soc.,Dalton Trans.,. 3423-3426 (1992)

[Publications] H.Ohtaki and Fukushima: "A Structural Study of Sarutared AQueors Solution of Some Alkail Halides by X-Ray Diffraction" J.Solution Chem.,. 21. 23-38 (1992)

[Publications] K.Ozutsumi,T.Takamuku,S.Ishiguro,and H.Ohtaki: "EXAFS and X-Ray Diffraction Studies on the Structure of the Tetrathiocyanatocadmate(II)Complex Ion Dimethyl Sulfoxide" Bull.Chem.Soc.Jpn.,. 65. 2104-2113 (1992)

[Publications] A.Miyamoto,H.Kobayashi,R.Kato,A.Kobayashi Y.Nishio,K Kajita,and W.Sesaki: "Metal Instability of(DMe-DCNQI)2Cu Induced by Uniaxial Stress and Enhancement of Electron Mass" Chem.Lett.,. 115-118 (1992)

[Publications] H.Tajima,S.Ikeda,A.Kobayashi,H.Kuroda,R.Kato and H.Kobayashi.: "Magnetoresistance of α-Et_2Me_2[Ni(dmit)_2]_2 Salt" Said State Commun.,. 82. 157-160 (1992)

[Publications] G.Saito,T.Komatsu,T.Nakamura,and H.Yamochi: "Design of Organic Superconductors Basec on BEDT-TTF" Mat.Res.Soc.,. 247. 483-494 (1992)

[Publications] G.Saito: "Organic Srperconductors Based on Sulfur and SElenium Compounds" Phosphrus,Sulfur,and Silecon.,. 67. 345-360 (1992)

[Publications] H.Kobayashi,N.Uryu,A.Tokiwa,T.Yamaguchi,Y.Sasaki,and T.Ito: "Magnctec Properties of Oxygen Centered Trinucear Ru(III)and Ph(III)" Bull.Chem.Soc.Jpn.,. 65. 198-202 (1992)

[Publications] D.Akashi,H.Kido,Y.Sasaki and T.Ito: "Preparation and Electrochemical Response of Poly(4-vinyl-pyrdine)-CoordinatedOxo-Acetato Triruthenium Cluster Film." Chem.Lett.,. 143-146 (1992)

[Publications] H.Takei,M.Koike,K.Imai,H.Sawa,and Y.Iye: "Growth and Properties of Li-deficient Lithium vanadium oxide singli ctystals" Materials Res.Bull.,. 27. 555-562 (1992)

[Publications] K.Imai,M.Koiki,H.sawa,and H.Takei: "Structural change in rhombohedral single ctystals Li_<1-x>VO_2(x=0.2)" J.Solid State Chem.,.

[Publications] M.Suzuku,Y.Hayashi,K.Munezawa,M.Suinaga,H.Senda,and A.Uehara: "Synthesid and Characterization of a Novel Dimer ofDi(μ-oxo)manganese Dimers with Two Coordinated Water Molecules in(III,IV,III,IV)Oxidation State" Chem.Lett.,. 1229-1932 (1991)

[Publications] Y.Hayashi,M.Suzuki,and A.Uehara: "(μ-Aikoxo)-diiron(II,II)Complexes of N,N,N,N'N'-Tetra-Kis(2-6-nethylpyridyl)nethyl)-1,3-diaminopropane-2-olate and Reversible Formation of the O_2-adduct" Chem.Lett.,. 91-94 (1992)

[Publications] K.Umakishi,A.Ichmura,I.Kinoshita,and S.Ooi: "The Dinuclear Palladium(II)Complex of Pyridine-2-thiol.synthesis,Structure and Electrochemistry" Inorg.Chem.,. 29. 4005-4010 (1990)

[Publications] T.Nishioka,I.Kinoshita,K.Kitano,and S.Ooi: "Synthesis of Lantern-type Dinucclear Mixed Metal Complex of Platinum(II)and Mickel(II)" Chem.Lett.,. 883-886 (1992)

[Publications] T.Shimada,M.Kodera,H.Okowa,and S.Kida: "Synthesis of 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-pctaaza-cyclohexatriacontane(L)and its Complex[Cu_4L(OH)_4](CIO_4)_4" J.Chem.Soc.DaltonTrans.,. 1121-1125 (1992)

[Publications] M.Tadakoro,H.Sakiyama,N.Matsumoto,M.kodera,H.Okawa,and S.Kida: "Tenplate Synthesis of Copper(II)-Lead(II)Complexes of New Binuceating Macrocycoes with Dissimilea Coordination Sites" J.Chem.Soc.Dalton Trans.,. 313-317 (1992)

[Publications] T.Kawamoto and Y.Kushi: "Ctystal and Moleculea structure of Tetra-palladium Cluster with a C,N,S-Tredentate Ligand" Chem.Lett.,. 1057-1059 (1992)

[Publications] T.Kawamoto and Y.Kushi: "Helical Bis[2-(ferrocanylethleneamino)benzenethiolato]Metal(II)Complexes(M=Ni,Zn or Pd)and a Related Mercury(II)Complex" J.Chem.Soc.Dalton Trans.,. 3137-3143 (1992)

[Publications] N.Sato and Y.Fukuda: "Anion Sensing Electrodes Based on Nicke(II)Mixed Ligand Complexes" Chem.Lett.,. 399-402 (1992)

[Publications] K.Yamada,K.Hore,and Y.Fukuda: "The Structure of(μ-Carbonato)bis[(acetylacetonato)(N,N,N'N'-Tetra-methylethylenedianine)nckel(II)][aqua(methanol)(acethlacetonato)(N,N,N',N'-tetramethylethylethylenediamine(mickel(II)]tetraphaphentlborate" Acta Cryst.,. (1993)

[Publications] K.Tsuge,S.Yajima,H.Imoto,T.Saito: "Synthesis of an Equilateral Trinagular Moltbdenum Cluster Complex[Mo_3(μ_3-S)_2(μ-S)_3(PMe_3)_6]with Elght Cluster Valence Electrons" J.Am.Chem.Soc.,. 114. 7910-7912 (1992)

[Publications] K.Tsuge.H.Imoto,T.Saito: "Synthesis of[Mo_4S_6(SH)_2(PME_3)_6]and [Mo_6S_<10>(SH)_2(PEt_3)_6]_6]Consisting of Fused Mo_3(μ_3-S)Cluster Units" Inorg.Chem.,. 23. 4715-4716 (1992)

[Publications] T.Yamaguchi,N.Nishimura,and T.Ito: "Triangular Platinum(II)ClusterComplexes[Pt_3(CH_3COO)_4(cdoh)_2(cdoh_2)]and [Pt_3(CH_3COO)_4(dmgh)_2(dmgH)_2(dmgH_2)](cdoH_2=cycohexanedionedioXime and dmgH_2=dimethyglyoXime)" J.Am.Chem.Soc.,. 115. (1993)

[Publications] Y.Sasaki,Y.Yoshida,A.Ohto,A.Tokiwa,T.Ito,H,Kobayashi,N.Uryu,andI.Mogi: "Mixed Chromium(III)-Ruthenuum(3)Trinuclear CompleX,[CrRu_2(μ_3-O)(μ-CH_3COO)_6(pyridine)_3]^+" Chem.Lett.,. 69-72 (1993)

[Publications] Y.Ozawa,A.Vazquez de Migiel,and K. Isobe: "μ-Methtlene Rhodium Complexes with SH Ligand:Synthesis and Structures of[Rh_2Cp^*_2(μ-CH_2)_2(μ-SH)Bph_4 and trans[Rh_2Cp^*=η^5-C_5ME_5)" J. Organomet.Chem.,. 433. 183-188 (1992)

[Publications] H.Akashi,K. Isobe,Y.Ozawa,and A. Yagasaki.,: "β-Methally6rhodium(III)Supported on a Vanadium Oxide Cluster:Synthesis,Structure,and Reaction" J.Cluster Sci.,. 2. 291-296 (1992)

[Publications] N.Ueyama: "Synthesis,Crysral Structure and Electronic properties of a 2Fe-2S Complex with a Buiky Yhiolato Ligand" J.Chem.Soc.,. 2723-2727 (1991)

[Publications] K.Mashima: "Rational Preparation and Characterization of a Tandem Tetrametal Clusters. Crystal Structure of Tetrakis(6-di-phenyphosphino-2-pyridonato)dimolybdenum" Chem.Lett.185-188 (1992)

[Publications] M.Munakata,S.Kitagawa,and K.Kawada: "Synthesis,Structures Formation Constants of Copper(I)Complexes with Alkynes and 1.10-Phenanthroline." J.Chem.Soc.,Dalton.Trans.,. 2225-2230 (1992)

[Publications] S.Kitagawa,M.Munakata,and T.Tanimura: "Synthesis of the Novel Infinete-Sheet and-Chain Copper(I)Complex Polymers,{[Cu(C^44H^4N^2)_<3/2>(CH_3CN)](PF_6)・0.5C_3H_6O}_∞and{[Cu(C_8H_<12>N_2)_3](ClO_4)_2}∞and Their X-ray Crystal Structures" Inorg.Chem.,. 31. 1714-1717 (1992)

伊藤翼東北大学, 理学部, 教授 (90007328)

[Publications] Y.Ozawa,A.Vazquez de Migiel,and K. Isobe: "μ-Methtlene Rhodium Complexes with SH Ligand:Synthesis and Structures of[Rh_2Cp^_2(μ-CH_2)_2(μ-SH)Bph_4 and trans[Rh_2Cp^=η^5-C_5ME_5)" J. Organomet.Chem.,. 433. 183-188 (1992)